CN106614250A - Preparation method of controlled-release self-synergism type multifunctional aquatic product disinfector - Google Patents
Preparation method of controlled-release self-synergism type multifunctional aquatic product disinfector Download PDFInfo
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- CN106614250A CN106614250A CN201611211712.3A CN201611211712A CN106614250A CN 106614250 A CN106614250 A CN 106614250A CN 201611211712 A CN201611211712 A CN 201611211712A CN 106614250 A CN106614250 A CN 106614250A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000013270 controlled release Methods 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims abstract description 9
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims abstract description 9
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims abstract description 9
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims abstract description 9
- 229940074393 chlorogenic acid Drugs 0.000 claims abstract description 9
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims abstract description 9
- 235000001368 chlorogenic acid Nutrition 0.000 claims abstract description 9
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims description 49
- 239000007788 liquid Substances 0.000 claims description 30
- 239000004695 Polyether sulfone Substances 0.000 claims description 24
- 229920006393 polyether sulfone Polymers 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 238000007654 immersion Methods 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 208000037656 Respiratory Sounds Diseases 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000013461 design Methods 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 10
- 230000002459 sustained effect Effects 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- 238000013268 sustained release Methods 0.000 claims description 8
- 239000012730 sustained-release form Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 7
- 238000003763 carbonization Methods 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 208000014903 transposition of the great arteries Diseases 0.000 claims description 7
- 238000007605 air drying Methods 0.000 claims description 6
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 230000010355 oscillation Effects 0.000 claims description 6
- 238000002411 thermogravimetry Methods 0.000 claims description 6
- 238000012032 thrombin generation assay Methods 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 39
- 230000001954 sterilising effect Effects 0.000 abstract description 27
- 230000000694 effects Effects 0.000 abstract description 22
- 239000000645 desinfectant Substances 0.000 abstract description 15
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 14
- 230000002147 killing effect Effects 0.000 abstract description 10
- 241000894006 Bacteria Species 0.000 abstract description 9
- 239000012528 membrane Substances 0.000 abstract description 6
- 238000001223 reverse osmosis Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 4
- 235000015097 nutrients Nutrition 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 244000052616 bacterial pathogen Species 0.000 abstract 2
- 230000002045 lasting effect Effects 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 8
- 238000000354 decomposition reaction Methods 0.000 description 8
- 239000008103 glucose Substances 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 238000002791 soaking Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 241000195493 Cryptophyta Species 0.000 description 4
- 241000700605 Viruses Species 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 230000000249 desinfective effect Effects 0.000 description 4
- 238000005538 encapsulation Methods 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 238000009360 aquaculture Methods 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 230000003111 delayed effect Effects 0.000 description 3
- 230000000994 depressogenic effect Effects 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 231100000167 toxic agent Toxicity 0.000 description 3
- 239000003440 toxic substance Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 244000000010 microbial pathogen Species 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 208000031295 Animal disease Diseases 0.000 description 1
- 240000009087 Crescentia cujete Species 0.000 description 1
- 235000005983 Crescentia cujete Nutrition 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 235000009797 Lagenaria vulgaris Nutrition 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000002651 drug therapy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 229940126701 oral medication Drugs 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000033458 reproduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a preparation method of a controlled-release self-synergism type multifunctional aquatic product disinfector, belonging to the technical field of preparing aquatic disinfection materials. The preparation method of the controlled-release self-synergism type multifunctional aquatic product disinfector comprises the following steps: adsorbing heavy metals in a water body, slowly increasing sterilization performance, slowly corroding and hydrolyzing a reverse osmosis membrane to release nutrients therein, attracting bacteria germs in the water body, sterilizing through chlorogenic acid released by the reverse osmosis membrane, and further killing the bacteria germs through a heavy metal-enriched disinfector, so that the problems that the existing aquatic product disinfectant is usually a disposable product, is short in effect lasting time, easy to decompose and loose effect, destructs the ecological balance of water in a cultivating pond and also causes damage to a human body and environment can be solved, the prepared disinfector has better disinfection effect and water body heavy metal adsorption effect, can be recycled, thus being green and environment-friendly, long in effect lasting time and free from harm after use, and having wide application prospects.
Description
Technical field
The invention discloses a kind of preparation method for being sustained the multi-functional aquatic products sterilizer of autosynergism type, belongs to aquatic products sterilization material
Material preparing technical field.
