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CN106480778B - Cigarette tipping paper and preparation method thereof - Google Patents

Cigarette tipping paper and preparation method thereof Download PDF

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Publication number
CN106480778B
CN106480778B CN201610891486.1A CN201610891486A CN106480778B CN 106480778 B CN106480778 B CN 106480778B CN 201610891486 A CN201610891486 A CN 201610891486A CN 106480778 B CN106480778 B CN 106480778B
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China
Prior art keywords
oleophobic
tipping paper
oil
layer
hydrophilic
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CN201610891486.1A
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CN106480778A (en
Inventor
徐善水
赵荣艳
杨江涛
杨立新
曹萼
杨二果
姚发征
王超
王云龙
余四军
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Anhui Jiexin Packaging Technology Co ltd
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ANHUI GENUINE PAPER PACKING Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46Non-macromolecular organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64Inorganic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/828Paper comprising more than one coating superposed two superposed coatings, the first applied being non-pigmented and the second applied being pigmented
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Abstract

The present invention provides a kind of cigarette tipping paper, including base paper for tipping paper, it is characterized in that, the base paper for tipping paper includes anti-oil reservoir and oleophobic hydrophilic layer, the anti-oil reservoir and the oleophobic hydrophilic layer are cascadingly set in at least one side of the base paper for tipping paper, the anti-oil reservoir and the oleophobic hydrophilic layer all have resin matrix, and the resin matrix of the two is compatible.The present invention further provides a kind of preparation methods of above-mentioned cigarette tipping paper.Cigarette tipping paper provided by the invention can effectively prevent the exudation of liquid fat, while meet the requirement of cigarette pack cigarette performance.

Description

烟用接装纸及其制备方法Cigarette tipping paper and preparation method thereof

技术领域technical field

本发明涉及香烟领域,特别是涉及一种烟用接装纸及其制备方法。The invention relates to the field of cigarettes, in particular to a cigarette tipping paper and a preparation method thereof.

背景技术Background technique

随着社会的发展、文明的进步,香烟已不再简单的只是烟,而是一种身份的符号,越来越多的人选择高档烟来提升自己的品味,更多地追求具有功能性的香烟,各种具有防伪功能、镭射功能、荧光功能、防渗透功能等等的香烟不断的出现在香烟市场。近期由云南卷烟厂、合肥卷烟厂、芜湖卷烟厂推出的爆珠烟,深受广大烟民喜爱。这种新型爆珠烟是通过手指捏破嵌在香烟烟束中的爆珠胶囊,来达到增加香烟抽吸过程中的香味和口味,根据爆珠的成分不同,香烟将具有不同的抽吸味道,如薄荷胶囊,王浆胶囊、人参胶囊等,通过添加这些物质,最终影响大家对香烟的判断力。然而上述胶囊在捏破的过程中香精香料等的渗透,会给抽烟者不好的体验。With the development of society and the progress of civilization, cigarettes are no longer simply cigarettes, but a symbol of identity. More and more people choose high-end cigarettes to improve their taste, and they are more pursuing functional products. Cigarettes, various cigarettes with anti-counterfeiting functions, laser functions, fluorescent functions, anti-penetration functions, etc. continue to appear in the cigarette market. Recently launched by Yunnan Tobacco Factory, Hefei Tobacco Factory and Wuhu Tobacco Factory, the popcorn cigarettes are very popular among smokers. This new type of puffed bead smoke is achieved by pinching the puffed puffed capsules embedded in the cigarette bundle with fingers to increase the aroma and taste of the cigarette during smoking. According to the different components of puffed puffs, cigarettes will have different smoking tastes , such as mint capsules, royal jelly capsules, ginseng capsules, etc., by adding these substances, it will ultimately affect everyone's judgment on cigarettes. However, the permeation of flavors and fragrances etc. in the process of crushing the above-mentioned capsules will give smokers a bad experience.

因此,需要提供一种能够阻隔香烟滤嘴棒中的油脂渗出的烟用接装纸,然而,通常能够阻隔油脂渗出的烟用接装纸表面具有疏水性,由于在实际生产过程中,需要使用水性胶黏剂将烟用接装纸包装卷接在滤嘴和烟支上,此时水性胶黏剂与疏水性烟用接装纸表面之间的结合性很差,导致烟用接装纸容易爆开,从而不能满足烟厂对香烟的包装卷接性能。Therefore, it is necessary to provide a tipping paper for cigarettes that can block the seepage of grease in the cigarette filter rod. However, the surface of the tipping paper for cigarettes that can usually block the seepage of grease has hydrophobicity. Because in the actual production process, It is necessary to use a water-based adhesive to roll the cigarette tipping paper on the filter and cigarettes. At this time, the bonding between the water-based adhesive and the surface of the hydrophobic cigarette tipping paper is very poor, resulting in Paper loading is easy to burst open, which cannot meet the cigarette factory's packaging rolling performance for cigarettes.

