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CN106520031A - Environment-friendly acrylate adhesive and preparation process thereof - Google Patents

Environment-friendly acrylate adhesive and preparation process thereof Download PDF

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Publication number
CN106520031A
CN106520031A CN201610855950.1A CN201610855950A CN106520031A CN 106520031 A CN106520031 A CN 106520031A CN 201610855950 A CN201610855950 A CN 201610855950A CN 106520031 A CN106520031 A CN 106520031A
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Prior art keywords
parts
acrylic acid
taken
ethyl acetate
adhesive
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CN201610855950.1A
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Chinese (zh)
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CN106520031B (en
Inventor
张中杰
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Yasusa Chemical Co Ltd
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Yasusa Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to the technical field of adhesive, and in particular, relates to an environment-friendly acrylate adhesive and a preparation process thereof. The environment-friendly acrylate adhesive comprises the following raw materials in parts by weight: 600 parts of butyl acrylate, 60 parts of isooctyl acrylate, 55 parts of acrylic acid, 1144 parts of ethyl acetate, 5 parts of 2-hydroxyethyl acrylate, 7 parts of AIBN, and 200 parts of rosin resin. A downstream product of the adhesive has no toluene volatilization, and has friendly environmental performance; at the same time, due to the preparation process of the product, a split charging method is adopted, the occurrence of explosive polymerization is effectively prevented, and the dispersion degree of the product is high; and through the split charging process, the performance of the product is controlled and improved, so that the product has a predetermined viscosity, and the amount of VOC of the downstream product is decreased significantly.