Background technology
With becoming increasingly popular and fast development for China's intensive aquaculture, Cultivated water receives serious pollution,
Various pathogenic microorganism amount reproductions, result in aquatic animal disease and frequently occur, the development of serious obstruction culture fishery.
While using oral drug therapy, people's disinfectant also in common use, to kill aquatic environment in harmful microorganism, improve
Aquatic animal environment from bottom to top.It was verified that fishery disinfectant not only Disinfection Effect is good and easy to use, price is relative
It is cheap.
Disinfectant is mainly used in eliminating or killing the pathogenic microorganism and other harmful microorganisms in external environment.By chemically
Matter can be divided into aldehyde disinfectant, bases disinfectant, acids disinfectant, salt disinfectant, halogen disinfectant, dye class sterilization
8 big class such as agent, oxidants disinfectant, heavy metal classes disinfectant.China's aquiculture animal is various in style, inhomogeneity sterilization
Agent is larger to the Difference In Toxicity of aquatic livestock, and it is dead that inappropriate medication easily causes fish and shrimp poisoning.Meanwhile, existing these aquatic products
Disinfectant is mostly disposable, has spilt in the rear short time effectively, just fails after decomposition, while the ecology that can destroy culturing pool is put down
Weighing apparatus, to aquatic products side effect is caused, and during having injured aquatic products, noxious material can be also deposited in aquatic products body, to human health
Produce stealthy harm.Therefore, good aquatic products sterile products of seeking a kind of environmental protection, holding effect length, Disinfection Effect become aquatic products and support
Grow the problem of industry urgent need to resolve.
The content of the invention
Present invention mainly solves technical problem：Disposable products, efficiency time mostly are for existing fishery disinfectant
It is short, easy decomposition failure, while the ecological balance of culturing pool can be destroyed, the defect that can be also worked the mischief to human body and environment is carried
For one kind using cucurbit as matrix, wherein impurity is removed by oxidation processes, subsequently carbonization increases absorption property, reuses xanthan
Sour sodium, TGA etc. are modified to the cucurbit that is carbonized, and increase the adsorption capacity of heavy metal, and be subsequently carbonized after modification cucurbit
One layer of self-control reverse osmosis membrane of interior load, while being modified to reverse osmosis membrane, loads chlorogenic acid, increases bactericidal property, so as to make
The method of the multi-functional aquatic products sterilizer of autosynergism type must be sustained, the present invention prepares the multi-functional aquatic products sterilizer of sustained release autosynergism type and leads to
The absorption of the middle heavy metal to water body is crossed, bactericidal property is slowly increased, is slowly corroded hydrolysis by reverse osmosis membrane, discharge it
Internal nutrients, attracts the bacterial micro-organism in water body, then the chlorogenic acid discharged by reverse osmosis membrane to carry out sterilization, while sharp
Bacterial micro-organism is further killed with the sterilizer of enriching heavy metal is removed, mostly be so as to efficiently solve existing fishery disinfectant
Disposable products, efficiency time is short, easy decomposition failure, while the ecological balance of culturing pool can be destroyed, can also be to human body and ring
The problem that border works the mischief, the obtained sterilizer of the present invention has the work of preferable sterilization effect and adsorbed water body heavy metal
With, after use will not decomposition failure, still recoverable, and sterilizer environmental protection, efficiency time is long, will not be to water after use
Produce, environment and human body work the mischief, have broad application prospects.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）Cucurbit seed of the cucurbit inside its open top, removal is taken, the cucurbit after remove seed is put in 60 DEG C of baking ovens and is dried 7
～8h, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setpoint frequency is
1.5～1.8MHz, shakes 20～25min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process cucurbit；
（2）It is pressurized into above-mentioned pretreatment cucurbit using nitrogen, when cucurbit surface to be pre-treated has crackle to occur, is kept pressure