发明内容Contents of the invention

基于此,有必要针对烟用接装纸不能同时满足阻隔油脂性能和对香烟的包装卷接性能的问题,提供一种烟用接装纸及其制备方法。Based on this, it is necessary to provide a tipping paper for cigarettes and a preparation method thereof for the problem that the tipping paper for cigarettes cannot satisfy the performance of blocking grease and wrapping cigarettes at the same time.

一种烟用接装纸,包括接装纸原纸,其特征在于,所述接装纸原纸包括防油层和疏油亲水层,所述防油层和所述疏油亲水层依次层叠设置于所述接装纸原纸的至少一面上,所述防油层和所述疏油亲水层均具有树脂基体,且两者的树脂基体相容。A tipping paper for cigarettes, comprising base paper for tipping paper, characterized in that the base paper for tipping paper comprises an oil-repellent layer and an oil-repellent and hydrophilic layer, and the oil-repellent layer and the oil-repellent and hydrophilic layer are sequentially stacked on the On at least one side of the base paper of the tipping paper, both the oil-repellent layer and the oleophobic hydrophilic layer have a resin matrix, and the resin matrix of the two is compatible.

在其中一个实施例中,所述防油层的树脂基体选自丙烯酸树脂类和聚氨酯类中的至少一种,或者选自聚苯丙氨酸、多聚苯丙氨酸、松香树脂、缩丁醛树脂和聚氨酯中的至少一种;所述疏油亲水层的树脂基体选自聚碳酸酯和聚氨酯中的至少一种。In one embodiment, the resin matrix of the oil-repellent layer is selected from at least one of acrylic resins and polyurethanes, or selected from polyphenylalanine, polyphenylalanine, rosin resin, butyral At least one of resin and polyurethane; the resin matrix of the oleophobic and hydrophilic layer is selected from at least one of polycarbonate and polyurethane.

在其中一个实施例中,所述疏油亲水层进一步包括无机填料,所述无机填料选自活性碳酸钙和滑石粉中的至少一种,所述疏油亲水层的树脂基体与所述无机填料的质量比为1:1~2:1。In one of the embodiments, the oleophobic and hydrophilic layer further includes an inorganic filler, the inorganic filler is selected from at least one of active calcium carbonate and talcum powder, and the resin matrix of the oleophobic and hydrophilic layer is combined with the The mass ratio of the inorganic filler is 1:1-2:1.

在其中一个实施例中,所述烟用接装纸的两面均包括依次层叠设置的所述防油层和所述疏油亲水层。In one of the embodiments, both sides of the tipping paper for cigarettes include the oil-repellent layer and the oleophobic and hydrophilic layer stacked in sequence.

在其中一个实施例中,所述烟用接装纸的至少一面上包括多个所述防油层和多个所述疏油亲水层交替设置。In one embodiment, at least one side of the tipping paper for cigarettes includes multiple oil-repellent layers and multiple oleophobic and hydrophilic layers arranged alternately.

在其中一个实施例中,所述防油层或所述疏油亲水层为多层结构。In one of the embodiments, the oil-repellent layer or the oleophobic-hydrophilic layer has a multilayer structure.

一种烟用接装纸的制备方法,其特征在于,包括:A method for preparing cigarette tipping paper, characterized in that it comprises:

S11,提供一接装纸原纸,所述接装纸原纸具有相对的第一面和第二面;S11, providing a base paper for tipping paper, the base paper for tipping paper has opposite first and second sides;

S12,提供防油涂料,在所述第一面上印刷或涂布所述防油涂料,制得第一防油层;S12, providing an oil-repellent coating, printing or coating the oil-repellent coating on the first surface to obtain a first oil-repellent layer;

S13,提供疏油亲水涂料,该疏油亲水涂料与上述防油涂料分别具有相容的树脂基体;S13, providing an oleophobic and hydrophilic coating, the oleophobic and hydrophilic coating and the above-mentioned oil-repellent coating respectively have a compatible resin matrix;

S14,在所述第一防油层上印刷或涂布所述疏油亲水涂料,制得第一疏油亲水层,获得所述烟用接装纸。S14, printing or coating the oleophobic and hydrophilic coating on the first oil-repellent layer to prepare a first oleophobic and hydrophilic layer, and obtaining the tipping paper for cigarettes.

在其中一个实施例中,所述防油涂料为水性丙烯酸树脂类和水性聚氨酯类中的至少一种,或油性聚苯丙氨酸、松香树脂、缩丁醛树脂、多聚苯丙氨酸和油性聚氨酯中的至少一种;所述疏油亲水涂料包括连接料、无机填料、乙醇和水,所述连接料为水性聚碳酸酯、水性聚氨酯中的至少一种,所述无机填料为活性碳酸钙和滑石粉中的至少一种,其中,所述连接料的质量百分比为15~30%,所述无机填料的质量百分比为15~30%,所述乙醇的质量百分比为20~30%,所述水的质量百分比为20~30%。In one of the embodiments, the oil-proof coating is at least one of water-based acrylic resins and water-based polyurethanes, or oily polyphenylalanine, rosin resin, butyral resin, polyphenylalanine and At least one of oily polyurethane; said oleophobic and hydrophilic coating includes binder, inorganic filler, ethanol and water, said binder is at least one of water-based polycarbonate, water-based polyurethane, and said inorganic filler is active At least one of calcium carbonate and talcum powder, wherein the mass percentage of the binder is 15-30%, the mass percentage of the inorganic filler is 15-30%, and the mass percentage of the ethanol is 20-30% , the mass percentage of the water is 20-30%.

