CN106536700B - Filth disposal composition - Google Patents
Filth disposal composition Download PDFInfo
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- CN106536700B CN106536700B CN201580033157.7A CN201580033157A CN106536700B CN 106536700 B CN106536700 B CN 106536700B CN 201580033157 A CN201580033157 A CN 201580033157A CN 106536700 B CN106536700 B CN 106536700B
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- Prior art keywords
- dirt
- cleansing composition
- environmental condition
- composition
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- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 239000004475 Arginine Substances 0.000 claims abstract description 23
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004744 fabric Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 238000011109 contamination Methods 0.000 claims description 12
- 230000007613 environmental effect Effects 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 claims description 4
- AKGWUHIOEVNNPC-LURJTMIESA-N Arg-OEt Chemical compound CCOC(=O)[C@@H](N)CCCNC(N)=N AKGWUHIOEVNNPC-LURJTMIESA-N 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 2
- WVSBBCCXKUUWGB-ZETCQYMHSA-N COC([C@@H](NCCC)CCO)=O Chemical class COC([C@@H](NCCC)CCO)=O WVSBBCCXKUUWGB-ZETCQYMHSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 description 22
- -1 arginine methyl esters Chemical class 0.000 description 20
- 239000003599 detergent Substances 0.000 description 18
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 10
- 229960003237 betaine Drugs 0.000 description 9
- 239000003876 biosurfactant Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 235000019197 fats Nutrition 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000005202 decontamination Methods 0.000 description 5
- 230000003588 decontaminative effect Effects 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000002888 zwitterionic surfactant Substances 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 238000010936 aqueous wash Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000007781 pre-processing Methods 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
- ZTOKUMPYMPKCFX-CZNUEWPDSA-N (E)-17-[(2R,3R,4S,5S,6R)-6-(acetyloxymethyl)-3-[(2S,3R,4S,5S,6R)-6-(acetyloxymethyl)-3,4,5-trihydroxyoxan-2-yl]oxy-4,5-dihydroxyoxan-2-yl]oxyoctadec-9-enoic acid Chemical compound OC(=O)CCCCCCC/C=C/CCCCCCC(C)O[C@@H]1O[C@H](COC(C)=O)[C@@H](O)[C@H](O)[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](COC(C)=O)O1 ZTOKUMPYMPKCFX-CZNUEWPDSA-N 0.000 description 2
- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical class O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 241000322338 Loeseliastrum Species 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000004900 laundering Methods 0.000 description 2
- 229940094506 lauryl betaine Drugs 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 239000013642 negative control Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 125000004437 phosphorous atom Chemical group 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 description 1
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- AFWTZXXDGQBIKW-UHFFFAOYSA-N C14 surfactin Natural products CCCCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 AFWTZXXDGQBIKW-UHFFFAOYSA-N 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- 229930186217 Glycolipid Natural products 0.000 description 1
- 102100024023 Histone PARylation factor 1 Human genes 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
- 108090001030 Lipoproteins Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000187561 Rhodococcus erythropolis Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Chemical group 0.000 description 1
- UBNVDFUEPGQZQS-UHFFFAOYSA-N acetic acid;n,n-dimethyldodecan-1-amine Chemical compound CC([O-])=O.CCCCCCCCCCCC[NH+](C)C UBNVDFUEPGQZQS-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- CXRIYAIXOLRMST-UHFFFAOYSA-M dodecyl(dimethyl)sulfanium;acetate Chemical compound CC([O-])=O.CCCCCCCCCCCC[S+](C)C CXRIYAIXOLRMST-UHFFFAOYSA-M 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- AGBQKNBQESQNJD-UHFFFAOYSA-N lipoic acid Chemical compound OC(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-N 0.000 description 1
- 108010005335 mannoproteins Proteins 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 description 1
- SFBHPFQSSDCYSL-UHFFFAOYSA-N n,n-dimethyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C SFBHPFQSSDCYSL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000001151 peptidyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000069 prophylactic effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000001047 purple dye Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- NJGWOFRZMQRKHT-UHFFFAOYSA-N surfactin Natural products CC(C)CCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-UHFFFAOYSA-N 0.000 description 1
- NJGWOFRZMQRKHT-WGVNQGGSSA-N surfactin C Chemical compound CC(C)CCCCCCCCC[C@@H]1CC(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-WGVNQGGSSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of cleansing composition includes arginine alkyl ester.
