CN106519826A - Waterproof heat-insulating radiation fluorocarbon coating material and preparation method thereof - Google Patents
Waterproof heat-insulating radiation fluorocarbon coating material and preparation method thereof Download PDFInfo
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- CN106519826A CN106519826A CN201610846303.4A CN201610846303A CN106519826A CN 106519826 A CN106519826 A CN 106519826A CN 201610846303 A CN201610846303 A CN 201610846303A CN 106519826 A CN106519826 A CN 106519826A
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- parts
- heat
- deionized water
- infrared absorption
- waterproof
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- 239000011248 coating agent Substances 0.000 title claims abstract description 41
- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 13
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 title abstract description 6
- 230000005855 radiation Effects 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000010521 absorption reaction Methods 0.000 claims abstract description 19
- 239000011858 nanopowder Substances 0.000 claims abstract description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims abstract description 11
- GAGGCOKRLXYWIV-UHFFFAOYSA-N europium(3+);trinitrate Chemical compound [Eu+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GAGGCOKRLXYWIV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 10
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229960000583 acetic acid Drugs 0.000 claims abstract description 8
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 8
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims abstract description 7
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 4
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000000839 emulsion Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 13
- FLJPGEWQYJVDPF-UHFFFAOYSA-L caesium sulfate Chemical compound [Cs+].[Cs+].[O-]S([O-])(=O)=O FLJPGEWQYJVDPF-UHFFFAOYSA-L 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
- -1 Lauryl Alcohol ester Chemical class 0.000 claims description 6
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000000600 sorbitol Substances 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 238000004137 mechanical activation Methods 0.000 claims description 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- 238000000643 oven drying Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 2
- 230000007717 exclusion Effects 0.000 claims description 2
- YXCDZXGJZDGMEP-UHFFFAOYSA-N 4-hydroxy-3,3-bis(hydroxymethyl)butan-2-one Chemical compound CC(=O)C(CO)(CO)CO YXCDZXGJZDGMEP-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- LZFMACRHJXVTIV-UHFFFAOYSA-N [F].C(=C)Cl Chemical compound [F].C(=C)Cl LZFMACRHJXVTIV-UHFFFAOYSA-N 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 abstract 1
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 abstract 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 abstract 1
- 229940015043 glyoxal Drugs 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001940 europium oxide Inorganic materials 0.000 description 1
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/24—Trifluorochloroethene
- C08F214/245—Trifluorochloroethene with non-fluorinated comonomers
- C08F214/247—Trifluorochloroethene with non-fluorinated comonomers with non-fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a waterproof heat-insulating radiation fluorocarbon coating material. The waterproof heat-insulating radiation fluorocarbon coating material is characterized by being prepared from the following raw materials: trifluorochloroethylene, infrared absorption nano-powder, perfluoro-methyl vinyl ether, butyl vinyl ether, hydroxypropyl methacrylate, ammonium persulfate, glyoxal, trihydroxymethylpropane tripolypropylene glycol ether, europium nitrate, butyl titanate, anhydrous ethanol, glacial acetic acid, polyethylene glycol, vinyl triethoxysilane, toluene, hydroxyethyl cellulose, 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate, dipropylene glycol mono butyl ether, a proper amount of sodium bicarbonate and a proper volume of deionized water. The waterproof heat-insulating radiation fluorocarbon coating material disclosed by the invention is good in heat insulating effect, has excellent mechanical properties, good adhesive power and good weather resistance, water resistance, stain resistance, scrubbing resistance and the like, is safe and environmentally friendly and is wide in applicable range.
Description
Technical field
The present invention relates to a kind of coating, more particularly to a kind of heat-insulated radial pattern coating of fluorine carbon of waterproof and preparation method thereof.
Background technology
With developing rapidly for China's building trade and becoming increasingly conspicuous for energy crisis, the energy-saving of building is got over
Send out important.The building energy consumption of China accounts for the 27% of national energy aggregate consumption, occupies first of national all kinds of energy consumptions.
The energy consumption of heating and air-conditioning accounts for the 55% of building total energy consumption, but also increases in the speed with annual 1 percentage point.
