CN106491637A - The anhydrous cleaning agent of burst accident - Google Patents
The anhydrous cleaning agent of burst accident Download PDFInfo
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Abstract
本发明公开了一种突发事故的无水清洗剂，是属于小化工产品洗洁剂配置生产技术领域。由芦荟甜菜碱防药源感染杀菌消毒清洗剂，壳聚糖甲壳素特种去污护肤无水杀菌消毒清洗剂，沸石膨润土光谱抗菌护肤滋润无水杀菌消毒清洗剂，樟树叶玫瑰花杀菌消毒清洗剂，人参草珊瑚杀菌消毒清洗剂组成。用于突发事故如地震、泥石流、旅游、野外作业、地质探测、汽车驾驶员、油漆等特殊工种人员，在断电、断水情况下用于手和全身皮肤污泥、油污、污垢的清洗保洁、杀菌、消毒、护肤、润肤。且自然芳香，使用方便，无需水洗，不刺激皮肤，用后感觉舒适，安全可靠。The invention discloses a waterless cleaning agent for sudden accidents, and belongs to the technical field of cleaning agent configuration and production for small chemical products. Aloe betaine anti-drug source infection sterilization and disinfection cleaning agent, chitosan chitin special decontamination skin care anhydrous sterilization and disinfection cleaning agent, zeolite bentonite spectrum antibacterial skin care moisturizing anhydrous sterilization and disinfection cleaning agent, camphor leaf rose sterilization and disinfection cleaning agent , composed of ginseng grass coral sterilizing and disinfecting cleaning agent. It is used for emergency accidents such as earthquakes, mudslides, tourism, field operations, geological exploration, car drivers, paint and other special types of workers. It is used for cleaning and cleaning the sludge, oil and dirt on the hands and body skin under the condition of power failure and water failure. , Sterilization, disinfection, skin care, moisturizing. And natural fragrance, easy to use, no need to wash, does not irritate the skin, feels comfortable after use, safe and reliable.
Description
技术领域：Technical field:
本发明公开了一种突发事故的无水清洗剂，是属于小化工产品洗洁剂配置生产技术领域。The invention discloses a waterless cleaning agent for sudden accidents, and belongs to the technical field of cleaning agent configuration and production for small chemical products.
背景技术：Background technique:
突发事故如地震泥石流或野外作业，地质探测人员、油漆化工等特殊工种人员及汽车驾驶员用于清除手部污泥，油污及其他污垢，同时可以杀菌消毒，清洁保护皮肤，防止皮肤粗糙，干燥脱皮，皲裂；特别适用地震，泥石流，矿山，井下沙漠作业和机修人员，以及干旱免水、缺水地区的人员，手部去污，清洁手部皮肤，杀菌消毒去污力强，使皮肤光滑，富有光泽弹性香味持久，无毒性，对皮肤无刺激，感觉清爽舒适，使用安全稳定好，无毒副作用；使用时只需一滴清洗剂，将手整个涂匀，反复搓擦，使脏物随液膜脱除，实用方便、用量少、易于携带，免水洗，用后皮肤无干燥发红、瘙痒不适症状、杀菌消毒，润肤防裂效果显著，实验研究除菌率达96.59％使用后6h仍有优异的抗菌延续效果。Emergency accidents such as earthquake debris flow or field operations, geological exploration personnel, paint chemical and other special types of workers and car drivers are used to remove sludge, oil and other dirt from hands, and at the same time can sterilize, clean and protect the skin, prevent rough skin, Dry peeling, chapped; especially suitable for earthquakes, mudslides, mines, underground desert operations and machine repair personnel, and personnel in drought-free and water-deficient areas. Hand decontamination, cleans the skin of the hands, has strong sterilization and detergency, and makes the skin Smooth, shiny, elastic, long-lasting fragrance, non-toxic, non-irritating to the skin, feeling refreshing and comfortable, safe and stable to use, and non-toxic and side effects; when using, just a drop of cleaning agent, spread the whole hand evenly, and rub it repeatedly to remove dirt It is removed with the liquid film, practical and convenient, less dosage, easy to carry, no washing, no dryness, redness, itching and discomfort on the skin after use, sterilization and disinfection, moisturizing and anti-cracking effect is remarkable, and the sterilization rate of experimental research reaches 96.59%. After 6h, there is still excellent antibacterial effect.