Description
The present invention relates to the cleansing compositions for dirt active under environmental condition.
The purpose of the present invention is remove dirt from the substrate of contamination.
US3707505 discloses a kind of enzyme-containing detergent compositions, the composition due to there are N- acylamino acid and
Its salt and ester and enhanced in terms of enzyme storage capability, the N- acyl group be the fatty acid with 6-20 carbon atom base
Group.Embodiment 10 describes a kind of by 15g lauryl alcohol sulfate, the alkylamide of 10g coco-nut oil fatty acid, 5g second
0.1g protease is added in pure and mild 2g N- myristoyl-L-arginine butyl ester lactate mixture and 1g amylase obtains
Liquid detergent.
In a first aspect, the present invention provides a kind of decontamination comprising arginine alkyl ester compounds and surfactant
Composition.Preferably, the arginine alkyl ester compounds be arginine methyl esters or arginine ethyl ester, or any combination thereof.
In second aspect, the method for substrate (for example, fabric) the removal dirt that the present invention provides a kind of from contamination, packet
Include the step of applying the cleansing composition of first aspect present invention to the dirt.
In the third aspect, the present invention provides a kind of pretreatment units, including going for (i) storage first aspect present invention
The distributor of dirt applying said compositions of the storeroom and (i) of dirty composition on basad, the pretreatment unit
It is preferably suitable for use in the method for second aspect.
In further aspect, the base from contamination is used for the present invention provides arginine alkyl ester and surfactant package
Bottom removes the purposes in oil/grease fat dirt.
Through the invention, at low temperature removal dirt obtain major improvement, and therefore out of habit or need and into
The area of row environment washing provides cost-effective improved household such as clothes cleaning.Improvement at a lower temperature is washed
Wash that performance is generally desired, but performance may also contribute to inhibit hot water washing adopting in these countries in a low temperature of improving
With as the raising and more people of the standard of living can afford substrate washing machine, hot water washing is in rising trend.This hair
It is bright to provide during environment temperature cleaning (using cold washing liquid) to the detergency ability of dirt and/or dirt, it is not necessarily to
The temperature sensitivity of ingredient during careful consideration storage.It more freely be designed with can therefore be based on other considerations.
As used herein, term " substrate " includes fabric and clothes and other surfaces, such as tableware, pottery
(crockery) and other household hard surfaces.
As used herein, term " arginine ester " and " arginine alkyl ester " are intended to include alloisomerism and racemic shape
Formula and its mixture.
Term " active under environmental condition " is intended to refer to lower than 25 degrees Celsius and preferably 22 degrees Celsius or lower, more preferable
15 degrees Celsius or lower, but it is always above 1 degree Celsius, and " active " refers to that in realizing decontamination be effective.
As used herein, term " decontamination " refers to according to the removal for eliminating unit or prophylactic iedex measurement.For visual
(passing through human eye) effect, effective decontamination eliminate disappearing for units and preferably greater than or equal to 5 units by being equal to or more than 2
Except indicating.
As used herein, abbreviation " wt% " refers to " % by weight ".Unless otherwise indicated, institute mentioned in this article
There is percentage to be relative to the weight percent of total composition calculating.
Dirt may include biomaterial, such as fat, oil, blood, starch and combinations thereof.
Method of the invention preferably includes Aqueous wash process.Accordingly it is preferred that the method includes to described group
It closes and adds the step of water is to form Aqueous wash liquid in object.