Because a little, research and develop insulating mold coating for construction and there is great economic benefit, environmental benefit and social benefit.Make in external wall
The original decoration of coating, protection and the function such as mould proof not only can be realized with the coating with heat insulating function, but also make coating
With heat-insulated function, keep indoor temperature constant, increase the temperature difference of indoor and outdoor, warm energy consumption is reduced in summer, reduced in the winter time
Heat cost.At present, heat-barrier material is just experiencing the transformation to based on heat-insulating heat-insulated from industry, and this is also heat-insulated material from now on
One of main development direction of material.Insulating moulding coating has the disadvantage that in the market：
1st, poor insulation property：The density of glass microballoon or ceramic fine bead is high with respect to borosilicate hollow glass micropearl, thus in phase
Under with addition consumption, the coating acquisition dry film heat insultating cavity using glass microballoon or ceramic fine bead is few, and coating thickness is relatively low, adiabatic
Poor performance；
2nd, poor storage stability：Glass microballoon or ceramic fine bead etc. are through surface treatment and density is relatively low, make coating in storage
During easily produce viscosity increase and the phenomenon for floating；
3rd, construct inconvenient：Using glass microballoon or the insulating moulding coating of ceramic fine bead, in order to prevent that what is floated during storing to show
As, the usual initial viscosity for improving coating, thus higher paint film can only be obtained by the way of blade coating or batch painting during construction
Thickness.
Author Li little Bing et al. exists《The preparation of multifunctional aqueous nano combined insulating mold coating for construction》It is in one text, poly- with aqueouss
Urethane is film former, with well dispersed Pulvis Talci as filler, the rutile titanium dioxide of high reflection, hollow glass micropearl be every
Hot merit energy color stuffing, adds the sericite of high radiance, and dispersion improves dispersibility of the Nano filling in coating, system to Jing at a high speed
Standby multifunctional aqueous nano composite heat insulation insulating moulding coating；The multifunctional aqueous nano composite heat insulation insulating moulding coating developed, its every
Hot excellent thermal insulation performance and the characteristic with high-quality low-cost.
The content of the invention
For the problems referred to above and demand existing for prior art, it is an object of the invention to provide good heat-insulation effect, storage
It is stable, heat-insulated radial pattern coating of fluorine carbon of the waterproof of easy construction and preparation method thereof.
For achieving the above object, technical scheme is as follows：
The heat-insulated radial pattern coating of fluorine carbon of a kind of waterproof, it is characterised in which is prepared from by the raw material of following weight portion：Trifluoro
200 parts of vinyl chloride, INFRARED ABSORPTION nano-powder 30-40 parts, perfluoro methyl vinyl ether 30-40 parts, butyl vinyl ether 30-40
Part, Hydroxypropyl methacrylate 15-20 parts, Ammonium persulfate. 3-5 parts, Biformyl 12-15 parts, three polypropylene glycol ether of trimethylol propane
6-8 parts, europium nitrate 12-15 parts, butyl titanate 15-20 parts, dehydrated alcohol 100-120 parts, glacial acetic acid 15-20 parts, Polyethylene Glycol
8-10 parts, VTES 6-8 parts, toluene 80-100 parts, hydroxyethyl cellulose 8-10 parts, Lauryl Alcohol ester 6-8
Part, dipropylene 8-10 parts, appropriate sodium bicarbonate, appropriate deionized water.
