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CN106581897B - Carbon dioxide colloidal foam extinguishing device - Google Patents

Carbon dioxide colloidal foam extinguishing device Download PDF

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Publication number
CN106581897B
CN106581897B CN201611053076.6A CN201611053076A CN106581897B CN 106581897 B CN106581897 B CN 106581897B CN 201611053076 A CN201611053076 A CN 201611053076A CN 106581897 B CN106581897 B CN 106581897B
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carbon dioxide
valve
fire extinguishing
tank
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CN106581897A (en
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王利亚
李波
李森兰
太军慧
周也
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Nanyang Normal University
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C5/00Making of fire-extinguishing materials immediately before use
    • A62C5/004Making of fire-extinguishing materials immediately before use for producing carbon-dioxide snow, carbon-dioxide ice, carbon-dioxide gas, carbon-dioxide liquid, or mixtures thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
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  • Emergency Management (AREA)
  • Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)

Abstract

本发明公开一种二氧化碳胶体泡沫灭火装置,包括混合罐,混合罐的上部设有稀释液入口管,混合罐的下部分别设有气体入口管和混合液出口管,所述混合液出口管依次连接有高压管Ⅱ和喷嘴,混合液出口管上沿液体流出方向依次设有单向阀Ⅲ、阀门Ⅲ和节流阀;所述气体入口管的末端连接至液体二氧化碳钢瓶,气体入口管上自混合罐至液体二氧化碳钢瓶之间依次设有单向阀Ⅰ、阀门Ⅰ和减压阀;所述稀释液入口管的末端与高压管Ⅰ连接并连通,高压管Ⅰ通过液压泵连通至稀释罐。本发明的装置喷出的泡沫在火灾现场生成胶体隔离膜,胶体颗粒微细,结合能力强、覆盖面积大,灭火能力强,灭火成本低,本装置结构简单,容易操作。

The invention discloses a carbon dioxide colloidal foam fire extinguishing device, which comprises a mixing tank, the upper part of the mixing tank is provided with a dilution liquid inlet pipe, and the lower part of the mixing tank is respectively provided with a gas inlet pipe and a mixed liquid outlet pipe, and the mixed liquid outlet pipes are sequentially connected There are high-pressure pipe II and nozzles, and the mixed liquid outlet pipe is provided with one-way valve III, valve III and throttle valve in sequence along the liquid outflow direction; the end of the gas inlet pipe is connected to the liquid carbon dioxide cylinder, and the gas inlet pipe is self-mixing Between the tank and the liquid carbon dioxide cylinder, a one-way valve I, a valve I and a pressure reducing valve are arranged in sequence; the end of the diluent inlet pipe is connected and communicated with the high-pressure pipe I, and the high-pressure pipe I is connected to the dilution tank through a hydraulic pump. The foam sprayed by the device of the present invention forms a colloidal isolation film at the fire scene, and the colloidal particles are fine, with strong binding ability, large coverage area, strong fire extinguishing ability, and low fire extinguishing cost. The device has a simple structure and is easy to operate.

Description

二氧化碳胶体泡沫灭火装置Carbon dioxide colloidal foam fire extinguishing device

技术领域technical field

本发明属于消防技术领域,具体涉及一种二氧化碳胶体泡沫灭火装置。The invention belongs to the technical field of fire protection, and in particular relates to a carbon dioxide colloidal foam fire extinguishing device.

背景技术Background technique

近些年来,随着我国建筑领域大量使用有机泡沫保温材料,民用建筑及工业厂房屡屡失火,且单用清水的救火难度也变得困难,往往是需要消耗大量的水资源,火灭了,东西也烧光了,消防的功效只能体现在阻止火灾向火灾孤立区以外继续蔓延。对于油类等易燃物质储罐泄露引起的火灾,用水最多只能起到降温作用;用沙土覆盖,一是短时间内难以获得大量的沙土,二是对大火实际上也难以操作。使用胶体泡沫灭火理论上讲,既合理也应当。但是,现有的胶体泡沫灭火专利有:(1)凝胶制备喷洒灭火设备(CN201320391560.5),(2)一种即配即用水系灭火剂添加剂及其使用方法(CN201610017551.8),(3)防治煤炭自燃的多相凝胶泡沫制备方法(CN200810025415.9),(4)煤岩体防灭火材料(CN201210243676.4),(5)一种灭火材料及其制备方法和应用(CN200910061231.2),(6)一种新型水成膜抗烧型泡沫灭火剂及其制备方法(CN201510741298.6),(7)一种防治煤炭自燃的智能凝胶材料(CN201410113510.X),(8)无氨凝胶(CN201310581681.0)等8个。其中(3)、(5)、(6)、(7)、(8)原料本身就包括有水不溶固体粉料,(1)、(2)、(4)原料中不包括水不溶固体粉料,但他们的共同特点是“胶体泡沫”都需要在喷射之前制成,而后喷出。这就存在两个毛病:一是可能引起设备堵塞,即使不堵塞,至少每次用完后必须彻底清洗设备;二是泡沫中的气体需要占用喷射设备大量的喷射流量,降低喷射设备的灭火效率,三是其中的固形物会使输送和喷射阻力增加,浪费能量。In recent years, with the large-scale use of organic foam insulation materials in the construction field of our country, civil buildings and industrial plants have repeatedly caught fire, and the difficulty of fighting fires with clean water has become difficult. It often requires a large amount of water resources to be consumed. Also burned out, the effect of firefighting can only be reflected in preventing the fire from continuing to spread outside the fire isolation zone. For fires caused by leakage of oil and other flammable storage tanks, water can only cool down at most; covering with sand, first, it is difficult to obtain a large amount of sand in a short period of time, and second, it is actually difficult to operate against large fires. Theoretically speaking, it is reasonable and necessary to use colloidal foam for fire extinguishing. However, the existing colloidal foam fire extinguishing patents include: (1) Sprinkling fire extinguishing equipment prepared by gel (CN201320391560.5), (2) A ready-to-use water-based fire extinguishing agent additive and its use method (CN201610017551.8), (CN201610017551.8), 3) Preparation method of multiphase gel foam for preventing spontaneous combustion of coal (CN200810025415.9), (4) Coal and rock fire prevention material (CN201210243676.4), (5) A fire extinguishing material and its preparation method and application (CN200910061231. 2), (6) A new type of aqueous film-forming anti-burning foam fire extinguishing agent and its preparation method (CN201510741298.6), (7) An intelligent gel material for preventing spontaneous combustion of coal (CN201410113510.X), (8) 8 such as ammonia-free gel (CN201310581681.0). Among them, (3), (5), (6), (7), and (8) the raw materials themselves include water-insoluble solid powder, and (1), (2), and (4) raw materials do not include water-insoluble solid powder materials, but their common feature is that "colloidal foam" needs to be made before spraying, and then sprayed. There are two problems: one is that the equipment may be blocked, even if it is not blocked, at least the equipment must be cleaned thoroughly after each use; the other is that the gas in the foam needs to occupy a large amount of injection flow of the injection equipment, reducing the fire extinguishing efficiency of the injection equipment , the third is that the solids therein will increase the resistance of delivery and injection, wasting energy.

