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CN106591709A - Creep-resistant alloy steel material for stir-welding head - Google Patents

Creep-resistant alloy steel material for stir-welding head Download PDF

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Publication number
CN106591709A
CN106591709A CN201611219741.4A CN201611219741A CN106591709A CN 106591709 A CN106591709 A CN 106591709A CN 201611219741 A CN201611219741 A CN 201611219741A CN 106591709 A CN106591709 A CN 106591709A
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CN
China
Prior art keywords
creep
stirring
head
stir
steel material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611219741.4A
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Chinese (zh)
Inventor
唐远金
徐安莲
杜彦斌
陈康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Send Special Mechanical And Electrical Co Ltd
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Chongqing Send Special Mechanical And Electrical Co Ltd
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Publication date
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Priority to CN201611219741.4A priority Critical patent/CN106591709A/en
Publication of CN106591709A publication Critical patent/CN106591709A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention relates to the field of stir-welding head materials and discloses a creep-resistant alloy steel material for a stir-welding head. The creep-resistant alloy steel material for the stir-welding head comprises, by weight, 0.12-0.28% of C, 0.3-1.5% of Si, 0.2-1.5% of Mn, 10.0-15.0% of Cr, 1.0-8.0% of W, 1.0-5.0% of Mo, 0.1-1.0% of Sr, 0.2-0.8% of V, 0.005-0.02% of B, 0.01-0.25% of Nb, 0.05-0.80% of In, 0.01-1.0% of Al, 0.03% of P or less, 0.03% of S or less and the balance Fe and inevitable impurities. According to the creep-resistant alloy steel material for the stir-welding head, the stir-welding head material has a good wear-resisting property, a good high-temperature oxidation resisting property and a good creep-resistant property, and the service life of the stir-welding head is remarkably prolonged.

