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CN106495721A - A kind of induction coil clay and preparation method thereof - Google Patents

A kind of induction coil clay and preparation method thereof Download PDF

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Publication number
CN106495721A
CN106495721A CN201611050044.0A CN201611050044A CN106495721A CN 106495721 A CN106495721 A CN 106495721A CN 201611050044 A CN201611050044 A CN 201611050044A CN 106495721 A CN106495721 A CN 106495721A
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CN
China
Prior art keywords
parts
brown alundum
induction coil
aluminium powder
particle diameter
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Pending
Application number
CN201611050044.0A
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Chinese (zh)
Inventor
王习华
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Sichuan Heyi Electric Furnace Technology Co Ltd
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Sichuan Heyi Electric Furnace Technology Co Ltd
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Priority to CN201611050044.0A priority Critical patent/CN106495721A/en
Publication of CN106495721A publication Critical patent/CN106495721A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669Resistance against chemicals, e.g. against molten glass or molten salts
    • C04B2235/9676Resistance against chemicals, e.g. against molten glass or molten salts against molten metals such as steel or aluminium

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses a kind of induction coil clay, including the component of following weight portion:0.2 0.4 parts of 14 18 parts of refractory cement, 28 35 parts of the Brown Alundum of 1 3mm, 12 18 parts of the Brown Alundum of 0 1mm, 16 20 parts of the Brown Alundum of 200 mesh, 6 10 parts of aluminium powder, 25 parts of silica flour, 59 parts of bentonite, 0.5 0.9 parts of iron oxide red and explosion-proof fiber.Preparation method is comprised the following steps:(1)Press formula to mix the Brown Alundum of 1 3mm, the Brown Alundum of 0 1mm, aluminium powder, bentonite and aluminium powder, stir, A must be expected;(2)Surplus materialss are mixed, is stirred, B must be expected;(3)A and material B mix homogeneously will be expected, mixed material will be obtained, in mixed material, then add the water of 11.5 12.5wt%, mix homogeneously to be obtained.The product cost is low, preparation process is simple, fire resistance, and the combination property such as insulating properties is good.

