CN106577724A - Composition containing thiamethoxam and js399-19, preparation method and application method - Google Patents
Composition containing thiamethoxam and js399-19, preparation method and application method Download PDFInfo
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- CN106577724A CN106577724A CN201610941100.3A CN201610941100A CN106577724A CN 106577724 A CN106577724 A CN 106577724A CN 201610941100 A CN201610941100 A CN 201610941100A CN 106577724 A CN106577724 A CN 106577724A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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Abstract
The invention provides a composition containing thiamethoxam and js399-19, a preparation method and an application method and relates to the technical field of production and application of pesticide taking insect killing and sterilization into consideration. The effective ingredients of the composition are the thiamethoxam and the js399-19. The thiamethoxam accounts for 5-10% of the total mass of the composition, and the js399-19 accounts for 10-20% of the total mass of the composition. The composition has the technical effect of taking insect killing and sterilization into consideration, is high in safety, long in lasting period and wide in suitable pesticide applying time range, can prevent rice premature senility, increase the yield and improve the rice quality, and meanwhile has the advantages of being low in toxicity, low in residue and environmentally friendly.
Description
Technical field
The present invention relates to production, the applied technical field of pesticide that parasite killing and sterilization take into account.
Background technology
Diacloden (thiamethoxam) belongs to second filial generation anabasine insecticide, i.e. sulfur nicotinic insecticide
(thianieotinylinsectides), its preparation is used for stem and leaf, soil and seed treatment.Diacloden is 1991 by Novartis
The anabasine insecticide of company's exploitation, its mechanism of action is similar to imidacloprid, and alternative suppresses insect CNS
Nicotinic acetylcholine esterase receptor, and then the normal conduction of insect CNS is blocked, when causing insect paralysis machine occur
It is dead.
Chemical name：3- (the chloro- 1,3- thiazoles -5- ylmethyls of 2-) -5- methyl isophthalic acids, 3,5- oxadiazines -4- bases fork (nitro)
Amine, molecular formula： C8H10ClN5O3S, molecular weight is：291.71, structural formula is as follows：
Diacloden not only have tag, the activity of stomach toxicity, interior suction, and with higher active, more preferable safety and wider
Insecticidal spectrum and its work fast, be to replace that those are high to mammalian toxicity, have residual and right the features such as the lasting period is long
The organophosphors of environmental pollution, carbamate, the preferable kind of organochlorine insecticides.To Homoptera, coleoptera, Diptera,
Lepidoptera, especially homoptera pest have high activity, can effectively prevent and treat various aphids, leafhopper, plant hopper, aleyrodid, chafer children
The insects such as worm, colorado potato bug, nematicide, ground beetle, leaf miner.With imidacloprid, Acetamiprid, Nitenpyram no interactions resistance.
Can be not only used for cauline leaf process, seed treatment and can also be used for soil treatment.Suitable for crop is rice class crop, Radix Betae, Brassica campestris L, Ma Ling
Potato, Cotton Gossypii, Kidney bean, fruit tree, Semen arachidis hypogaeae, Helianthi, Semen sojae atricolor, Nicotiana tabacum L. and mandarin orange etc..Use to crop safety, nothing under recommended dose
Poisoning.
Diacloden makes insect paralysis dead using its drug action mainly as insecticide in the neuronal transmission system of insecticide.
The medicament has tags, stomach toxicity, quick-acting, lasting period length, the features such as insecticidal spectrum is wide and has excellent preventive effect simultaneously to sucking insect
Very high insecticidal activity is shown in very low dosage.It is mainly used in preventing and treating Semen Tritici aestivi, Oryza sativa L., Cotton Gossypii, vegetable, fruit tree, Nicotiana tabacum L.
Coleoptera, Diptera, lepidoptera pest are had simultaneously efficient etc. the insect in various crop and cockroach, Coptotermes formosanus Shtrari., housefly etc. are defended
Raw insect have the efficient medicament it is fool proof to mammal, birds and aquatile to crop without poisoning.It is brown to rice grub
Plant hopper, white backed planthopper, small brown rice planthopper, rice green leafhopper, rice spider rafter stinkbug, star stinkbug, Nezara viridula smaragdula Fabricius. as, it is red must fleahopper, rice negative mixed worm, rice
Cylinder water snout moth's larva is efficient.It is effective to striped rice borer, oryza chinensis class.To veterinary antibiotics insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, Zhu
The latent fly of acrosternumhilare, small heart-eating peach worm, Fructus Citri tangerinae lyonetid, Caloptiliatheivora, striped flea-beetle, bean is efficient.Diagonal cured a red-spotted lizard, diamondback moth, two secret notes are chrysomelid,
Scirothrips dorsalis, onion thrips, golden thistle horse, Citrus golden thistle horse, soybean pod gall-midge, Fructus Lycopersici esculenti Liriomyza etc. are effectively.