发明内容Contents of the invention

为解决上述技术问题,本发明提供一种二氧化碳胶体泡沫灭火装置,该装置喷出的泡沫在火灾现场生成胶体隔离膜,胶体颗粒微细,结合能力强、覆盖面积大,灭火能力强,灭火成本低,本装置结构简单,容易操作。In order to solve the above technical problems, the present invention provides a carbon dioxide colloidal foam fire extinguishing device, the foam sprayed by the device forms a colloidal isolation film at the fire scene, the colloidal particles are fine, the binding ability is strong, the coverage area is large, the fire extinguishing ability is strong, and the fire extinguishing cost is low , the device has a simple structure and is easy to operate.

本发明所采用的技术方案是:二氧化碳胶体泡沫灭火装置,包括混合罐,混合罐的上部设有稀释液入口管,混合罐的下部分别设有气体入口管和混合液出口管,所述混合液出口管依次连接有高压管Ⅱ和喷嘴,混合液出口管上沿液体流出方向依次设有单向阀Ⅲ、阀门Ⅲ和节流阀;所述气体入口管的末端连接至液体二氧化碳钢瓶,气体入口管上自混合罐至液体二氧化碳钢瓶之间依次设有单向阀Ⅰ、阀门Ⅰ和减压阀;所述稀释液入口管的末端与高压管Ⅰ连接并连通,高压管Ⅰ通过液压泵连通至稀释罐,稀释液入口管上自反应罐至稀释罐之间依次设有单向阀Ⅱ和阀门Ⅱ;The technical scheme adopted in the present invention is: a carbon dioxide colloidal foam fire extinguishing device, comprising a mixing tank, the upper part of the mixing tank is provided with a dilution liquid inlet pipe, and the lower part of the mixing tank is respectively provided with a gas inlet pipe and a mixed liquid outlet pipe, and the mixed liquid The outlet pipe is connected with the high-pressure pipe II and the nozzle in turn, and the outlet pipe of the mixed liquid is provided with a one-way valve III, a valve III and a throttle valve in sequence along the liquid outflow direction; the end of the gas inlet pipe is connected to the liquid carbon dioxide cylinder, and the gas inlet A one-way valve Ⅰ, a valve Ⅰ and a pressure reducing valve are arranged in sequence on the pipe from the mixing tank to the liquid carbon dioxide cylinder; Dilution tank, the diluent inlet pipe is provided with check valve II and valve II in sequence from the reaction tank to the dilution tank;

所述稀释罐内按照1:(20~40)的重量比混合有二氧化碳胶体灭火剂和水,二氧化碳胶体灭火剂按照重量份数由以下原料制成:尿素5-11份、六水氯化镁6-13份、椰子油脂肪酸二乙醇酰胺4-10份、硼砂1-7份、磷酸1-4份和水68-70份。The dilution tank is mixed with carbon dioxide colloidal fire extinguishing agent and water according to the weight ratio of 1: (20-40), and the carbon dioxide colloidal fire extinguishing agent is made of the following raw materials according to parts by weight: urea 5-11 parts, magnesium chloride hexahydrate 6- 13 parts, 4-10 parts of coconut oil fatty acid diethanolamide, 1-7 parts of borax, 1-4 parts of phosphoric acid and 68-70 parts of water.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述混合罐的顶部设有压力表。As a further optimization of the carbon dioxide colloidal foam fire extinguishing device of the present invention, a pressure gauge is provided on the top of the mixing tank.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述混合罐通过支脚支撑。As a further optimization of the carbon dioxide colloidal foam fire extinguishing device of the present invention, the mixing tank is supported by feet.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述混合罐的侧面设有液位计。As a further optimization of the carbon dioxide colloidal foam fire extinguishing device of the present invention, a liquid level gauge is provided on the side of the mixing tank.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述的二氧化碳胶体灭火剂按照重量份数由以下原料制成:尿素10.35份、六水氯化镁12.05份、椰子油脂肪酸二乙醇酰胺4.12份、硼砂2.82份、磷酸1.64份和水69.02份。As a further optimization of a carbon dioxide colloid foam fire extinguishing device of the present invention, the carbon dioxide colloid fire extinguishing agent is made of the following raw materials in parts by weight: 10.35 parts of urea, 12.05 parts of magnesium chloride hexahydrate, 4.12 parts of coconut oil fatty acid diethanolamide, 2.82 parts of borax, 1.64 parts of phosphoric acid and 69.02 parts of water.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述的二氧化碳胶体灭火剂按照重量份数由以下原料制成:尿素8.13份、六水氯化镁9.46份、椰子油脂肪酸二乙醇酰胺6.48份、硼砂4.44份、磷酸2.58份和水68.91份。As a further optimization of a carbon dioxide colloid foam fire extinguishing device of the present invention, the carbon dioxide colloid fire extinguishing agent is made of the following raw materials in parts by weight: 8.13 parts of urea, 9.46 parts of magnesium chloride hexahydrate, 6.48 parts of coconut oil fatty acid diethanolamide, 4.44 parts of borax, 2.58 parts of phosphoric acid and 68.91 parts of water.