发明内容：Invention content:
本发明的目的在于提供一种用于突发事故的无水清洗剂。The purpose of the present invention is to provide a kind of anhydrous cleaning agent that is used for emergencies.
本发明的技术解决方案是：Technical solution of the present invention is:
1、一种突发事故的无水清洗剂，其特征是：所述芦荟甜菜碱防药源感染杀菌消毒清洗剂，按下列质量配比配成％1. An anhydrous cleaning agent for emergencies, characterized in that: the aloe betaine anti-drug source infection sterilization and disinfection cleaning agent is formulated according to the following mass ratio:
制备方法：Preparation:
制备方法如下The preparation method is as follows
(1)提前1d将透明质酸钠浸入蒸馏水中，使其溶解备用。(1) Immerse sodium hyaluronate in distilled water 1 day in advance to dissolve it for later use.
(2)另将十二烷基硫酸钠在搅拌情况下，慢慢加入到蒸馏水中，加热，不断搅拌至完全溶解，然后加入柠檬酸，搅拌至均匀，以单乙醇胺缓慢调节PH至5.(2) Slowly add sodium lauryl sulfate into distilled water while stirring, heat, stir continuously until completely dissolved, then add citric acid, stir until uniform, and slowly adjust the pH to 5.0 with monoethanolamine.
(3)另将2.4.4一三氯-2’-羚基二苯醚、对氯间二甲苯酚在室温下溶于异丙醇中，完全溶解后，将其加入溶液(2)中，再加入完全溶解并经过滤的透明质酸钠溶液，然后以单乙醇胺调节PH至5.5，最后以蒸馏水稀释，灌装即可。(3) In addition, 2.4.4-trichloro-2'-anthyl diphenyl ether and p-chloro-m-xylenol were dissolved in isopropanol at room temperature, and after they were completely dissolved, they were added to the solution (2), Then add the completely dissolved and filtered sodium hyaluronate solution, then adjust the pH to 5.5 with monoethanolamine, finally dilute with distilled water, and fill it.
Al2O3是远红外辐射杀菌的代表。Al 2 O 3 is a representative of far-infrared radiation sterilization.
对氯间二甲苯酚对多数革兰阳性、阴性菌、真菌、霉菌都有杀灭功效；属安全高效广谱的防霉抗菌剂。P-chloro-m-xylenol has killing effect on most Gram-positive and negative bacteria, fungi and mold; it is a safe, efficient and broad-spectrum anti-mold and antibacterial agent.
2.4.4一三氯-2-羚基二苯醚(纯度＞90)为卤代二苯醚，是高效光谱抗菌剂，它对引起感染的病原性革兰氏阳性及阴性菌、真菌、酵母及病毒(如甲肝、乙肝病毒，狂犬病毒，艾滋病毒等)具有广泛的杀灭及抑制作用，对顽固的病原性皮肤菌效果尤其突出，对抗生素耐药菌及非抗生素耐药菌同样有效，而且于皮肤有极好的亲和性，在低浓度下即可达到消毒灭菌效果。2.4.4-Trichloro-2-anthyl diphenyl ether (purity>90) is a halogenated diphenyl ether, which is a high-efficiency spectrum antibacterial agent, which is effective against pathogenic Gram-positive and negative bacteria, fungi, and yeasts that cause infection And viruses (such as hepatitis A, hepatitis B virus, rabies virus, HIV, etc.) have a wide range of killing and inhibiting effects, especially for stubborn pathogenic skin bacteria, and are equally effective for antibiotic-resistant bacteria and non-antibiotic-resistant bacteria. Moreover, it has excellent affinity to the skin, and can achieve disinfection and sterilization effects at low concentrations.
