CN106508924A - Nematicide composition containing fluazaindolizine and amino-oligosaccharin - Google Patents
Nematicide composition containing fluazaindolizine and amino-oligosaccharin Download PDFInfo
- Publication number
- CN106508924A CN106508924A CN201610955180.8A CN201610955180A CN106508924A CN 106508924 A CN106508924 A CN 106508924A CN 201610955180 A CN201610955180 A CN 201610955180A CN 106508924 A CN106508924 A CN 106508924A
- Authority
- CN
- China
- Prior art keywords
- amino
- oligosaccharide
- pyridine amide
- miaow pyridine
- composition pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a nematicide composition containing fluazaindolizine and amino-oligosaccharin. The active components of the nematicide composition contains fluazaindolizine and amino-oligosaccharin, wherein the weight ratio of fluazaindolizine to amino-oligosaccharin is 1: 30-30:1, and preferably 1:10-10:1. The mutual synergism between two active components of the nematicide composition can increase the prevention and treatment effects, reduces the pesticide application amount, is safe to environment, and is worth of popularization and application.
Description
Technical field
The invention belongs to pesticide nematicide technical field, and in particular to be a kind of few with amino containing trifluoro miaow pyridine amide
The nematicidal composition of sugared element.
Background technology
Nematicide is the common agricultural disease of a class, and host range is extensively, often cause harm melon, solanaceous vegetables, beans and Radix Raphani, white
30 various crop such as dish, Rhizoma Zingiberis Recens, Herba Alii fistulosi, Bulbus Allii, Fructus Musae.Root-knot nematode is common are, the root knot that plant root forms enlargement is often resulted in, no
Energy normal absorption nutrient, causes plant withered and yellow or dead, while some funguses and bacterial disease can also be propagated.
Trifluoro miaow pyridine amide (fluazaindolizine), non-stifling property nematicide, to soybean cyst nematode Heterodera glycines, kidney shape line
Worm, pratylenchus, root-knot nematode, minute hand nematicide etc. are respectively provided with fabulous biological activity.
Amino-oligosaccharide, English name:Oligosaccharins, research have found amino-oligosaccharide to root-knot nematode and ovum
Activity it is very high, the protein coat and cell wall of nematicide, line eggs, funguses, antibacterial and virus can be dissolved, can also after use
Enough stimulate the generation of plant itself chitinase and antibiotic, the immunity of activated plant and growing system reaction, suppress pathogen
Intrusion, promote plant growth promoter, so as to effectively treat and defend the generation of crop pest and virosiss.And be crop
Middle and trace element is supplemented, crop quality is improved, and to the various crop safety such as melon, Fructus Musae, green onion, ginger and garlic, Solanaceae, vegetable.
The mixture of different pesticide species, is the agriculture disease-resistant, worm of preventing and treating, the common methods of crop smothering.Screened by formulation of pesticide,
Rational formula is filtered out, actual prevention effect can be effectively improved, reduce dosage, reduces cost delays disease drug resistance
Produce, be disease, worm, the important means of crop smothering comprehensive control.Present inventor is by trifluoro miaow pyridine amide and amino-oligosacchride
The further investigation of plain recipe determination, finds for trifluoro miaow pyridine amide and amino-oligosaccharide to carry out mixture, in certain mixed ratio
In the range of there is obvious potentiation to nematicide, can effectively preventing crops nematicide, reduce dosage, meet " pesticide zero
The demand of growth ".After further research, complete the present invention.At present, there is no with regard to trifluoro miaow pyridine amide and amino-oligosaccharide
The relevant report of compounding.
The content of the invention
It is an object of the invention to provide a kind of pesticide that can prevent and treat crops root-knot nematodes and seedling stage diseases and pests simultaneously
Compositionss.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that：A kind of composition pesticide, it is characterised in that activity
Composition includes trifluoro miaow pyridine amide and amino-oligosaccharide, wherein, trifluoro miaow pyridine amide is 1 with the weight ratio of amino-oligosaccharide:30-
30:1, preferably 1:10-10:1.
The formulations of pesticide that described nematicidal composition of the present invention can be prepared are suspending agent, wettable powder, water preparation, water
Dispersible granule, aqueous emulsion, microemulsion, granule, micro-capsule suspension.Wherein effective ingredient trifluoro miaow pyridine amide and amino-oligosacchride
Element gross mass in the formulation accounts for the 1%～80% of the whole quality of the pharmaceutical preparations, wherein when accounting for 3%～60%, toxicity and residual reach
Preferably balance, cost is relatively low.Further, the composition pesticide also include other agricultural active compositions, such as insecticide,
Antibacterial, herbicide, fertilizer, safener.