5～8min of power, is subsequently depressurized to standard atmospheric pressure, and the pretreatment cucurbit with crackle is put in carbide furnace, and design temperature is
300～350 DEG C, be carbonized 2～3h, collects carbonization cucurbit, obtains sterilizer matrix；
（3）Count by weight, take 70～80 parts of distilled water, 25～30 parts of sodium xanthogenates, 16～19 parts of TGAs and 7～9
Part citric acid, stirs, and obtains immersion liquid, and above-mentioned sterilizer matrix is soaked in immersion liquid, controls dip temperature for 40～45 DEG C,
3～5h of immersion, subsequently takes out sterilizer matrix, is put in drying box and is dried overnight, and collects dried sterilizer matrix, standby
With；
（4）In mass ratio 1:4, take polyether sulfone and METHYLPYRROLIDONE is put into three mouthfuls of burnings with agitator and thermometer
In bottle, and there-necked flask is placed in water-bath, design temperature is 60～65 DEG C, 2～4h is stirred with 160r/min, then respectively to
Polyethylene glycol, the chlorogenic acid of polyether sulfone quality 5～8% and the polyether sulfone quality 3 of polyether sulfone quality 7～9% are added in there-necked flask
～6% pyromellitic trimethylsilyl chloride, is warming up to 70～75 DEG C, continues to stir 4～5h, the mixture in collection vessel；
（5）In mass ratio 2:1, the mixture in said vesse pours step into（3）In standby dried sterilizer matrix, and
Dried sterilizer matrix is put in liquid machine for shaking, 30～50min is rocked, subsequently by dried sterilizer matrix
Liquid pour out, will pour out the sterilizer matrix after liquid be put in 60 DEG C of baking ovens be dried 3～5h, many work(of autosynergism type must be sustained
Can aquatic products sterilizer.
The present invention application process be：To be sustained certainly obtained in the present invention with the glucose solution that mass fraction is 5% first
The multi-functional aquatic products sterilizer of Synergistic type is filled, and to carrying out encapsulation process at sterilizer opening, and the sterilizer after sealing is used
Rope is fixed, and is subsequently thrown in aquatic product sprout and is raised first 10～15 days, and sterilizer is rendered in water body to be carried out at soaking disinfection
Reason, input number is 4/m2, after soaking 9～12 days, sterilizer is taken out, then routinely seed is thrown in feeding by cultural method
Support, putting after seedling every 30～50 days, in the same way, sterilizer glucose solution is filled up after sealing and renders to water body
In, a routine disinfection is carried out to water body, disinfecting time is 2～4 days, treats that every time sterilization is completed, and sterilizer is taken out.Jing
Detection, the multi-functional aquatic products disinfector of the obtained sustained release autosynergism type of the present invention has preferable sterilization effect, in water body
Virus, bacterium, fungi, algae there is extremely strong killing action, wherein, to colibacillary sterilizing rate up to 97.2～99.6%,
To the sterilizing rate of thermophilic water monad up to more than 95.3%, to the killing rate of water mo(u)ld up to more than 90%, while disappearing obtained in the present invention
Malicious utensil plays the role of heavy metal in preferable adsorbed water body, and Heavy Metals in Waters content can be made to reduce 15～35%, can reach and change
The effect of kind water ecological setting, and sterilizer of the present invention is easy to use, efficiency time is long, and action time and disinfection efficiency are relatively passed
System disinfectant improves 2～3 times, it is to avoid the defect of the easy decomposition failure of traditional disinfection agent, using rear recoverable, will not be right
Environment and human body work the mischief.
The invention has the beneficial effects as follows：
（1）The multi-functional aquatic products sterilizer of sustained release autosynergism type can be done directly on the compact district of aquatic livestock obtained in of the invention,
Dipping bath can sterilize while Aquatic farming animals, effectively increase disinfection efficiency, and reduce aquaculture cost；
（2）The multi-functional aquatic products sterilizer of sustained release autosynergism type can effectively adsorb the heavy metal in Cultivated water obtained in of the invention,
Efficiency time is long, using rear recoverable, and any toxic and side effect will not be produced to aquatic products, environment and human body, with preferable
Prospect of the application.