Preferably, the method includes compositions described in the region local application of based dirt or contamination.The side
Method can be preprocess method, and then carry out Aqueous wash step.Pre-treatment step can not further add any water
It is carried out in the case where (in addition to any water contained in composition).Alternately or additionally, preprocessing process may include by substrate
The step being immersed in the aqueous solution for adding treatment compositions thereto.Optionally, preprocessing process may include passing through spray
(spraying) is applied, (brushing), friction (rubbing) is brushed or scrubs (scrubbing) etc. using the step of composition
Suddenly.
The second step of method of the invention can be for " master " washing and can be hand-washing processes and/or in washing machine
Washing process.Any suitable detergent composition can be used in second step.Preferably, the detergent composition include it is a kind of or
A variety of surfactants as described below and/or other functional components, auxiliary agent etc..
For pretreatment according to the present invention, subsequent step can not needed further using arginine alkyl ester.
Preferably, the washing process duration of the invention is less than 90 minutes, and more preferably less than 60 minutes and most preferably
Less than 30 minutes.In pretreatment embodiment, pre-treatment step is preferably smaller than 5 minutes, and more preferably less than 2 minutes.
Processing for beef and pig fat dirt, arginine alkyl ester is preferably with the dense of 0.01mg/ml-10 mg/ml
Degree is more preferably present in wash liquid with the concentration of 0.31mg/ml-0.62mg/ml.For the place of frying fat and butterfat
It manages, arginine methyl esters/arginine ethyl ester concentration is preferably 0.15mg/ml to 10mg/ml in wash liquid.
Preferably, arginine alkyl ester exists with the concentration of the 320mg-4000 of every dose of 40mg-5000mg, preferably every dose mg
In any combination object of the invention.The composition is with individually dosed pattern or multi-dose, free-flowing pattern (powder, liquid
Body, gel, paste etc.) it provides, it is measured by consumer using proportioning device.The dosage can be 10ml to 100ml.
Preferably, the wash liquid has the pH within the scope of 4-9.5.
Pretreatment unit can be any suitable device, such as roller applicator or pipe, sprayer (spray), be sprayed
Device (aerosol), paste body (paste), pump-type distributor or filth disposal pen or brush etc..Pretreatment unit may include tool
There is the scrub component of brush, bristle, tuft, bump, relief etc. or any combination thereof, further detergent to be helped to combine
The based application of object.
Preferably, the treatment compositions are active under environmental condition.Correspondingly, the wash liquid of water washing process
Therefore the temperature of step is consistently lower than 40 DEG C during washing (but during not including dry), is preferably shorter than 30 DEG C, is more preferably low
In 25 DEG C, more preferably lower than or equal to 22 DEG C, even more preferably 15 DEG C or lower.Encouraging cold washing liquid is environmentally
With economical advantages.
Treatment compositions of the invention and/or any detergent composition then used may include any following component.
Surfactant can be synthetic surfactant, or by bacterium, fungi or other microorganism Microbe synthesis
Biosurfactant.Biosurfactant preferably comprises biosurfactant derived from microorganism.Preferably,
Glycolipid class biological surface comprising that can be rhamnolipid or sophorolipid or seaweed glycolipid or mannosylerythritol lipid (MEL)
Activating agent.Optionally, biosurfactant can advantageously comprise cellobiose, peptidyl biosurfactant, lipoprotein
(preferably there is hydrocarbon chain C with lipopeptid (such as Surfactin), fatty acid such as corynomucolic acid12-C14), phosphorus
Rouge (for example, the phosphatidyl-ethanolamine generated by the Rhodococcus erythropolis that is grown on normal alkane, cause water and hexadecane it
Between interfacial tension decrease below the CMC of 1mN m-1 and 30mg L-1) (Kretschner et al., 1982) and needle spore
Acid；Polymerization including emulsifier (emulsan), rouge emulsifier (liposan), Mannoproteins and polysaccharide protein complex is raw
Object surfactant.
Preferably, the biosurfactant includes rhamnolipid.