在其中一个实施例中,所述疏油亲水涂料的细度小于30μm。In one embodiment, the fineness of the oleophobic and hydrophilic coating is less than 30 μm.

在其中一个实施例中,所述烟用接装纸的制备方法进一步包括在所述接装纸原纸的第二面依次印刷或涂布所述防油涂料和所述疏油亲水涂料,得到第二防油层和第二疏油亲水层的步骤。In one of the embodiments, the preparation method of the tipping paper for cigarettes further comprises sequentially printing or coating the oil-repellent coating and the oleophobic and hydrophilic coating on the second side of the base paper of the tipping paper, to obtain The steps of the second oil-repellent layer and the second oleophobic and hydrophilic layer.

本发明提供的烟用接装纸具有依次层叠设置的防油层和疏油亲水层,使得烟用接装纸具有疏油亲水功能,这种疏油亲水性可以完全阻隔液体油脂的渗出,且能够很好的适应香烟卷接过程中的包装卷接性,很好的解决了烟用接装纸市场对这种疏油亲水功能型烟用接装纸的大量需求。The cigarette tipping paper provided by the present invention has an oil-repellent layer and an oleophobic and hydrophilic layer which are sequentially stacked, so that the cigarette tipping paper has an oleophobic and hydrophilic function, and this oleophobic and hydrophilic property can completely block the penetration of liquid oil. It can be well adapted to the packaging wrapping properties in the cigarette rolling process, and it can well solve the large demand for this oleophobic and hydrophilic functional cigarette tipping paper in the cigarette tipping paper market.

所述防油层和疏油亲水层的树脂基体之间具有很好的相容性,且成膜性好,因此,所述防油层和疏油亲水层的贴合性很好。The oil-repellent layer has good compatibility with the resin matrix of the oleophobic and hydrophilic layer, and has good film-forming properties. Therefore, the adhesion between the oil-repellent layer and the oleophobic and hydrophilic layer is very good.

通过设定所述疏油亲水层中树脂基体和无机填料的成分以及比例,使得所述疏油亲水层具有较小的吸水性,从而使得所述烟用接装纸在运输、存储和使用过程中始终保持符合要求的含水率。By setting the composition and ratio of the resin matrix and the inorganic filler in the oleophobic and hydrophilic layer, the oleophobic and hydrophilic layer has less water absorption, so that the cigarette tipping paper can be transported, stored and Always maintain the required moisture content during use.

本发明提供的烟用接装纸的制备方法,在所述接装纸原纸上首先制备一防油层,既可以使所述接装纸原纸在印刷和涂布所述疏油防水涂料时不会吸水变形,又能在所述烟用接装纸使用时起到隔离油脂的作用,所述疏油亲水层能满足所述烟用接装纸对包装卷接性能的要求。In the preparation method of tipping paper for cigarettes provided by the present invention, an oil-proof layer is firstly prepared on the base paper of the tipping paper, so that the base paper of the tipping paper will not It is deformed by water absorption, and can also play the role of isolating grease when the tipping paper for cigarettes is used, and the oleophobic and hydrophilic layer can meet the requirements of the tipping paper for cigarettes on the wrapping performance of the package.

附图说明Description of drawings

图1为本发明提供的烟用接装纸的结构示意图;Fig. 1 is the structural representation of the cigarette tipping paper provided by the present invention;

图2为本发明提供的烟用接装纸的另一结构示意图;Fig. 2 is another schematic structural view of the tipping paper for cigarettes provided by the present invention;

图3为本发明提供的香烟的结构示意图;Fig. 3 is the structural representation of the cigarette provided by the present invention;

图4为本发明提供的烟用接装纸的制备方法的流程图。Fig. 4 is a flow chart of the preparation method of the tipping paper for cigarettes provided by the present invention.

具体实施方式Detailed ways

请参阅图1,本发明提供一种烟用接装纸1,包括接装纸原纸10、第一防油层20和第一疏油亲水层30,所述接装纸原纸1具有相对的第一面以及第二面,所述第一防油层20和所述第一疏油亲水层30依次层叠设置于所述第一面上。所述一防油层20和第一疏油亲水层30均具有阻隔液体油脂的作用,所述第一疏油亲水层30使所述烟用接装纸1具有良好的包装卷接性能。Please refer to Fig. 1, the present invention provides a tipping paper 1 for cigarettes, comprising a tipping paper base paper 10, a first oil-repellent layer 20 and a first oleophobic and hydrophilic layer 30, the tipping paper base paper 1 has a relative first On one side and the second side, the first oil-repellent layer 20 and the first oleophobic and hydrophilic layer 30 are sequentially stacked on the first side. Both the first oil-repellent layer 20 and the first oleophobic and hydrophilic layer 30 have the function of blocking liquid grease, and the first oleophobic and hydrophilic layer 30 makes the tipping paper 1 for cigarettes have good wrapping performance.