十二烷基硫酸钠、十二烷基醚硫酸钠、异丙基苯磺酸钠、甜菜碱等均为表面活性。Sodium lauryl sulfate, sodium lauryl ether sulfate, sodium cumene sulfonate, betaine, etc. are all surface active.
乙醇、1.2-丙二醇，异丙醇等均为低分子醇。Ethanol, 1.2-propanediol, isopropanol, etc. are all low molecular alcohols.
透明质酸钠可从动物器官中提取或通过微生物发酵产生，它是天然保湿润滑剂，对皮肤具有保湿作用。Sodium hyaluronate, which can be extracted from animal organs or produced by microbial fermentation, is a natural moisturizing lubricant and has a moisturizing effect on the skin.
香精可根据需要选用Fragrance can be selected according to needs
本品主要用于用于突发事故及其他场合的手部消毒毒能够降低感染的发生率；This product is mainly used for hand disinfection in emergencies and other occasions to reduce the incidence of infection;
本品工艺便于操作，配方合理，广谱抗菌，使用效果显著，无刺激性，长期使用可靠。The process of this product is easy to operate, the formula is reasonable, broad-spectrum antibacterial, the use effect is remarkable, non-irritating, and long-term use is reliable.
(2)一种突发事故的无水清洗剂，其特征是：所述壳聚糖甲壳素特种去污护肤无水杀菌消毒清洗剂，按下列质量配比配成％(2) a waterless cleaning agent for unexpected accidents, characterized in that: the chitosan chitin special decontamination skin care anhydrous sterilization and disinfection cleaning agent is formulated according to the following mass ratio
制备及使用方法Preparation and method of use
(1)将两种烷基酚聚氧乙烯醚，壳聚糖、甲壳素、钛白粉、油酸和液体石蜡混合，搅拌均匀待用。(1) Mix two kinds of alkylphenol polyoxyethylene ethers, chitosan, chitin, titanium dioxide, oleic acid and liquid paraffin, stir evenly and set aside.
(2)将氢氧化钠置于水中，搅拌使其溶解。(2) Put sodium hydroxide in water and stir to dissolve it.
(3)在不断搅拌下，将步骤(1)制得的溶液倒入步骤(2)制得的溶液中，继续搅拌5-10min即得。(3) Under constant stirring, pour the solution prepared in step (1) into the solution prepared in step (2), and continue stirring for 5-10 minutes to obtain the product.
本剂是以两种烷基酚聚氧化乙烯(5)(10)醚、油酸、氢氧化钠、液体石腊、壳聚糖、钛白粉等为原料组成，本剂具有下列特点：This agent is composed of two kinds of alkylphenol polyethylene oxide (5) (10) ether, oleic acid, sodium hydroxide, liquid paraffin, chitosan, titanium dioxide, etc., and has the following characteristics:
(1)去污力强，能去除较难洗去的物质、如油漆、沥青、树脂、油墨等。(1) Strong detergency, able to remove substances that are difficult to wash off, such as paint, asphalt, resin, ink, etc.
(2)不伤皮肤，不会引起皮肤干裂、脱皮等现象。(2) It will not hurt the skin, and will not cause dry and cracked skin, peeling and other phenomena.
(3)无毒无害无刺激性、且不污染周围环境。(3) Non-toxic, harmless, non-irritating, and does not pollute the surrounding environment.
主要用于各种油漆工、原油开采工、印刷工等工种的工人、对衣服上的油垢、油渍也有洗涤作用。It is mainly used for various painters, crude oil mining workers, printing workers and other types of workers. It also has a washing effect on the grease stains and oil stains on the clothes.
原材料raw material
壳聚糖甲壳素是天然的抗菌剂，克生物降解，安全环保。Chitosan Chitin is a natural antibacterial agent, biodegradable, safe and environmentally friendly.
烷基酚聚氧乙烯(10)醚，本剂用作表面活性剂、洗净剂。Alkylphenol polyoxyethylene (10) ether, this agent is used as a surfactant and cleaning agent.
烷基酚聚氧乙烯(5)醚，又名乳化剂OP5乳化剂OP系列的一种，淡黄至黄色油状液体，能溶于油及有机溶剂中，具有良好的乳化性能，本剂中用作乳化剂、洗净剂。Alkylphenol polyoxyethylene (5) ether, also known as emulsifier OP5, a kind of emulsifier OP series, light yellow to yellow oily liquid, soluble in oil and organic solvent, has good emulsifying performance, used in this agent For emulsifier, detergent.
油酸 又名顺势-9-十八稀酸、顺势十八碳-9-稀酸、无色或几乎无色的液体。4℃凝固成结晶，在大气中加热到80～100℃时分解。暴露在空气中氧化，变成黄色或棕色，并酸化，能溶于醇、苯和氯仿、几乎不溶于水。用作乳化剂、润滑剂、塑料增塑剂等、本剂中用作溶解剂，溶解油性污垢。Oleic acid, also known as homeopathic-9-octadecenoic acid, homeopathic octadecan-9-dilute acid, is a colorless or almost colorless liquid. It solidifies into crystals at 4°C and decomposes when heated to 80-100°C in the atmosphere. Exposure to air oxidation, turning yellow or brown, and acidification, soluble in alcohol, benzene and chloroform, almost insoluble in water. Used as an emulsifier, lubricant, plasticizer, etc., and used as a solvent in this agent to dissolve oily dirt.
氢氧化钠 又名苛性钠、苛性碱、烧碱、火碱。白色易潮解固体，有块状、片状、棒状和粒状。易溶于水，也易溶于乙醇和甘油，不溶于丙酮和乙醚，露置空气中易吸收而逐渐溶成粘稠状液体具强碱性，是基本的化工原料之一本剂中用作碱性剂，。Sodium hydroxide is also known as caustic soda, caustic soda, caustic soda, and caustic soda. White deliquescent solid, there are blocks, flakes, sticks and granules. Soluble in water, soluble in ethanol and glycerin, insoluble in acetone and ether, easy to absorb in the air and gradually dissolve into viscous liquid with strong alkalinity, it is one of the basic chemical raw materials used in this agent Alkaline agent,.
液体石腊 又名白色油、石蜡油，石油产品的一种，无色透明粘稠状液体，无臭、无味、无荧光。一般由石蜡烃和环烷烃(C16C18)组成一种溶于许多油脂和蜡，溶于二硫化碳，乙醚、氯仿、苯及热乙醇中，不溶于水，冷乙醇和甘油能溶于樟脑，薄荷油及麝香等香料中，本剂中用作润肤剂。Liquid paraffin, also known as white oil and paraffin oil, is a kind of petroleum product, a colorless transparent viscous liquid, odorless, tasteless, and non-fluorescent. Generally composed of paraffin and cycloalkane (C16C18), it is soluble in many oils and waxes, soluble in carbon disulfide, ether, chloroform, benzene and hot ethanol, insoluble in water, cold ethanol and glycerin can be soluble in camphor, peppermint oil and In spices such as musk, this agent is used as an emollient.
(3)一种突发事故的无水清洗剂，其特征是：所述沸石膨润土光谱抗菌护肤滋润无水杀菌消毒清洗剂，按下列质量配比配成％(3) a waterless cleaning agent for sudden accidents, characterized in that: the zeolite bentonite spectrum antibacterial skin care moisturizing anhydrous sterilizing and disinfecting cleaning agent is formulated as % by the following mass ratio
制备方法 将各组分溶于水中即可。Preparation method Dissolve each component in water.
将沸石微粉浸在金属可溶性盐的水溶液或溶盐中、使其中的钠离子被铜、银、锌等金属离子置换，即可获得具有抗菌功能的沸石。The zeolite with antibacterial function can be obtained by immersing the zeolite fine powder in the aqueous solution or dissolved salt of metal soluble salt, and replacing the sodium ion with copper, silver, zinc and other metal ions.