Description

A kind of environmentally-friendly acrylic ester adhesive and its preparation technology
Technical field
The present invention relates to field of adhesive technology, and in particular to a kind of environmentally-friendly acrylic ester adhesive and its preparation work Skill.
Background technology
Adhesive, also known as adhesive, abbreviation glue (bonding agent, adhesive), is to make object tight with another object The close nonmetallic media material for connecting as one.Between two adherend faces, adhesive only accounts for one layer of very thin volume, but makes After completing to be glued construction with adhesive, gained bonded part can meet actual need in terms of mechanical performance and physical and chemical performance The requirements wanted.Can effectively by materials from bonding together.
Extensively, preparation process is simple is rapid with drying and moulding, and the transparency is good for acrylate adhesive raw material sources, There is to multiple material good bond performance, and weatherability, resistance to water, chemical proofing are also good.Particularly to hydrophobic table Facestock material also has excellent cohesiveness, and the resistance to weathering of this rubber-like adhesive can be more excellent, and easy to use, bonding connects Head durability is good.The curing mechanism of acrylate adhesive is:Under light or heat effect, under initiator effect, promote acrylic acid In double bond open, carry out radical chain addition reaction.Can be with oxidative cure:Cause radical chain under oxygen effect Polymerisation.Traditional adhesive, can discharge harmful substance in the curing process, cause VOC often too high, be human health Potential " killer ".
Traditional adhesive, VOC are often too high, are potential " killers " of human health;This product, is used as much as possible The material of low volatility, effectively protects the health of the mankind and environment from source.
Meanwhile, in the adhesive for being prepared for the purpose of environmental protection at present, major part has some shortcomings, low due to having given up Volatile raw material, therefore lose the advantage that these raw materials bring, usually durability is not enough to cause the adhesive for preparing, guarantees the quality Phase is shorter, the unstable properties of adhesive, prolongation over time, and the performance of adhesive reduces very fast, and adhesive is viscous Larger, relative viscosity is spent, adhesion strength reduces, which increases and use difficulty.
The content of the invention
The invention aims to solve the above problems, there is provided a kind of environmentally-friendly acrylic ester adhesive and its preparation work Skill.
In order to reach foregoing invention purpose, the present invention is employed the following technical solutions:
A kind of environmentally-friendly acrylic ester adhesive, its raw materials by weight portion meter include following components:Butyl acrylate 600 Part, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, 1144 parts of ethyl acetate, 5 parts of acrylic acid -2- hydroxyl ethyl esters, 7 parts of AIBN, pine 200 parts of botany bar gum.
Also include property-modifying additive, the property-modifying additive is counted by weight including following components:Sulphur phosphorus brothers alkyl 8 parts of zinc salt, 5 parts of sulfide isobutene, 3 parts of calcium sulfenyl phenolate, 2 parts of pentaerythrite, 1 part of glycerol acrylate, trimethyl phosphate 0.5 part, 0.3 part of nanoscale zirconia, 0.3 part of titanium carbide, 0.5 part of magnesium silicate.
A kind of preparation technology of the environmentally-friendly acrylic ester adhesive of the claims, specifically includes following steps:
1) following raw material is taken by weight ratio:600 parts of butyl acrylate, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, second 1144 parts of acetoacetic ester, 5 parts of acrylic acid -2- hydroxyl ethyl esters, AIBN7 parts, 200 parts of rosin resin;
2) 400 parts of butyl acrylates, 60 parts of Isooctyl acrylate monomers and 500 parts of ethyl acetate are taken, is added in reactor, Stir 1 hour at 60-65 DEG C;
3) 40 parts of acrylic acid, 4 parts of acrylic acid -2- hydroxyl ethyl esters are taken, step 2 is added to) in reactor in, at 60-65 DEG C Lower stirring 0.5 hour;
4) take 200 parts of butyl acrylates, 100 parts of ethyl acetate, 15 parts of acrylic acid, 1 part of acrylic acid -2- hydroxyl ethyl ester to be added to In reactor in step c, stir 1 hour at 60-65 DEG C;
5) take respectively 1.1 parts of AIBN, 0.6 part, 0.6 part, 0.3 part, 0.4 part, 4 parts, then take respectively 10 parts of ethyl acetate, 5 Part, 5 parts, 5 parts, 5 parts, 14 parts, the AIBN for being taken is dissolved separately in taken ethyl acetate successively, and by obtain six parts Solution is added sequentially to step 4) in reactor in, feeding interval be 20 minutes, charging terminate after, stir 1 at 70-80 DEG C Hour;
6) 200 parts of rosin resins are taken to be dissolved in 500 parts of ethyl acetate, step 5 after dissolving, is added to) in reactor in, Stir 1 hour at 80 DEG C, obtain environment-friendly type acrylic acid fat adhesive.
The property-modifying additive was uniformly added into wherein after the completion of step (5) in 10 minutes, was then stirred at 95 DEG C 30 minutes.
Compared with prior art, beneficial effect is the present invention:
Compared with the product of toluene solvant used in prior art, although the basic indifference in performance;Due to this product Preparation technology, using the method for gradation charging, effectively prevent the generation of implode, the decentralization of product is high, and passes through acne The technique of charging causes the performance to product to carry out control improvement, possesses predetermined viscosity so as to not only make product, also makes downstream The VOC amounts of product are substantially reduced.
This product be applied to have environmental requirement (low VOC) field all kinds of materials single or double pressure sensitive adhesive tape, Automobile and confined space are used, such as the field such as the adhering components such as vehicle internal decoration carpet, seat and home decoration;It is particularly well-suited to state Family is fixed to the various interior trims in the strict management and control fields of VOC, and market prospects are very good.