2-cyano-3-amino-3-phenylancryic acetate is developed by Jiangsu Pesticide Research Institute Co., Ltd, is a kind of new type bactericide, chemical name
For 2- cyano group -3- amino -3- ethyl phenylacrylates, its structural formula is as follows：
2-cyano-3-amino-3-phenylancryic acetate belongs to 2- cyanoacrylate antibacterial, and its structure is novel, and model of action is unique.Its efficient, micro- poison,
Wide spectrum, low-residual, environmentally friendly, the head blight that causes to the Fusarium graminearum of Fusarium, fusarium moniliforme cause Oryza sativa L.
Bakanae disease, Fusarium oxysporum cause watermelon blight to have very high biological activity, the Fructus Cucumidis sativi downy mildew caused to Pseudoperonospora cubensis
Bacterial blight of rice, the microbial pepper anthracnose of Fructus Capsici anthrax, Bei Lunge Fructus Vitis viniferae seats chamber bacterium that disease, rice Xanthomonas cause
The ring rot of apple for causing also has certain inhibitory action.2-cyano-3-amino-3-phenylancryic acetate is poisoned to Apiss, silkworm low toxicity to fish, Carnis Coturnicis japonicae etc.,
Bio-concentration factor in fish body is less than 10, is weak bioconcentration pesticide.
Diacloden and 2-cyano-3-amino-3-phenylancryic acetate can be used as single dose pesticide in enterprising enforcement of crops, at present all achieved with agriculture chemical registration
Card.
Diacloden only has preventive effect as insecticide to the insect of crop, invalid in the disease that the same period is broken out to crops.Thiophene
The hydrolysis rate of worm piperazine increases with the rising of pH and the rising of temperature, but hardly degrades in acetone solvent.
2-cyano-3-amino-3-phenylancryic acetate is that a new and effective antibacterial only has preventive effect to the disease of crop, to the insect of crop without anti-
Effect.
The content of the invention
It is an object of the invention to provide a kind of compositionss containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate so as to soak seed or spray being used for
Pathogenic bacteria can not only be effectively killed during plant simultaneously can long-acting killing insect.
Effective ingredient containing Diacloden and the compositionss of 2-cyano-3-amino-3-phenylancryic acetate of the present invention is Diacloden and 2-cyano-3-amino-3-phenylancryic acetate, described
Diacloden accounts for the 5～10% of compositionss gross mass, and the 2-cyano-3-amino-3-phenylancryic acetate accounts for the 10～20% of compositionss gross mass.
The compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate are more than their single dose field recommended densities to the prevention effect of crop disease pest
Under prevention effect.The insect of crop can not only be killed using said composition in the disease pest generation phase, and can simultaneously prevent and kill off crop
Disease.Not only dart transfer but also the usage amount of pesticide had been reduced, had reduced the pollution to environment.After compounding, can be different
Site plays pesticide-germicide effect, so as to avoid because action site is single, single medicament life-time service causes pathogenic bacteria Drug resistance
Generation.The present invention will delay or reduce the Drug resistance of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate, drop after Diacloden and 2-cyano-3-amino-3-phenylancryic acetate compounding
Low persticide residue, reduces the pollution to environment.
In addition, the mass ratio of Diacloden of the present invention and 2-cyano-3-amino-3-phenylancryic acetate is 1: 2, synergy highest is 1.1901.