所述第一防油层20和所述第一疏油亲水层30均具有树脂基体,且两者的树脂基体相容,从而使该两层之间具有很好的贴合性能。所述第一防油层20和所述第一疏油亲水层30的树脂基体不能选择芳香类树脂,因为芳香类树脂在合成过程中,单体或是助剂类的物质会影响芳香类树脂VOC含量,而烟用接装纸对VOC的含量有严格地限制。所述第一防油层20的树脂基体可选自丙烯酸树脂类和聚氨酯类中的至少一种,或者选自聚苯丙氨酸、多聚苯丙氨酸、松香树脂、缩丁醛树脂和聚氨酯中的至少一种;所述第一疏油亲水层30的树脂基体可选自聚碳酸酯和聚氨酯中的至少一种,以上树脂基体均具有较好的成膜性。Both the first oil-repellent layer 20 and the first oleophobic and hydrophilic layer 30 have a resin matrix, and the resin matrix of the two is compatible, so that the two layers have good bonding performance. The resin matrix of the first oil-repellent layer 20 and the first oleophobic and hydrophilic layer 30 cannot be selected from aromatic resins, because during the synthesis of aromatic resins, monomers or additives will affect the aromatic resins. VOC content, and cigarette tipping paper has strict restrictions on the content of VOC. The resin matrix of the first oil-proof layer 20 can be selected from at least one of acrylic resins and polyurethanes, or selected from polyphenylalanine, polyphenylalanine, rosin resin, butyral resin and polyurethane At least one of them; the resin matrix of the first oleophobic and hydrophilic layer 30 can be selected from at least one of polycarbonate and polyurethane, and the above resin matrixes all have good film-forming properties.

所述第一疏油亲水层30进一步包括无机填料,所述第一疏油亲水层30的树脂基体与所述无机填料的质量比为1:1~2:1。所述无机填料选自活性碳酸钙和滑石粉中的至少一种。所述无机填料均匀分散于所述第一疏油亲水层30中。具有亲水性的树脂基体一般都具有很强的吸水性,在所述烟用接装纸1后续的运输、存储和制备香烟过程中会不断吸水,从而导致所述烟用接装纸的含水率超出规定标准;加入所述无机填料可以降低所述第一疏油亲水层30的吸水性,从而始终将所述烟用接装纸1的含水率控制在规定范围内。The first oleophobic and hydrophilic layer 30 further includes inorganic fillers, and the mass ratio of the resin matrix of the first oleophobic and hydrophilic layer 30 to the inorganic fillers is 1:1˜2:1. The inorganic filler is selected from at least one of active calcium carbonate and talcum powder. The inorganic filler is uniformly dispersed in the first oleophobic and hydrophilic layer 30 . The resin matrix with hydrophilicity generally has strong water absorption, and will continuously absorb water during the subsequent transportation, storage and preparation of cigarettes of the cigarette tipping paper 1, resulting in the moisture content of the cigarette tipping paper 1. The rate exceeds the specified standard; adding the inorganic filler can reduce the water absorption of the first oleophobic and hydrophilic layer 30, so that the moisture content of the cigarette tipping paper 1 is always controlled within the specified range.

所述第一疏油亲水层30还可进一步包括爽滑剂、防沉剂、消泡剂、流平剂等助剂中的至少一种,以使所述第一疏油亲水层30更平整、光滑。所述爽滑剂可以为蜡粉。所述防沉剂可以为离子型表面活性剂。所述消泡剂可以为乳化硅油、高碳醇脂肪酸酯化合物。所述流平剂可以为聚二甲基硅氧烷(PDMS)、烷基改性有机硅氧烷和聚醚聚酯改性有机硅氧烷中的一种或是几种。可以理解,本领域的技术人员可以根据实际需要对上述助剂进行选择。The first oleophobic and hydrophilic layer 30 may further include at least one of auxiliary agents such as slip agent, anti-settling agent, defoamer, and leveling agent, so that the first oleophobic and hydrophilic layer 30 Smoother and smoother. The slippery agent can be wax powder. The anti-settling agent can be an ionic surfactant. The defoamer can be emulsified silicone oil, high-carbon alcohol fatty acid ester compound. The leveling agent can be one or more of polydimethylsiloxane (PDMS), alkyl-modified organosiloxane and polyether polyester-modified organosiloxane. It can be understood that those skilled in the art can select the above-mentioned auxiliary agents according to actual needs.