作为本发明一种二氧化碳胶体泡沫灭火装置的进一步优化,所述的二氧化碳胶体灭火剂按照重量份数由以下原料制成:尿素5.69份、六水氯化镁6.62份、椰子油脂肪酸二乙醇酰胺9.07份、硼砂6.21份、磷酸3.61份和水68.8份。As a further optimization of a carbon dioxide colloid foam fire extinguishing device of the present invention, the carbon dioxide colloid fire extinguishing agent is made of the following raw materials in parts by weight: 5.69 parts of urea, 6.62 parts of magnesium chloride hexahydrate, 9.07 parts of coconut oil fatty acid diethanolamide, 6.21 parts of borax, 3.61 parts of phosphoric acid and 68.8 parts of water.

与现有技术相比,本发明至少具有下述优点及有益效果:Compared with the prior art, the present invention has at least the following advantages and beneficial effects:

本发明提供的自发泡胶体泡沫灭火装置喷出的泡沫在火灾现场生成胶体隔离膜,胶体颗粒微细,结合能力强、覆盖面积大;同样体积的原料,灭火能力成几倍提高,灭火成本显著下降。The foam sprayed by the self-foaming colloidal foam fire extinguishing device provided by the present invention forms a colloidal isolation film at the fire scene, and the colloidal particles are fine, with strong binding ability and large coverage area; with the same volume of raw materials, the fire extinguishing ability is increased several times, and the fire extinguishing cost is significantly reduced .

本发明的灭火剂本身及灭火后的生成物无毒无害,既节水又小污染,既适用于密度大于水的燃烧物灭火,也适用于密度小于水的燃烧物灭火,适用范围广。本发明的装置结构简单,操作方便,通过与自发泡胶体泡沫灭火剂相结合,灭火效率较高。The fire extinguishing agent itself and the products after fire extinguishing are non-toxic and harmless, save water and cause little pollution, and are suitable for extinguishing fires of combustibles with a density greater than water and with densities smaller than water, and have a wide range of applications. The device of the present invention has simple structure and convenient operation, and is combined with the self-foaming colloidal foam fire extinguishing agent to have high fire extinguishing efficiency.

本发明喷出的泡沫到达火场后随着温度升高泡沫变大,另一方面尿素受热会发生缩聚生成不可燃烧的二聚、三聚或多聚体(统称为缩脲),从而把镁离子释放出来,与自带的磷酸、硼酸、二氧化碳及燃烧产生的二氧化碳生成磷酸镁、硼酸镁、碱式碳酸镁或碳酸镁,它们与缩脲一起形成一层泡沫胶体膜覆盖在可燃物上,起到灭火作用,且灭火作用显著。After the foam sprayed by the present invention reaches the fire site, the foam becomes larger as the temperature rises. On the other hand, urea will undergo polycondensation when heated to form incombustible dimers, trimers or polymers (collectively referred to as urets), so that the magnesium ions Released, with its own phosphoric acid, boric acid, carbon dioxide and carbon dioxide produced by combustion to generate magnesium phosphate, magnesium borate, basic magnesium carbonate or magnesium carbonate, which together with uret form a layer of foam colloid film to cover the combustibles. To the fire extinguishing effect, and the fire extinguishing effect is significant.

附图说明Description of drawings

图1为本发明的结构示意图;Fig. 1 is a structural representation of the present invention;

附图标记:1、支脚,2、气体入口管,3、液体二氧化碳钢瓶,4、单向阀Ⅰ,5、阀门Ⅰ,6、减压阀,7、液位计,8、混合液,9、气体腔,10、压力表,11、稀释液入口管,12、单向阀Ⅱ,13、阀门Ⅱ,14、高压管Ⅰ,15、液压泵,16、搅拌器,17、稀释液,18、稀释罐,19、喷嘴,20、高压管Ⅱ,21、阀门Ⅲ,22、单向阀Ⅲ,23、混合液出口管,24、混合罐,25、节流阀。Reference signs: 1. Leg, 2. Gas inlet pipe, 3. Liquid carbon dioxide cylinder, 4. One-way valve I, 5, Valve I, 6. Pressure reducing valve, 7. Liquid level gauge, 8. Mixed liquid, 9 , gas chamber, 10, pressure gauge, 11, diluent inlet pipe, 12, one-way valve Ⅱ, 13, valve Ⅱ, 14, high pressure pipe Ⅰ, 15, hydraulic pump, 16, agitator, 17, diluent, 18 , dilution tank, 19, nozzle, 20, high-pressure pipe II, 21, valve III, 22, one-way valve III, 23, mixed solution outlet pipe, 24, mixing tank, 25, throttle valve.

具体实施方式Detailed ways

为使本发明的内容更明显易懂,以下结合具体实施例,对本发明进行详细描述。In order to make the content of the present invention more obvious and understandable, the present invention will be described in detail below in conjunction with specific embodiments.

如图1所示,二氧化碳胶体泡沫灭火装置,包括混合罐24,混合罐24的顶部设有压力表10,混合罐24通过支脚1支撑,混合罐24的侧面设有液位计7,混合罐24的上部设有稀释液入口管11,混合罐24的下部分别设有气体入口管2和混合液出口管23,所述混合液出口管23依次连接有高压管Ⅱ20和喷嘴19,混合液出口管23上沿液体流出方向依次设有单向阀Ⅲ22、阀门Ⅲ21和节流阀25;所述气体入口管2的末端连接至液体二氧化碳钢瓶3,气体入口管2上自混合罐24至液体二氧化碳钢瓶3之间依次设有单向阀Ⅰ4、阀门Ⅰ5和减压阀6;所述稀释液入口管11的末端与高压管Ⅰ14连接并连通,高压管Ⅰ14通过液压泵15连通至稀释罐18,稀释液入口管11上自混合罐24至稀释罐18之间依次设有单向阀Ⅱ12和阀门Ⅱ13;As shown in Figure 1, the carbon dioxide colloidal foam fire extinguishing device comprises mixing tank 24, and the top of mixing tank 24 is provided with pressure gauge 10, and mixing tank 24 is supported by leg 1, and the side of mixing tank 24 is provided with liquid level gauge 7, mixing tank The upper part of 24 is provided with dilution liquid inlet pipe 11, and the lower part of mixing tank 24 is respectively provided with gas inlet pipe 2 and mixed liquid outlet pipe 23, and described mixed liquid outlet pipe 23 is connected with high-pressure pipe II 20 and nozzle 19 in sequence, and mixed liquid outlet The pipe 23 is provided with a one-way valve III22, a valve III21 and a throttle valve 25 sequentially along the liquid outflow direction; the end of the gas inlet pipe 2 is connected to the liquid carbon dioxide steel cylinder 3, and the gas inlet pipe 2 is connected from the mixing tank 24 to the liquid carbon dioxide A one-way valve I4, a valve I5 and a pressure reducing valve 6 are sequentially arranged between the steel cylinders 3; the end of the diluent inlet pipe 11 is connected and communicated with the high-pressure pipe I14, and the high-pressure pipe I14 is connected to the dilution tank 18 through the hydraulic pump 15, A one-way valve II12 and a valve II13 are sequentially provided on the dilution liquid inlet pipe 11 from the mixing tank 24 to the dilution tank 18;