Surfactant can be by weight with 3-85 weight %, preferably 3-60 weight %, more preferable 3-40 weight %, most
It is preferred that the level of 3-35% is present in composition.
Be preferably based on the total weight of existing surfactant, anionic surfactant with 0.1-95 weight %,
It is preferred that the horizontal of 1-50 weight %, more preferable 1.5-25 weight % exists.
Preferably, the surfactant is anionic surfactant.
Anionic surfactant is defined herein as the amphiphile, amphiphilic molecule comprising one or more functional groups, the official
It can roll into a ball in the aqueous solution under the Normal Wash pH between 6-11 and show net anionic charge.
Preferred anion biosurfactant is the lactonic acid form of rhamnolipid and sophorolipid.Not by biological table
Up to for anionic form but being modified to provide/improve the biosurfactant of anionic nature and be included in the present invention.
Preferred synthetic anion surface active agent is to have the alkane comprising about 6-24 carbon atom in its molecular structure
The alkali metal salt of the organic sulfur reaction product of base group and the group selected from sulfonate group and sulfate groups.
Although any anionic surfactant being hereinafter described can be used, such as alkyl ether sulfate, soap, aliphatic ester
Sulfonate, alkylbenzene sulfonate, sulfosuccinate, primary alkyl sulphates, alkene sulfonate, alkane (paraffin) sulfonic acid
Salt and organic phosphate；Preferred anionic surfactant is the alkali metal salt and alkali salt, fat of fatty acid carboxylate
Alcohol sulfate, preferably primary alkyl sulphates, more preferably it is ethoxylation, such as alkyl ether sulfate；And alkyl benzene sulphonate
Or mixtures thereof salt.
Amphoteric surfactant and/or zwitterionic surfactant may be present in composition according to the present invention.It is right
It is preferably between 6-10 in the pH of amphoteric surfactant, wash liquid.Preferably, both sexes or amphoteric ion surface-active
Agent exists with 0.1-20 weight %, the horizontal of more preferable 0.25-15 weight %, even more preferably 0.5-10 weight %.
Suitable zwitterionic surfactant is illustratively that can be called as aliphatic quaternary ammonium, Liu He Phosphonium chemical combination
Those of derivative of object, contains a long chain alkyl group with about 8 to about 18 carbon atoms and at least one is selected from sulfuric acid
Foundation group, sulfonate group, carboxylate group, phosphate groups or phosphonate groups water solubilizing group.These compounds
General formula are as follows:
R1(R2)XY+R3Z-
Wherein R1Include alkyl, alkenyl or hydroxyalkyl group with 8-18 carbon atom, 0-10 ethyleneoxy group group
Or 0-2 glycerol unit；Y is nitrogen, sulphur or phosphorus atoms；R2For alkyl or hydroxyalkyl group with 1-3 carbon atom；When Y is
When sulphur atom, X 1, when Y is nitrogen or phosphorus atoms, X 2；R3For alkyl or hydroxyalkyl group with 1-5 carbon atom,
And Z is the group selected from sulfate groups, sulfonate group, carboxylate group, phosphate groups or phosphonate groups.
Preferred amphoteric surfactant is amine oxide, such as coco dimethyl amine oxide.Preferred amphoteric ion table
Face activating agent is glycine betaine, especially amido betaine.Preferred glycine betaine is C8-C18Alkyl amidoalkyl betaines,
Such as cocamidopropyl glycine betaine.These can be used as cosurfactant and are introduced into, preferably with the 0- based on total composition weight
The amount presence of 10 weight %, more preferable 1-5 weight %.
Preferred both sexes or zwitterionic surfactant for being introduced into composition according to the present invention are glycine betaine
Surfactant.These example refers in being exemplified below.
Sulfatobetaine, such as 3- (dodecyl dimethyl ammonium) -1- propane sulfate；With 2- (coco dimethyl ammonium)-
1- ethanesulfonate.