黏土抗菌剂中的膨润土，因其具有很强的吸附能力和离子交换能力，而成为无机抗菌剂的理想载体。具有广谱抗菌性，对格兰阴性菌、真菌霉菌等都具有理想的抑制效果。经中国预防医学科学院对该纳米银抗菌剂制备的抗菌液检测，其对大肠杆菌和金黄色葡萄球菌的抗菌率可达到99.9％，而且该抗菌剂安全性无毒无刺激，抗菌持久。Bentonite in clay antibacterial agents has become an ideal carrier for inorganic antibacterial agents because of its strong adsorption capacity and ion exchange capacity. It has broad-spectrum antibacterial properties, and has ideal inhibitory effects on Gram-negative bacteria, fungi, and molds. According to the antibacterial liquid prepared by the Chinese Academy of Preventive Medicine, the antibacterial rate against Escherichia coli and Staphylococcus aureus can reach 99.9%, and the antibacterial agent is safe, non-toxic and non-irritating, and has a long-lasting antibacterial effect.
柏树精油、茶树油，丙二醇、维生素、卡波树脂对皮肤有保湿、祛斑、杀螨和去除污垢的作用；乙醇具有杀菌、消毒、分解污垢、挥发的作用；香精使本品气味清香；去离子水可起到稀释作用。Cypress essential oil, tea tree oil, propylene glycol, vitamins, and carbo resin have the functions of moisturizing, removing freckles, killing mites and removing dirt on the skin; ethanol has the functions of sterilizing, disinfecting, decomposing dirt and volatilizing; the fragrance makes the product smell fragrant; deionization Water acts as a diluent.
本品能够在不用水洗的情况下将人手清洗干净，并且具有护肤，滋润和杀菌的功效。This product can clean human hands without washing with water, and has the effects of skin care, moisturizing and sterilization.
本品原料易得，工艺简单，配方合理，去污力强，使用效果好，无毒副作用，长期使用安全可靠。The raw materials of this product are easy to obtain, the process is simple, the formula is reasonable, the detergency is strong, the use effect is good, there is no side effect, and it is safe and reliable for long-term use.
(4)、一种突发事故的无水清洗剂，其特征是：所述樟树叶玫瑰花杀菌消毒清洗剂，按下列质量配比配成％(4), a waterless cleaning agent for unexpected accidents, is characterized in that: the camphor tree leaf rose sterilizing and disinfecting cleaning agent is made into % by the following mass ratio
制备方法：Preparation:
(1)、在不锈钢加盖反应锅中加入去离子水，将卡波泊分3-5次缓慢地加入到去离子水中，边加边搅拌，搅拌充分分散得到均匀浑浊分散体，充分溶胀，所得作为甲液。(1) Add deionized water into the stainless steel capped reaction pot, slowly add carbopol into the deionized water in 3-5 times, stir while adding, stir to fully disperse to obtain a uniform turbid dispersion, fully swell, The resulting as a liquid.
(2)在另一不锈钢加盖反应锅中加入部分乙醇，然后加入三氯生、拉丝粉混合溶解，匀速搅拌直至液体澄清透明，所得乙液，密封保存。(2) Add part of ethanol to another stainless steel reaction pot with a cover, then add triclosan and wire drawing powder to mix and dissolve, stir at a constant speed until the liquid is clear and transparent, and the obtained liquid B is sealed and stored.
(3)将乙液到入甲液中，并加入剩余的乙醇，搅拌，混合均匀。(3) Put liquid B into liquid A, and add the remaining ethanol, stir and mix well.
(4)向物料(3)中依次加入载银纳米(AT)二氧化钛抗菌剂、玫瑰花提取液、樟树叶提取液、蛇油、茶树油、保湿剂、助溶剂，混合溶解，搅拌至均匀分散，加入PH调节剂，调节至6.7-8.7，在加入香精，补充去离子水，即得成品。(4) Add silver-loaded nano (AT) titanium dioxide antibacterial agent, rose extract, camphor leaf extract, snake oil, tea tree oil, humectant, cosolvent to material (3) in sequence, mix and dissolve, and stir until uniformly dispersed , adding a PH regulator to adjust to 6.7-8.7, adding essence and replenishing deionized water to obtain the finished product.