所述稀释罐18内按照1:(20~40)的重量比混合有二氧化碳胶体灭火剂和水,二氧化碳胶体灭火剂按照重量份数由以下原料制成:尿素5-11份、六水氯化镁6-13份、椰子油脂肪酸二乙醇酰胺4-10份、硼砂1-7份、磷酸1-4份和水68-70份。The dilution tank 18 is mixed with carbon dioxide colloid fire extinguishing agent and water according to the weight ratio of 1: (20-40), and the carbon dioxide colloid fire extinguishing agent is made of the following raw materials in parts by weight: 5-11 parts of urea, 6 parts of magnesium chloride hexahydrate -13 parts, 4-10 parts of coconut oil fatty acid diethanolamide, 1-7 parts of borax, 1-4 parts of phosphoric acid and 68-70 parts of water.

配方一、所述的二氧化碳胶体低起泡性灭火剂按照重量份数由以下原料制成:尿素10.35份、六水氯化镁12.05份、椰子油脂肪酸二乙醇酰胺4.12份、硼砂2.82份、磷酸1.64份和水69.02份。Formula 1. The carbon dioxide colloidal low-foaming fire extinguishing agent is made of the following raw materials in parts by weight: 10.35 parts of urea, 12.05 parts of magnesium chloride hexahydrate, 4.12 parts of coconut oil fatty acid diethanolamide, 2.82 parts of borax, and 1.64 parts of phosphoric acid and 69.02 parts of water.

配方二、所述的二氧化碳胶体中起泡性灭火剂按照重量份数由以下原料制成:尿素8.13份、六水氯化镁9.46份、椰子油脂肪酸二乙醇酰胺6.48份、硼砂4.44份、磷酸2.58份和水68.91份。Formula 2, the foaming fire extinguishing agent in the carbon dioxide colloid is made of the following raw materials according to parts by weight: 8.13 parts of urea, 9.46 parts of magnesium chloride hexahydrate, 6.48 parts of coconut oil fatty acid diethanolamide, 4.44 parts of borax, and 2.58 parts of phosphoric acid and 68.91 parts of water.

配方三、所述的二氧化碳胶体高起泡性灭火剂按照重量份数由以下原料制成:尿素5.69份、六水氯化镁6.62份、椰子油脂肪酸二乙醇酰胺9.07份、硼砂6.21份、磷酸3.61份和水68.8份。Formula 3. The carbon dioxide colloidal high-foaming fire extinguishing agent is made of the following raw materials in parts by weight: 5.69 parts of urea, 6.62 parts of magnesium chloride hexahydrate, 9.07 parts of coconut oil fatty acid diethanolamide, 6.21 parts of borax, and 3.61 parts of phosphoric acid and 68.8 parts of water.

所述的自发泡二氧化碳胶体灭火剂的配制方法,包括以下步骤:The preparation method of described self-foaming carbon dioxide colloid fire extinguishing agent comprises the following steps:

步骤一、先按照上述重量份数取原料尿素、六水氯化镁、椰子油脂肪酸二乙醇酰胺、硼砂、磷酸和水,备用;Step 1, first take the raw materials urea, magnesium chloride hexahydrate, coconut oil fatty acid diethanolamide, borax, phosphoric acid and water according to the above parts by weight, and set aside;

步骤二、在搅拌反应罐中,先加入步骤一得到的40%重量的水,开启搅拌器,控制温度为100℃加热,然后依次加入磷酸、硼砂,使其溶解;Step 2. In the stirred reaction tank, first add 40% by weight of water obtained in Step 1, turn on the stirrer, control the temperature to 100°C for heating, then add phosphoric acid and borax in turn to dissolve it;

步骤三、在另一个容器中,取步骤一得到的40%重量的水,加入尿素、六水氯化镁,搅拌溶解后将其加入到步骤二的搅拌反应罐中,再加入椰子油脂肪酸二乙醇酰胺搅拌均匀;Step 3: In another container, take 40% by weight of water obtained in Step 1, add urea and magnesium chloride hexahydrate, stir and dissolve, then add it to the stirring reaction tank of Step 2, and then add coconut oil fatty acid diethanolamide Stir well;

步骤四、用余量的水洗涤所用容器、工具,并把洗涤水加入到搅拌反应罐中,搅拌均匀即可得到自发泡胶体泡沫灭火剂。Step 4, washing the used containers and tools with the rest of the water, adding the washing water into the stirring reaction tank, and stirring evenly to obtain the self-foaming colloidal foam fire extinguishing agent.

本发明自发泡二氧化碳胶体灭火剂在使用时,按1:(20~40)稀释,用液压泵(压力≥1MPa)抽吸稀释液,用二氧化碳液体钢瓶供给二氧化碳(耗用重量等于灭火剂原液重量的10~20%),让稀释液和二氧化碳分别沿混合罐侧壁的切线相同方向进入混合罐,经旋转混合,使二氧化碳溶于稀释液中形成混合液。在混合罐侧壁还设有一个切线方向的输送管,输送管另一端连接一个喇叭形喷嘴,这样就可以把混合液输送到灭火现场。When the self-foaming carbon dioxide colloidal fire extinguishing agent of the present invention is in use, dilute it according to 1: (20-40), pump the diluent with a hydraulic pump (pressure ≥ 1MPa), and supply carbon dioxide with a carbon dioxide liquid steel cylinder (the consumption weight is equal to the weight of the stock solution of the fire extinguishing agent) 10-20% of the total), let the diluent and carbon dioxide enter the mixing tank in the same direction along the tangent of the side wall of the mixing tank, and rotate and mix to make the carbon dioxide dissolve in the diluent to form a mixed solution. A delivery pipe in a tangential direction is also arranged on the side wall of the mixing tank, and the other end of the delivery pipe is connected with a horn-shaped nozzle, so that the mixed solution can be delivered to the fire extinguishing site.