请参阅图2,所述烟用接装纸1的第二面可进一步设置有第二防油层22。所述第二疏油亲水层22上可进一步设置有第二疏油亲水层32。所述第二防油层22与所述第一防油层20相同,所述第二疏油亲水层32和所述第一疏油亲水层30相同,在此不再赘述。Please refer to FIG. 2 , the second surface of the tipping paper 1 for cigarettes may be further provided with a second oil-proof layer 22 . A second oleophobic and hydrophilic layer 32 may be further disposed on the second oleophobic and hydrophilic layer 22 . The second oil-repellent layer 22 is the same as the first oil-repellent layer 20 , and the second oleophobic and hydrophilic layer 32 is the same as the first oleophobic and hydrophilic layer 30 , which will not be repeated here.

所述第一防油层20、第一疏油亲水层30、第二防油层22或第二疏油亲水层32均可以为多层结构,从而达到有效阻止液态油脂渗出的目的。The first oil-repellent layer 20 , the first oleophobic and hydrophilic layer 30 , the second oil-repellent layer 22 or the second oleophobic and hydrophilic layer 32 can all be multilayer structures, so as to achieve the purpose of effectively preventing liquid grease from seeping out.

所述第一防油层20和所述第一疏油亲水层30可以进一步在所述接装纸原纸1的第一面上交替进行设置。所述第二防油层22和所述第二疏油亲水层32可以进一步在所述接装纸原纸1的第二面上交替进行设置。The first oil-repellent layer 20 and the first oleophobic and hydrophilic layer 30 may be further arranged alternately on the first surface of the tipping paper base paper 1 . The second oil-repellent layer 22 and the second oleophobic and hydrophilic layer 32 can be further arranged alternately on the second surface of the tipping paper base paper 1 .

请参阅图3,本发明进一步提供一种香烟,包括所述烟用接装纸1、滤嘴2和烟支3,所述烟用接装纸1包裹所述滤嘴2和所述烟支3,并将所述滤嘴2和所述烟支3连接在一起。Please refer to Fig. 3, the present invention further provides a cigarette, comprising the tipping paper 1 for cigarettes, a filter 2 and cigarettes 3, the tipping paper 1 for cigarettes wraps the filter 2 and the cigarettes 3, and connect the filter 2 and the cigarette 3 together.

本发明提供的香烟在存储和使用过程中不容易爆开,且具有阻隔油脂的作用,可以给抽烟者提供良好的体验。The cigarette provided by the invention is not easy to explode during storage and use, has the function of blocking grease, and can provide smokers with good experience.

请参阅图4,本发明进一步提供一种烟用接装纸的制备方法,包括:Please refer to Fig. 4, the present invention further provides a preparation method of tipping paper for cigarettes, comprising:

S11,提供一接装纸原纸,所述接装纸原纸具有相对的第一面和第二面;S11, providing a base paper for tipping paper, the base paper for tipping paper has opposite first and second sides;

S12,提供防油涂料,在所述第一面上印刷或涂布所述防油涂料,制得第一防油层;S12, providing an oil-repellent coating, printing or coating the oil-repellent coating on the first surface to obtain a first oil-repellent layer;

S13,提供疏油亲水涂料,该疏油亲水涂料与上述防油涂料分别具有相容的树脂基体;S13, providing an oleophobic and hydrophilic coating, the oleophobic and hydrophilic coating and the above-mentioned oil-repellent coating respectively have a compatible resin matrix;

S14,在所述第一防油层上印刷或涂布所述疏油亲水涂料,制得第一疏油亲水层,获得所述烟用接装纸。S14, printing or coating the oleophobic and hydrophilic coating on the first oil-repellent layer to prepare a first oleophobic and hydrophilic layer, and obtaining the tipping paper for cigarettes.

在步骤S12中,所述防油涂料印刷或涂布到所述接装纸原纸后,所述防油涂料中的溶剂全部挥发完毕,从而得到所述第一防油层。所述第一防油层一方面能够在步骤S13印刷或涂布所述疏油亲水涂料时,防止所述接装纸原纸吸水变形,另一方面也能为所述烟用接装纸提供隔离油脂的性能。进一步地,可根据实际需要,在所述接装纸原纸上多次印刷或涂布所述防油涂料,以获得多层第一防油层,从而达到有效阻止液态油脂渗出的目的。In step S12, after the oil-repellent paint is printed or coated on the base paper of the tipping paper, all the solvents in the oil-repellent paint are volatilized, so as to obtain the first oil-repellent layer. On the one hand, the first oil-proof layer can prevent the base paper of the tipping paper from absorbing water and deforming when printing or coating the oleophobic and hydrophilic coating in step S13; on the other hand, it can also provide isolation for the tipping paper for cigarettes. Grease properties. Further, according to actual needs, the oil-repellent paint can be printed or coated on the base paper of the tipping paper multiple times to obtain a multi-layer first oil-repellent layer, so as to effectively prevent liquid grease from seeping out.