Further, the insecticide-applying way of composition pesticide of the invention using spreading fertilizer over the fields, ditch spread, spread manuer in holes, rush what is applied, spray etc.
One kind, frequency of administration and amount of application change with weather conditions and nematicide situation of the harm and change, and can pass through to apply appropriate agent
Amount reaches prevents and treats purpose.
Further, composition pesticide of the invention is applied to preventing and treating elimination of underground destructive pests, especially prevents and treats root knot line
Worm.
Compared with prior art, the beneficial effects of the present invention is：
（1）The nematicidal composition of the present invention, serves synergistic function each other, reduces agriculture to the preventing and treating of nematicide
The usage amount of medicine, increased prevention effect, be conducive to saving drug cost and the pollution to environment；
（2）The nematicidal composition of the present invention has the advantages that technique is easy to control, product quality is stable, continuously can produce, and fits
Together in industrialization.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that it is all the present invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
Embodiment 1：6% trifluoro miaow pyridine amide and amino-oligosaccharide granule
Trifluoro miaow pyridine amide 5%
Amino-oligosaccharide 1%
Sodium lauryl sulphate 1%
Dispersant NNO 3%
Kaolin complementary
Above-mentioned material is accurately weighed in mass ratio, is crushed by jet mill after mix homogeneously, by the medicated powder after crushing
Enter kneading, extruder grain, drying, obtain final product 6% trifluoro miaow pyridine amide and amino-oligosaccharide granule after screening.
Embodiment 2：20% trifluoro miaow pyridine amide and amino-oligosaccharide aqueous emulsion
Trifluoro miaow pyridine amide 18%
Amino-oligosaccharide 2%
Dimethylformamide（Solvent） 5%
Dimethylbenzene（Solvent） 15%
Ketohexamethylene（Solvent） 3%
Alkylphenol polyoxyethylene block copolymer（Emulsifying agent) 5%
Fatty alcohol-polyoxyethylene ether (emulsifying agent） 2%
Ethylene glycol（Antifreezing agent） 3%
Deionized water complementary
Above-mentioned active compound is accurately weighed in mass ratio, stirring solvent dissolving is added, and emulsifying agent mixing is added after active compound dissolving completely
Oil phase liquid is uniformly made, remaining deionized water and antifreezing agent is added in oil phase and is sheared when adding, can be stablized after shearing
20% trifluoro miaow pyridine amide and amino-oligosaccharide aqueous emulsion.
Embodiment 3：11% trifluoro miaow pyridine amide and amino-oligosaccharide micro-capsule suspension
Trifluoro miaow pyridine amide 10%
Amino-oligosaccharide 1%
Dimethylbenzene 10%
Emulsifying agent EW-36 6%
Ethylenediamine 4%
Wetting dispersing agent T/36 10%
Polyisocyanates 4%
Water complementary
In the reaction vessel that band protects gentle agitation, active component trifluoro miaow pyridine amide solvent is dissolved, amino-oligosacchride is added
After element, emulsifying agent, wetting dispersing agent, water and cyst material high-speed stirred are uniform (0.5 hour), initiator is added, low speed is changed to
Stirring, and 50 DEG C are progressively warming up to, then 8 hours of stirring at low speed under 50 DEG C of heat-retaining conditions, obtain containing 11% trifluoro miaow pyridine acyl
Amine and amino-oligosaccharide micro-capsule suspension.Wherein, the technological parameter in above-mentioned preparation method is:High-speed stirred speed controlling is
1000～1500 revs/min, the speed controlling of stirring at low speed is 60～150 revs/min.
Comparative example 1：5% trifluoro miaow pyridine amide granule
Trifluoro miaow pyridine amide 5%
Sodium lauryl sulphate 1%
Dispersant NNO 3%
Kaolin complementary
Above-mentioned material is accurately weighed in mass ratio, is crushed by jet mill after mix homogeneously, by the medicated powder after crushing
Enter kneading, extruder grain, drying, obtain final product 5% trifluoro miaow pyridine amide granule after screening.
Comparative example 2：1% amino-oligosaccharide granule
Amino-oligosaccharide 1%
Sodium lauryl sulphate 1%
Dispersant NNO 3%
Kaolin complementary
Above-mentioned material is accurately weighed in mass ratio, is crushed by jet mill after mix homogeneously, by the medicated powder after crushing
Enter kneading, extruder grain, drying, obtain final product 1% amino-oligosaccharide granule after screening.