Description

A kind of induction coil clay and preparation method thereof
Technical field
The present invention relates to induction coil clay technical field, and in particular to a kind of induction coil clay and preparation method thereof.
Background technology
Induction furnace is due to being widely used to non-ferrous metal and ferrous metallurgy, wherein, furnace lining with series of advantages The working environment of material is very severe, and reason is:The hot face of furnace lining is directly contacted with high-temperature metal liquation, by metal and slag Erosion;The back side is cooled down by induction apparatuss cooling water so that there is very big thermograde in furnace lining;Additionally, molten metal in stove Violent function composite by electromagnetic stirring is subject to, strong mechanical damage is produced to furnace lining;Periodically batch operation can also cause furnace lining The damage of rapid heat cycle is repeatedly subjected to, such as misoperation or shortage maintenance is easily caused and wear stove accident.
Existing induction coil insulation furnace lining has the disadvantages that:
(1)How using high alumina ceramic or quartz glass tube, the molding furnace lining fragility made of this based composition is big, is held using process It is easily cracked, reason is in combinations thereof that cementing compositions granule is larger, binding material is poor with the adhesive property of other compositionss, leads Cause furnace lining resistance to heat shocks low, elevated temperature strength is low, and heat stability is poor, and anti-slag and anti-molten steel ability are low, while high temperature sintering is needed, Complex manufacturing technology and high energy consumption.
(2)Some components in molding furnace lining reaction bonded formed energy, and be not involved in react, therefore, various components Particle size distribution and the ratio of aggregate and fine powder there is extremely important impact on the performance of molding furnace lining.
(3)Raw material taste is had high demands, production cost is bigger than normal, with the continuous consumption of Mineral Resources in China, cost of material Rise steadily, competitiveness can gradually be lost with the production model that high-grade raw material prepares clay.
(4)Some clay are using slag containing titanium dioxide industry as raw material, although take full advantage of in industrial slag, but industrial slag Calcium content too high, substantial amounts of dicalcium silicate can be produced during use, and the crystal conversion of dicalcium silicate then can produce efflorescence, Volume stability during impact clay use, for induction furnace, especially normally using for intermediate frequency furnace has imprevision Danger.
(5)Fire resistance, poor insulativity, stability are poor, and service life is short.
In sum, there is high cost in existing induction coil clay, complicated process of preparation, corrosion resistance, fire resistance, absolutely The shortcomings of edge, stability difference and short service life.
Content of the invention
For above-mentioned deficiency of the prior art, the invention provides a kind of induction coil clay and preparation method thereof, can The high cost that the existing induction coil clay of effectively solving is present, complicated process of preparation are corrosion resistance, fire resistance, insulating properties, steady The problems such as qualitative difference and short service life.
A kind of induction coil clay, including the component of following weight portion:Refractory cement 14-18 parts, the Brown Alundum of 1-3mm 28-35 parts, particle diameter less than Brown Alundum 12-18 parts of 1mm, Brown Alundum 16-20 parts of 200 mesh, aluminium powder 6-10 parts, silica flour 2-5 parts, Bentonite 5-9 parts, iron oxide red 0.5-0.9 parts and explosion-proof fiber 0.2-0.4 part.
Further, a kind of induction coil clay, including the component of following weight portion:Refractory cement 15-17 parts, 1-3mm Brown Alundum 28-32 parts, particle diameter is less than Brown Alundum 14-17 parts of 1mm, Brown Alundum 18-20 parts of 200 mesh, aluminium powder 7-10 parts, silicon Powder 3-5 parts, bentonite 6-9 parts, iron oxide red 0.5-0.8 parts and explosion-proof fiber 0.3-0.4 part.
Further, a kind of induction coil clay, including the component of following weight portion:16 parts of refractory cement, the palm fibre of 1-3mm 15 parts of the Brown Alundum of 30 parts of corundum, particle diameter less than 1mm, 18.75 parts of the Brown Alundum of 200 mesh, 8.25 parts of aluminium powder, 4 parts of silica flour, swelling 0.3 part of 7 parts of soil, 0.7 part of iron oxide red and explosion-proof fiber.
Further, aluminium powder particle diameter is 400-500 mesh.
Further, silica flour particle diameter is 400-500 mesh.
Further, the length of explosion-proof fiber is 4-5cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)A and material B mix homogeneously will be expected, mixed material will be obtained, in mixed material, then add the water of 11.5-12.5wt%, mixing Uniformly, induction coil clay is obtained.
Induction coil clay that the present invention is provided and preparation method thereof, has the advantages that:
(1)In the present invention, each grain diameter of components reasonable mixture ratio, improves material volume density, rupture strength and the porosity, so as to carry The performances such as the high intensity of furnace lining, thermal shock resistance, the chemical erosion ability of anti-molten steel.
(2)Cost of material is low, and preparation method is simple, and the product fire resistance prepared, insulating properties are significantly improved, also Extend service life.
Specific embodiment
Embodiment 1
A kind of induction coil clay, including the component of following weight portion:14 parts of refractory cement, 28 parts of the Brown Alundum of 1-3mm, particle diameter Less than 12 parts of the Brown Alundum of 1mm, 16 parts of the Brown Alundum of 200 mesh, 6 parts of aluminium powder, 2 parts of silica flour, 5 parts of bentonite, 0.5 part of iron oxide red and anti- 0.2 part of quick-fried fiber;Wherein, aluminium powder particle diameter is 400 mesh;Silica flour particle diameter is 400 mesh;The length of explosion-proof fiber is 4cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)Will material A and material B mix homogeneously, obtain mixed material, then in mixed material plus 11.5wt% water, mix homogeneously, Obtain induction coil clay.