Sulfonic group glycine betaine, such as 3- (dodecyl dimethyl ammonium) -2- hydroxyl -1- propane sulfonate；3- (myristyl
Dimethyl ammonium) -1- propane sulfonate；3-(C12-C14Alkyl-amide base propyl-dimethyl ammonium) -2- hydroxyl -1- propane sulfonic acid
Salt；With 3- (coco dimethyl ammonium) -1- propane sulfonate.
Carboxybetaine, such as (dodecyl dimethyl ammonium) acetate (also referred to as lauryl betaine)；(myristyl
Dimethyl ammonium) acetate (also referred to as myristyl betaine)；(coco dimethyl ammonium) acetate (also referred to as coconut beet
Alkali)；(oleyl dimethyl ammonium) acetate (also referred to as oil-based betaine)；(dodecyloxy methyl dimethoxy base ammonium) acetate；With
(acylamidopropyldimethyl ammonium) acetate (also referred to as coconut oleoyl amine-propyl betaine or CAPB).
Sulfonium glycine betaine, such as: (dodecyl dimethyl sulfonium) acetate；With 3- (coco dimethyl-sulfonium) -1- propane sulfonic acid
Salt.
Phosphonium glycine betaine, such as: 4- (San Jia Ji Phosphonium) -1- hexadecane sulfonate；3- (Shi bis- Wan base Er Jia Ji Phosphonium) -1- propane
Sulfonate；With 2- (Shi bis- Wan base Er Jia Ji Phosphonium) -1- ethane sulfonate.
Composition according to the present invention preferably comprise or mixtures thereof carboxybetaine or sulfobetaines as both sexes or
Zwitterionic surfactant.Especially preferably lauryl betaine.
Further optional compositions include additional surfactant such as nonionic and cationic surfactant, glue
Spend regulator, foam booster, preservative (such as fungicide), pH buffer, polyelectrolyte, antishrinking agent, anti wrinkling agent, antioxygen
Agent, sun-screening agent, corrosion inhibitor, pendency imparting agent, antistatic agent and ironing aids.The composition can further include
Toner, pearling agent and/or opacifier, and masking dyestuff, fluorescer.
The composition may include enzyme.The composition is preferably free of or at least substantially without protease and/or starch
Enzyme.
The composition is preferably free of or is at least substantially free of the alkylamide of coco-nut oil fatty acid.
Experiment
Embodiment
The following describe illustrative laundry detergent compositions, can add arginine alkyl ester thereto.
Wherein Neodol 25-7 comes from shell ,=C12-C15Alcohol 7- ethoxylate.
LAS acid=C10-C14Alkyl benzene sulphonate；
SLES=C12-C13Alcohol 3- ethoxylated sulfate, Na salt :=Sodium Lauryl Ether Sulphate (has average 3 oxygen
Change vinyl group)；
In these embodiments, the arginine alkyl ester in laundry detergent composition is tested to determine it with various
Mode handles the ability of the dirt from cotton fabric.All values from beginning to end are weight %.
End-point method washing tests
Reagent
● the fabric samples (centered on test material BV) of following contamination are punching into disk and are transferred to 300 μ l
96 orifice plates.
● fatty dirt: the used frying fat (CS-46) of purple dye, coloring tallow (CS-61).
● laundry detergent composition: (i.e. following stock solution is in wash liquid for working concentration stock solution dilution=1: 428
Middle 1: 428 times of dilution)
● without enzyme laundry detergent composition
● arginine methyl esters (arginine methyl esters dihydrochloride form, Sigma catalog number (Cat.No.): 26340-89-6, EC 247-
622-0)
Program
Staining fabric pre-washes
By the fabric disk of contamination being pre-washed below to remove the free dirt of any remnants:
● 200 μ l distilled water are added into each hole
● plate is shaken 2 minutes at 250rpm on plate shaking table
● it goes to remove water
The fabric stain with diamines pretreatment, then carries out main washing
Following tests and control mixture are added in hole:
● test mixture
● 100 μ l of laundry detergent composition
● 80 μ l of distilled water
● 20 μ l of arginine methyl esters dilution *
* arginine alkyl ester is diluted to ultimate density 5mg/ml.
● control mixture (the only laundry detergent composition of negative control)
● 100 μ l of laundry detergent composition
● 100 μ l of distilled water
By the fabric of contamination at room temperature without joltily being cultivated 5 minutes in preprocessing solution.Then removal pretreatment is washed
Wash liquid.After pretreatment, the fabric (250rpm, 1 hour, room temperature) of contamination is washed in following mixture:
● 100 μ l of laundry detergent composition
● 100 μ l of distilled water
After washing, then remove wash liquid, and on plate shaking table at 250rpm with 200 μ l distilled water laundering of textile fabrics 4
× 5 minutes.It is dried at room temperature for fabric overnight.
(2b) utilizes the main washing of the staining fabric of diamines
Following tests and control mixture are added in hole:
● test mixture
● 100 μ l of laundry detergent composition
● 80 μ l of distilled water
● 20 μ l of arginine methyl esters
* by diluted chemical compound to ultimate density: 10,5,2.5,1.25,0.62,0.31 and 0.15mg/ml.
● control mixture (the only negative control of laundry detergent composition)
● 100 μ l of laundry detergent composition
● 100 μ l of distilled water
The fabric of contamination washs 1 hour at 250rpm at room temperature.After washing, wash liquid is then removed, and in plate
With 200 μ l distilled water laundering of textile fabrics 4 × 5 minutes at 250rpm on shaking table.Then do fabric at room temperature before the scan
It is dry overnight.
After drying, digital scanning dirt plate simultaneously measures its Δ E.This value is for indicating cleaning effect and being defined as calico
And the color difference stain between cloth after washing.For mathematically, Δ E's is defined as:
Δ E=[(Δ L)2+(Δa)2+(Δb)2]1/2
Wherein Δ L is the other measurement of darkness differential for washing cloth and calico；Δ a and Δ b is two kinds of cloth respectively in redness and Huang
The measurement of difference on degree.According to this equation, it is clear that the value of Δ E is lower, and cloth will be whiter.About this color measurement technique, reference
International Commission on Illumination (CIE) (Commission International de l ' Eclairage)；Recommendation
On Uniform Colour Spaces, colour difference equations, psychometric colour
Terms, the 15th phase of the 2nd phase CIE publication supplementary issue, Colormetry, Bureau Central de la CIE, Paris 1978.
In the following table, cleaning effect is indicated in the form of decontamination index (SRI)；
SRI=100- Δ E.
SRI is higher, and cloth more cleans, SRI=100 (white).
As a result
Frying fat dirt result
Tallow dirt result
Conclusion
Arginine alkyl ester is combined with laundry detergent composition as the result is shown, the preprocess form before with main washing
And when both form applications for being directly included in main washing, the cleaning of fatty staining fabric can be improved.In general, cleaning improves
It is dose-dependent.
Claims (12)
1. a kind of for including from active cleansing composition, the composition under the environmental condition of the substrate of contamination removal dirt
Arginine alkyl ester and surfactant.
2. active cleansing composition under environmental condition according to claim 1, wherein the arginine alkyl ester is essence
Propylhomoserin methyl esters or arginine ethyl ester or any combination thereof.
3. active cleansing composition according to claim 1 or under environmental condition as claimed in claim 2, wherein the surface is living
Property agent includes anionic surfactant.
4. active cleansing composition according to claim 1 or under environmental condition as claimed in claim 2, wherein the surface is living
Property agent includes rhamnolipid.
5. a kind of pretreatment unit stores active under environmental condition according to claim 1-4 go comprising (i)
The distributor of composition described in the dirt local application of the storeroom of dirty composition and (ii) on basad.
6. a kind of method from the substrate of contamination removal dirt, including the ring to any one of dirt application claim 1-4
Under the conditions of border the step of active cleansing composition, the step carries out at ambient temperature.
7. according to the method described in claim 6, include under environmental condition active cleansing composition addition water to form water
The step of property wash liquid, the liquid is at ambient temperature.
8. according to the method described in claim 6, including dirt local application claim 1-4 on the fabric of contamination any
Active cleansing composition under the environmental condition of item.
9. according to the method described in claim 6, being wherein use the step of active cleansing composition under the conditions of applying environment
The pre-treatment step of the pretreatment unit of claim 5.
10. according to the method described in claim 7, wherein the arginine alkyl ester with 0.01-10mg/ml is present in described wash
It washs in liquid.
11. according to the method described in claim 6, wherein the substrate includes tableware, pottery and other household hard surfaces.
12. the purposes that arginine alkyl ester and surfactant package are used to remove oil/grease fat dirt.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14173221 | 2014-06-20 | ||
| EP14173221.4 | 2014-06-20 | ||
| PCT/EP2015/063233 WO2015193205A1 (en) | 2014-06-20 | 2015-06-12 | Stain treatment compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106536700A CN106536700A (en) | 2017-03-22 |
| CN106536700B true CN106536700B (en) | 2019-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580033157.7A Active CN106536700B (en) | 2014-06-20 | 2015-06-12 | Filth disposal composition |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP3158046B1 (en) |
| CN (1) | CN106536700B (en) |
| BR (1) | BR112016029725B1 (en) |
| WO (1) | WO2015193205A1 (en) |
| ZA (1) | ZA201608405B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317684B (en) * | 2018-06-22 | 2021-05-25 | 华东师范大学 | Natural environment-friendly nontoxic kitchen oil stain cleaning agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1942236U (en) * | 1966-04-27 | 1966-07-14 | Emsdettener Matratzenschoner F | MATTRESS COVER. |
| US3707505A (en) * | 1969-12-30 | 1972-12-26 | Ajinomoto Kk | Enzyme-containing detergent composition |
| EP2305785A1 (en) * | 2009-10-02 | 2011-04-06 | Unilever N.V. | Use of a carboxylic or amino compound as cleaning aid for hard surfaces and method of cleaning such hard surfaces |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1942236A1 (en) * | 1969-08-20 | 1971-03-04 | Henkel & Cie Gmbh | Enzymatic washing agents and detergents |
| WO1997045510A1 (en) * | 1996-05-30 | 1997-12-04 | Salient Science, Inc. | Foaming acidic detergent/cleansing gel |
-
2015
- 2015-06-12 WO PCT/EP2015/063233 patent/WO2015193205A1/en active Application Filing
- 2015-06-12 EP EP15729808.4A patent/EP3158046B1/en active Active
- 2015-06-12 CN CN201580033157.7A patent/CN106536700B/en active Active
- 2015-06-12 BR BR112016029725-3A patent/BR112016029725B1/en active IP Right Grant
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2016
- 2016-12-06 ZA ZA2016/08405A patent/ZA201608405B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1942236U (en) * | 1966-04-27 | 1966-07-14 | Emsdettener Matratzenschoner F | MATTRESS COVER. |
| US3707505A (en) * | 1969-12-30 | 1972-12-26 | Ajinomoto Kk | Enzyme-containing detergent composition |
| EP2305785A1 (en) * | 2009-10-02 | 2011-04-06 | Unilever N.V. | Use of a carboxylic or amino compound as cleaning aid for hard surfaces and method of cleaning such hard surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015193205A1 (en) | 2015-12-23 |
| CN106536700A (en) | 2017-03-22 |
| BR112016029725B1 (en) | 2022-05-10 |
| ZA201608405B (en) | 2019-03-27 |
| EP3158046B1 (en) | 2018-08-15 |
| EP3158046A1 (en) | 2017-04-26 |
| BR112016029725A2 (en) | 2017-08-22 |
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