Following table is comparative test result（Ratio is mass ratio in table）：
Second purpose of the invention is the preparation method for proposing above product, is comprised the steps：
1）Acetone is sprayed on the mixture formed by Diacloden and calcium alginate, the calcium alginate for penetrating into Diacloden is obtained；
The present invention is first by Diacloden and calcium alginate mix homogeneously so that Diacloden is fully infiltered in the micropore of calcium alginate,
It is sprayed to using acetone again on the mixture formed by Diacloden and calcium alginate, acetone effect is the photodissociation for slowing down Diacloden,
Extend the shelf life of Diacloden, the calcium alginate for penetrating into Diacloden is obtained with this；
2）The calcium alginate and sodium alginate mix homogeneously of Diacloden will be penetrated into, makes sodium alginate and calcium alginate form cladding thiophene
The microsphere of worm piperazine, obtains the microsphere of cladding Diacloden；
3）Under stirring condition, the 2-cyano-3-amino-3-phenylancryic acetate of atomization is sprayed at into the microsphere surface of cladding Diacloden, obtains 2-cyano-3-amino-3-phenylancryic acetate cladding
Microsphere；
4）The microsphere that 2-cyano-3-amino-3-phenylancryic acetate is coated and filler, dispersant, wetting agent mix homogeneously, obtain final product containing Diacloden and cyanogen alkene bacterium
The compositionss of ester.
The Diacloden of the present invention quality that feeds intake accounts for total raw material and feeds intake the 5～10% of quality, and the 2-cyano-3-amino-3-phenylancryic acetate feeds intake quality
Account for total raw material and feed intake the 10～20% of quality.
The compositionss containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate of the present invention are when its preparation is prepared first by Diacloden and calcium alginate
Be sufficiently mixed in the micropore for making Diacloden fully infilter calcium alginate add sodium alginate make sodium alginate and penetrate into thiophene worm
The calcium alginate of piperazine is thoroughly mixed to form the microsphere of cladding Diacloden；Then the Nanoparticle of 2-cyano-3-amino-3-phenylancryic acetate is sprayed on into cladding
The microsphere surface of Diacloden；It is eventually adding filler, dispersant and wetting agent to mix.Dispersant is on the surface of solid particle
Formed adsorption layer make solid particles surface electric charge increase solid particle between because of electrostatic repulsion away from so as to be watered use when
System even suspension performance increase can be made not precipitate.Wetting agent can make water insoluble or can be by water for water-moistened 2-cyano-3-amino-3-phenylancryic acetate
Soak surface tension or interfacial tension to reduce water medicinal liquid can be made to moisten on crop, polypide and pathogenic bacteria body surface and launch so as to
Improve prevention effect.2-cyano-3-amino-3-phenylancryic acetate when in use of the invention plays first the subsequent Diacloden of bactericidal action, and slowly release can delay drug effect
The time of useful effect.It is particularly suited for corn, the process of fruit and vegerable seed-soaking can kill root feeding habits insect while also can make
Use to sprinkle sowing agent.The invention can ensure that compositionss can keep long-acting pesticidal effect its consumption few while sterilization, sterilization is killed
The good pollution to surrounding of worm effect is little.
It is 1: 2 to reach the mass ratio for taking optimum synergistic effect, Diacloden of the present invention and 2-cyano-3-amino-3-phenylancryic acetate.
The step 1）In, the particle diameter of calcium alginate is 50～200nm, and the calcium alginate quality that feeds intake accounts for total raw material and feeds intake matter
The 10～20% of amount.The particle diameter of calcium alginate is 50～200nm in the present invention, and its per surface area maximum adsorption power is most strong；And
The calcium alginate quality that feeds intake accounts for total raw material and feeds intake the 10～20% of quality, Diacloden and 2-cyano-3-amino-3-phenylancryic acetate can be fully adsorbed, and strengthens
Suspensibility and stability of the effective ingredient in suspension.
The step 2）In, the sodium alginate quality that feeds intake accounts for total raw material and feeds intake the 5～10% of quality.The throwing of sodium alginate
Material is acted on so as to and calcium alginate is used in combination, to improve using effect.
In addition, the filler be Kaolin, white carbon, precipitated calcium carbonate at least any one；The wetting agent
In for pull open powder, dodecylbenzene sodium sulfonate at least any one；The dispersant is sodium lignin sulfonate, how sulfonic acid and formaldehyde
At least appointing in condensation substance sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, glycerine fatty acid ester APEO
Meaning is a kind of.Pull open powder or dodecylbenzene sodium sulfonate in wetting agent, can significantly reduce the surface tension of water in suspension, tool
There is excellent penetration and wettability, while having emulsifying, diffusion and frothiness energy, improve the permeability of pesticide.It is each above
The Main Function of dispersant is to reduce the interfacial tension between liquid-liquid and solid-liquid, contributes to Diacloden and 2-cyano-3-amino-3-phenylancryic acetate fine particle
Cohesion keep dispersion stable, form stable suspension.