在混合液离开喷嘴之前,一方面由于二氧化碳在压力作用下能溶于混合液中,另一方面氯化镁与尿素形成了配合物,也不会产生镁化合物沉淀,混合液是澄清的。一旦混合液离开喷嘴,压力减小,溶解的二氧化碳析出、膨胀,在表面活性剂6501(椰子油脂肪酸二乙醇酰胺)的作用下,混合液将变成泡沫。Before the mixed liquid leaves the nozzle, on the one hand, carbon dioxide can dissolve in the mixed liquid under pressure, and on the other hand, magnesium chloride and urea form a complex, and magnesium compound precipitation will not occur, so the mixed liquid is clear. Once the mixture leaves the nozzle, the pressure decreases, and the dissolved carbon dioxide precipitates and expands. Under the action of surfactant 6501 (coconut oil fatty acid diethanolamide), the mixture will become foam.

当泡沫到达火场后,由于温度升高,一方面泡沫会变大,另一方面尿素受热会发生缩聚生成不可燃烧的二聚、三聚或多聚体(统称为缩脲),势必把镁离子释放出来,与自带的磷酸、硼酸、二氧化碳及燃烧产生的二氧化碳生成磷酸镁、硼酸镁、碱式碳酸镁或碳酸镁,它们与缩脲一起形成一层泡沫胶体膜覆盖在可燃物上,起到灭火作用。When the foam reaches the fire site, due to the increase in temperature, on the one hand, the foam will become larger; Released, with its own phosphoric acid, boric acid, carbon dioxide and carbon dioxide produced by combustion to generate magnesium phosphate, magnesium borate, basic magnesium carbonate or magnesium carbonate, which together with uret form a layer of foam colloid film to cover the combustibles. to the fire extinguishing effect.

一、本发明灭火装置的使用方法One, the using method of fire extinguishing device of the present invention

1、根据灭火对象对泡沫密度的要求,在稀释罐18中加入定量水,启动搅拌器16,而后按(20~40):1的比例加入成品胶体灭火剂,搅匀。1. According to the foam density requirements of the fire extinguishing object, add quantitative water into the dilution tank 18, start the agitator 16, and then add the finished colloidal fire extinguishing agent according to the ratio of (20-40): 1, and stir well.

2、开启阀门Ⅱ13,用液压泵15(压力≥1MPa)把稀释液17输送到混合罐24中,当液面到达液位计7的中上部时,关闭液压泵15。2. Open the valve II13, and use the hydraulic pump 15 (pressure ≥ 1MPa) to deliver the diluent 17 to the mixing tank 24. When the liquid level reaches the middle and upper part of the liquid level gauge 7, close the hydraulic pump 15.

3、开启液体二氧化碳钢瓶总阀,调节减压阀6,使混合液液面保持在可观察范围内,观察压力表10,并实时调节减压阀6,使二氧化碳的压力不低于压力表10的压力。3. Open the main valve of the liquid carbon dioxide cylinder, adjust the pressure reducing valve 6 to keep the mixed liquid level within the observable range, observe the pressure gauge 10, and adjust the pressure reducing valve 6 in real time so that the pressure of carbon dioxide is not lower than the pressure gauge 10 pressure.

4、当压力表10的压力达到喷射压力要求后,让喷嘴对准灭火目标,而后适当开启节流阀25启动液压泵15,同时开启阀门Ⅲ21,再调节节流阀25,以能维持混合罐24的目标压力为准,进行灭火。4. When the pressure of the pressure gauge 10 reaches the injection pressure requirement, aim the nozzle at the fire extinguishing target, then properly open the throttle valve 25 to start the hydraulic pump 15, open the valve III 21 at the same time, and then adjust the throttle valve 25 to maintain the mixing tank 24 target pressure shall prevail to extinguish the fire.

5、注意观察液位计7、当液面上升时,应适当增加减压阀的输出压力,当液面下降时,应调小节流阀25的流量;同时注意稀释罐的液面,及时补充水和胶体灭火剂,补充的方法是:另取一个容器按比例加入水和胶体灭火剂,简单搅拌后加入到稀释罐中即可。5. Pay attention to observe the liquid level gauge. 7. When the liquid level rises, the output pressure of the pressure reducing valve should be appropriately increased. When the liquid level drops, the flow rate of the throttle valve 25 should be reduced; meanwhile, pay attention to the liquid level of the dilution tank and replenish For water and colloidal fire extinguishing agent, the supplementary method is: take another container and add water and colloidal fire extinguishing agent in proportion, simply stir and add to the dilution tank.

6、灭火完毕,先关闭阀门Ⅰ5,再关闭钢瓶总阀、液压泵电源、阀门Ⅱ13、阀门Ⅲ21,并断开钢瓶与混合罐24的连接,放出残留的二氧化碳。6. After extinguishing the fire, first close the valve I5, then close the main valve of the steel cylinder, the power supply of the hydraulic pump, the valve II13, and the valve III21, and disconnect the connection between the steel cylinder and the mixing tank 24 to release the residual carbon dioxide.

7、值班消防设备,一般只需清洗输送管道,若长期不用,则需用清水清洗混合罐24、稀释罐18,及相关管道。7. The fire-fighting equipment on duty generally only needs to clean the conveying pipeline. If it is not used for a long time, it needs to clean the mixing tank 24, the dilution tank 18, and related pipelines with clean water.