Comparative example 3：18% trifluoro miaow pyridine amide aqueous emulsion
Trifluoro miaow pyridine amide 18%
Dimethylformamide（Solvent） 5%
Dimethylbenzene（Solvent） 15%
Ketohexamethylene（Solvent） 3%
Alkylphenol polyoxyethylene block copolymer（Emulsifying agent) 5%
Fatty alcohol-polyoxyethylene ether (emulsifying agent） 2%
Ethylene glycol（Antifreezing agent） 3%
Deionized water complementary
Above-mentioned active compound is accurately weighed in mass ratio, stirring solvent dissolving is added, and emulsifying agent mixing is added after active compound dissolving completely
Oil phase liquid is uniformly made, remaining deionized water and antifreezing agent is added in oil phase and is sheared when adding, can be stablized after shearing
18% trifluoro miaow pyridine amide aqueous emulsion.
Comparative example 4：2% amino-oligosaccharide water preparation
Amino-oligosaccharide 2%
Sodium benzoate 0.5%
Water complementary
Above-mentioned active compound is accurately weighed in mass ratio, adds the water of surplus, stirring and dissolving to obtain final product 2% amino-oligosacchride after fully dissolving
Plain water preparation.
Comparative example 5：10% trifluoro miaow pyridine amide micro-capsule suspension
Trifluoro miaow pyridine amide 10%
Dimethylbenzene 10%
Emulsifying agent EW-36 6%
Ethylenediamine 4%
Wetting dispersing agent T/36 10%
Polyisocyanates 4%
Water complementary
In the reaction vessel that band protects gentle agitation, active component trifluoro miaow pyridine amide solvent is dissolved, add emulsifying agent, profit
After hygroscopic water powder, water and cyst material high-speed stirred are uniform (0.5 hour), initiator are added, stirring at low speed is changed to, and is progressively risen
To 50 DEG C, then 8 hours of stirring at low speed under 50 DEG C of heat-retaining conditions, obtain and suspend containing 10% trifluoro miaow pyridine amide microcapsule temperature
Agent.Wherein, the technological parameter in above-mentioned preparation method is：High-speed stirred speed controlling is 1000～1500 revs/min, low speed
The speed controlling of stirring is 60～150 revs/min.
Comparative example 6：1% amino-oligosaccharide micro-capsule suspension
Amino-oligosaccharide 1%
Emulsifying agent EW-36 2%
Ethylenediamine 4%
Wetting dispersing agent T/36 4%
Polyisocyanates 4%
Water complementary
In the reaction vessel that band protects gentle agitation, by active component amino-oligosaccharide part aqueous solution, emulsifying agent, profit are added
After hygroscopic water powder, water and cyst material high-speed stirred are uniform (0.5 hour), initiator are added, stirring at low speed is changed to, and is progressively risen
To 50 DEG C, then 8 hours of stirring at low speed under 50 DEG C of heat-retaining conditions, obtain containing 1% amino-oligosaccharide micro-capsule suspension temperature.
Wherein, the technological parameter in above-mentioned preparation method is：High-speed stirred speed controlling is 1000～1500 revs/min, stirring at low speed
Speed controlling be 60～150 revs/min.
2nd, Assays Example
Test name：Trifluoro miaow pyridine amide is tested to the indoor biometricses of Fructus Cucumidis sativi root-knot nematode with amino-oligosaccharide mixture
Test method：The cucumber root for producing a large amount of root knots is taken, tap water is gently rinsed well, with dissecting needle gently picking old complaint
On milky egg capsule, be put in the little culture dish of diameter 6cm, add a small amount of sterilized water, hatch 3-4d in 25 DEG C of calorstats,
2 instar larvaes are collected, and adds sterilized water to be configured to finite concentration（500/milliliter or so）Suspension it is standby.
Arrange variable concentrations gradient to process, with sterilized water as blank, take 96 porocyte culture plates, add per hole and prepare
Variable concentrations medicament 150mL, add isopyknic nematicide suspension, moisturizing culture under the conditions of 25 DEG C, respectively place
Different time after reason checks the amount of survival and The dead quantity of 2 instar of Meloidogyne incognita, nematicide in stiff motionless for dead worm,
Line is filled in bending wriggling state for worm living.Calculate mortality rate and corrected mortality.