Specific embodiment
Cucurbit seed of the cucurbit inside its open top, removal is taken first, and the cucurbit after remove seed is put in 60 DEG C of baking ovens
7～8h is dried, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setting is frequently
Rate is 1.5～1.8MHz, shakes 20～25min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process calabash
Reed；Subsequently it is pressurized into above-mentioned pretreatment cucurbit using nitrogen, when cucurbit surface to be pre-treated has crackle to occur, is kept pressure
5～8min of power, is subsequently depressurized to standard atmospheric pressure, and the pretreatment cucurbit with crackle is put in carbide furnace, and design temperature is
300～350 DEG C, be carbonized 2～3h, collects carbonization cucurbit, obtains sterilizer matrix；Count by weight again, take 70～80 parts of distillations
Water, 25～30 parts of sodium xanthogenates, 16～19 parts of TGAs and 7～9 parts of citric acids, stir, and immersion liquid are obtained, by above-mentioned sterilization
Device matrix is soaked in immersion liquid, controls dip temperature for 40～45 DEG C, soaks 3～5h, subsequently takes out sterilizer matrix, is put into
It is dried overnight in drying box, collects dried sterilizer matrix, it is standby；Again in mass ratio 1:4, take polyether sulfone and N- methyl-
2-Pyrrolidone is put in the there-necked flask with agitator and thermometer, and there-necked flask is placed in water-bath, setting temperature
Spend for 60～65 DEG C, 2～4h, then the poly- second for adding polyether sulfone quality 7～9% in there-necked flask respectively are stirred with 160r/min
The pyromellitic trimethylsilyl chloride of glycol, the chlorogenic acid of polyether sulfone quality 5～8% and polyether sulfone quality 3～6%, is warming up to 70～75 DEG C, after
4～5h of continuous stirring, the mixture in collection vessel；Last in mass ratio 2:1, the mixture in said vesse is poured into above-mentioned standby
Dried sterilizer matrix in, and dried sterilizer matrix is put in liquid machine for shaking, rock 30～50min,
Subsequently the liquid in dried sterilizer matrix is poured out, will pour out the sterilizer matrix after liquid be put in 60 DEG C of baking ovens do
Dry 3～5h, must be sustained the multi-functional aquatic products sterilizer of autosynergism type.
Example 1
Cucurbit seed of the cucurbit inside its open top, removal is taken first, the cucurbit after remove seed is put in 60 DEG C of baking ovens and is dried
7h, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setpoint frequency is
1.5MHz, shakes 20min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process cucurbit；Subsequently use nitrogen
Gas is pressurized into above-mentioned pretreatment cucurbit, when cucurbit surface to be pre-treated has crackle to occur, keeps pressure 5min, subsequently drop
Standard atmospheric pressure is depressed into, the pretreatment cucurbit with crackle is put in carbide furnace, design temperature is 300 DEG C, be carbonized 2h, collects
Carbonization cucurbit, obtains sterilizer matrix；Count by weight again, take 70 parts of distilled water, 25 parts of sodium xanthogenates, 16 parts of TGAs and
7 parts of citric acids, stir, and obtain immersion liquid, and above-mentioned sterilizer matrix is soaked in immersion liquid, control dip temperature for 40 DEG C, leaching
Bubble 3h, subsequently takes out sterilizer matrix, is put in drying box and is dried overnight, and collects dried sterilizer matrix, standby；Again
In mass ratio 1:4, take polyether sulfone and METHYLPYRROLIDONE is put in the there-necked flask with agitator and thermometer, and
There-necked flask is placed in water-bath, design temperature is 60 DEG C, 2h, then the addition in there-necked flask respectively are stirred with 160r/min
The pyromellitic trimethylsilyl chloride of the polyethylene glycol, the chlorogenic acid of polyether sulfone quality 5% and polyether sulfone quality 3% of polyether sulfone quality 7%, heats up
To 70 DEG C, continue to stir 4h, the mixture in collection vessel；Last in mass ratio 2:1, the mixture in said vesse is poured into
In stating standby dried sterilizer matrix, and dried sterilizer matrix is put in liquid machine for shaking, is rocked
30min, subsequently pours out the liquid in dried sterilizer matrix, will pour out the sterilizer matrix after liquid and is put into 60 DEG C of bakings
3h is dried in case, the multi-functional aquatic products sterilizer of autosynergism type must be sustained.