After testing, green volume density is 2.19-2.22g/cm to induction coil clay manufactured in the present embodiment3;Green compact show The porosity is 11-12%;Green compact rupture strength is 10.1-11.8MPa;Green compressive strength is 43.19-45.98MPa;Body after burning Product density is 2.28-2.39g/cm3;After burning, apparent porosity is 12-13%;After burning, rupture strength is 9.3-10.2MPa;Resistance to after burning Compressive Strength is 39.36-43.12MPa.
Embodiment 2
A kind of induction coil clay, including the component of following weight portion:18 parts of refractory cement, 35 parts of the Brown Alundum of 1-3mm, particle diameter Less than 18 parts of the Brown Alundum of 1mm, 20 parts of the Brown Alundum of 200 mesh, 10 parts of aluminium powder, 5 parts of silica flour, 9 parts of bentonite, 0.9 part of iron oxide red and 0.4 part of explosion-proof fiber;Wherein, aluminium powder particle diameter is 500 mesh;Silica flour particle diameter is 500 mesh;The length of explosion-proof fiber is 5cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)Will material A and material B mix homogeneously, obtain mixed material, then in mixed material plus 12.5wt% water, mix homogeneously, Obtain induction coil clay.
After testing, green volume density is 2.23-2.31g/cm to induction coil clay manufactured in the present embodiment3;Green compact show The porosity is 12-13%;Green compact rupture strength is 11.1-12.6MPa;Green compressive strength is 44.18-46.87MPa;Body after burning Product density is 2.35-2.45g/cm3;After burning, apparent porosity is 13-14%;After burning, rupture strength is 10.1-11.3MPa;Resistance to after burning Compressive Strength is 39.87-43.98MPa.
Embodiment 3
A kind of induction coil clay, including the component of following weight portion:15 parts of refractory cement, 28 parts of the Brown Alundum of 1-3mm, particle diameter Less than 14 parts of the Brown Alundum of 1mm, 18 parts of the Brown Alundum of 200 mesh, 7 parts of aluminium powder, 3 parts of silica flour, 6 parts of bentonite, 0.5 part of iron oxide red and anti- 0.3 part of quick-fried fiber;Wherein, aluminium powder particle diameter is 450 mesh;Silica flour particle diameter is 450 mesh;The length of explosion-proof fiber is 4cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)A and material B mix homogeneously will be expected, mixed material will be obtained, in mixed material, then add the water of 12wt%, mix homogeneously to obtain Induction coil clay.
After testing, green volume density is 2.26-2.36g/cm to induction coil clay manufactured in the present embodiment3;Green compact show The porosity is 12-13%;Green compact rupture strength is 12.0-13.2MPa;Green compressive strength is 44.36-46.88MPa;Body after burning Product density is 2.41-2.55g/cm3;After burning, apparent porosity is 13-14%;After burning, rupture strength is 11.1-11.9MPa;Resistance to after burning Compressive Strength is 39.96-44.39MPa.
Embodiment 4
A kind of induction coil clay, including the component of following weight portion:17 parts of refractory cement, 32 parts of the Brown Alundum of 1-3mm, particle diameter Less than 17 parts of the Brown Alundum of 1mm, 20 parts of the Brown Alundum of 200 mesh, 10 parts of aluminium powder, 5 parts of silica flour, 9 parts of bentonite, 0.8 part of iron oxide red and 0.4 part of explosion-proof fiber;Wherein, aluminium powder particle diameter is 450 mesh;Silica flour particle diameter is 500 mesh;The length of explosion-proof fiber is 4cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)Will material A and material B mix homogeneously, obtain mixed material, then in mixed material plus 12.5wt% water, mix homogeneously, Obtain induction coil clay.
After testing, green volume density is 2.29-2.41g/cm to induction coil clay manufactured in the present embodiment3;Green compact show The porosity is 13-14%;Green compact rupture strength is 12.3-13.6MPa;Green compressive strength is 44.41-46.95MPa;Body after burning Product density is 2.46-2.61g/cm3;After burning, apparent porosity is 14-15%;After burning, rupture strength is 11.5-12.3MPa;Resistance to after burning Compressive Strength is 40.03-44.40MPa.
Embodiment 5
A kind of induction coil clay, including the component of following weight portion:16 parts of refractory cement, 30 parts of the Brown Alundum of 1-3mm, particle diameter 15 parts of Brown Alundum, 18.75 parts of the Brown Alundum of 200 mesh less than 1mm, 8.25 parts of aluminium powder, 4 parts of silica flour, 7 parts of bentonite, iron oxide red 0.7 0.3 part of part and explosion-proof fiber;Wherein, aluminium powder particle diameter is 400 mesh;Silica flour particle diameter is 500 mesh;The length of explosion-proof fiber is 4cm.
The preparation method of above-mentioned induction coil clay, comprises the following steps:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)A and material B mix homogeneously will be expected, mixed material will be obtained, in mixed material, then add the water of 12wt%, mix homogeneously to obtain Induction coil clay.
After testing, green volume density is 2.30-2.40g/cm to induction coil clay manufactured in the present embodiment3;Green compact show The porosity is 13-14%;Green compact rupture strength is 12.8-14.1MPa;Green compressive strength is 44.50-46.99MPa;Body after burning Product density is 2.47-2.62g/cm3;After burning, apparent porosity is 14-15%;After burning, rupture strength is 12.0-12.8MPa;Resistance to after burning Compressive Strength is 40.15-44.43MPa.
Poor insulativity during traditional induction coil clay use, easily produces spark, and turn-to-turn easily produces electric arc damage Hinder coil, have crack, easily come off, corrosion-resistant easily receives molten metal corrode, and use time is short, is usually no more than three Month, and induction coil clay good insulating prepared by the present invention, electric arc will not be produced during use, spark will not be produced, and do not had There is crack to be not easy to come off, period also will not receive molten metal corrosion, using more than half a year there are no any exception.