According to survey data, the corrected mortality of each process is calculated.And the abundant methods of Sun Yun are adopted with reference to NY/T1154.1-2006
Calculate the co-toxicity coefficient of mixture（CTC values）.If control mortality rate ＜ 5%, does not correct；Control mortality rate is carried out between 5-20%
Correction；Control mortality rate ＞ 20%, test need to be reformed.With drug concentration（mg/L）Logarithm value be independent variable x, to correct death
The niqueMin of rate is dependent variable y, sets up virulence regression equation respectively, using DPS computed in software single dose and each proportioning mixture
LC50,95% confidence limit and mixture co-toxicity coefficient, compare potentiation situation.Act on according to NY/T11547.7-2006 insecticide combinations
The criteria for classifying：Co-toxicity coefficient（CTC values）>=120 show as potentiation；Co-toxicity coefficient（CTC values）≤ 80 is antagonism；80
＜ co-toxicity coefficients（CTC values）＜ 120 is summation action.Trifluoro miaow pyridine amide is combined to Fructus Cucumidis sativi root-knot nematode with amino-oligosaccharide
Exercising result is as shown in table 1.
As can be seen from Table 1, trifluoro miaow pyridine amide and amino-oligosaccharide are 1:30-30:To Radix Cucumidis sativi tie lines in the range of 1
The preventing and treating of worm shows synergistic function, wherein, when both proportionings are 1:10-10:In the range of 1, to Fructus Cucumidis sativi root-knot nematode
, more than 200, synergistic function is more notable for the preventing and treating co-toxicity coefficient of disease.
3rd, field control effectiveness test
In order to preferably verify the field practical application effect of composition pesticide of the present invention, using embodiment of the present invention 1-3 and right
The composition pesticide of ratio 1-6 carries out preventing and treating Cucumber root-knot nematode disease field control effectiveness test, often processes in triplicate, per cell one
Individual repetition, is arranged using random district's groups, 20 m of plot area2.It is shallow mixed in preplanting treatment dispenser is broadcast, it is random to sow.Respectively at medicine
Investigate root-knot nematode quantity within 30,60 days afterwards.Using diagonal sampling method, per samples 3 plants, investigates disease index and sickness rate root
The Recording criteria of knot eelworm harm, raw many major general's state of an illness according to root knot and is divided into Pyatyi：
0 grade without root knot；
1 grade of root knot accounts for the 1-25% of full root system；
2 grades of root knots account for the 26-50% of full root system；
3 grades of root knots account for the 51-75% of full root system
4 grades of root knots account for the 76-100% of full root system
According to formula（5）And formula（6）Calculate the prevention effect of Fructus Cucumidis sativi root-knot nematode：
Table of field test results is bright, and the preventing and treating of the compositionss of trifluoro miaow pyridine amide and amino-oligosaccharide to Fructus Cucumidis sativi root-knot nematode is showed
Go out preferable lasting effect and quick-acting, the composition pesticide of example of formulations 1-3 is 1.5 Kg/ mus in effective ingredient dosage
When, preventive effect is above trifluoro miaow pyridine amide and amino-oligosaccharide single dose, illustrates that the composition pesticide of the present invention can be prevented and treated well
Crops nematicide, reduction dosage, reduces cost delay the drug-fast generation of nematicide, reduce the pollution to environment.To sum up,
The composition pesticide of the present invention is worth the popularization and application in production.
Claims (7)
1. a kind of composition pesticide, it is characterised in that active component includes trifluoro miaow pyridine amide and amino-oligosaccharide.
2. composition pesticide according to claim 1, it is characterised in that the trifluoro miaow pyridine amide and amino-oligosaccharide
Weight ratio is 1:30-30:1.
3. composition pesticide according to claim 2, it is characterised in that the trifluoro miaow pyridine amide and amino-oligosaccharide
Weight ratio is 1:10-10:1.
4. the composition pesticide according to any one of claim 1-3 claim, it is characterised in that the pesticide combination
Thing also includes other agricultural active compositions, such as insecticide, antibacterial, herbicide, fertilizer, safener.
5. the composition pesticide according to any one of claim 1-3 claim, it is characterised in that the pesticide combination
The auxiliary element that thing is aided with Pesticide formulation is prepared into any one dosage form for agriculturally allowing.
6. the composition pesticide according to any one of claim 1-5 claim, it is characterised in that its dosage form for
In granule, microemulsion, aqueous emulsion, suspending agent, suspension emulsion, micro-capsule suspension any one.