Description

A kind of stirring-head creep resistant alloy Steel material
Technical field
The present invention relates to stirring-head Material Field, more particularly to a kind of stirring-head creep resistant alloy Steel material
Background technology
Stirring-head is the key of agitating friction welding technology, is described as the heart of agitating friction weldering.The quality of stirring-head is not only The performance of friction stir welding is determined, and decides the production cost of agitating friction weldering.Stirring-head is by the shaft shoulder, clamping part Divide and mixing needle composition.During agitating friction weldering, mixing needle will be rotating at the combination interface of insertion materials to be welded, and Advance along weld seam under certain speed.Therefore, in agitating friction weldering, the working environment of mixing needle is more severe, to wear resistance Can, especially high-temperature wearable damages performance requirement height.
Domestic the most frequently used stirring head material is H13 steel.But the stirring-head that H13 steel makes is in long-time welding aluminum alloy During structural member, when such as welding aluminum alloy hull and tubular store part, easily there is creep and creep fatigue phenomenon in stirring-head, shortens The service life of stirring-head, affects operating efficiency, increases entreprise cost.The service life of stirring-head how is improved, birth is developed Production. art is easy, stir head material using reliable, cheap and good-quality new creep resistant, is the current technical problem be badly in need of and solving.
The Chinese invention patent of Application No. 201510991313.2 discloses a kind of high nitrogen steel of agitating friction weldering and stirs Mix head and its manufacturing process.The high nitrogen steel material of the stirring-head by weight percentage, containing following element:Mn:16-19%; Cr:20-30%;N:0.5-0.9%;Mo:1.5-2.5%;Ni:≤ 0.2%;S:≤ 0.03%;P:≤ 0.03%;C:≤ 0.03%;Si:≤ 0.4%, balance of iron and inevitable impurity.High nitrogen steel strength of materials height, creep resistant, the fatigue behaviour Good, the stirring-head intensity made using the material is high, benefits from life-span length, and heat production is stable, disclosure satisfy that the low melting points such as aluminium alloy have Requirement of the non-ferrous metal to stirring-head performance.
But the creep resistance able person of above-mentioned stirring head material is not ideal enough, need further raising.
The content of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of stirring-head creep resistant alloy Steel material.The present invention Stirring head material not only there is excellent abrasion resistance properties, high temperature oxidation resistance, and with excellent creep-resistant property, Significantly extend the service life of stirring-head.
The present invention concrete technical scheme be:A kind of stirring-head creep resistant alloy Steel material, by following percentage by weight Raw material composition:0.12-0.28%C, 0.3-1.5%Si, 0.2-1.5%Mn, 10.0-15.0%Cr, 1.0-8.0%W, 1.0- 5.0%Mo, 0.1-1.0%Sr, 0.2-0.8%V, 0.005-0.02%B, 0.01-0.25%Nb, 0.05-0.80%In, 0.01-1.0%Al ,≤0.03%P ,≤0.03%S, balance of iron and inevitable impurity.The inevitable impurity Content≤0.10%.
The invention of this life has carried out strict regulation and control to the content of each element in stirring head material so that stirring head material not only has There are excellent abrasion resistance properties, high temperature oxidation resistance, and with excellent creep-resistant property, significantly extend making for stirring-head Use the life-span.Wherein, in steel alloy:
The Main Function of carbon (C) is to maintain the preferable intensity of steel alloy.
The Main Function of silicon (Si) is, as reducing agent and deoxidier, and to improve the elastic limit of steel alloy, yield point, anti- Tensile strength and antioxygenic property.
The Main Function of manganese (Mn) is, as deoxidier and desulfurizing agent, and to improve the obdurability of steel alloy, improves steel alloy Hot-working character.
The Main Function of chromium (Cr) is intensity, hardness, wearability, non-oxidizability and the corrosion resistance for improving steel alloy.
The Main Function of tungsten (W) is the creep resisting ability and abrasion resistance properties for improving steel alloy.
The Main Function of molybdenum (Mo) is crystal grain thinning, improves the quenching degree and thermostrength of steel alloy, makes steel alloy in height Enough intensity and creep resisting ability are kept when warm.
The Main Function of strontium (Sr) is the high-temperature oxidation resistance for improving steel alloy, strengthens the high-temperature wearable damage property of steel alloy Energy.