The heat-insulated radial pattern coating of fluorine carbon of described waterproof, it is characterised in that described INFRARED ABSORPTION nano-powder, by such as
The raw material of lower weight portion is prepared from：100 parts of Sorbitol, ethylene glycol 60-80 parts, 30 parts of wolframic acid, cesium sulfate 10-15 parts, go from
Sub- appropriate amount of water, appropriate dehydrated alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：By Sorbitol and second
Glycol heating for dissolving in jacket reactor, adds wolframic acid and cesium sulfate, and after high-speed stirred 30-40min, pumping into homogenizer is carried out
Circulation homogenizes, and pumps into product and be heated in 140-150 DEG C of autoclave after 60-80min, and autoclave is turned
Speed is set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, closes each valve of autoclave, with 10-15
DEG C/temperature of reaction kettle rises to 350 DEG C, and is incubated 10-12h by the heating rate of min, 140-150 DEG C is cooled to, reaction is released
Product, is added thereto to deionized water, and material is squeezed into pressure filter, with deionized water, absolute ethanol washing 3-5 time, by filter cake
Put vacuum drying oven drying into, then carry out mechanical activation comminution and comminution by gas stream, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of fluorine carbon of described waterproof, it is characterised in that the heat-insulated radial pattern of fluorine carbon of described waterproof
Coating its be prepared from by following steps：
（1）1/2 dehydrated alcohol, glacial acetic acid, Polyethylene Glycol and deionized water equivalent to 5-6 times of europium nitrate weight portion are mixed
Close, add europium nitrate, after stirring and dissolving, obtain solution；The solution that butyl titanate is configured with remaining dehydrated alcohol is slowly added dropwise,
Stirring 4-5h, is added in toluene Jing after standing, be dried, adds VTES, stir 40-50min, be passed through nitrogen
Gas, is warming up to 75-80 DEG C under the protection of nitrogen, stirring reaction 4-6h, washs, is dried；
（2）By CTFE, INFRARED ABSORPTION nano-powder, equivalent to the deionized water of 10-12 times of CTFE weight portion,
Be added in reactor, sodium bicarbonate added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, fourth
Base vinyl ethers and Hydroxypropyl methacrylate, high-speed stirred dispersion and emulsion 40-50min obtain emulsion droplets particle diameter less than 800nm
Pre-emulsion to be polymerized；Continue the logical nitrogen in reactor under high velocity agitation, the oxygen concentration in exclusion reactor to 80ppm
Hereinafter, under nitrogen atmosphere, the emulsion in reactor is made to be warmed up to 60-70 DEG C, Deca Ammonium persulfate. and equivalent to Ammonium persulfate. weight
The solution of the deionized water configuration of 5-6 times of part of amount, controls in 40-60min completion of dropping, and 60-70 DEG C of isothermal reaction 5-8h heats up
Continue reaction 1-2h to 75-85 DEG C, cool to 30 DEG C, add sodium bicarbonate, the pH value of emulsion is adjusted to 6-7；Add Biformyl,
50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add three polypropylene glycol ether of trimethylol propane, step（1）Product and hydroxy ethyl fiber
Element, stirs 30-60min with 1800-2000rpm；Lauryl Alcohol ester and dipropylene is added, is stirred with 800-1000rpm
40-50min, obtains final product the heat-insulated radial pattern coating of fluorine carbon of waterproof.
Using technical scheme, with following technique effect：
The present invention adds INFRARED ABSORPTION nano-powder, using solvent thermal liquid phase method technique, with wolframic acid, cesium sulfate production caesium tungsten bronze
INFRARED ABSORPTION nano-powder；Concentrate on 0.78-2.5 mum wavelengths based on 95% of heat energy in sunlight wave band, and caesium tungsten bronze
Lacking oxygen in INFRARED ABSORPTION nano-powder can produce to absorb to the infrared ray of this section of wavelength makes the electron transition of caesium and tungsten paramount
Energy position, produces the reflection and diffraction of light wave luminous energy, enters basic unit so as to separate heat energy, obtains good effect of heat insulation；This
Invention is polymerized the fluorocarbon resin for obtaining as film former with CTFE and butyl vinyl ether, then with Hydroxypropyl methacrylate
Fluorocarbon resin is carried out with Biformyl cross-linking modified, enhances the toughness and weatherability of coating, improve coating wearability and
Adhesion property；The present invention prepares nano titanium oxide and nano europium oxide using butyl titanate, europium nitrate and glacial acetic acid, and at which
Surface grafting VTES, obtains super-hydrophobic nanometer powder, improves insulating moulding coating water resistance and wear-resisting
Performance；The heat-insulated radial pattern coating good heat-insulation effect of fluorine carbon of the present invention；And with excellent mechanical performance, excellent adhesive force；
Excellent weatherability, resistance to water, stain resistance, abrasion resistance etc.；Safety and environmental protection, it is applied widely.
Specific embodiment
The heat-insulated radial pattern coating of fluorine carbon of the waterproof of the present embodiment, which is prepared from by the raw material of following weight portion：Trifluoro
200 parts of vinyl chloride, 40 parts of INFRARED ABSORPTION nano-powder, 40 parts of perfluoro methyl vinyl ether, 40 parts of butyl vinyl ether, methyl-prop
20 parts of olefin(e) acid hydroxypropyl acrylate, 5 parts of Ammonium persulfate., 15 parts of Biformyl, 8 parts of three polypropylene glycol ether of trimethylol propane, 15 parts of europium nitrate, titanium
20 parts of acid butyl ester, 120 parts of dehydrated alcohol, 20 parts of glacial acetic acid, 10 parts of Polyethylene Glycol, 8 parts of VTES, toluene
100 parts, 10 parts of hydroxyethyl cellulose, 8 parts of Lauryl Alcohol ester, 10 parts of dipropylene, appropriate sodium bicarbonate, deionized water fit
Amount.
