CN106563619A - Method for forming protection layer on object surface and product with protection layer formed on surface - Google Patents
Method for forming protection layer on object surface and product with protection layer formed on surface Download PDFInfo
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- CN106563619A CN106563619A CN201610898032.7A CN201610898032A CN106563619A CN 106563619 A CN106563619 A CN 106563619A CN 201610898032 A CN201610898032 A CN 201610898032A CN 106563619 A CN106563619 A CN 106563619A
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- Prior art keywords
- plasma
- protective layer
- body surface
- product
- electrode
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- 238000000034 method Methods 0.000 title claims abstract description 34
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
- 239000001257 hydrogen Substances 0.000 claims abstract description 23
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 19
- 150000002367 halogens Chemical group 0.000 claims abstract description 18
- 239000007789 gas Substances 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 11
- 150000002431 hydrogen Chemical group 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- -1 alkenyl halide Chemical group 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 239000011241 protective layer Substances 0.000 claims description 46
- 238000004891 communication Methods 0.000 claims description 10
- 125000001188 haloalkyl group Chemical group 0.000 claims description 9
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 7
- 239000012159 carrier gas Substances 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 3
- 125000001967 indiganyl group Chemical group [H][In]([H])[*] 0.000 claims description 3
- 229910052756 noble gas Inorganic materials 0.000 claims description 2
- 150000002835 noble gases Chemical class 0.000 claims description 2
- 150000001350 alkyl halides Chemical group 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/62—Plasma-deposition of organic layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
The invention provides a method for forming a protection layer on an object surface. The method comprises the steps that at least one part of the surface of an object is exposed in plasma, gases forming the plasma at least comprise a compound shown in the chemical formula (I), wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, alkyl groups, alkyl halide and alkenyl halide or optional aryl groups with hydrogen replaced by halogen, and x can be any number of 10, 11 and 12. The invention further provides a product with the protection layer formed on the surface. The protection layer is formed on the surface of the product through the method.
Description
Technical field
The present invention relates to a kind of product that the method for protective layer and surface formation matcoveredn are formed in body surface.
Background technology
People production and daily life in, it is often necessary to its object for using avoid by liquid (water, oil, aqueous solution or
Person other contain water, mixing liquid etc. of oil) contact its surface, cause object to be contaminated, soak, or because these liquid
Act on and cause physical damage.Here, the object that people use is product.For example, product include electrical equipment, electronic equipment,
Filter membrane, wrist-watch and wearing product.
In the existing technology for preventing object from being contacted by liquid, disclose it is a kind of by using the grade containing polymer from
Daughter forms protective polymers layer in body surface, and for example, Chinese Patent Application No. CN200780002557 discloses one kind and exists
Body surface forms protective polymers layer, to prevent object to be contaminated by the liquid or soak.Again for example, Chinese Patent Application No.
CN200780002557 discloses a kind of surface of electric either electronic equipment or its part and is formed with protective polymers layer
A kind of method that product and surface in electric either electronic equipment or its part form protective polymers layer.Again for example, in
State number of patent application CN200880114449 discloses the filter membrane that a kind of surface is formed with polymeric layer.However, existing
By using the plasma containing polymer in the technology that body surface forms protective polymers layer, existing prevents object quilt
The ability of fluid contact surface is weak, and the problems such as the adhesion difference of protective polymers layer and body surface.
The content of the invention
In order to solve the above problems, the present invention proposes a kind of method for forming protective layer in body surface, by the present invention
The method for forming protective layer in body surface for proposing, it is possible to increase prevent object by the ability of fluid contact surface, and improve
The adhesion of protective layer and body surface.The present invention also proposes that a kind of surface forms the product of matcoveredn, the protection of the product
Layer can be improved and prevent product by the ability of fluid contact surface, and improve the adhesion of protective layer and product surface.