The Main Function of vanadium (V) is crystal grain thinning, improve steel intensity and and toughness, improve steel wearability and thermohardening And temper resistance.
The Main Function of boron (B) is the compactness for improving steel alloy, improves intensity.
The Main Function of niobium (Nb) is crystal grain thinning, the superheated susceptivity of reduction steel alloy and temper brittleness, improves intensity And decay resistance.
The Main Function of indium (In) is the toughness for improving steel alloy.
The main use of aluminium (Al) is crystal grain thinning, and as deoxidier, so as to improve the obdurability of steel alloy.
Additionally due to sulphur (S), phosphorus (P) are easy to sulfide, the phosphide that iron forms fragility, deteriorate the performance of steel alloy, institute S, P content in need strict control steel alloy.
In preparation process, melting, heat treatment all adopt conventional method to the stirring-head of the present invention.
Preferably, above-mentioned stirring-head creep resistant alloy Steel material is comprised the following raw materials by weight percent:0.15- 0.25%C, 0.5-1.2%Si, 0.3-1.3%Mn, 11.0-14.5%Cr, 2.0-7.0%W, 2.0-4.5%Mo, 0.2- 0.9%Sr, 0.3-0.7%V, 0.006-0.015%B, 0.05-0.20%Nb, 0.08-0.75%In, 0.05-0.9%Al ,≤ 0.02%P ,≤0.02%S, balance of iron and inevitable impurity, content≤0.10% of the impurity.
As further preferred, above-mentioned stirring-head with creep resistant alloy Steel material by following percentage by weight raw material group Into:0.18-0.20%C, 0.6-1.1%Si, 0.5-1.2%Mn, 11.5-14.0%Cr, 2.7-6.8%W, 2.5-4.2%Mo, 0.3-0.85%Sr, 0.35-0.65%V, 0.008-0.012%B, 0.08-0.18%Nb, 0.09-0.70%In, 0.08- 0.85%Al ,≤0.01%P ,≤0.01%S, balance of iron and inevitable impurity, content≤0.10% of the impurity.
It is compared with the prior art, the invention has the beneficial effects as follows:The stirring head material of the present invention not only has excellent resistance to Polishing machine, high temperature oxidation resistance, and with excellent creep-resistant property, significantly extend the service life of stirring-head.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.20%C, 0.9% Si, 0.85%Mn, 12.5%Cr, 4.5%W, 3.0%Mo, 0.5%Sr, 0.5%V, 0.01%B, 0.13%Nb, 0.40%In, 0.50%Al, 0.03%P, 0.03%S, inevitable impurity 0.08%, balance of Fe.
Embodiment 2
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.12%C, 1.5% Si, 0.2%Mn, 15.0%Cr, 1.0%W, 5.0%Mo, 0.1%Sr, 0.8%V, 0.005%B, 0.25%Nb, 0.05%In, 1.0%Al, 0.01%P, 0.01%S, inevitable impurity 0.08%, balance of Fe.
Embodiment 3
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.28%C, 0.3% Si, 1.5%Mn, 10.0%Cr, 8.0%W, 1.0%Mo, 1.0%Sr, 0.2%V, 0.02%B, 0.01%Nb, 0.80%In, 0.01%Al, 0.001%P, 0.006%S, inevitable impurity 0.08%, balance of Fe.
0.18-0.20%C, 0.6-1.1%Si, 0.5-1.2%Mn, 11.5-14.0%Cr, 2.7-6.8%W, 2.5- 4.2%Mo, 0.3-0.85%Sr, 0.35-0.65%V, 0.008-0.012%B, 0.08-0.18%Nb, 0.09-0.70%In, 0.08-0.85%Al ,≤0.01%P ,≤0.01%S, balance of iron and inevitable impurity.
Embodiment 4
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.19%C, 0.9% Si, 0.9%Mn, 12.4%Cr, 5.2%W, 3.8%Mo, 0.65%Sr, 0.55%V, 0.012%B, 0.11%Nb, 0.2% In, 0.50%Al, 0.005%P, 0.005%S, inevitable impurity 0.08%, balance of Fe.
Embodiment 5
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.19%C, 0.85%Si, 0.85%Mn, 13.0%Cr, 4.5%W, 3.3%Mo, 0.6%Sr, 0.45%V, 0.01%B, 0.13%Nb, 0.40%In, 0.45%Al, 0.005%P, 0.005%S, inevitable impurity 0.08%, balance of Fe.
Embodiment 6
A kind of stirring-head creep resistant alloy Steel material, comprises the following raw materials by weight percent:0.19%C, 0.78%Si, 1.35%Mn, 13.5%Cr, 3.8%W, 3.5%Mo, 0.45%Sr, 0.52%V, 0.01%B, 0.15%Nb, 0.45%In, 0.35%Al, 0.005%P, 0.005%S, inevitable impurity 0.08%, balance of Fe.
A kind of stirring-head creep resistant alloy Steel material described in each embodiment, contrasts with the test data of H13 Steel materials:
Embodiment Relative creep-resistant property under 25 DEG C of test conditions Relative creep-resistant property under 500 DEG C of test conditions
H13 steel 1 1
Embodiment 1 1.41 1.54
Embodiment 2 1.32 1.43
Embodiment 3 1.19 1.28
Embodiment 4 1.48 1.63
Embodiment 5 1.53 1.72
Embodiment 6 1.46 1.61
Raw materials used in the present invention, equipment, unless otherwise noted, is the conventional raw material, equipment of this area;In the present invention Method therefor, unless otherwise noted, is the conventional method of this area.
The above, is only presently preferred embodiments of the present invention, and not the present invention is imposed any restrictions, every according to the present invention Any simple modification, change and equivalent transformation that technical spirit is made to above example, still fall within the technology of the present invention side The protection domain of case.