3rd purpose of the invention is the using method for proposing above product.
Method one：For soaking seed before frumentum, the sowing of fruit and vegerable seed：Take described in 150～200g containing Diacloden and cyanogen alkene bacterium
After the compositionss of ester are diluted to 1500～2000 times with water, soak seed for the frumentum before sowing to 100kg or fruit and vegerable seed,
Seed soaking time is 1～48 hour.
When using as seed soaking agent, its particle for being formed is attached to the surface of the seed 2-cyano-3-amino-3-phenylancryic acetate and first works killing
Pathogenic bacteria is slowly discharged because there is Diacloden good hydrophilic to be dissolved in sodium alginate bag with plant seed germination Diacloden
Diacloden in coating first discharge its be easier to be absorbed by plants cause the bud after germination, leaf, stem, the Diacloden content in root compared with
Height can effectively kill the Diacloden that the insect for gnawing progressively dissolves in calcium alginate with sodium alginate and slowly discharge due to there is sea
Sodium alginate and calcium alginate stop that Diacloden can keep long-acting and be difficult that the Increased Plasma Half-life of its drug effect can be made to 15 by photodissociation
Be enough within 1 support the growth in plant seedlings stage.
Method two：For frumentum, the preventing and treating of fruit and vegerable pest and disease damage：Take compositionss of the 50～100g containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate
It is watered after being diluted to 400～500 times, for 667m2Sprayed on plant surface on area.
Tests prove that：Said composition is to rice grub brown paddy plant hopper, white backed planthopper, small brown rice planthopper, rice green leafhopper, rice spider rafter stinkbug
As, star stinkbug, Nezara viridula smaragdula Fabricius. as, it is red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva have it is efficient.Striped rice borer, the preventing and treating of oryza chinensis class are had
Effect.It is thin to veterinary antibiotics insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, Zhu's acrosternumhilare, small heart-eating peach worm, Fructus Citri tangerinae lyonetid, tea
The latent fly of moth, striped flea-beetle, bean is efficient.Diagonal cured a red-spotted lizard, diamondback moth, chrysomelid two secret notes, Scirothrips dorsalis, onion thrips, golden thistle horse, Citrus
The preventing and treating such as golden thistle horse, soybean pod gall-midge, Fructus Lycopersici esculenti Liriomyza is effective.The Fusarium graminearum of Fusarium is caused simultaneously is red mould
Disease, fusarium moniliforme cause bakanae disease of rice, Fusarium oxysporum to cause watermelon blight preventing and treating effective；Pseudoperonospora cubensis are caused
Cucumber downy mildew, the rice Xanthomonas bacterial blight of rice, the microbial pepper anthracnose of Fructus Capsici anthrax, the Bei Lunge that cause
The microbial ring rot of apple in Fructus Vitis viniferae seat chamber also has certain inhibitory action.
Specific embodiment
First, raw materials for production prepare：
Diacloden 10kg is weighed respectively；2-cyano-3-amino-3-phenylancryic acetate 20kg；Particle diameter is the calcium alginate 10kg of 50～200nm；Sodium alginate
5kg；The kg of acetone 2；The kg of Kaolin 46 is used as filler；Pull open powder 5kg is used as wetting agent；The kg conducts of sodium lignin sulfonate 2
Dispersant.
2nd, compositionss are prepared：
1st, by Diacloden and calcium alginate be sufficiently mixed stirring so that Diacloden is fully infiltered in the micropore of calcium alginate, so
Afterwards under conditions of stirring, then acetone is sprayed on the mixture formed by Diacloden and calcium alginate, obtains and penetrate into thiophene worm
The calcium alginate of piperazine.
2nd, the calcium alginate and sodium alginate that penetrate into Diacloden are mixed again, makes sodium alginate and calcium alginate shape
Into the microsphere of cladding Diacloden, the microsphere of cladding Diacloden is obtained.
3rd, the superfine powder for first forming 2-cyano-3-amino-3-phenylancryic acetate after fluid bed crushing, during stirring is sprayed under spray pattern
The microsphere surface of cladding Diacloden, obtains the microsphere of 2-cyano-3-amino-3-phenylancryic acetate cladding.
4th, the microsphere for coating 2-cyano-3-amino-3-phenylancryic acetate and filler, dispersant and wetting agent mixing and stirring, obtain worm containing thiophene
The compositionss of piperazine and 2-cyano-3-amino-3-phenylancryic acetate.
Separately, above filler can be the one kind in Kaolin, white carbon, precipitated calcium carbonate.
Wetting agent can be the one kind in pull open powder, dodecylbenzene sodium sulfonate.
Dispersant can be sodium lignin sulfonate, how sulfonic formaldehyde condensation compound sodium salt, alkylphenol polyoxyethylene, fatty acid
One kind in polyoxyethylene ester, glycerine fatty acid ester APEO.
Raw material components can also be following mass component composition（It is total 100 parts）：
5～10 parts of Diacloden
10～20 parts of 2-cyano-3-amino-3-phenylancryic acetate
10～20 parts of calcium alginate
5～10 parts of sodium alginate
40～50 parts of filler
5～10 parts of wetting agent
2～8 parts of dispersant
1～2 part of acetone.
3rd, apply：
1st, soaked seed using product made by process above：
Take after the compositionss containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate are diluted to 1500～2000 times with water described in 150～200g, for right
Frumentum or fruit and vegerable seed before 100kg sowings is soaked seed, and seed soaking time is 1～48 hour.
As a result prove：Composition suspended floating particles are attached to the surface of the seed 2-cyano-3-amino-3-phenylancryic acetate and first work killing pathogenic bacteria with plant
The thiophene worm that the slow release of germination Diacloden due to Diacloden there is good hydrophilic to be dissolved in sodium alginate clad
Piperazine first discharges it and is easier to be absorbed by plants so that Diacloden content in the bud, leaf, stem, root after germinateing is higher can effectively kill
The Diacloden that the insect for gnawing progressively is dissolved in calcium alginate with sodium alginate is slowly discharged due to having sodium alginate and Sargassum
The stop Diacloden of sour calcium can keep long-acting and be difficult by photodissociation the Increased Plasma Half-life of its drug effect can be made to be enough to prop up to 15～20 days
Hold the growth in plant seedlings stage.
2nd, rice terrace test is carried out using product made by process above：
Take compositionss of the 50～100g containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate and be watered and be diluted to 400～500 times（Weight）Afterwards, for 1
Mu（667m2）Sprayed on the plant surface of area（The dosage in i.e. every mu field is 50～100g）.
As a result prove：The compositionss that examples detailed above is obtained are to rice grub brown paddy plant hopper, white backed planthopper, small brown rice planthopper, black tail leaf
Cicadae, rice spider rafter stinkbug, star stinkbug, Nezara viridula smaragdula Fabricius. as, it is red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva it is efficient.To striped rice borer, oryza chinensis class
Preventing and treating is effective.To veterinary antibiotics insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, Zhu's acrosternumhilare, small heart-eating peach worm, Fructus Citri tangerinae lyonetid,
The latent fly of Caloptiliatheivora, striped flea-beetle, bean is efficient.Diagonal cured a red-spotted lizard, diamondback moth, chrysomelid two secret notes, Scirothrips dorsalis, onion thrips, golden thistle horse,
The preventing and treating such as Citrus golden thistle horse, soybean pod gall-midge, Fructus Lycopersici esculenti Liriomyza is effective.The Fusarium graminearum of Fusarium is caused simultaneously is red
Mildew, fusarium moniliforme cause bakanae disease of rice, Fusarium oxysporum to cause watermelon blight preventing and treating effective；Pseudoperonospora cubensis are drawn
Cucumber downy mildew, the rice Xanthomonas bacterial blight of rice, the microbial pepper anthracnose of Fructus Capsici anthrax, the Bei Lun that cause for rising
The microbial ring rot of apple in lattice Fructus Vitis viniferae seat chamber also has certain inhibitory action.
Claims (9)
1. a kind of compositionss containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate, it is characterised in that effective ingredient is Diacloden and 2-cyano-3-amino-3-phenylancryic acetate；Institute
Diacloden accounts for compositionss gross mass 5～10% are stated, the 2-cyano-3-amino-3-phenylancryic acetate accounts for the 10～20% of compositionss gross mass.
2. the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate are contained according to claim 1, it is characterised in that the Diacloden and cyanogen alkene
The mass ratio of bacterium ester is 1: 2.
3. the preparation method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained as claimed in claim 1, it is characterised in that including as follows
Step：
1）Acetone is sprayed on the mixture formed by Diacloden and calcium alginate, the calcium alginate for penetrating into Diacloden is obtained；
2）The calcium alginate and sodium alginate mix homogeneously of Diacloden will be penetrated into, obtain the microsphere of cladding Diacloden；
3）Under stirring condition, the 2-cyano-3-amino-3-phenylancryic acetate of atomization is sprayed at into the microsphere surface of cladding Diacloden, obtains 2-cyano-3-amino-3-phenylancryic acetate cladding
Microsphere；
4）The microsphere that 2-cyano-3-amino-3-phenylancryic acetate is coated and filler, dispersant, wetting agent mix homogeneously, obtain final product containing Diacloden and cyanogen alkene bacterium
The compositionss of ester；
The Diacloden quality that feeds intake accounts for total raw material and feeds intake the 5～10% of quality, and the 2-cyano-3-amino-3-phenylancryic acetate quality that feeds intake accounts for total raw material throwing
The 10～20% of material quality.
4. the preparation method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained according to claim 3, it is characterised in that the thiophene
The mass ratio that feeds intake of worm piperazine and 2-cyano-3-amino-3-phenylancryic acetate is 1: 2.
5. the preparation method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained according to claim 3 or 4, it is characterised in that described
Step 1）In, the particle diameter of calcium alginate is 50～200nm, and the calcium alginate quality that feeds intake accounts for total raw material and feeds intake the 10～20% of quality.
6. the preparation method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained according to claim 3 or 4, it is characterised in that described
Step 2）In, the sodium alginate quality that feeds intake accounts for total raw material and feeds intake the 5～10% of quality.
7. the preparation method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained according to claim 3 or 4, it is characterised in that described
Filler be Kaolin, white carbon, precipitated calcium carbonate at least any one；The wetting agent is pull open powder, dodecyl
In benzene sulfonic acid sodium salt at least any one；The dispersant is sodium lignin sulfonate, how sulfonic formaldehyde condensation compound sodium salt, alkyl phenol
In polyoxyethylene ether, polyoxyethylene carboxylate, glycerine fatty acid ester APEO at least any one.
8. the using method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained as claimed in claim 1, it is characterised in that：Take 150
After compositionss containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate described in～200g are diluted to 1500～2000 times with water, for sowing to 100kg
Front frumentum or fruit and vegerable seed is soaked seed, and seed soaking time is 1～48 hour.
9. the using method of the compositionss of Diacloden and 2-cyano-3-amino-3-phenylancryic acetate is contained as claimed in claim 1, it is characterised in that：Take 50～
Compositionss of the 100g containing Diacloden and 2-cyano-3-amino-3-phenylancryic acetate are watered after being diluted to 400～500 times, for 667m2Plant on area
Sprayed on surface.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610941100.3A CN106577724A (en) | 2016-10-26 | 2016-10-26 | Composition containing thiamethoxam and js399-19, preparation method and application method |
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| CN201610941100.3A CN106577724A (en) | 2016-10-26 | 2016-10-26 | Composition containing thiamethoxam and js399-19, preparation method and application method |
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| CN201610941100.3A Pending CN106577724A (en) | 2016-10-26 | 2016-10-26 | Composition containing thiamethoxam and js399-19, preparation method and application method |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1559210A (en) * | 2004-02-18 | 2005-01-05 | 江苏省农药研究所有限公司 | 2-cyano-3-amino-3-ethyl phenylacrylate used for prevention and control of plant disease and elimination of pests |
| CN103202312A (en) * | 2013-04-28 | 2013-07-17 | 江苏龙灯化学有限公司 | Bacteriocidal and insecticidal composite |
| CN104381289A (en) * | 2014-11-13 | 2015-03-04 | 陕西上格之路生物科学有限公司 | Safe and multi-effect seed treatment composition |
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2016
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1559210A (en) * | 2004-02-18 | 2005-01-05 | 江苏省农药研究所有限公司 | 2-cyano-3-amino-3-ethyl phenylacrylate used for prevention and control of plant disease and elimination of pests |
| CN103202312A (en) * | 2013-04-28 | 2013-07-17 | 江苏龙灯化学有限公司 | Bacteriocidal and insecticidal composite |
| CN104381289A (en) * | 2014-11-13 | 2015-03-04 | 陕西上格之路生物科学有限公司 | Safe and multi-effect seed treatment composition |
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