所述防油涂料的树脂基体可选自丙烯酸树脂类和聚氨酯类中的至少一种,或者选自聚苯丙氨酸、多聚苯丙氨酸、松香树脂、缩丁醛树脂和聚氨酯中的至少一种。所述防油涂料可以是水性涂料,也可以是油性涂料。所述防油涂料为水性丙烯酸树脂类和水性聚氨酯类中的至少一种,或油性聚苯丙氨酸、松香树脂、缩丁醛树脂、多聚苯丙氨酸和油性聚氨酯中的至少一种。The resin matrix of the oil-proof coating can be selected from at least one of acrylic resins and polyurethanes, or selected from polyphenylalanine, polyphenylalanine, rosin resin, butyral resin and polyurethane at least one. The oil-proof paint can be water-based paint or oil-based paint. The oil-proof coating is at least one of water-based acrylic resins and water-based polyurethanes, or at least one of oily polyphenylalanine, rosin resin, butyral resin, polyphenylalanine and oily polyurethane .

在步骤S13中,所述疏油亲水涂料印刷或涂布到所述第一防油层后,所述溶剂全部挥发完全,从而得到所述第一疏油亲水层。所述疏油亲水涂料的树脂基体可选自聚碳酸酯和聚氨酯中的至少一种。In step S13, after the oleophobic and hydrophilic coating is printed or coated on the first oil-repellent layer, all the solvents are completely volatilized, thereby obtaining the first oleophobic and hydrophilic layer. The resin matrix of the oleophobic and hydrophilic coating can be selected from at least one of polycarbonate and polyurethane.

在一实施例中,所述疏油亲水涂料包括连接料、无机填料、乙醇和水,其中,所述连接料为水性聚碳酸酯、水性聚氨酯中的至少一种,所述无机填料为活性碳酸钙和滑石粉中的至少一种,所述连接料的质量百分比为15~30%,所述无机填料的质量百分比为15~30%,所述乙醇的质量百分比为20~30%,所述水的质量百分比为20~30%。当乙醇和水完全挥发之后,所述连接料转变为基料,所述无机填料均匀分散在所述基料中,从而得到所述第一疏油亲水层。In one embodiment, the oleophobic and hydrophilic coating includes a binder, an inorganic filler, ethanol and water, wherein the binder is at least one of water-based polycarbonate and water-based polyurethane, and the inorganic filler is an active At least one of calcium carbonate and talcum powder, the mass percentage of the binder is 15-30%, the mass percentage of the inorganic filler is 15-30%, and the mass percentage of the ethanol is 20-30%, so The mass percentage of the water is 20-30%. After the ethanol and water are completely volatilized, the connecting material is transformed into a base material, and the inorganic filler is uniformly dispersed in the base material, thereby obtaining the first oleophobic and hydrophilic layer.

将无机填料加入所述疏油亲水涂料中,可以降低所述第一疏油亲水层的吸水性,从而始终将所述烟用接装纸的含水率控制在规定范围内。所述乙醇和水可以配合所述无机填料和所述连接料,将所述疏油亲水涂料的粘度控制在20s~30s(20-30℃,英式3#查恩杯),以满足所述疏油亲水涂料的涂覆性能。Adding inorganic fillers to the oleophobic and hydrophilic coating can reduce the water absorption of the first oleophobic and hydrophilic layer, so that the moisture content of the cigarette tipping paper is always controlled within a specified range. The ethanol and water can be combined with the inorganic filler and the binder to control the viscosity of the oleophobic and hydrophilic coating at 20s to 30s (20-30°C, English 3# Charn cup), so as to meet the requirements of all The coating performance of the oleophobic and hydrophilic coatings.

优选地,所述疏油亲水涂料的细度小于30μm,以使所述疏油亲水涂料具有很好的印刷和涂布效果,防止使用时出现刀线、堵版等问题。Preferably, the fineness of the oleophobic and hydrophilic coating is less than 30 μm, so that the oleophobic and hydrophilic coating has a good printing and coating effect, and prevents problems such as knife line and plate blocking during use.

所述疏油亲水涂料可以进一步包括爽滑剂、防沉剂、消泡剂、流平剂等助剂中的至少一种,以获得更平整、光滑的第一疏油亲水层。所述爽滑剂、防沉剂、消泡剂或流平剂的质量百分比为0.1~1%。所述爽滑剂可以为蜡粉。所述防沉剂可以为离子型表面活性剂。所述消泡剂可以为乳化硅油、高碳醇脂肪酸酯化合物。所述流平剂可以为聚二甲基硅氧烷(PDMS)、烷基改性有机硅氧烷和聚醚聚酯改性有机硅氧烷中的一种或是几种。The oleophobic and hydrophilic coating may further include at least one of auxiliary agents such as slip agent, anti-settling agent, defoamer, and leveling agent, so as to obtain a smoother and smoother first oleophobic and hydrophilic layer. The mass percent of the slippery agent, anti-settling agent, defoamer or leveling agent is 0.1-1%. The slippery agent can be wax powder. The anti-settling agent can be an ionic surfactant. The defoamer can be emulsified silicone oil, high-carbon alcohol fatty acid ester compound. The leveling agent can be one or more of polydimethylsiloxane (PDMS), alkyl-modified organosiloxane and polyether polyester-modified organosiloxane.

