CN106590527A - Multifunctional environmentally friendly adhesive and preparation method thereof - Google Patents
Multifunctional environmentally friendly adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106590527A CN106590527A CN201611171645.7A CN201611171645A CN106590527A CN 106590527 A CN106590527 A CN 106590527A CN 201611171645 A CN201611171645 A CN 201611171645A CN 106590527 A CN106590527 A CN 106590527A
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- parts
- agent
- waste
- organo
- colophonium
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a multifunctional environmentally friendly adhesive and a preparation method thereof. The multifunctional environmentally friendly adhesive consists of the following formula components by weight: 10-20 parts of mother liquor, 5-10 parts of waste polystyrene, 16-18 parts of waste glass, 6-8 parts of organosilicon coupling agent solution, 12-14 parts of gypsum powder, 14-15 parts of white cement, 3-4 parts of tackifier, 1-2 parts of thickener, 1-3 parts of whitening agent, 3-5 parts of curing agent, 6-10 parts of EVA emulsion, and 10-12 parts of asphalt. The adhesive prepared by the method does not contain harmful substances such as benzene and formaldehyde, and has the advantages of good adhesion, high bonding strength and good water resistance, and also low manufacturing cost, low price and wide range of uses. The adhesive can be used for plywoods, fiberboards, medium and high-grade density fiber boards, furniture, etc., and can also be used for bonding metals, ceramics, glass, etc., and can also be used in construction, decoration and other fields.
Description
Technical field
The present invention relates to technical field of adhesive, in particular to a kind of multi-functional environment-protection adhesive and its preparation side
Method.
Background technology
At present, the adhesive type that China uses is a lot, the adhesive for producing in the prior art, due to its raw material
Difference, the performance of glue have in very big difference, but most of adhesive according to respective composition difference, such as neoprene-phenolic resin glue
In disadvantage containing the harmful substance composition such as benzene,toluene,xylene, formaldehyde, life-time service is not only made to environment
Into pollution, and damage the health of people；Environmental requirement is not met, and this kind of adhesive raw material is single, complex process is subject to
The restriction of industrial chemicals, manufacturing cost are high, so a definite limitation is subject in use.For this purpose, the present invention adopts waste or used plastics
(PS) and waste and used rubber tyre, using plastics and rubber therefore some characteristics, and its good physics, mechanically and chemically performance,
Thick glue liquid is made with organic solvent, then adds a certain amount of chemical addition agent and adjuvant, be adequately mixed uniform, the property made
Excellent, the cheap multi-functional environment-protection adhesive of energy, and product variety and product use can be controlled by adjusting proportioning component
On the way, make the adhesive suitable for fields such as sheet material manufacturing industry, the bonding of metal and nonmetal and building decorations.With China its people
The consumption of economic fast development, China's polystyrene foam plastics (PS) and rubber is increasing, and major part is all
Single use, millions of ton of white garbage and waste and old rubber product dissipate and can neither rot to convert in nature, again can not be certainly
So degrade, on the one hand cause serious environmental pollution, the waste of one side and valuable non-renewable resources, other side to return
Receive using also difficult, for making multi-functional environment-protection adhesive, both accelerated the comprehensive utilization of resource, and reduced pollution again,
Protect environment, and aboundresources.
The content of the invention
The invention provides a kind of multi-functional environment-protection adhesive and preparation method thereof, the adhesive prepared by the present invention is not contained
The harmful substance composition such as benzene, formaldehyde, cohesive are good, and adhesive strength is high, and water-resistance is good.And low cost of manufacture, cheap, purposes
Extensively.Plywood, fibre board, medium-to-high grade density board, furniture etc. are can be not only used for, can be used for the viscous of metal, ceramics, glass etc. again
Connect, it may also be used for the field such as building, decoration.
For achieving the above object, the present invention provides following technical scheme：
A kind of multi-functional environment-protection adhesive and preparation method thereof, is made up of following mass fraction formula components：Mother solution 10-20
It is part, waste and old polystyrol 5-10 parts, discarded glass 16-18 parts, organo-silicon coupling agent solution 6-8 parts, Gypsum Fibrosum powder 12-14 parts, white
Cement 14-15 parts, viscosifier 3-4 parts, thickening agent 1-2 parts, brightening agent 1-3 parts, firming agent 3-5 parts, EVA emulsion 6-10 parts, drip
Blue or green 10-12 parts.
Further：It is made up of following mass fraction formula components：10 parts of mother solution, 5 parts of waste and old polystyrol, discarded glass 16
It is part, 6 parts of organo-silicon coupling agent solution, 12 parts of Gypsum Fibrosum powder, 14 parts of white cement, 3 parts of viscosifier, 1 part of thickening agent, 1 part of brightening agent, solid
3 parts of agent, 6 parts of EVA emulsions, 10 parts of Colophonium.