实施例1(平面油类火灾灭火)Embodiment 1 (plane oil fire extinguishing)

在一个空旷场地,挖一个深5~6mm、面积约为1m2的凹地,铺上一层塑料薄膜,塑料薄膜的边超出凹地边约10cm,以土覆盖超出部分。在塑料薄膜凹陷处加入柴油,使油面能布满凹坑。In an open field, dig a depression with a depth of 5-6mm and an area of about 1m2, spread a layer of plastic film, the edge of the plastic film is about 10cm beyond the edge of the depression, and cover the excess with soil. Add diesel oil to the depression of the plastic film so that the oil surface can be covered with pits.

灭火实验过程如下:The fire extinguishing experiment process is as follows:

1、选用配方三的产品。在稀释罐18中加入定量水,启动搅拌器16,而后按40:1的比例加入成品胶体灭火剂,搅匀。1. Select the product of formula three. Add quantitative water into the dilution tank 18, start the agitator 16, then add the finished colloidal fire extinguishing agent in a ratio of 40:1, and stir well.

2、开启阀门Ⅱ13,用液压泵15(0.6MPa)把稀释液17输送到混合罐24中,当液面到达液位计7的中上部时,关闭液压泵15。2. Open the valve II13, and use the hydraulic pump 15 (0.6MPa) to deliver the diluent 17 to the mixing tank 24. When the liquid level reaches the middle and upper part of the liquid level gauge 7, close the hydraulic pump 15.

3、开启液体二氧化碳钢瓶总阀,调节减压阀6,使混合液液面保持在可观察范围内,观察压力表10,并实时调节减压阀6,使二氧化碳的压力不低于压力表10的压力(0.6MPa)。3. Open the main valve of the liquid carbon dioxide cylinder, adjust the pressure reducing valve 6 to keep the mixed liquid level within the observable range, observe the pressure gauge 10, and adjust the pressure reducing valve 6 in real time so that the pressure of carbon dioxide is not lower than the pressure gauge 10 pressure (0.6MPa).

4、当压力表10的压力达到喷射压力要求后,让喷嘴对准灭火目标,而后适当开启节流阀25启动液压泵15,同时开启阀门Ⅲ21,再调节节流阀25,以能维持混合罐24的目标压力为准,进行灭火。4. When the pressure of the pressure gauge 10 reaches the injection pressure requirement, aim the nozzle at the fire extinguishing target, then properly open the throttle valve 25 to start the hydraulic pump 15, open the valve III 21 at the same time, and then adjust the throttle valve 25 to maintain the mixing tank 24 target pressure shall prevail to extinguish the fire.

5、本实施例输送管20的管径为5mm,但喷嘴喷出的泡沫柱的直径约为50mm,喷射水平距离约15m。5. The diameter of the delivery pipe 20 in this embodiment is 5mm, but the diameter of the foam column sprayed out by the nozzle is about 50mm, and the spraying horizontal distance is about 15m.

6、点燃柴油后火焰迅速蔓延、并覆盖凹坑。让泡沫柱由近到远喷到凹坑上,内侧火焰边界逐步移向远处,并很快熄灭。6. After the diesel is ignited, the flame spreads rapidly and covers the pits. Let the foam column spray on the pit from near to far, and the inner flame boundary will gradually move to the distance, and will be extinguished soon.

6、灭火完毕,先关闭阀门Ⅰ5,再关闭钢瓶总阀、液压泵电源、阀门Ⅱ13、阀门Ⅲ21,并断开钢瓶与混合罐24的连接,放出残留的二氧化碳。6. After extinguishing the fire, first close the valve I5, then close the main valve of the steel cylinder, the power supply of the hydraulic pump, the valve II13, and the valve III21, and disconnect the connection between the steel cylinder and the mixing tank 24 to release the residual carbon dioxide.

用同样的方式(清除浮于柴油表面的泡沫残留物,补充柴油),对本发明胶体灭火剂的配方Ⅰ、Ⅱ进行了实验,稀释比例分别为1:20和1:30,除了胶体灭火剂用量不同外,灭火效果未见明显差异。这显然与燃油均处于同一平面有关。In the same way (remove the foam residue floating on the surface of the diesel oil, supplement the diesel oil), the formulations I and II of the colloid fire extinguishing agent of the present invention were tested, and the dilution ratios were 1:20 and 1:30 respectively, except that the amount of the colloid fire extinguishing agent There was no significant difference in the fire extinguishing effect except for the difference. This obviously has something to do with the fuel being on the same plane.

实施例2(不规则油面燃烧灭火)Embodiment 2 (fire extinguishing by irregular oil surface combustion)

在一个空旷场地,挖一个深5~6mm、面积约为1m2的凹地,铺上一层塑料薄膜,塑料薄膜的边超出凹地边约10cm,以土覆盖超出部分。在塑料薄膜凹陷处架起横、竖的木材,而后浇上柴油,并使油面能布满凹坑。In an open field, dig a depression with a depth of 5-6mm and an area of about 1m2, spread a layer of plastic film, the edge of the plastic film is about 10cm beyond the edge of the depression, and cover the excess with soil. Set up horizontal and vertical timbers in the depressions of the plastic film, then pour diesel oil, and make the oil surface be full of pits.

灭火实验过程如下:The fire extinguishing experiment process is as follows:

1、选用配方三的产品。在稀释罐18中加入定量水,启动搅拌器16,而后按40:1的比例加入成品胶体灭火剂,搅匀。1. Select the product of formula three. Add quantitative water into the dilution tank 18, start the agitator 16, then add the finished colloidal fire extinguishing agent in a ratio of 40:1, and stir well.

2、开启阀门Ⅱ13,用液压泵15(0.6MPa)把稀释液17输送到混合罐24中,当液面到达液位计7的中上部时,关闭液压泵15。2. Open the valve II13, and use the hydraulic pump 15 (0.6MPa) to deliver the diluent 17 to the mixing tank 24. When the liquid level reaches the middle and upper part of the liquid level gauge 7, close the hydraulic pump 15.

3、开启液体二氧化碳钢瓶总阀,调节减压阀6,使混合液液面保持在可观察范围内,观察压力表10,并实时调节减压阀6,使二氧化碳的压力不低于压力表10的压力(0.6MPa)。3. Open the main valve of the liquid carbon dioxide cylinder, adjust the pressure reducing valve 6 to keep the mixed liquid level within the observable range, observe the pressure gauge 10, and adjust the pressure reducing valve 6 in real time so that the pressure of carbon dioxide is not lower than the pressure gauge 10 pressure (0.6MPa).