7. the purposes of the composition pesticide according to any one of claim 1-6 claim, it is characterised in that for preventing
Except root-knot nematode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955180.8A CN106508924A (en) | 2016-10-27 | 2016-10-27 | Nematicide composition containing fluazaindolizine and amino-oligosaccharin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955180.8A CN106508924A (en) | 2016-10-27 | 2016-10-27 | Nematicide composition containing fluazaindolizine and amino-oligosaccharin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106508924A true CN106508924A (en) | 2017-03-22 |
Family
ID=58326789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610955180.8A Pending CN106508924A (en) | 2016-10-27 | 2016-10-27 | Nematicide composition containing fluazaindolizine and amino-oligosaccharin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106508924A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857581A (en) * | 2017-02-28 | 2017-06-20 | 广东真格生物科技有限公司 | A kind of nematicidal composition containing trifluoro miaow pyridine acid amides |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102413693A (en) * | 2009-05-04 | 2012-04-11 | 杜邦公司 | Nematocidal sulfonamides |
| CN105175413A (en) * | 2011-10-13 | 2015-12-23 | 纳幕尔杜邦公司 | Solid Forms Of Nematocidal Sulfonamides |
| CN105284906A (en) * | 2015-11-19 | 2016-02-03 | 佳木斯兴宇生物技术开发有限公司 | Pesticide composition for preventing and treating soybean cyst nematode |
-
2016
- 2016-10-27 CN CN201610955180.8A patent/CN106508924A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102413693A (en) * | 2009-05-04 | 2012-04-11 | 杜邦公司 | Nematocidal sulfonamides |
| CN105175413A (en) * | 2011-10-13 | 2015-12-23 | 纳幕尔杜邦公司 | Solid Forms Of Nematocidal Sulfonamides |
| CN105284906A (en) * | 2015-11-19 | 2016-02-03 | 佳木斯兴宇生物技术开发有限公司 | Pesticide composition for preventing and treating soybean cyst nematode |
Non-Patent Citations (2)
| Title |
|---|
| 王泊理等: "阿维菌素和氨基寡糖素复配对黄瓜根结线虫的药效试验研究", 《福建农业》 * |
| 郭志刚: "氨基寡糖素（0.5%水剂对黄瓜根结线虫病的防治试验", 《农业科技通讯》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857581A (en) * | 2017-02-28 | 2017-06-20 | 广东真格生物科技有限公司 | A kind of nematicidal composition containing trifluoro miaow pyridine acid amides |
| CN106857581B (en) * | 2017-02-28 | 2020-06-30 | 广东真格生物科技有限公司 | Nematicidal composition containing trifluromiazinamide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102771510B (en) | Insecticidal composition containing fosthiazate | |
| CN103385251A (en) | Insecticidal composition comprising pyriproxyfen | |
| CN102204564B (en) | Pesticide composition containing fosthiazate and carbosulfan | |
| CN106857560A (en) | A kind of new nematicide and its application | |
| CN103651563B (en) | A kind of Fungicidal insecticidal composition containing brassin lactones | |
| CN106508956A (en) | Nematicidal composition containing trifluoro-pyrimidine amide and thiazole phosphine | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN107087636A (en) | A kind of the pyridine acid amides of miaow containing trifluoro and Imicyafos kill line composition | |
| CN108208000A (en) | A kind of nematicidal agent composition containing imicyafos | |
| CN106962372A (en) | A kind of the pyridine acid amides of miaow containing trifluoro and Tioxazafen kill line composition | |
| CN106719673A (en) | A kind of composition pesticide of containing fluopyram and chitosan | |
| CN106942255A (en) | Include the nematicidal composition of iprodione | |
| CN106689175A (en) | Nematicidal composition containing fluazaindolizine and iprodione | |
| CN103120183B (en) | Fosthiazate and Fluoxastrobin composition pesticide | |
| CN106508924A (en) | Nematicide composition containing fluazaindolizine and amino-oligosaccharin | |
| CN106508969A (en) | Fluazaindolizine-Paecilomyces lilacinus-containing nematicide composition | |
| CN106489955A (en) | A kind of fluorine-containing thiophene worm sulfone and the nematicidal composition of chitosan | |
| CN106879606A (en) | It is a kind of to kill line composition containing Tioxazafen and fluorine thiophene worm sulfone | |
| CN106342825A (en) | Nematicidal composition containing fluensulfone | |
| CN105145642A (en) | Nematicidal granules containing fosthiazate | |
| CN101444213A (en) | Desinsection composite and application thereof | |
| CN105028442A (en) | Insecticidal composition containing diflubenzuron and pymetrozine and application thereof | |
| CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
| CN105767007A (en) | Pesticide composition comprising harpin protein and biological sources | |
| CN103734181B (en) | A kind of Fungicidal insecticidal composition containing cyflufenamid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |