CN106589929A - Flame-retarding nylon composite for acid-base resisting electric power fitting and manufacturing method thereof - Google Patents
Flame-retarding nylon composite for acid-base resisting electric power fitting and manufacturing method thereof Download PDFInfo
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- CN106589929A CN106589929A CN201611006104.9A CN201611006104A CN106589929A CN 106589929 A CN106589929 A CN 106589929A CN 201611006104 A CN201611006104 A CN 201611006104A CN 106589929 A CN106589929 A CN 106589929A
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- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 239000004677 Nylon Substances 0.000 title claims abstract description 19
- 229920001778 nylon Polymers 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 15
- 239000004917 carbon fiber Substances 0.000 claims abstract description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003063 flame retardant Substances 0.000 claims abstract description 13
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 7
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- 239000001257 hydrogen Substances 0.000 claims abstract description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 7
- 229920002545 silicone oil Polymers 0.000 claims abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 239000012948 isocyanate Substances 0.000 claims description 6
- 229950000845 politef Drugs 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000007788 roughening Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract description 2
- 239000012779 reinforcing material Substances 0.000 abstract description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 239000010893 paper waste Substances 0.000 abstract 1
- -1 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 230000005540 biological transmission Effects 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a flame-retarding nylon composite for an acid-base resisting electric power fitting. The flame-retarding nylon composite is prepared from, by weight, 78-82 parts of nylon 67, 21-23 parts of polytetrafluoroethylene, 24-26 parts of carbon fiber, 8.4-8.6 parts of melamine cyanurate, 25-27 parts of aluminum oxide, 4-6 parts of hydrogen-containing silicone oil, 8-10 parts of talcum powder, 1.2-1.5 parts of carbonyl iron powder, 5-7 parts of polyethylene glycol, 10-11 parts of vinyl trimethoxy silane, 6-8 parts of waste paper pulp, 1.6-1.8 parts of nano cerium oxide and 7-8 parts of toluene diisocynate. The melamine cyanurate is adopted as a fire retardant, the aluminum oxide is adopted as a heat conducting filler after being subjected to silane modification, carbon fiber is adopted as a reinforcing material, and other effective components are matched and composited to obtain the electric power fitting. The electric power fitting has the good acid-base resistance, impact resistance, creep resistance and heat resistance, is good in overall performance and can be continuously produced.
Description
Technical field
The present invention relates to technical field of composite materials, more particularly to a kind of acid and alkali-resistance electric armour clamp fire-retardant nylon composite wood
Material and preparation method thereof.
Background technology
Electric armour clamp be connection and combinational electric system in all kinds of devices, play transmission mechanical load, electrical load and
The metal-ware of certain protective action, used as part indispensable on transmission line of electricity, its electric energy loss is always power department
The problem of concern.In addition to improving from electric armour clamp casting technique, the selection to its material is particularly important, and material is prepared at present
Mainly based on nonmagnetic aluminium alloy, although compared with the ferrimagnet for using in the past, electrical network energy-saving and emission-reduction are played necessarily
Effect, but used as metallic conductor, eddy-current loss is still present, and energy loss is still unavoidable from, and Al-alloy products must
Must obtain through the high energy consumptions such as ore dressing, exploitation, electrolysis, melting, high pollution operation, belong to national developmental limitation industry, it is impossible to full
The economic needs of sufficient transmission line of electricity.Replace metal material with insulant, so that it may reduce eddy-current loss, reach more preferable energy-conservation effect
Really.With the fast development of brand-new material science, the composite with insulating properties is applied to more and more power industry
In, as the making material of electric armour clamp, it is up to decrease or even eliminate the purpose of eddy-current loss.
It is known that fibre reinforced composites have the performance such as lightweight, high-strength, anti-corrosion, insulation, environmental protection, in power industry
Be widely used in transmission and distribution networkses, thus in order to solve the problems, such as electric line in steel and aluminum alloy hardware high energy consumption,
Reduce line loss, document《The development and application of modified composite material conductor spacer and suspension clamp》Tens of kinds of engineering plastics are entered
Go and selected and study, it is determined that using PA66 nylon as the base material of composite.In the substrate add glass fibre, toughener,
Resistance to ozone and corrosion-resistant etc. material modified, and by repetition test test and formulation optimization, successfully develop a kind of modified compound
Material, and the design of conductor spacer and suspension clamp, trial-production and experimental study based on modified composite material have been carried out, as a result show it
Performance meets national standard and power industry standard requirement, and the suspension clamp based on composite has been applied to 35 kV and 220
In kV overhead transmission lines, operation conditions is good.
Belong to combustible material yet with nylon material, electric armour clamp is used for for a long time open air, especially during the broiling summer
Hold fire hazardous with dry winter, and the improvement of the performance such as fire-retardant to material in document, cold-resistant, ageing-resistant does not add elaboration,
Thus the electric armour clamp with fire resistance for developing a kind of multifunction efficient energy-saving have with modified composite nylon material it is good
Good application prospect.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of acid and alkali-resistance electric armour clamp fire-retardant nylon
Composite and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of acid and alkali-resistance electric armour clamp fire-retardant nylon composite, is prepared by the raw materials in：Nylon66 fiber 78-82,
Politef 21-23, carbon fiber 24-26, melamine cyanurate 8.4-8.6, aluminium oxide 25-27, containing hydrogen silicone oil 4-6,
Pulvis Talci 8-10, carbonyl iron dust 1.2-1.5, Polyethylene Glycol 5-7, vinyltrimethoxy silane 10-11, secondary stock 6-8, nanometer
Cerium oxide 1.6-1.8, toluene di-isocyanate(TDI) 7-8.
A kind of described acid and alkali-resistance electric armour clamp manufacture method of fire-retardant nylon composite, comprises the following steps：
（1）By secondary stock add 10-12 times of quality water in stirring and evenly mixing heated and boiled, keeping temperature add nano-cerium oxide,
Polyethylene Glycol continues to stir 10-20 minutes, is cooled to 45-55 DEG C, adds melamine cyanurate ultrasonic disperse 20-30 point
Clock, is spray-dried to obtain modified melamine cyanurate；
（2）By aluminium oxide in 810-910 DEG C of calcination processing 30-40 minute, 110-120 DEG C of addition toluene di-isocyanate(TDI) is cooled to
Grinding 20-30 minutes, it is cooled to 75-80 DEG C and adds vinyltrimethoxy silane, containing hydrogen silicone oil ultrasonic disperse 10-15 minutes,
Room temperature dries to obtain modified aluminas；
（3）Carbon fiber is placed in the salpeter solution that mass concentration is 25%-40%, is soaked 10-20 minutes under room temperature condition, then
With in the sodium hydroxide solution of mass concentration 5%-20% and residual acid solution, final rinse water to neutrality is dried must be roughened place
Reason carbon fiber；
（4）By nylon66 fiber, politef, step（1）、（2）Material and other residual componentss mix homogeneously in mixer, Jing
Upstream spout, sends into double screw extruder, while by step（3）Middle roughening treatment carbon fiber Jing fed downstream mouths, send into double
Screw extruder melting extrusion, pelletize, discharging.
It is an advantage of the invention that：With melamine cyanurate as fire retardant, addition nano-cerium oxide is changed the present invention
Property after its crystal can be made to be generally uniformly dispersed in nylon matrix, in burning by itself endothermic decomposition, generation can not combustion gas
Body, realizes that gas phase is intercepted, and so as to play fire retardation, and leaves nanoporous on composite self-extinguishment face；The present invention will
Aluminium oxide carry out it is silane-modified after be added in raw material as heat filling, and nylon matrix wellability it is good be uniformly dispersed, carry
The thermal diffusivity and heat resistance of high material；As reinforcing material, again other effective ingredient of compatibility are mutually combined system to addition carbon fiber
The electric armour clamp for obtaining has good resistance to acids and bases, impact resistance, creep-resistant property and heat resistance, and high comprehensive performance can
Continuously produced.