In addition, the performance of the additive of this product product that is remains able to possess good durability and ageing, glue Stick stable performance and year of product is reduced to a certain extent, improve the adhesion strength of product.
Specific embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, implements Method employed in example, is the conventional method of this area.
Embodiment 1:
A kind of environmentally-friendly acrylic ester adhesive, its raw materials by weight portion meter include following components:Butyl acrylate 600 Part, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, 1144 parts of ethyl acetate, 5 parts of acrylic acid -2- hydroxyl ethyl esters, 7 parts of AIBN, pine 200 parts of botany bar gum.
For above raw material, the preparation technology of the environmentally-friendly acrylic ester adhesive of this case, following steps are specifically included: (per part is 100g below)
1) following raw material is taken by weight ratio:600 parts of butyl acrylate, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, second 1144 parts of acetoacetic ester, 5 parts of acrylic acid -2- hydroxyl ethyl esters, AIBN7 parts, 200 parts of rosin resin;
2) 400 parts of butyl acrylates, 60 parts of Isooctyl acrylate monomers and 500 parts of ethyl acetate are taken, is added in reactor, Stir 1 hour at 60-65 DEG C;
3) 40 parts of acrylic acid, 4 parts of acrylic acid -2- hydroxyl ethyl esters are taken, step 2 is added to) in reactor in, at 60-65 DEG C Lower stirring 0.5 hour;
4) take 200 parts of butyl acrylates, 100 parts of ethyl acetate, 15 parts of acrylic acid, 1 part of acrylic acid -2- hydroxyl ethyl ester to be added to In reactor in step c, stir 1 hour at 60-65 DEG C;
5) take respectively 1.1 parts of AIBN, 0.6 part, 0.6 part, 0.3 part, 0.4 part, 4 parts, then take respectively 10 parts of ethyl acetate, 5 Part, 5 parts, 5 parts, 5 parts, 14 parts, the AIBN for being taken is dissolved separately in taken ethyl acetate successively, and by obtain six parts Solution is added sequentially to step 4) in reactor in, feeding interval be 20 minutes, charging terminate after, stir 1 at 70-80 DEG C Hour;
6) 200 parts of rosin resins are taken to be dissolved in 500 parts of ethyl acetate, step 5 after dissolving, is added to) in reactor in, Stir 1 hour at 80 DEG C, obtain environment-friendly type acrylic acid fat adhesive.
The product main technical performance index of preparation
1st, solid content (%):47.0±1.0;
2nd, viscosity (cP/25 DEG C):9000-11000;
3rd, adhesion strength (gf/25mm):1200-1400;
4th, confining force (mm):0-0.5;
5th, initial bonding strength (steel ball number):7—12;
6th, maturation condition:40℃×72H.
Embodiment 2:
A kind of environmentally-friendly acrylic ester adhesive, it is characterised in that its raw materials by weight portion meter includes following components:Third 600 parts of olefin(e) acid butyl ester, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, 1144 parts of ethyl acetate, 5 parts of acrylic acid -2- hydroxyl ethyl esters, 7 parts of AIBN, 200 parts of rosin resin and property-modifying additive, property-modifying additive include:8 parts of sulphur phosphorus brothers alkyl zinc salt, vulcanizes different 5 parts of butylene, 3 parts of calcium sulfenyl phenolate, 2 parts of pentaerythrite, 1 part of glycerol acrylate, 0.5 part of trimethyl phosphate, nanoscale oxygen Change 0.3 part of zirconium, 0.3 part of titanium carbide, 0.5 part of magnesium silicate.
For above raw material, and additive, the preparation technology of the environmentally-friendly acrylic ester adhesive in this case, specifically include Following steps:
1) following raw material is taken by weight ratio:600 parts of butyl acrylate, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, second 1144 parts of acetoacetic ester, 5 parts of acrylic acid -2- hydroxyl ethyl esters, AIBN7 parts, 200 parts of rosin resin;
2) 400 parts of butyl acrylates, 60 parts of Isooctyl acrylate monomers and 500 parts of ethyl acetate are taken, is added in reactor, Stir 1 hour at 60-65 DEG C;
3) 40 parts of acrylic acid, 4 parts of acrylic acid -2- hydroxyl ethyl esters are taken, step 2 is added to) in reactor in, at 60-65 DEG C Lower stirring 0.5 hour;
4) take 200 parts of butyl acrylates, 100 parts of ethyl acetate, 15 parts of acrylic acid, 1 part of acrylic acid -2- hydroxyl ethyl ester to be added to In reactor in step c, stir 1 hour at 60-65 DEG C;
5) take respectively 1.1 parts of AIBN, 0.6 part, 0.6 part, 0.3 part, 0.4 part, 4 parts, then take respectively 10 parts of ethyl acetate, 5 Part, 5 parts, 5 parts, 5 parts, 14 parts, the AIBN for being taken is dissolved separately in taken ethyl acetate successively, and by obtain six parts Solution is added sequentially to step 4) in reactor in, feeding interval be 20 minutes, charging terminate after, stir 1 at 70-80 DEG C Hour;Then property-modifying additive is uniformly added into wherein in 10 minutes, is then stirred 30 minutes at 95 DEG C.
6) 200 parts of rosin resins are taken to be dissolved in 500 parts of ethyl acetate, step 5 after dissolving, is added to) in reactor in, Stir 1 hour at 80 DEG C, obtain environment-friendly type acrylic acid fat adhesive.
The product main technical performance index of preparation
1st, solid content (%):47.0±1.0;
2nd, viscosity (cP/25 DEG C):7000-8000;
3rd, adhesion strength (gf/25mm):1300-1500;
4th, confining force (mm):0-0.5;
5th, initial bonding strength (steel ball number):7—12;
6th, maturation condition:40℃×72H.
From properties of product data, this product it is annual moderate, adhesion strength is preferable, it is adaptable to have environmental requirement (low VOC) the single or double pressure sensitive adhesive tape of all kinds of materials in field, automobile and confined space use, such as vehicle internal decoration carpet, The field such as the adhering components such as seat and home decoration;It is particularly well-suited to country to fix the various interior trims in the strict management and control fields of VOC, Market prospects are very good.
In addition, embodiment 2 is compared with Example 1, viscosity is reduced, and adhesion strength is improved.