This example operation is easy, when using, will be delayed obtained in the present invention with the glucose solution that mass fraction is 5% first
Release the multi-functional aquatic products sterilizer of autosynergism type to fill, and to carrying out encapsulation process at sterilizer opening, and by the sterilization after sealing
Device is fixed with rope, is subsequently thrown in aquatic product sprout and is raised first 10 days, and sterilizer is rendered in water body to be carried out at soaking disinfection
Reason, input number is 4/m2, after soaking 5 days, sterilizer is taken out, then routinely seed is thrown in raising by cultural method,
After seedling is put every 30 days, in the same way, sterilizer glucose solution is filled up and is rendered in water body after sealing, water body is entered
Routine disinfection of row, disinfecting time is 2 days, treats that every time sterilization is completed, and sterilizer is taken out.After testing, present invention system
The multi-functional aquatic products disinfector of sustained release autosynergism type have preferable sterilization effect, to the virus in water body, bacterium, true
Bacterium, algae have extremely strong killing action, wherein, to colibacillary sterilizing rate up to 97.2%, the sterilizing rate to thermophilic water monad
Up to 95.5%, to the killing rate of water mo(u)ld up to 91%, while the obtained sterilizer of the present invention has a huge sum of money in preferable adsorbed water body
The effect of category, can make Heavy Metals in Waters content reduce 15%, and can reach improves the effect of water ecological setting, and the present invention disappears
Malicious device is easy to use, and efficiency time is long, action time and disinfection efficiency improve 2 times compared with traditional disinfection agent, it is to avoid tradition disappears
The defect of the easy decomposition failure of toxic agent, using rear recoverable, will not work the mischief to environment and human body.
Example 2
Cucurbit seed of the cucurbit inside its open top, removal is taken first, the cucurbit after remove seed is put in 60 DEG C of baking ovens and is dried
8h, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setpoint frequency is
1.6MHz, shakes 23min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process cucurbit；Subsequently use nitrogen
Gas is pressurized into above-mentioned pretreatment cucurbit, when cucurbit surface to be pre-treated has crackle to occur, keeps pressure 6min, subsequently drop
Standard atmospheric pressure is depressed into, the pretreatment cucurbit with crackle is put in carbide furnace, design temperature is 325 DEG C, be carbonized 2h, collects
Carbonization cucurbit, obtains sterilizer matrix；Count by weight again, take 75 parts of distilled water, 28 parts of sodium xanthogenates, 18 parts of TGAs and
8 parts of citric acids, stir, and obtain immersion liquid, and above-mentioned sterilizer matrix is soaked in immersion liquid, control dip temperature for 43 DEG C, leaching
Bubble 4h, subsequently takes out sterilizer matrix, is put in drying box and is dried overnight, and collects dried sterilizer matrix, standby；Again
In mass ratio 1:4, take polyether sulfone and METHYLPYRROLIDONE is put in the there-necked flask with agitator and thermometer, and
There-necked flask is placed in water-bath, design temperature is 63 DEG C, 3h, then the addition in there-necked flask respectively are stirred with 160r/min
The pyromellitic trimethylsilyl chloride of the polyethylene glycol, the chlorogenic acid of polyether sulfone quality 6% and polyether sulfone quality 5% of polyether sulfone quality 8%, heats up
To 73 DEG C, continue to stir 4h, the mixture in collection vessel；Last in mass ratio 2:1, the mixture in said vesse is poured into
In stating standby dried sterilizer matrix, and dried sterilizer matrix is put in liquid machine for shaking, is rocked
40min, subsequently pours out the liquid in dried sterilizer matrix, will pour out the sterilizer matrix after liquid and is put into 60 DEG C of bakings
4h is dried in case, the multi-functional aquatic products sterilizer of autosynergism type must be sustained.
This example operation is easy, when using, will be delayed obtained in the present invention with the glucose solution that mass fraction is 5% first
Release the multi-functional aquatic products sterilizer of autosynergism type to fill, and to carrying out encapsulation process at sterilizer opening, and by the sterilization after sealing
Device is fixed with rope, is subsequently thrown in aquatic product sprout and is raised first 13 days, and sterilizer is rendered in water body to be carried out at soaking disinfection
Reason, input number is 4/m2, after soaking 6 days, sterilizer is taken out, then routinely seed is thrown in raising by cultural method,
After seedling is put every 40 days, in the same way, sterilizer glucose solution is filled up and is rendered in water body after sealing, water body is entered
Routine disinfection of row, disinfecting time is 3 days, treats that every time sterilization is completed, and sterilizer is taken out.After testing, present invention system
The multi-functional aquatic products disinfector of sustained release autosynergism type have preferable sterilization effect, to the virus in water body, bacterium, true
Bacterium, algae have extremely strong killing action, wherein, to colibacillary sterilizing rate up to 98.4%, the sterilizing rate to thermophilic water monad
Up to 95.8%, to the killing rate of water mo(u)ld up to 92%, while the obtained sterilizer of the present invention has a huge sum of money in preferable adsorbed water body
The effect of category, can make Heavy Metals in Waters content reduce 25%, and can reach improves the effect of water ecological setting, and the present invention disappears
Malicious device is easy to use, and efficiency time is long, action time and disinfection efficiency improve 2 times compared with traditional disinfection agent, it is to avoid tradition disappears
The defect of the easy decomposition failure of toxic agent, using rear recoverable, will not work the mischief to environment and human body.