Specific embodiment
A kind of acid and alkali-resistance electric armour clamp fire-retardant nylon composite, is prepared by the raw materials in：Nylon66 fiber
78th, politef 21, carbon fiber 24, melamine cyanurate 8.4, aluminium oxide 25, containing hydrogen silicone oil 4, Pulvis Talci 8, carbonyl
Iron powder 1.2, Polyethylene Glycol 5, vinyltrimethoxy silane 10, secondary stock 6, nano-cerium oxide 1.6, toluene di-isocyanate(TDI) 7.
A kind of described acid and alkali-resistance electric armour clamp manufacture method of fire-retardant nylon composite, comprises the following steps：
（1）By secondary stock add 10-12 times of quality water in stirring and evenly mixing heated and boiled, keeping temperature add nano-cerium oxide,
Polyethylene Glycol continues to stir 10-20 minutes, is cooled to 45-55 DEG C, adds melamine cyanurate ultrasonic disperse 20-30 point
Clock, is spray-dried to obtain modified melamine cyanurate；
（2）By aluminium oxide in 810-910 DEG C of calcination processing 30-40 minute, 110-120 DEG C of addition toluene di-isocyanate(TDI) is cooled to
Grinding 20-30 minutes, it is cooled to 75-80 DEG C and adds vinyltrimethoxy silane, containing hydrogen silicone oil ultrasonic disperse 10-15 minutes,
Room temperature dries to obtain modified aluminas；
（3）Carbon fiber is placed in the salpeter solution that mass concentration is 25%-40%, is soaked 10-20 minutes under room temperature condition, then
With in the sodium hydroxide solution of mass concentration 5%-20% and residual acid solution, final rinse water to neutrality is dried must be roughened place
Reason carbon fiber；
（4）By nylon66 fiber, politef, step（1）、（2）Material and other residual componentss mix homogeneously in mixer, Jing
Upstream spout, sends into double screw extruder, while by step（3）Middle roughening treatment carbon fiber Jing fed downstream mouths, send into double
Screw extruder melting extrusion, pelletize, discharging.
It is 216MPa using electric armour clamp fire-retardant nylon composite material tensile strength obtained in the present invention, elongation percentage is
5.16%。
Claims (2)
1. a kind of acid and alkali-resistance electric armour clamp fire-retardant nylon composite, it is characterised in that be prepared by the raw materials in：
Nylon66 fiber 78-82, politef 21-23, carbon fiber 24-26, melamine cyanurate 8.4-8.6, aluminium oxide 25-27,
It is containing hydrogen silicone oil 4-6, Pulvis Talci 8-10, carbonyl iron dust 1.2-1.5, Polyethylene Glycol 5-7, vinyltrimethoxy silane 10-11, useless
Paper pulp 6-8, nano-cerium oxide 1.6-1.8, toluene di-isocyanate(TDI) 7-8.