Further：It is made up of following mass fraction formula components：15 parts of mother solution, 7.5 parts of waste and old polystyrol, discarded glass
17 parts, 7 parts of organo-silicon coupling agent solution, 13 parts of Gypsum Fibrosum powder, 14.5 parts of white cement, 3.5 parts of viscosifier, 1.5 parts of thickening agent, brighten
2 parts of agent, 4 parts of firming agent, 8 parts of EVA emulsions, 11 parts of Colophonium.
Further：It is made up of following mass fraction formula components：20 parts of mother solution, 10 parts of waste and old polystyrol, discarded glass
18 parts, 8 parts of organo-silicon coupling agent solution, 14 parts of Gypsum Fibrosum powder, 15 parts of white cement, 4 parts of viscosifier, 2 parts of thickening agent, 3 parts of brightening agent,
5 parts of firming agent, 10 parts of EVA emulsions, 12 parts of Colophonium.
Further：Preparation method of the present invention has following steps：
Step one, with waste and old polystyrol and waste and used rubber tyre as main material, it is waste and old poly- with solvent naphtha 200# dissolvings
Mother solution is made in polymerization under styrene and waste and used rubber tyre room temperature；
Step 2, then addition discarded glass and Colophonium synthesizing organo-silicon coupling agent at a temperature of 200 DEG C～250 DEG C are molten
Liquid；
Step 3, add viscosifier, thickening agent, brightening agent, firming agent mixing be put in retort, 65 DEG C～100
2-3 hours are stirred at a temperature of DEG C；
Step 4, will obtained by step 3 add surplus stock after be allowed to abundant polyreaction, cooling gets product.
The invention has the beneficial effects as follows：
1st, without harmful substance compositions such as benzene, formaldehyde, cohesive is good for the adhesive prepared by the present invention, and adhesive strength is high,
Water-resistance is good；
2nd, and low cost of manufacture, it is cheap, it is of many uses；
3rd, plywood, fibre board, medium-to-high grade density board, furniture etc. are can be not only used for, can be used for metal, ceramics, glass etc. again
Bonding, it may also be used for building, decoration etc. field.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of multi-functional environment-protection adhesive is made up of following mass fraction formula components：Mother solution 10-20 parts, waste and old polyphenyl second
Alkene 5-10 parts, discarded glass 16-18 parts, organo-silicon coupling agent solution 6-8 parts, Gypsum Fibrosum powder 12-14 parts, white cement 14-15 parts, increasing
Stick 3-4 parts, thickening agent 1-2 parts, brightening agent 1-3 parts, firming agent 3-5 parts, EVA emulsion 6-10 parts, Colophonium 10-12 parts.
Embodiment two：
A kind of multi-functional environment-protection adhesive is made up of following mass fraction formula components：10 parts of mother solution, waste and old polystyrol 5
Part, 16 parts of discarded glass, 6 parts of organo-silicon coupling agent solution, 12 parts of Gypsum Fibrosum powder, 14 parts of white cement, 3 parts of viscosifier, thickening agent 1
Part, 1 part of brightening agent, 3 parts of firming agent, 6 parts of EVA emulsions, 10 parts of Colophonium.
Embodiment three：
A kind of multi-functional environment-protection adhesive is made up of following mass fraction formula components：15 parts of mother solution, waste and old polystyrol
7.5 parts, 17 parts of discarded glass, 7 parts of organo-silicon coupling agent solution, 13 parts of Gypsum Fibrosum powder, 14.5 parts of white cement, 3.5 parts of viscosifier, increase
Thick dose 1.5 parts, 2 parts of brightening agent, 4 parts of firming agent, 8 parts of EVA emulsions, 11 parts of Colophonium.
Example IV：
A kind of multi-functional environment-protection adhesive is made up of following mass fraction formula components：20 parts of mother solution, waste and old polystyrol
10 parts, 18 parts of discarded glass, 8 parts of organo-silicon coupling agent solution, 14 parts of Gypsum Fibrosum powder, 15 parts of white cement, 4 parts of viscosifier, thickening agent 2
Part, 3 parts of brightening agent, 5 parts of firming agent, 10 parts of EVA emulsions, 12 parts of Colophonium.
Embodiment five：
A kind of preparation method preparation method of multi-functional environment-protection adhesive comprises the steps：
Step one, with waste and old polystyrol and waste and used rubber tyre as main material, it is waste and old poly- with solvent naphtha 200# dissolvings
Mother solution is made in polymerization under styrene and waste and used rubber tyre room temperature；
Step 2, then addition discarded glass and Colophonium synthesizing organo-silicon coupling agent at a temperature of 200 DEG C～250 DEG C are molten
Liquid；
Step 3, add viscosifier, thickening agent, brightening agent, firming agent mixing be put in retort, 65 DEG C～100
2-3 hours are stirred at a temperature of DEG C；
Step 4, will obtained by step 3 add surplus stock after be allowed to abundant polyreaction, cooling gets product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity
Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of multi-functional environment-protection adhesive, it is characterised in that：It is made up of following mass fraction formula components：
Mother solution 10-20 parts, waste and old polystyrol 5-10 parts, discarded glass 16-18 parts, organo-silicon coupling agent solution 6-8 parts, Gypsum Fibrosum
Powder 12-14 parts, white cement 14-15 parts, viscosifier 3-4 parts, thickening agent 1-2 parts, brightening agent 1-3 parts, firming agent 3-5 parts, EVA are newborn
Liquid 6-10 parts, Colophonium 10-12 parts.