Claims (3)

1. a kind of stirring-head creep resistant alloy Steel material, it is characterised in that comprise the following raw materials by weight percent:0.12- 0.28%C, 0.3-1.5%Si, 0.2-1.5%Mn, 10.0-15.0%Cr, 1.0-8.0%W, 1.0-5.0%Mo, 0.1- 1.0%Sr, 0.2-0.8%V, 0.005-0.02%B, 0.01-0.25%Nb, 0.05-0.80%In, 0.01-1.0%Al ,≤ 0.03%P ,≤0.03%S, balance of iron and inevitable impurity, content≤0.10% of the impurity.
2. a kind of stirring-head creep resistant alloy Steel material as claimed in claim 1, it is characterised in that by following weight percent The raw material composition of ratio:0.15-0.25%C, 0.5-1.2%Si, 0.3-1.3%Mn, 11.0-14.5%Cr, 2.0-7.0%W, 2.0-4.5%Mo, 0.2-0.9%Sr, 0.3-0.7%V, 0.006-0.015%B, 0.05-0.20%Nb, 0.08-0.75% In, 0.05-0.9%Al ,≤0.02%P ,≤0.02%S, balance of iron and inevitable impurity, the content of the impurity≤ 0.10%.
3. a kind of stirring-head creep resistant alloy Steel material as claimed in claim 1, it is characterised in that by following weight percent The raw material composition of ratio:0.18-0.20%C, 0.6-1.1%Si, 0.5-1.2%Mn, 11.5-14.0%Cr, 2.7-6.8%W, 2.5-4.2%Mo, 0.3-0.85%Sr, 0.35-0.65%V, 0.008-0.012%B, 0.08-0.18%Nb, 0.09- 0.70%In, 0.08-0.85%Al ,≤0.01%P ,≤0.01%S, balance of iron and inevitable impurity, the impurity Content≤0.10%.
CN201611219741.4A 2016-12-26 2016-12-26 Creep-resistant alloy steel material for stir-welding head Pending CN106591709A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108118246A (en) * 2017-12-28 2018-06-05 重庆派馨特机电有限公司 A kind of anti-fracture wear-resistant steel alloy of high tenacity

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55110758A (en) * 1979-02-20 1980-08-26 Sumitomo Metal Ind Ltd High temperature use chromium steel
CN88100065A (en) * 1987-01-09 1988-10-05 株式会社日立制作所 Heat-resistant steel and gas turbine made of the same
JPH0610041A (en) * 1992-06-25 1994-01-18 Sumitomo Metal Ind Ltd Method for producing high Cr ferritic steel excellent in creep rupture strength and ductility
CN1406287A (en) * 2000-12-26 2003-03-26 株式会社日本制钢所 High Cr ferritic heat resistance steel
CN102453843A (en) * 2010-10-25 2012-05-16 宝山钢铁股份有限公司 Ferrite heat-resistant steel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55110758A (en) * 1979-02-20 1980-08-26 Sumitomo Metal Ind Ltd High temperature use chromium steel
CN88100065A (en) * 1987-01-09 1988-10-05 株式会社日立制作所 Heat-resistant steel and gas turbine made of the same
JPH0610041A (en) * 1992-06-25 1994-01-18 Sumitomo Metal Ind Ltd Method for producing high Cr ferritic steel excellent in creep rupture strength and ductility
CN1406287A (en) * 2000-12-26 2003-03-26 株式会社日本制钢所 High Cr ferritic heat resistance steel
CN102453843A (en) * 2010-10-25 2012-05-16 宝山钢铁股份有限公司 Ferrite heat-resistant steel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108118246A (en) * 2017-12-28 2018-06-05 重庆派馨特机电有限公司 A kind of anti-fracture wear-resistant steel alloy of high tenacity

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