Claims (4)

1. a kind of environmentally-friendly acrylic ester adhesive, it is characterised in that its raw materials by weight portion meter includes following components:Propylene 600 parts of acid butyl ester, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, 1144 parts of ethyl acetate, 5 parts of acrylic acid -2- hydroxyl ethyl esters, 7 parts of AIBN, 200 parts of rosin resin.
2. a kind of environmentally-friendly acrylic ester adhesive according to claim 1, it is characterised in that also including modified addition Agent, the property-modifying additive are counted by weight including following components:8 parts of sulphur phosphorus brothers alkyl zinc salt, 5 parts of sulfide isobutene, 3 parts of calcium sulfenyl phenolate, 2 parts of pentaerythrite, 1 part of glycerol acrylate, 0.5 part of trimethyl phosphate, nanoscale zirconia 0.3 Part, 0.3 part of titanium carbide, 0.5 part of magnesium silicate.
3. the preparation technology of the environmentally-friendly acrylic ester adhesive of a kind of the claims, it is characterised in that specifically include with Lower step:
1) following raw material is taken by weight ratio:600 parts of butyl acrylate, 60 parts of Isooctyl acrylate monomer, 55 parts of acrylic acid, acetic acid second 1144 parts of ester, 5 parts of acrylic acid -2- hydroxyl ethyl esters, AIBN7 parts, 200 parts of rosin resin;
2) 400 parts of butyl acrylates, 60 parts of Isooctyl acrylate monomers and 500 parts of ethyl acetate are taken, is added in reactor, in 60- Stir 1 hour at 65 DEG C;
3) 40 parts of acrylic acid, 4 parts of acrylic acid -2- hydroxyl ethyl esters are taken, step 2 is added to) in reactor in, stir at 60-65 DEG C Mix 0.5 hour;
4) 200 parts of butyl acrylates, 100 parts of ethyl acetate, 15 parts of acrylic acid, 1 part of acrylic acid -2- hydroxyl ethyl ester are taken and is added to step In reactor in c, stir 1 hour at 60-65 DEG C;
5) take respectively 1.1 parts of AIBN, 0.6 part, 0.6 part, 0.3 part, 0.4 part, 4 parts, then take respectively 10 parts of ethyl acetate, 5 parts, 5 Part, 5 parts, 5 parts, 14 parts, the AIBN for being taken is dissolved separately in taken ethyl acetate successively, and by obtain six parts of solution Be added sequentially to step 4) in reactor in, feeding interval is 20 minutes, and after charging terminates, at 70-80 DEG C, stirring is 1 little When;
6) 200 parts of rosin resins are taken to be dissolved in 500 parts of ethyl acetate, step 5 after dissolving, is added to) in reactor in, 80 Stir 1 hour at DEG C, obtain environment-friendly type acrylic acid fat adhesive.
4. the preparation technology of a kind of environmentally-friendly acrylic ester adhesive according to claim 3, it is characterised in that described to change Property additive after the completion of step (5), be uniformly added into wherein in 10 minutes, then at 95 DEG C stir 30 minutes.
CN201610855950.1A 2016-09-28 2016-09-28 A kind of environmentally-friendly acrylic ester adhesive and its preparation process Active CN106520031B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551455A (en) * 2019-08-05 2019-12-10 安佐化学有限公司 low-odor low-VOC benzene-free acrylate adhesive
CN112812715A (en) * 2019-11-18 2021-05-18 德莎欧洲股份公司 Flame-retardant pressure-sensitive adhesive
CN112852352A (en) * 2021-01-06 2021-05-28 广东银洋环保新材料有限公司 Water-based adhesive for compounding automotive carpet and preparation method thereof
CN114058297A (en) * 2021-12-23 2022-02-18 平湖市浙江工业大学新材料研究院 Preparation method of low-VOC halogen-free flame-retardant pressure-sensitive adhesive