Example 3
Cucurbit seed of the cucurbit inside its open top, removal is taken first, the cucurbit after remove seed is put in 60 DEG C of baking ovens and is dried
8h, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setpoint frequency is
1.8MHz, shakes 25min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process cucurbit；Subsequently use nitrogen
Gas is pressurized into above-mentioned pretreatment cucurbit, when cucurbit surface to be pre-treated has crackle to occur, keeps pressure 8min, subsequently drop
Standard atmospheric pressure is depressed into, the pretreatment cucurbit with crackle is put in carbide furnace, design temperature is 350 DEG C, be carbonized 3h, collects
Carbonization cucurbit, obtains sterilizer matrix；Count by weight again, take 80 parts of distilled water, 30 parts of sodium xanthogenates, 19 parts of TGAs and
9 parts of citric acids, stir, and obtain immersion liquid, and above-mentioned sterilizer matrix is soaked in immersion liquid, control dip temperature for 45 DEG C, leaching
Bubble 5h, subsequently takes out sterilizer matrix, is put in drying box and is dried overnight, and collects dried sterilizer matrix, standby；Again
In mass ratio 1:4, take polyether sulfone and METHYLPYRROLIDONE is put in the there-necked flask with agitator and thermometer, and
There-necked flask is placed in water-bath, design temperature is 65 DEG C, 4h, then the addition in there-necked flask respectively are stirred with 160r/min
The pyromellitic trimethylsilyl chloride of the polyethylene glycol, the chlorogenic acid of polyether sulfone quality 8% and polyether sulfone quality 6% of polyether sulfone quality 9%, heats up
To 75 DEG C, continue to stir 5h, the mixture in collection vessel；Last in mass ratio 2:1, the mixture in said vesse is poured into
In stating standby dried sterilizer matrix, and dried sterilizer matrix is put in liquid machine for shaking, is rocked
50min, subsequently pours out the liquid in dried sterilizer matrix, will pour out the sterilizer matrix after liquid and is put into 60 DEG C of bakings
5h is dried in case, the multi-functional aquatic products sterilizer of autosynergism type must be sustained.
This example operation is easy, when using, will be delayed obtained in the present invention with the glucose solution that mass fraction is 5% first
Release the multi-functional aquatic products sterilizer of autosynergism type to fill, and to carrying out encapsulation process at sterilizer opening, and by the sterilization after sealing
Device is fixed with rope, is subsequently thrown in aquatic product sprout and is raised first 15 days, and sterilizer is rendered in water body to be carried out at soaking disinfection
Reason, input number is 4/m2, after soaking 7 days, sterilizer is taken out, then routinely seed is thrown in raising by cultural method,
After seedling is put every 50 days, in the same way, sterilizer glucose solution is filled up and is rendered in water body after sealing, water body is entered
Routine disinfection of row, disinfecting time is 4 days, treats that every time sterilization is completed, and sterilizer is taken out.After testing, present invention system
The multi-functional aquatic products disinfector of sustained release autosynergism type have preferable sterilization effect, to the virus in water body, bacterium, true
Bacterium, algae have extremely strong killing action, wherein, to colibacillary sterilizing rate up to 99.6%, the sterilizing rate to thermophilic water monad
Up to 96.1%, to the killing rate of water mo(u)ld up to 93%, while the obtained sterilizer of the present invention has a huge sum of money in preferable adsorbed water body
The effect of category, can make Heavy Metals in Waters content reduce 35%, and can reach improves the effect of water ecological setting, and the present invention disappears
Malicious device is easy to use, and efficiency time is long, action time and disinfection efficiency improve 3 times compared with traditional disinfection agent, it is to avoid tradition disappears
The defect of the easy decomposition failure of toxic agent, using rear recoverable, will not work the mischief to environment and human body.