According to an aspect of the present invention, the present invention provides a kind of method for forming protective layer in body surface, including：
At least a portion surface of the object is exposed in plasma, the gas of the plasma is formed at least
Including the compound represented by chemical formula (I),
Wherein, R1、R2、R3、R4、R5、R6、R7Separately selected from hydrogen, halogen, alkyl, haloalkyl, alkenyl halide or
The aryl that optionally hydrogen is optionally substituted by halogen；And x is any one number in 10,11,12.
According to an aspect of the present invention, x is 10 or 11.
According to an aspect of the present invention, R1、R2For hydrogen or halogen, R3For hydrogen, halogen, C1-10 alkyl or C1-10 halogen
Substituted alkyl.
According to an aspect of the present invention, R4、R5、R6、R7Optionally from hydrogen, halogen, C1-10 alkyl or C1-10 alkyl halides
Base.
According to an aspect of the present invention, R4、R5、R6、R7For hydrogen.
According to an aspect of the present invention, R1、R2、R3、R4、R5、R6、R7For hydrogen.
According to an aspect of the present invention, formed plasma gas also include carrier gas, carrier gas selected from noble gases,
CF4、C3F8、N2、H2In at least one.
According to an aspect of the present invention, including the gas for forming plasma of the compound represented by chemical formula (I)
Plasma is formed in the plasma chamber of plasma apparatus.Plasma apparatus include the electrode being arranged in pairs, into
Electrode to arranging is contained in plasma chamber.
According to an aspect of the present invention, the electrode being arranged in pairs is connected with continuous radio-frequency power supply, is applied to and sets in pairs
The continuous electric power range of the electrode put is 0.0001-5000w/m3；At least a portion surface of the object be exposed to etc. from
Time in daughter is -60 minutes 0.001 second；Pressure in plasma chamber is 0.0001-1000 millitorrs.
According to an aspect of the present invention, the continuous electric power range for being applied to the electrode being arranged in pairs is 300-3000w/
m3；At least a portion surface of object is exposed to the time in plasma for 1-60 minutes；Pressure in plasma chamber
For 0.1-500 millitorrs.
According to an aspect of the present invention, the continuous electric power range for being applied to the electrode being arranged in pairs is 600-2000w/
m3；At least a portion surface of object is exposed to the time in plasma for 5-15 minutes；Pressure in plasma chamber
For 0.1-200 millitorrs.
According to an aspect of the present invention, the electrode being arranged in pairs is connected with pulse radiation frequency power supply, be applied to it is described into
To electrode pulsed electric power scope be 0.0001-5000w/m3；Pressure in plasma chamber is 0.0001-1000 millis
Support；At least a portion surface of the object is exposed to the time in plasma for -80 minutes 0.001 second；It is applied to described
The pulse frequency of paired electrode is 10-5000Hz.Dutycycle is 5%-95%.
According to an aspect of the present invention, the pulsed electric power scope for being applied to the electrode being arranged in pairs is 10-
2000w/m3；Pressure in plasma chamber is 0.1-500 millitorrs；At least a portion surface of object is exposed to plasma
In time be 1-55 minutes.
According to an aspect of the present invention, the pulsed electric power scope for being applied to the electrode being arranged in pairs is 50-1200w/
m3；Pressure in plasma chamber is 0.1-300 millitorrs；At least a portion surface of object be exposed in plasma when
Between be 2-30 minutes.
According to an aspect of the present invention, protective layer is lyophobicity protective layer.
The method for forming protective layer in body surface proposed by one aspect of the present invention, it is possible to increase prevent thing
Body improves the adhesion of protective layer and body surface by the ability of fluid contact surface.
According to another aspect of the present invention, there is provided a kind of surface forms the product of matcoveredn, and the protective layer is by upper
State the surface that the method for forming protective layer in body surface that one aspect of the present invention proposed is formed at the product.
According to another aspect of the present invention, the product includes：Electrical equipment, electronic equipment, cloth, permeable membrane, handss
At least one in table and wearing product.
According to another aspect of the present invention, electrical equipment includes：Communication base station, converting equipment, data exchange equipment, friendship
At least one and/or any of which part in logical instrument, outdoor lightings.
According to another aspect of the present invention, electronic equipment includes：It is handheld communication devices, electronic game station, wearable
At least one and/or any of which part in electronic equipment.
According to another aspect of the present invention, at least one that product is included in clothing, shoes and hats and/or ornaments is dressed.
The surface for being provided according to another aspect of the present invention forms the product of matcoveredn, the protective layer energy of the product
Enough raising prevents product by the ability of fluid contact surface, and improves the adhesion of protective layer and product surface.
Specific embodiment
The technical scheme of the more than one embodiment of the present invention is described below.Obviously, described embodiment
Only it is a part of embodiment of the invention, rather than the embodiment of whole.It should be noted that based on these enforcements in the present invention
Example, the every other embodiment that those of ordinary skill in the art are obtained belongs to the scope of protection of the invention.
It should be noted that in the present invention, the statement of " gas " refer to individually or form of mixtures gas or
Steam and aerosol.
In one embodiment of the invention, there is provided it is a kind of body surface formed protective layer method, including：
At least a portion surface of object is exposed in plasma, forming the gas of the plasma at least includes
The compound represented by chemical formula (I),
Wherein, R1、R2、R3、R4、R5、R6、R7Separately selected from hydrogen, halogen, alkyl, haloalkyl, alkenyl halide or
The aryl that optionally hydrogen is optionally substituted by halogen；And x can be any one number in 10,11,12.
In an example of embodiments of the invention, x can be 10.In another example of embodiments of the invention
In, x can be 11.
In an example of embodiments of the invention, R1、R2Can be hydrogen or halogen, R3Can be hydrogen, halogen, C1-
(namely C quantity is for 10 alkyl (namely C quantity is the alkyl of any one integer in 1-10) or C1-10 haloalkyls
The haloalkyl of any one integer in 1-10).
In an example of embodiments of the invention, R4、R5、R6、R7Respectively optionally from hydrogen, halogen, C1-10 alkyl or
C1-10 haloalkyls.Work as R4、R5、R6、R7For C1-10 alkyl or C1-10 haloalkyls when, can further improve protective layer
Lyophoby performance.Used as an example, halogen can be fluorine or chlorine.
In an example of embodiments of the invention, R4、R5、R6、R7Can be hydrogen.
In an example of embodiments of the invention, R1、R2、R3、R4、R5、R6、R7For hydrogen.
According to an embodiment of the invention an example, forms the gas of plasma also including carrier gas, and carrier gas is selected from lazy
Property gas, CF4、C3F8、N2、H2In at least one.
According to an embodiment of the invention an example, including the compound represented by chemical formula (I) plasma is formed
The gas of body forms plasma in the plasma chamber of plasma apparatus.Plasma apparatus include what is be arranged in pairs
Electrode, the electrode being arranged in pairs is contained in plasma chamber.
An example according to an embodiment of the invention, the electrode being arranged in pairs is connected with continuous radio-frequency power supply, applies
Continuous electric power range to the electrode being arranged in pairs is 0.0001-5000w/m3.At least a portion surface of the object is sudden and violent
The time being exposed in plasma is -60 minutes 0.001 second.Pressure in plasma chamber is 0.0001-1000 millitorrs.
Further say, according to an embodiment of the invention an example, be applied to the continuous electricity of the electrode being arranged in pairs
Power bracket is 300-3000w/m3.At least a portion surface of object is exposed to the time in plasma for 1-60 minutes.
Pressure in plasma chamber is 0.1-500 millitorrs.
Further say, according to an embodiment of the invention an example, be applied to the continuous electricity of the electrode being arranged in pairs
Power bracket is 600-2000w/m3.At least a portion surface of object is exposed to the time in plasma for 5-15 minutes.
Pressure in plasma chamber is 0.1-200 millitorrs.