The INFRARED ABSORPTION nano-powder of the present embodiment, is prepared from by the raw material of following weight portion：100 parts of Sorbitol, second
60 parts of glycol, 30 parts of wolframic acid, 15 parts of cesium sulfate, appropriate deionized water, appropriate dehydrated alcohol；Described INFRARED ABSORPTION nano powder
Body, is prepared from by following steps：The heating for dissolving in jacket reactor by Sorbitol and ethylene glycol, adds wolframic acid and sulphuric acid
Caesium, after high-speed stirred 40min, pumps into homogenizer and is circulated and homogenize, pump into product and be heated to 150 DEG C after 80min
In autoclave, autoclave rotating speed is set to into 200r/min, after above-mentioned material is completely transferred to autoclave, is closed high
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 15 DEG C/min, and is incubated 12h, cooled to by each valve of pressure reactor
150 DEG C, product is released, deionized water is added thereto to, material is squeezed into into pressure filter, washed with deionized water, dehydrated alcohol
Wash 5 times, put filter cake into vacuum drying oven drying, then carry out mechanical activation comminution and comminution by gas stream, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of fluorine carbon of the waterproof of the present embodiment its be prepared from by following steps：
（1）By 1/2 dehydrated alcohol, glacial acetic acid, Polyethylene Glycol and the deionized water mixing equivalent to 6 times of europium nitrate weight portion,
Europium nitrate is added, solution after stirring and dissolving, is obtained；The solution that butyl titanate is configured with remaining dehydrated alcohol is slowly added dropwise, is stirred
5h, is added in toluene Jing after standing, be dried, adds VTES, stir 50min, be passed through nitrogen, in nitrogen
Protection under be warming up to 80 DEG C, stirring reaction 6h, washing, be dried；
（2）By CTFE, INFRARED ABSORPTION nano-powder, equivalent to the deionized water of 12 times of CTFE weight portion, plus
To in reactor, sodium bicarbonate is added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, butyl
Vinyl ethers and Hydroxypropyl methacrylate, high-speed stirred dispersion and emulsion 50min obtain emulsion droplets particle diameter treating less than 800nm
Polymerization pre-emulsion；Continue under high velocity agitation in reactor lead to nitrogen, exclude reactor in oxygen concentration to 80ppm with
Under, under nitrogen atmosphere, make the emulsion in reactor be warmed up to 70 DEG C, Deca Ammonium persulfate. and equivalent to Ammonium persulfate. weight portion 6
The solution of deionized water configuration again, controls in 60min completion of dropping, 70 DEG C of isothermal reaction 8h, is warmed up to 85 DEG C and continues reaction
2h, cools to 30 DEG C, adds sodium bicarbonate, adjusts the pH value of emulsion to 6-7；Biformyl is added, 60 DEG C are continued reaction 8h；
（3）To step（2）Product in add three polypropylene glycol ether of trimethylol propane, step（1）Product and hydroxy ethyl fiber
Element, stirs 60min with 2000rpm；Lauryl Alcohol ester and dipropylene is added, 50min is stirred with 1000rpm, is obtained final product anti-
The heat-insulated radial pattern coating of fluorine carbon of water.
Jing is tested, and the temperature difference of coating both sides is more than 10 DEG C, and heat-insulated rate is more than 85%.
Claims (3)
1. the heat-insulated radial pattern coating of the fluorine carbon of a kind of waterproof, it is characterised in which is prepared from by the raw material of following weight portion：Three
200 parts of fluorine vinyl chloride, INFRARED ABSORPTION nano-powder 30-40 parts, perfluoro methyl vinyl ether 30-40 parts, butyl vinyl ether 30-
40 parts, Hydroxypropyl methacrylate 15-20 parts, Ammonium persulfate. 3-5 parts, Biformyl 12-15 parts, three polypropylene glycol of trimethylol propane
Ether 6-8 parts, europium nitrate 12-15 parts, butyl titanate 15-20 parts, dehydrated alcohol 100-120 parts, glacial acetic acid 15-20 parts, poly- second two
Alcohol 8-10 parts, VTES 6-8 parts, toluene 80-100 parts, hydroxyethyl cellulose 8-10 parts, Lauryl Alcohol ester 6-
8 parts, dipropylene 8-10 parts, appropriate sodium bicarbonate, appropriate deionized water.