Claims (7)

1. a kind of induction coil clay, it is characterised in that including the component of following weight portion:Refractory cement 14-18 parts, 1-3mm Brown Alundum 28-35 parts, particle diameter is less than Brown Alundum 12-18 parts of 1mm, Brown Alundum 16-20 parts of 200 mesh, aluminium powder 6-10 parts, silicon Powder 2-5 parts, bentonite 5-9 parts, iron oxide red 0.5-0.9 parts and explosion-proof fiber 0.2-0.4 part.
2. induction coil clay according to claim 1, it is characterised in that including the component of following weight portion:Fire resisting water The Brown Alundum 14-17 parts of mud 15-17 parts, Brown Alundum 28-32 parts of 1-3mm, particle diameter less than 1mm, the Brown Alundum 18-20 of 200 mesh Part, aluminium powder 7-10 parts, silica flour 3-5 parts, bentonite 6-9 parts, iron oxide red 0.5-0.8 parts and explosion-proof fiber 0.3-0.4 part.
3. induction coil clay according to claim 2, it is characterised in that including the component of following weight portion:Fire resisting water 30 parts of the Brown Alundum of 16 parts of mud, particle diameter less than 3mm, 15 parts of the Brown Alundum of 0-1mm, 18.75 parts of the Brown Alundum of 200 mesh, aluminium powder 0.3 part of 8.25 parts, 4 parts of silica flour, 7 parts of bentonite, 0.7 part of iron oxide red and explosion-proof fiber.
4. the induction coil clay according to any one of claim 1-3, it is characterised in that aluminium powder particle diameter is 400-500 mesh.
5. the induction coil clay according to any one of claim 1-3, it is characterised in that silica flour particle diameter is 400-500 mesh.
6. the induction coil clay according to any one of claim 1-3, it is characterised in that the length of explosion-proof fiber is 4- 5cm.
7. the preparation method of the induction coil clay as described in any one of claim 1-6, it is characterised in that including following step Suddenly:
(1)Brown Alundum of the formula by the Brown Alundum of 1-3mm, particle diameter less than 1mm, aluminium powder, bentonite and aluminium powder mixing is pressed, stirring is Even, A must be expected;
(2)Surplus materialss are mixed, is stirred, B must be expected;
(3)A and material B mix homogeneously will be expected, mixed material will be obtained, in mixed material, then add the water of 11.5-12.5wt%, mixing Uniformly, induction coil clay is obtained.
CN201611050044.0A 2016-11-25 2016-11-25 A kind of induction coil clay and preparation method thereof Pending CN106495721A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611050044.0A CN106495721A (en) 2016-11-25 2016-11-25 A kind of induction coil clay and preparation method thereof