An example according to an embodiment of the invention, the electrode being arranged in pairs is connected with pulse radiation frequency power supply, applies
Pulsed electric power scope to the paired electrode is 0.0001-5000w/m3.Pressure in plasma chamber is
0.0001-1000 millitorrs.At least a portion surface of the object be exposed to the time in plasma for 0.001 second -80 points
Clock.The pulse frequency for being applied to the paired electrode is 10-5000Hz.Dutycycle is 5%-95%.
Further say, according to an embodiment of the invention an example, be applied to the arteries and veins of the electrode being arranged in pairs
Electric power range is rushed for 10-2000w/m3.Pressure in plasma chamber is 0.1-500 millitorrs.At least a portion of object
Surface is exposed to the time in plasma for 1-55 minutes.
Further say, according to an embodiment of the invention an example, be applied to the pulse electricity of the electrode being arranged in pairs
Power bracket is 50-1200w/m3.Pressure in plasma chamber is 0.1-300 millitorrs.At least a portion surface of object
The time being exposed in plasma is 2-30 minutes.Thus, being favorably improved the lyophobicity of protective layer.
An example according to an embodiment of the invention, protective layer is lyophobicity protective layer.Here, " liquid " of lyophobicity is
Refer to liquid.Specifically, liquid include water, oil, aqueous solution or other contain in mixing liquid of water or oil etc. at least
It is a kind of.
An example according to an embodiment of the invention, when needed, can be to filling the chemical combination represented by chemical formula (I)
The container of thing is heated to predetermined temperature, to ensure that the compound represented by chemical formula (I) is transported to plasma with the form of gas
In the plasma chamber of body equipment.Further say, when needed, can be defeated to the compound that will be represented by chemical formula (I)
The passage for being sent to the plasma chamber of plasma apparatus is heated, and keeps being heated to predetermined temperature.
An example according to an embodiment of the invention, the electrode being arranged in pairs first is connected with continuous radio-frequency power supply, and
And continuous radio-frequency power supply applies above-mentioned continuous radio frequency power and the persistently very first time to the electrode being arranged in pairs, and then, sets in pairs
The electrode put first is connected with pulse radiation frequency power supply, and pulse radiation frequency power supply applies above-mentioned pulse and penetrates to the electrode being arranged in pairs
Frequency electric power simultaneously continued for the second time.
The method for forming protective layer in body surface proposed by one embodiment of the present of invention, it is possible to increase prevent
Object improves the adhesion of protective layer and body surface by the ability of fluid contact surface.
According to another embodiment of the invention, there is provided a kind of surface forms the product of matcoveredn, the protective layer passes through
The method for forming protective layer in body surface that one embodiment of the invention described above is proposed is formed at the surface of the product.
It is recognised that the concept " object " being mentioned above includes product here.
An example according to another embodiment of the invention, product includes：Electrical equipment, electronic equipment, cloth, mistake
At least one in filter membrane, wrist-watch and wearing product.
An example according to another embodiment of the invention, electrical equipment includes：Communication base station, converting equipment, number
According at least one in switching equipment, the vehicles and outdoor lightings.Electrical equipment can also include：Communication base station, change
The part of any one of electric equipment, data exchange equipment, the vehicles and outdoor lightings.
An example according to another embodiment of the invention, electronic equipment includes：Handheld communication devices, electronic game
Any one of equipment, wearable electronic.Electronic equipment can also include handheld communication devices, electronic game station,
Any part of any one of wearable electronic.
An example according to another embodiment of the invention, wearing product includes clothing, shoes and hats and/or ornaments.
The surface for being provided according to another aspect of the present invention forms the product of matcoveredn, the protective layer energy of the product
Enough raising prevents product by the ability of fluid contact surface, and improves the adhesion of protective layer and product surface.
Although being not particularly illustrated to the present invention above, it will be understood to those skilled in the art that disclosed in prior art
Content can by connected applications in the present invention.Prior art includes but is not limited to Chinese Patent Application No.
CN200780002629, CN200780048614, CN200980120491, CN200780002557 and CN200880114449.
For example, those skilled in the art is it is recognised that object and product in the present invention and being not limited to above description and being limited
, all objects and product disclosed in these patents can also be included.For example, during electronic equipment described in the invention also includes
All electronic equipments disclosed in state number of patent application CN200780002557.Again for example, if the present invention is illustrated,
Technological parameter, method, embodiment disclosed in these prior arts etc. can also be attached to the present invention by way of replacing
In.
Above to it is provided by the present invention it is a kind of body surface formed protective layer method and surface be formed with protection
The product of layer is described in detail, and specific case used herein is explained the principle and embodiment of the present invention
State, the explanation of above example is only intended to help and understands the method for the present invention and inventive concept；Simultaneously for the one of this area
As technical staff, according to the present invention thought, will change in specific embodiments and applications, to sum up institute
State, this specification content should not be construed as limiting the invention.
Claims (20)
1. it is a kind of body surface formed protective layer method, it is characterised in that include：
At least a portion surface of the object is exposed in plasma, forming the gas of the plasma at least includes
The compound represented by chemical formula (I),
Wherein, R1、R2、R3、R4、R5、R6、R7Separately selected from hydrogen, halogen, alkyl, haloalkyl, alkenyl halide or optional
The aryl that ground hydrogen is optionally substituted by halogen；And
X is any one number in 10,11,12.
2. it is according to claim 1 body surface formed protective layer method, it is characterised in that
X is 10 or 11.
3. it is according to claim 1 body surface formed protective layer method, it is characterised in that
R1、R2For hydrogen or halogen, R3For hydrogen, halogen, C1-10 alkyl or C1-10 haloalkyls.
4. it is according to claim 1 body surface formed protective layer method, it is characterised in that
R4、R5、R6、R7Optionally from hydrogen, halogen, C1-10 alkyl or C1-10 haloalkyls.
5. the method for forming protective layer in body surface stated according to claim 4, it is characterised in that
R4、R5、R6、R7For hydrogen.
6. it is according to claim 1 body surface formed protective layer method, it is characterised in that
R1、R2、R3、R4、R5、R6、R7For hydrogen.
7. it is according to claim 1 body surface formed protective layer method, it is characterised in that
Forming the gas of plasma also includes carrier gas, and carrier gas is selected from noble gases, CF4、C3F8、N2、H2In at least one.
8. it is according to claim 1 body surface formed protective layer method, it is characterised in that：
Including the compound represented by chemical formula (I) the gas for forming the plasma plasma apparatus plasma
The plasma is formed in body cavity body；
The plasma apparatus include the electrode being arranged in pairs, and the electrode being arranged in pairs is contained in the plasma chamber
In body.
9. it is according to claim 8 body surface formed protective layer method, it is characterised in that：
The electrode being arranged in pairs is connected with continuous radio-frequency power supply, is applied to the continuous electrical power model of the paired electrode
Enclose for 0.0001-5000w/m3；At least a portion surface of the object be exposed to the time in plasma for 0.001 second-
60 minutes；Pressure in plasma chamber is 0.0001-10000 millitorrs.
10. it is according to claim 9 body surface formed protective layer method, it is characterised in that：
The continuous electric power range for being applied to the paired electrode is 100-3000w/m3；At least a portion table of the object
Face is exposed to the time in plasma for 1-60 minutes；Pressure in plasma chamber is 0.1-1000 millitorrs.
11. methods for forming protective layer in body surface according to claim 10, it is characterised in that：
The continuous electric power range for being applied to the paired electrode is 600-2000w/m3；At least a portion table of the object
Face is exposed to the time in plasma for 5-15 minutes；Pressure in plasma chamber is 0.1-200 millitorrs.
12. methods for forming protective layer in body surface according to claim 8, it is characterised in that：
The paired electrode is connected with pulse radiation frequency power supply, and the pulsed electric power scope for being applied to the paired electrode is
0.0001-5000w/m3；Pressure in plasma chamber is 0.0001-1000 millitorrs；At least a portion table of the object
Face is exposed to the time in plasma for -80 minutes 0.001 second；The pulse frequency for being applied to the paired electrode is 10-
5000Hz.Dutycycle is 5%-95%.
13. methods for forming protective layer in body surface according to claim 12, it is characterised in that：
The pulsed electric power scope for being applied to the paired electrode is 10-2000w/m3；Pressure in plasma chamber is
0.1-500 millitorrs；At least a portion surface of the object is exposed to the time in plasma for 1-55 minutes.
14. methods for forming protective layer in body surface according to claim 13, it is characterised in that：
The pulsed electric power scope for being applied to the paired electrode is 50-1200w/m3；Pressure in plasma chamber is
0.1-300 millitorrs；At least a portion surface of the object is exposed to the time in plasma for 2-30 minutes.
15. methods for forming protective layer in body surface according to claim 1, it is characterised in that：
The protective layer is lyophobicity protective layer.
A kind of 16. surfaces form the product of matcoveredn, it is characterised in that：
The protective layer is by the method shape that protective layer is formed in body surface as any one of claim 1-15
The surface of product described in Cheng Yu.
17. surfaces according to claim 16 form the product of matcoveredn, it is characterised in that：The product includes：
At least one in electrical equipment, electronic equipment, wrist-watch, cloth, permeable membrane and wearing product.
18. surfaces according to claim 17 form the product of matcoveredn, it is characterised in that：
The electrical equipment includes：In communication base station, converting equipment, data exchange equipment, the vehicles, outdoor lightings
Any one of any and/or communication base station, converting equipment, data exchange equipment, the vehicles, outdoor lightings
Any part.
19. surfaces according to claim 17 form the product of matcoveredn, it is characterised in that：
The electronic equipment includes：Any one of handheld communication devices, electronic game station, wearable electronic and/
Or any part of any one of handheld communication devices, electronic game station, wearable electronic.
20. surfaces according to claim 17 form the product of matcoveredn, it is characterised in that：
The wearing product includes clothing, shoes and hats and/or ornaments.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610898032.7A CN106563619A (en) | 2016-10-14 | 2016-10-14 | Method for forming protection layer on object surface and product with protection layer formed on surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610898032.7A CN106563619A (en) | 2016-10-14 | 2016-10-14 | Method for forming protection layer on object surface and product with protection layer formed on surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106563619A true CN106563619A (en) | 2017-04-19 |
Family
ID=58531961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610898032.7A Pending CN106563619A (en) | 2016-10-14 | 2016-10-14 | Method for forming protection layer on object surface and product with protection layer formed on surface |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106563619A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107134302A (en) * | 2017-06-26 | 2017-09-05 | 苏州热工研究院有限公司 | A kind of laser decontamination plant under radioactivity operating mode |
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| CN1946488A (en) * | 2004-03-18 | 2007-04-11 | 英国国防部 | Coating of a polymer layer using low powder pulsed plasma in a plasma chamber of a large volume |
| CN104718258A (en) * | 2012-08-13 | 2015-06-17 | 欧洲等离子公司 | Surface coatings |
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| CN1503833A (en) * | 2001-04-25 | 2004-06-09 | ������������ʽ���� | Water and oil-repellent composition |
| CN1946488A (en) * | 2004-03-18 | 2007-04-11 | 英国国防部 | Coating of a polymer layer using low powder pulsed plasma in a plasma chamber of a large volume |
| CN104718258A (en) * | 2012-08-13 | 2015-06-17 | 欧洲等离子公司 | Surface coatings |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107134302A (en) * | 2017-06-26 | 2017-09-05 | 苏州热工研究院有限公司 | A kind of laser decontamination plant under radioactivity operating mode |
| CN107134302B (en) * | 2017-06-26 | 2024-02-13 | 苏州热工研究院有限公司 | Laser decontamination plant under radioactivity operating mode |
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