4、当压力表10的压力达到喷射压力要求后,让喷嘴对准灭火目标,而后适当开启节流阀25启动液压泵15,同时开启阀门Ⅲ21,再调节节流阀25,以能维持混合罐24的目标压力为准,进行灭火。4. When the pressure of the pressure gauge 10 reaches the injection pressure requirement, aim the nozzle at the fire extinguishing target, then properly open the throttle valve 25 to start the hydraulic pump 15, open the valve III 21 at the same time, and then adjust the throttle valve 25 to maintain the mixing tank 24 target pressure shall prevail to extinguish the fire.

5、本实施例输送管20的管径为5mm,但喷嘴喷出的泡沫柱的直径约为50mm,喷射水平距离约15m。5. The diameter of the delivery pipe 20 in this embodiment is 5mm, but the diameter of the foam column sprayed out by the nozzle is about 50mm, and the spraying horizontal distance is about 15m.

6、点燃柴油后火焰迅速蔓延、遍及木材及凹坑,让泡沫柱由近到远喷火源,木材内侧及凹坑火焰熄灭,但木材远侧仍有火苗存在,直到从对面喷射,火苗才全部熄灭。6. After igniting the diesel, the flame spreads rapidly and spreads all over the wood and pits. Let the foam column spray the fire source from near to far. The flame inside the wood and the pits is extinguished, but there are still flames on the far side of the wood. It is not until the flame is sprayed from the opposite side. All off.

6、灭火完毕,先关闭阀门Ⅰ5,再关闭钢瓶总阀、液压泵电源、阀门Ⅱ13、阀门Ⅲ21,并断开钢瓶与混合罐24的连接,放出残留的二氧化碳。6. After extinguishing the fire, first close the valve I5, then close the main valve of the steel cylinder, the power supply of the hydraulic pump, the valve II13, and the valve III21, and disconnect the connection between the steel cylinder and the mixing tank 24 to release the residual carbon dioxide.

用同样的方式(更换木材并清除浮于柴油表面的泡沫残留物,补充柴油),对本发明胶体灭火剂的配方Ⅰ、Ⅱ进行了实验,稀释比例分别为1:20和1:30,发现配方一,抵抗残留火苗的能力最强。但都存在从单一方向喷射胶体泡沫难以将火苗全部扑灭。除非用胶体泡沫把可燃物完全埋没。In the same way (replacing the wood and removing the foam residue floating on the surface of the diesel oil, supplementing the diesel oil), the formulations I and II of the colloidal fire extinguishing agent of the present invention were tested, and the dilution ratios were 1:20 and 1:30 respectively. It was found that the formulations One, the ability to resist residual flames is the strongest. But all exist to spray colloidal foam from one direction and be difficult to all extinguish flame. Unless the combustibles are completely buried with colloidal foam.

实施例3(非油类火灾灭火)Embodiment 3 (non-oil fire extinguishing)

在一个空旷场地,用砖和泥浆筑起三面围墙,高度1.5m,长、均为1m,上面盖上一块1mm厚钢板,其内放入引火火把(蘸油)、木材,泡沫塑料、废旧衣物,堆积成40cm厚的可燃物。In an open space, build three walls with bricks and mud, with a height of 1.5m and a length of 1m. A 1mm thick steel plate is covered on the top, and a fire torch (dipped in oil), wood, foam plastic, and waste clothes are placed in it. , piled up into 40cm thick combustibles.

灭火实验过程如下:The fire extinguishing experiment process is as follows:

1、选用配方三的产品。在稀释罐18中加入定量水,启动搅拌器16,而后按40:1的比例加入成品胶体灭火剂,搅匀。1. Select the product of formula three. Add quantitative water into the dilution tank 18, start the agitator 16, then add the finished colloidal fire extinguishing agent in a ratio of 40:1, and stir well.

2、开启阀门Ⅱ13,用液压泵15(0.6MPa)把稀释液17输送到混合罐24中,当液面到达液位计7的中上部时,关闭液压泵15。2. Open the valve II13, and use the hydraulic pump 15 (0.6MPa) to deliver the diluent 17 to the mixing tank 24. When the liquid level reaches the middle and upper part of the liquid level gauge 7, close the hydraulic pump 15.

3、开启液体二氧化碳钢瓶总阀,调节减压阀6,使混合液液面保持在可观察范围内,观察压力表10,并实时调节减压阀6,使二氧化碳的压力不低于压力表10的压力(0.6MPa)。3. Open the main valve of the liquid carbon dioxide cylinder, adjust the pressure reducing valve 6 to keep the mixed liquid level within the observable range, observe the pressure gauge 10, and adjust the pressure reducing valve 6 in real time so that the pressure of carbon dioxide is not lower than the pressure gauge 10 pressure (0.6MPa).

4、当压力表10的压力达到喷射压力要求后,让喷嘴对准灭火目标,而后适当开启节流阀25启动液压泵15,同时开启阀门Ⅲ21,再调节节流阀25,以能维持混合罐24的目标压力为准,进行灭火。4. When the pressure of the pressure gauge 10 reaches the injection pressure requirement, aim the nozzle at the fire extinguishing target, then properly open the throttle valve 25 to start the hydraulic pump 15, open the valve III 21 at the same time, and then adjust the throttle valve 25 to maintain the mixing tank 24 target pressure shall prevail to extinguish the fire.

5、本实施例输送管20的管径为5mm,但喷嘴喷出的泡沫柱的直径约为50mm,喷射水平距离约15m。5. The diameter of the delivery pipe 20 in this embodiment is 5mm, but the diameter of the foam column sprayed out by the nozzle is about 50mm, and the spraying horizontal distance is about 15m.