2. the heat-insulated radial pattern coating of the fluorine carbon of waterproof according to claim 1, it is characterised in that described INFRARED ABSORPTION is received
Rice flour body, is prepared from by the raw material of following weight portion：100 parts of Sorbitol, ethylene glycol 60-80 parts, 30 parts of wolframic acid, cesium sulfate
10-15 parts, appropriate deionized water, appropriate dehydrated alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：
The heating for dissolving in jacket reactor by Sorbitol and ethylene glycol, adds wolframic acid and cesium sulfate, after high-speed stirred 30-40min, pump
Enter homogenizer and be circulated to homogenize, product is pumped into after 60-80min and be heated in 140-150 DEG C of autoclave, will
Autoclave rotating speed is set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, closes autoclave each
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 10-15 DEG C/min, and is incubated 10-12h, cools to 140- by valve
150 DEG C, product is released, deionized water is added thereto to, material is squeezed into into pressure filter, washed with deionized water, dehydrated alcohol
Wash 3-5 time, put filter cake into vacuum drying oven drying, then carry out mechanical activation comminution and comminution by gas stream, that is, obtain INFRARED ABSORPTION nano powder
Body.
3. the heat-insulated radial pattern coating of the fluorine carbon of waterproof according to claim 1, it is characterised in that the fluorine carbon of described waterproof
Heat-insulated radial pattern coating its be prepared from by following steps：
（1）1/2 dehydrated alcohol, glacial acetic acid, Polyethylene Glycol and deionized water equivalent to 5-6 times of europium nitrate weight portion are mixed
Close, add europium nitrate, after stirring and dissolving, obtain solution；The solution that butyl titanate is configured with remaining dehydrated alcohol is slowly added dropwise,
Stirring 4-5h, is added in toluene Jing after standing, be dried, adds VTES, stir 40-50min, be passed through nitrogen
Gas, is warming up to 75-80 DEG C under the protection of nitrogen, stirring reaction 4-6h, washs, is dried；
（2）By CTFE, INFRARED ABSORPTION nano-powder, equivalent to the deionized water of 10-12 times of CTFE weight portion,
Be added in reactor, sodium bicarbonate added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, fourth
Base vinyl ethers and Hydroxypropyl methacrylate, high-speed stirred dispersion and emulsion 40-50min obtain emulsion droplets particle diameter less than 800nm
Pre-emulsion to be polymerized；Continue the logical nitrogen in reactor under high velocity agitation, the oxygen concentration in exclusion reactor to 80ppm
Hereinafter, under nitrogen atmosphere, the emulsion in reactor is made to be warmed up to 60-70 DEG C, Deca Ammonium persulfate. and equivalent to Ammonium persulfate. weight
The solution of the deionized water configuration of 5-6 times of part of amount, controls in 40-60min completion of dropping, and 60-70 DEG C of isothermal reaction 5-8h heats up
Continue reaction 1-2h to 75-85 DEG C, cool to 30 DEG C, add sodium bicarbonate, the pH value of emulsion is adjusted to 6-7；Add Biformyl,
50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add three polypropylene glycol ether of trimethylol propane, step（1）Product and hydroxy ethyl fiber
Element, stirs 30-60min with 1800-2000rpm；Lauryl Alcohol ester and dipropylene is added, is stirred with 800-1000rpm
40-50min, obtains final product the heat-insulated radial pattern coating of fluorine carbon of waterproof.
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| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104403476A (en) * | 2014-11-28 | 2015-03-11 | 安徽省金盾涂料有限责任公司 | Self-cleaning antibacterial fluorocarbon coating |
| CN105131772A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Self-cleaning antifouling inter wall paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104403476A (en) * | 2014-11-28 | 2015-03-11 | 安徽省金盾涂料有限责任公司 | Self-cleaning antibacterial fluorocarbon coating |
| CN105131772A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Self-cleaning antifouling inter wall paint |
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