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Application Number Priority Date Filing Date Title
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Publications (1)

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CN106495721A true CN106495721A (en) 2017-03-15

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107042299A (en) * 2017-06-16 2017-08-15 武汉科技大学 The control device and method of a kind of refining ladle slag emulsification
CN109516786A (en) * 2018-12-10 2019-03-26 海城市金福锋科技有限公司 A kind of intermediate frequency furnace protects clay, preparation and construction method with coil
CN112028652A (en) * 2020-09-10 2020-12-04 刘树峰 Super-silica powder cement composite material and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5523004A (en) * 1978-08-02 1980-02-19 Towa Taika Kogyo Kk Spinel castable refractories
CN101162636A (en) * 2007-08-27 2008-04-16 浙江工业大学 Induction coil protection layer for intermediate frequency stove
CN101279854A (en) * 2008-05-16 2008-10-08 西安理工大学 A kind of coil insulation safety furnace lining material and preparation method thereof
CN101693623A (en) * 2009-10-19 2010-04-14 长沙环宇石英砂有限公司 Insulating and refractory mortar for induction coils and preparation process thereof
CN104030704A (en) * 2014-05-28 2014-09-10 长兴北辰耐火阻燃材料有限公司 Cement for intermediate frequency furnace lining
CN104030703A (en) * 2014-05-28 2014-09-10 长兴北辰耐火阻燃材料有限公司 Preparation method of cement gum for intermediate frequency furnace
CN105481373A (en) * 2014-09-18 2016-04-13 青岛炜烨锻压机械有限公司 Insulating fireproof mortar and preparation method thereof
CN105777148A (en) * 2016-01-30 2016-07-20 武汉科技大学 Coil daub for medium-frequency induction furnace and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5523004A (en) * 1978-08-02 1980-02-19 Towa Taika Kogyo Kk Spinel castable refractories
CN101162636A (en) * 2007-08-27 2008-04-16 浙江工业大学 Induction coil protection layer for intermediate frequency stove
CN101279854A (en) * 2008-05-16 2008-10-08 西安理工大学 A kind of coil insulation safety furnace lining material and preparation method thereof
CN101693623A (en) * 2009-10-19 2010-04-14 长沙环宇石英砂有限公司 Insulating and refractory mortar for induction coils and preparation process thereof
CN104030704A (en) * 2014-05-28 2014-09-10 长兴北辰耐火阻燃材料有限公司 Cement for intermediate frequency furnace lining
CN104030703A (en) * 2014-05-28 2014-09-10 长兴北辰耐火阻燃材料有限公司 Preparation method of cement gum for intermediate frequency furnace
CN105481373A (en) * 2014-09-18 2016-04-13 青岛炜烨锻压机械有限公司 Insulating fireproof mortar and preparation method thereof
CN105777148A (en) * 2016-01-30 2016-07-20 武汉科技大学 Coil daub for medium-frequency induction furnace and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107042299A (en) * 2017-06-16 2017-08-15 武汉科技大学 The control device and method of a kind of refining ladle slag emulsification
CN109516786A (en) * 2018-12-10 2019-03-26 海城市金福锋科技有限公司 A kind of intermediate frequency furnace protects clay, preparation and construction method with coil
CN112028652A (en) * 2020-09-10 2020-12-04 刘树峰 Super-silica powder cement composite material and preparation method thereof

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Application publication date: 20170315