在一实施例中,进一步提供一种所述疏油亲水涂料的制备方法,包括:In one embodiment, a kind of preparation method of described oleophobic hydrophilic coating is further provided, comprising:

S21,将乙醇和水混合,搅拌均匀,得到一溶液;S21, mixing ethanol and water and stirring evenly to obtain a solution;

S22,将所述连接料加入所述溶液,搅拌均匀,得到一乳液;S22, adding the binder into the solution, stirring evenly to obtain an emulsion;

S23,将所述无机填料加入到上述乳液,搅拌均匀,得到一悬浊液;S23, adding the inorganic filler to the above emulsion, stirring evenly to obtain a suspension;

S24,将上述悬浊液进行砂磨,得到所述疏油亲水涂料。S24, sanding the suspension to obtain the oleophobic and hydrophilic coating.

所述步骤S23和步骤S24之间进一步包括一在所述悬浊液中加入所述爽滑剂、防沉剂、消泡剂、流平剂等助剂中的至少一种的步骤。Between the step S23 and the step S24, there is further included a step of adding at least one of the auxiliary agents such as slip agent, anti-sedimentation agent, defoamer, and leveling agent to the suspension.

所述砂磨的目的使细化所述涂料。所述砂磨的时间为30~90分钟。The purpose of the sanding is to refine the paint. The sanding time is 30-90 minutes.

进一步地,可根据实际需要,在所述第一防油层上多次印刷或涂布所述疏油亲水涂料,以获得多层所述第一疏油亲水层,从而有效提高所述烟用接装纸的包装卷接性能。Further, according to actual needs, the oleophobic and hydrophilic coating can be printed or coated on the first oil-repellent layer multiple times to obtain multiple layers of the first oleophobic and hydrophilic layer, thereby effectively improving the smoke resistance. Wrap splicing performance with tipping paper.

步骤S12和S14中,印刷的方式可以是凹版印刷、柔版印刷等,涂布方式可以是刮涂、三辊涂布、喷涂、逗号涂布、逆向涂布等。In steps S12 and S14, the printing method may be gravure printing, flexographic printing, etc., and the coating method may be blade coating, three-roll coating, spray coating, comma coating, reverse coating, etc.

所述烟用接装纸的制备方法可以进一步包括在所述接装纸原纸的第二面印刷或涂布所述防油涂料,得到第二防油层的步骤,这一步骤与所述步骤S12基本相同,在此不再赘述。该步骤可以在步骤S12之后进行,也可以在步骤S14之后进行。此时,所述第一防油层和第二防油层可以共同对液态油脂进行阻隔,从而大大增强了所述烟用接装纸阻隔油脂的性能。The preparation method of the tipping paper for cigarettes may further include the step of printing or coating the oil-repellent coating on the second side of the base paper of the tipping paper to obtain a second oil-repellent layer. This step is the same as the step S12 They are basically the same and will not be repeated here. This step can be performed after step S12, or after step S14. At this time, the first oil-proof layer and the second oil-proof layer can jointly block liquid grease, thereby greatly enhancing the grease-blocking performance of the tipping paper for cigarettes.

所述烟用接装纸的制备方法可以进一步包括在所述第二防油层上印刷或涂布所述疏油亲水涂料,得到第二疏油亲水层的步骤,这一步骤与所述步骤S12基本相同,在此不再赘述。此时,所述烟用接装纸的两面均设置有防油层和疏油亲水层。The preparation method of the tipping paper for cigarettes may further include the step of printing or coating the oleophobic and hydrophilic coating on the second oil-repellent layer to obtain a second oleophobic and hydrophilic layer, which is the same as the Step S12 is basically the same and will not be repeated here. At this time, both sides of the tipping paper for cigarettes are provided with an oil-repellent layer and an oleophobic and hydrophilic layer.

所述烟用接装纸的制备方法可以进一步包括在所述第一面或第二面交替印刷或涂布所述防油涂料和疏油亲水涂料的步骤,得到交替层叠设置的第一防油层和第一疏油亲水层,或第二防油层和第二疏油亲水层。The preparation method of the tipping paper for cigarettes may further include the step of printing or coating the oil-repellent coating and the oleophobic and hydrophilic coating alternately on the first surface or the second surface, so as to obtain the first anti-corrosion coating arranged alternately. An oil layer and a first oleophobic and hydrophilic layer, or a second oil repellent layer and a second oleophobic and hydrophilic layer.