本品主要用于突发事故如地震、泥石流等断电断水情况下无水清洁双手，能强效广谱杀灭大肠埃希菌、金黄色葡萄球菌、伤寒杆菌、痢疾、霍乱等各种传染性致病生物菌。This product is mainly used to clean hands without water in emergencies such as earthquakes, mudslides and other power outages. It can effectively and broadly kill Escherichia coli, Staphylococcus aureus, typhoid bacillus, dysentery, cholera and other infections Sexually pathogenic bacteria.
(5)、一种突发事故的无水清洗剂，其特征是：所述人参草珊瑚杀菌消毒清洗剂，按下列质量配比配成％(5), a waterless cleaning agent for unexpected accidents, is characterized in that: the ginseng grass coral sterilizing and disinfecting cleaning agent is made into % by the following mass ratio
制备方法：Preparation:
按配方将原料放置于容器中，进行搅拌，直至分散均匀全部溶解后即得成品。Put the raw materials in the container according to the formula, and stir until they are evenly dispersed and completely dissolved to obtain the finished product.
本品使用时用布条或棉纱蘸取少量擦于污垢出，强力杀菌消毒祛污。When using this product, use a cloth or cotton yarn to dip a small amount and wipe it on the dirt, for strong sterilization and decontamination.
下面结合实施例子对本发明进一步阐明：Below in conjunction with implementation example the present invention is further clarified:
具体实施方法：Specific implementation method:
实施例1、一种突发事故的无水清洗剂，其特征是：所述芦荟甜菜碱防药源感染杀菌消毒清洗剂按下列质量配比配成％Embodiment 1, a kind of waterless cleaning agent of sudden accident is characterized in that: described aloe betaine anti-drug source infection sterilizing and disinfecting cleaning agent is made into % by the following mass ratio
实施例2、一种突发事故的无水清洗剂，其特征是：所述壳聚糖甲壳素特种去污护肤无水杀菌消毒清洗剂，按下列质量配比配成％Embodiment 2, a waterless cleaning agent for sudden accidents is characterized in that: the chitosan chitin special decontamination skin care anhydrous sterilization and disinfection cleaning agent is formulated according to the following mass ratio
实施例3、一种突发事故的无水清洗剂，其特征是：所述沸石膨润土光谱抗菌护肤滋润无水杀菌消毒清洗剂，按下列质量配比配成％Embodiment 3, a waterless cleaning agent for sudden accidents is characterized in that: the zeolite bentonite spectrum antibacterial skin care moisturizing anhydrous sterilization and disinfection cleaning agent is formulated according to the following mass ratio
实施例4、一种突发事故的无水清洗剂，其特征是：所述樟树叶玫瑰花杀菌消毒清洗剂，按下列质量配比配成％Embodiment 4, a kind of waterless cleaning agent of sudden accident is characterized in that: described camphor tree leaf rose sterilizing and disinfecting cleaning agent is made into % by the following mass proportioning
实施例5、一种突发事故的无水清洗剂，其特征是：所述人参草珊瑚杀菌消毒清洗剂，按下列质量配比配成％Embodiment 5, a waterless cleaning agent for sudden accidents, is characterized in that: the ginseng grass coral sterilizing and disinfecting cleaning agent is made into % by the following mass ratio
Claims (5)
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| CN201610719491.4A CN106491637A (en) | 2016-08-16 | 2016-08-16 | The anhydrous cleaning agent of burst accident |
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| CN108852905A (en) * | 2018-07-09 | 2018-11-23 | 安徽衣露士生物科技有限公司 | A kind of preparation method of the hand cleanser of effect stability |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104905988A (en) * | 2015-04-24 | 2015-09-16 | 南通蛇类治疗研究所 | Water-free disinfection sterilization hand cleaning cream |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104905988A (en) * | 2015-04-24 | 2015-09-16 | 南通蛇类治疗研究所 | Water-free disinfection sterilization hand cleaning cream |
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| 李东光主编: "《精细化学品配方（六）》", 31 January 2008, 江苏科学技术出版社 * |
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| CN108852905A (en) * | 2018-07-09 | 2018-11-23 | 安徽衣露士生物科技有限公司 | A kind of preparation method of the hand cleanser of effect stability |
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