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238334A (en) * 2015-11-12 2016-01-13 四川厚生天佐药业有限公司 Single-component cross-linking type medical polyacrylate pressure-sensitive adhesive
CN105542687A (en) * 2016-02-29 2016-05-04 安佐化学有限公司 Preparation technology of acrylate adhesive and acrylate adhesive product
CN105950081A (en) * 2016-06-23 2016-09-21 哈尔滨工业大学无锡新材料研究院 High/low-temperature-alternation-resistant pressure-sensitive adhesive and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238334A (en) * 2015-11-12 2016-01-13 四川厚生天佐药业有限公司 Single-component cross-linking type medical polyacrylate pressure-sensitive adhesive
CN105542687A (en) * 2016-02-29 2016-05-04 安佐化学有限公司 Preparation technology of acrylate adhesive and acrylate adhesive product
CN105950081A (en) * 2016-06-23 2016-09-21 哈尔滨工业大学无锡新材料研究院 High/low-temperature-alternation-resistant pressure-sensitive adhesive and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551455A (en) * 2019-08-05 2019-12-10 安佐化学有限公司 low-odor low-VOC benzene-free acrylate adhesive
CN112812715A (en) * 2019-11-18 2021-05-18 德莎欧洲股份公司 Flame-retardant pressure-sensitive adhesive
EP3822329A1 (en) * 2019-11-18 2021-05-19 tesa SE Fire-retardant pressure sensitive adhesive
CN112852352A (en) * 2021-01-06 2021-05-28 广东银洋环保新材料有限公司 Water-based adhesive for compounding automotive carpet and preparation method thereof
CN114058297A (en) * 2021-12-23 2022-02-18 平湖市浙江工业大学新材料研究院 Preparation method of low-VOC halogen-free flame-retardant pressure-sensitive adhesive
CN114058297B (en) * 2021-12-23 2022-12-13 平湖市浙江工业大学新材料研究院 Preparation method of low-VOC halogen-free flame-retardant pressure-sensitive adhesive

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Denomination of invention: An environment-friendly acrylate adhesive and its preparation process

Effective date of registration: 20211026

Granted publication date: 20181102

Pledgee: Dushangang sub branch of Zhejiang Pinghu Rural Commercial Bank Co., Ltd

Pledgor: YASUSA CHEMICAL Co.,Ltd.

Registration number: Y2021330001966