6、点燃火把,并让火焰充满试验空间后开始灭火,不到1分钟,火焰熄灭,胶体泡沫在可燃物上覆盖了一层约1cm的胶体泡沫。6、灭火完毕,先关闭阀门Ⅰ5,再关闭钢瓶总阀、液压泵电源、阀门Ⅱ13、阀门Ⅲ21,并断开钢瓶与混合罐24的连接,放出残留的二氧化碳。6. Light the torch, let the flame fill the test space, and then start to extinguish the fire. In less than 1 minute, the flame goes out, and the colloidal foam covers the combustibles with a layer of colloidal foam of about 1cm. 6. After extinguishing the fire, first close the valve I5, then close the main valve of the steel cylinder, the power supply of the hydraulic pump, the valve II13, and the valve III21, and disconnect the connection between the steel cylinder and the mixing tank 24 to release the residual carbon dioxide.

用同样的方式(更换木材并清除浮于柴油表面的泡沫残留物,补充柴油),对本发明胶体灭火剂的配方Ⅰ、Ⅱ进行了实验,稀释比例分别为1:20和1:30,发现均可以实现快速灭火,但以配方三的灭火速度最快。In the same way (replacing the wood and removing the foam residue floating on the surface of the diesel oil, supplementing the diesel oil), the formulations I and II of the colloidal fire extinguishing agent of the present invention were tested, and the dilution ratios were 1:20 and 1:30 respectively. Rapid fire extinguishing can be achieved, but the fire extinguishing speed of formula three is the fastest.

现场当时观察的情况是,三个配方都可以看到泡沫的泡由小变大,最后破裂,1h后观察,配方一的灭火后残留物,发现可燃物上表面均覆盖了一层薄薄的胶体膜。The situation observed at the scene at the time was that the bubbles of the three formulas could be seen to grow from small to large, and finally burst. After 1 hour of observation, the residue after extinguishing the fire of formula 1 was found to be covered with a thin layer of foam on the upper surface of the combustible Colloidal film.

本说明书的实施例,仅用来说明本发明,因此在不违背本发明结构、原理的情况下,相关专业人员很容易结合行业专业实际设计出本发明的各种变体,出现这种情况,本发明设计者认为应视为对本发明的侵权。The embodiments of this specification are only used to illustrate the present invention. Therefore, without violating the structure and principle of the present invention, relevant professionals can easily design various variants of the present invention in combination with the professional practice of the industry. In this case, The designer of the present invention considers it to be an infringement of the present invention.

Claims (7)

1. carbon dioxide colloidal foam extinguishing device, it is characterised in that:Including blending tank(24), blending tank(24)Top be provided with Dilution inlet tube(11), blending tank(24)Bottom be respectively equipped with gas inlet pipe(2)With mixture export pipe(23), it is described Mixture export pipe(23)It is connected with high-voltage tube II in turn(20)And nozzle(19), mixture export pipe(23)On flowed out along liquid Direction is sequentially provided with check valve III(22), valve III(21)And choke valve(25);The gas inlet pipe(2)End be connected to Liquid CO 2 steel cylinder(3), gas inlet pipe(2)On from blending tank(24)To liquid CO 2 steel cylinder(3)Between successively Provided with check valve I(4), valve I(5)And pressure-reducing valve(6);The dilution inlet tube(11)End and high-voltage tube I(14)Even Connect and connect, high-voltage tube I(14)Pass through hydraulic pump(15)It is communicated to thinning tank(18), dilution inlet tube(11)On from blending tank (24)To thinning tank(18)Between be sequentially provided with check valve II(12)With valve II(13);
The thinning tank(18)It is interior according to 1:(20~40)Weight ratio be mixed with carbon dioxide Gel Extinguishing Technology and water, titanium dioxide Carbon colloid extinguishing chemical is made up according to parts by weight of following raw material:Urea 5-11 parts, magnesium chloride hexahydrate 6-13 parts, coconut oil fat Sour diglycollic amide 4-10 parts, borax 1-7 parts, -4 parts of phosphatase 11 and water 68-70 parts.
2. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:The blending tank(24)Top Portion is provided with pressure gauge(10).
3. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:The blending tank(24)Pass through Leg(1)Support.
4. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:The blending tank(24)Side Face is provided with liquid level gauge(7).
5. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:Described carbon dioxide colloid Extinguishing chemical is made up according to parts by weight of following raw material:10.35 parts of urea, 12.05 parts of magnesium chloride hexahydrate, coco-nut oil fatty acid two 69.02 parts of 4.12 parts of glycollic amide, 2.82 parts of borax, phosphatase 11 .64 parts and water.
6. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:Described carbon dioxide colloid Extinguishing chemical is made up according to parts by weight of following raw material:8.13 parts of urea, 9.46 parts of magnesium chloride hexahydrate, coco-nut oil fatty acid diethyl 68.91 parts of 6.48 parts of alkylolamides, 4.44 parts of borax, 2.58 parts of phosphoric acid and water.
7. carbon dioxide colloidal foam extinguishing device as claimed in claim 1, it is characterised in that:Described carbon dioxide colloid Extinguishing chemical is made up according to parts by weight of following raw material:5.69 parts of urea, 6.62 parts of magnesium chloride hexahydrate, coco-nut oil fatty acid diethyl 68.8 parts of 9.07 parts of alkylolamides, 6.21 parts of borax, 3.61 parts of phosphoric acid and water.
CN201611053076.6A 2016-11-25 2016-11-25 Carbon dioxide colloidal foam extinguishing device Expired - Fee Related CN106581897B (en)

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CN108525168B (en) 2017-03-01 2021-05-28 中国石油化工股份有限公司 Foam generating method and application thereof and fire extinguishing method
CN111840870B (en) * 2020-07-22 2021-08-27 西安科技大学 Multi-agent combined fire extinguishing system and method based on liquid carbon dioxide

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CN101371944A (en) * 2008-08-22 2009-02-25 杭州新纪元安全产品有限公司 Extinguishment product using clear gas as sponging agent as well as production method and fire-extinguishing system
CN201664485U (en) * 2009-12-11 2010-12-08 江苏卡威专用汽车制造有限公司 Fixed type composite jet fire extinguishing device
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CN103007478A (en) * 2012-12-31 2013-04-03 西安科技大学 Fire extinguishing agent and preparation method thereof

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CN101371944A (en) * 2008-08-22 2009-02-25 杭州新纪元安全产品有限公司 Extinguishment product using clear gas as sponging agent as well as production method and fire-extinguishing system
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