2. a kind of acid and alkali-resistance electric armour clamp according to claim 1 manufacture method of fire-retardant nylon composite, it is special
Levy is to comprise the following steps：
（1）By secondary stock add 10-12 times of quality water in stirring and evenly mixing heated and boiled, keeping temperature add nano-cerium oxide,
Polyethylene Glycol continues to stir 10-20 minutes, is cooled to 45-55 DEG C, adds melamine cyanurate ultrasonic disperse 20-30 point
Clock, is spray-dried to obtain modified melamine cyanurate；
（2）By aluminium oxide in 810-910 DEG C of calcination processing 30-40 minute, 110-120 DEG C of addition toluene di-isocyanate(TDI) is cooled to
Grinding 20-30 minutes, it is cooled to 75-80 DEG C and adds vinyltrimethoxy silane, containing hydrogen silicone oil ultrasonic disperse 10-15 minutes,
Room temperature dries to obtain modified aluminas；
（3）Carbon fiber is placed in the salpeter solution that mass concentration is 25%-40%, is soaked 10-20 minutes under room temperature condition, then
With in the sodium hydroxide solution of mass concentration 5%-20% and residual acid solution, final rinse water to neutrality is dried must be roughened place
Reason carbon fiber；
（4）By nylon66 fiber, politef, step（1）、（2）Material and other residual componentss mix homogeneously in mixer, Jing
Upstream spout, sends into double screw extruder, while by step（3）Middle roughening treatment carbon fiber Jing fed downstream mouths, send into double
Screw extruder melting extrusion, pelletize, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611006104.9A CN106589929A (en) | 2016-11-16 | 2016-11-16 | Flame-retarding nylon composite for acid-base resisting electric power fitting and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611006104.9A CN106589929A (en) | 2016-11-16 | 2016-11-16 | Flame-retarding nylon composite for acid-base resisting electric power fitting and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589929A true CN106589929A (en) | 2017-04-26 |
Family
ID=58591095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611006104.9A Pending CN106589929A (en) | 2016-11-16 | 2016-11-16 | Flame-retarding nylon composite for acid-base resisting electric power fitting and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106589929A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085520A (en) * | 2021-11-30 | 2022-02-25 | 上海试四化学品有限公司 | Modified high-flame-retardant-temperature nylon 66 and preparation method thereof |
| CN115746558A (en) * | 2022-12-29 | 2023-03-07 | 湖北洋田塑料制品有限公司 | High-temperature wear-resistant flame-retardant rare earth nylon composite material and preparation method thereof |
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|---|---|---|---|---|
| CN1292394A (en) * | 2000-10-20 | 2001-04-25 | 清华大学 | Preparation method of carbon fibre reinforced cast nylon composite material |
| CN1401702A (en) * | 2002-09-19 | 2003-03-12 | 上海交通大学 | Method for mfg. high barrier nylon composite material |
| CN103333581A (en) * | 2013-07-01 | 2013-10-02 | 国家电网公司 | Nano cerium oxide/epoxy composite paint and preparation method thereof |
| CN103756321A (en) * | 2014-01-03 | 2014-04-30 | 中山市点石塑胶有限公司 | High-thermal-conductivity polymer composite and preparation method thereof |
| CN103756308A (en) * | 2013-12-27 | 2014-04-30 | 吴江市东泰电力特种开关有限公司 | Inflaming retarding wear-resisting nylon composite material and preparation method thereof |
| CN103788633A (en) * | 2014-01-15 | 2014-05-14 | 中山市点石塑胶有限公司 | High-heat-conductivity environment-friendly flame-retarding nylon composite material and preparation method thereof |
| CN104592753A (en) * | 2015-02-16 | 2015-05-06 | 中国科学院理化技术研究所 | Nano-cellulose reinforced and toughened nylon 66 composite material and preparation method thereof |
-
2016
- 2016-11-16 CN CN201611006104.9A patent/CN106589929A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1292394A (en) * | 2000-10-20 | 2001-04-25 | 清华大学 | Preparation method of carbon fibre reinforced cast nylon composite material |
| CN1401702A (en) * | 2002-09-19 | 2003-03-12 | 上海交通大学 | Method for mfg. high barrier nylon composite material |
| CN103333581A (en) * | 2013-07-01 | 2013-10-02 | 国家电网公司 | Nano cerium oxide/epoxy composite paint and preparation method thereof |
| CN103756308A (en) * | 2013-12-27 | 2014-04-30 | 吴江市东泰电力特种开关有限公司 | Inflaming retarding wear-resisting nylon composite material and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085520A (en) * | 2021-11-30 | 2022-02-25 | 上海试四化学品有限公司 | Modified high-flame-retardant-temperature nylon 66 and preparation method thereof |
| CN115746558A (en) * | 2022-12-29 | 2023-03-07 | 湖北洋田塑料制品有限公司 | High-temperature wear-resistant flame-retardant rare earth nylon composite material and preparation method thereof |
| CN115746558B (en) * | 2022-12-29 | 2024-01-16 | 湖北洋田塑料制品有限公司 | High-temperature wear-resistant flame-retardant rare earth nylon composite material and preparation method thereof |
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