2. a kind of multi-functional environment-protection adhesive according to claim 1, it is characterised in that：By following mass fraction formula into
It is grouped into：
10 parts of mother solution, 5 parts of waste and old polystyrol, 16 parts of discarded glass, 6 parts of organo-silicon coupling agent solution, 12 parts of Gypsum Fibrosum powder, plain boiled water
14 parts of mud, 3 parts of viscosifier, 1 part of thickening agent, 1 part of brightening agent, 3 parts of firming agent, 6 parts of EVA emulsions, 10 parts of Colophonium.
3. a kind of multi-functional environment-protection adhesive according to claim 1, it is characterised in that：By following mass fraction formula into
It is grouped into：
It is 15 parts of mother solution, 7.5 parts of waste and old polystyrol, 17 parts of discarded glass, 7 parts of organo-silicon coupling agent solution, 13 parts of Gypsum Fibrosum powder, white
14.5 parts of cement, 3.5 parts of viscosifier, 1.5 parts of thickening agent, 2 parts of brightening agent, 4 parts of firming agent, 8 parts of EVA emulsions, 11 parts of Colophonium.
4. a kind of multi-functional environment-protection adhesive according to claim 1, it is characterised in that：By following mass fraction formula into
It is grouped into：
It is 20 parts of mother solution, 10 parts of waste and old polystyrol, 18 parts of discarded glass, 8 parts of organo-silicon coupling agent solution, 14 parts of Gypsum Fibrosum powder, white
15 parts of cement, 4 parts of viscosifier, 2 parts of thickening agent, 3 parts of brightening agent, 5 parts of firming agent, 10 parts of EVA emulsions, 12 parts of Colophonium.
5. a kind of a kind of preparation method of multi-functional environment-protection adhesive according to claim 1, it is characterised in that：Including such as
Lower step：
Step one, with waste and old polystyrol and waste and used rubber tyre as main material, dissolve waste and old polyphenyl second with solvent naphtha 200#
Mother solution is made in polymerization under alkene and waste and used rubber tyre room temperature；
Step 2, then the addition discarded glass and Colophonium synthesizing organo-silicon coupling agent solution at a temperature of 200 DEG C～250 DEG C；
Step 3, add viscosifier, thickening agent, brightening agent, firming agent mixing be put in retort, it is warm at 65 DEG C～100 DEG C
The lower stirring 2-3 hours of degree；
Step 4, will obtained by step 3 add surplus stock after be allowed to abundant polyreaction, cooling gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171645.7A CN106590527A (en) | 2016-12-17 | 2016-12-17 | Multifunctional environmentally friendly adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171645.7A CN106590527A (en) | 2016-12-17 | 2016-12-17 | Multifunctional environmentally friendly adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590527A true CN106590527A (en) | 2017-04-26 |
Family
ID=58601189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611171645.7A Pending CN106590527A (en) | 2016-12-17 | 2016-12-17 | Multifunctional environmentally friendly adhesive and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN106590527A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114874750A (en) * | 2022-06-16 | 2022-08-09 | 东莞市奥嘉特高分子材料有限公司 | Water-based adhesive for bonding rubber and metal and preparation method thereof |
| WO2023113631A1 (en) * | 2021-12-17 | 2023-06-22 | The Climate Change Srl | Asphalt concrete with aggregates and waste derived from recycled glass and plastics and manufacturing process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563238A (en) * | 2004-04-12 | 2005-01-12 | 谢兆坤 | Multifunctional environmental protection type adhesive and preparation method |
| CN101580690A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Leather glue prepared by adopting waste materials and preparation method thereof |
| CN101580689A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Special floor tile glue prepared by adopting waste materials and preparation method thereof |
| CN101580691A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
-
2016
- 2016-12-17 CN CN201611171645.7A patent/CN106590527A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563238A (en) * | 2004-04-12 | 2005-01-12 | 谢兆坤 | Multifunctional environmental protection type adhesive and preparation method |
| CN101580690A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Leather glue prepared by adopting waste materials and preparation method thereof |
| CN101580689A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Special floor tile glue prepared by adopting waste materials and preparation method thereof |
| CN101580691A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023113631A1 (en) * | 2021-12-17 | 2023-06-22 | The Climate Change Srl | Asphalt concrete with aggregates and waste derived from recycled glass and plastics and manufacturing process |
| CN114874750A (en) * | 2022-06-16 | 2022-08-09 | 东莞市奥嘉特高分子材料有限公司 | Water-based adhesive for bonding rubber and metal and preparation method thereof |
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Application publication date: 20170426 |