Claims (1)
1. a kind of preparation method of the sustained release multi-functional aquatic products sterilizer of autosynergism type, it is characterised in that concrete preparation process is：
（1）Cucurbit seed of the cucurbit inside its open top, removal is taken, the cucurbit after remove seed is put in 60 DEG C of baking ovens and is dried 7
～8h, mass fraction is filled in dried cucurbit for after 15% hydrogen peroxide, in being placed in ultrasonic oscillation device, setpoint frequency is
1.5～1.8MHz, shakes 20～25min, subsequently pours out in the mixture in cucurbit, and natural air drying, must pre-process cucurbit；
（2）It is pressurized into above-mentioned pretreatment cucurbit using nitrogen, when cucurbit surface to be pre-treated has crackle to occur, is kept pressure
5～8min of power, is subsequently depressurized to standard atmospheric pressure, and the pretreatment cucurbit with crackle is put in carbide furnace, and design temperature is
300～350 DEG C, be carbonized 2～3h, collects carbonization cucurbit, obtains sterilizer matrix；
（3）Count by weight, take 70～80 parts of distilled water, 25～30 parts of sodium xanthogenates, 16～19 parts of TGAs and 7～9
Part citric acid, stirs, and obtains immersion liquid, and above-mentioned sterilizer matrix is soaked in immersion liquid, controls dip temperature for 40～45 DEG C,
3～5h of immersion, subsequently takes out sterilizer matrix, is put in drying box and is dried overnight, and collects dried sterilizer matrix, standby
With；
（4）In mass ratio 1:4, take polyether sulfone and METHYLPYRROLIDONE is put into three mouthfuls of burnings with agitator and thermometer
In bottle, and there-necked flask is placed in water-bath, design temperature is 60～65 DEG C, 2～4h is stirred with 160r/min, then respectively to
Polyethylene glycol, the chlorogenic acid of polyether sulfone quality 5～8% and the polyether sulfone quality 3 of polyether sulfone quality 7～9% are added in there-necked flask
～6% pyromellitic trimethylsilyl chloride, is warming up to 70～75 DEG C, continues to stir 4～5h, the mixture in collection vessel；
（5）In mass ratio 2:1, the mixture in said vesse pours step into（3）In standby dried sterilizer matrix, and
Dried sterilizer matrix is put in liquid machine for shaking, 30～50min is rocked, subsequently by dried sterilizer matrix
Liquid pour out, will pour out the sterilizer matrix after liquid be put in 60 DEG C of baking ovens be dried 3～5h, many work(of autosynergism type must be sustained
Can aquatic products sterilizer.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110790457A (en) * | 2019-11-17 | 2020-02-14 | 南通职业大学 | Low-toxicity treatment process for trichlorfon wastewater |
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| CN202890215U (en) * | 2012-10-08 | 2013-04-24 | 任青松 | Sterilizing aquaculture box |
| US20150216146A1 (en) * | 2012-08-14 | 2015-08-06 | Stp Co., Ltd. | Sterilization system for aquaculture |
| CN204762836U (en) * | 2015-07-13 | 2015-11-18 | 孙博文 | Special aquaculture case in supermarket |
| CN105594737A (en) * | 2015-12-09 | 2016-05-25 | 王芳 | Sterilization disinfectant liquid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1311695A (en) * | 1998-07-28 | 2001-09-05 | 美国3M公司 | Method for mfg. antimicrobial articles |
| US20150216146A1 (en) * | 2012-08-14 | 2015-08-06 | Stp Co., Ltd. | Sterilization system for aquaculture |
| CN202890215U (en) * | 2012-10-08 | 2013-04-24 | 任青松 | Sterilizing aquaculture box |
| CN204762836U (en) * | 2015-07-13 | 2015-11-18 | 孙博文 | Special aquaculture case in supermarket |
| CN105594737A (en) * | 2015-12-09 | 2016-05-25 | 王芳 | Sterilization disinfectant liquid |
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| CN110790457A (en) * | 2019-11-17 | 2020-02-14 | 南通职业大学 | Low-toxicity treatment process for trichlorfon wastewater |
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