实施例1Example 1

本实施例中疏油亲水涂料的配方(质量百分比)如下:30%水性聚碳酸酯、15%活性碳酸钙、25%乙醇、26%水、1%爽滑剂、1%防沉降剂、1%流平剂、1%消泡剂。所述疏油亲水涂料的制备方法如下:The formula (mass percentage) of oleophobic hydrophilic coating in the present embodiment is as follows: 30% aqueous polycarbonate, 15% activated calcium carbonate, 25% ethanol, 26% water, 1% smooth agent, 1% anti-settling agent, 1% leveling agent, 1% defoamer. The preparation method of described oleophobic hydrophilic coating is as follows:

(1)将乙醇和水混合,搅拌均匀,得到一溶液;(1) Mix ethanol and water and stir evenly to obtain a solution;

(2)将水性聚碳酸酯加入上述溶液,搅拌均匀,得到一乳液;(2) adding water-based polycarbonate to the above solution, stirring evenly to obtain an emulsion;

(3)将活性碳酸钙加入到上述乳液中,搅拌均匀,得到一悬浊液;(3) active calcium carbonate is added in the above-mentioned emulsion, stir evenly, obtain a suspension;

(4)将爽滑剂、防沉剂、消泡剂、流平剂加入到上述悬浊液中;(4) Add slip agent, anti-sedimentation agent, defoamer, and leveling agent to the above-mentioned suspension;

(5)将步骤(4)得到的悬浊液砂磨60min,得到细度为25μm、粘度为22s(24℃,英式3#查恩杯)的疏油亲水涂料。(5) Sand mill the suspension obtained in step (4) for 60 min to obtain an oleophobic and hydrophilic coating with a fineness of 25 μm and a viscosity of 22 s (24° C., British 3# Charn cup).

所述烟用接装纸的制备方法如下:The preparation method of the tipping paper for cigarettes is as follows:

(1)使用水性丙烯酸树脂类乳液,通过凹版印刷的方式在接装纸原纸上印刷一层或多层防油层;(1) Use water-based acrylic resin emulsion to print one or more oil-proof layers on the base paper of the tipping paper by gravure printing;

(2)使用上述疏油亲水涂料,通过凹版印刷的方式在防油层上印刷一层或多层疏油亲水层,得到所述烟用接装纸。(2) Using the above-mentioned oleophobic and hydrophilic coating, one or more layers of oleophobic and hydrophilic layers are printed on the oil-proof layer by gravure printing to obtain the tipping paper for cigarettes.

本实施例进一步在所述烟用接装纸的隔离层面或隔离层反面进行图文印刷。In this embodiment, graphics and text are further printed on the isolation layer or the reverse side of the isolation layer of the tipping paper for cigarettes.

实施例2Example 2

本实施例中疏油亲水涂料的配方(质量百分比)如下:30%水性聚碳酸酯/聚氨酯混合乳液、15%滑石粉、28%乙醇,25%水、0.5%爽滑剂、0.5%防沉降剂、0.5%流平剂、0.5%消泡剂。The formula (mass percentage) of oleophobic hydrophilic coating in the present embodiment is as follows: 30% aqueous polycarbonate/polyurethane mixed emulsion, 15% talcum powder, 28% ethanol, 25% water, 0.5% smooth agent, 0.5% anti-corrosion Settling agent, 0.5% leveling agent, 0.5% defoamer.

所述疏油亲水涂料的制备方法如下:The preparation method of described oleophobic hydrophilic coating is as follows:

(1)将乙醇和水混合,搅拌均匀,得到一溶液;(1) Mix ethanol and water and stir evenly to obtain a solution;

(2)将水性聚碳酸酯/聚氨酯混合乳液加入上述溶液,搅拌均匀,得到一乳液;(2) adding the aqueous polycarbonate/polyurethane mixed emulsion to the above solution, stirring evenly to obtain an emulsion;

(3)将滑石粉加入到上述乳液中,搅拌均匀,得到一悬浊液;(3) Add talcum powder to the above-mentioned emulsion, stir evenly to obtain a suspension;

(4)将爽滑剂、防沉剂、消泡剂、流平剂加入到上述悬浊液中;(4) Add slip agent, anti-sedimentation agent, defoamer, and leveling agent to the above-mentioned suspension;

(5)将步骤(4)得到的悬浊液砂磨60min,得到细度为23μm、粘度在22s(25℃,英式3#查恩杯)的疏油亲水涂料。(5) Sand mill the suspension obtained in step (4) for 60 minutes to obtain an oleophobic and hydrophilic coating with a fineness of 23 μm and a viscosity of 22 s (25° C., British 3# Charn cup).

所述烟用接装纸的制备方法如下:The preparation method of the tipping paper for cigarettes is as follows:

(1)使用油性聚氨酯乳液,通过喷涂的方式在接装纸原纸上喷涂一层或多层防油层;(1) Use oily polyurethane emulsion to spray one or more oil-proof layers on the base paper of the tipping paper by spraying;

(2)使用上述疏油亲水涂料,通过喷涂的方式在防油层上喷涂一层或多层疏油亲水层,得到所述烟用接装纸。(2) Using the above-mentioned oleophobic and hydrophilic coating, one or more layers of oleophobic and hydrophilic layers are sprayed on the oil-repellent layer by spraying to obtain the tipping paper for cigarettes.

本实施例进一步在所述烟用接装纸的隔离层面或隔离层反面进行图文印刷。In this embodiment, graphics and text are further printed on the isolation layer or the reverse side of the isolation layer of the tipping paper for cigarettes.

实施例3Example 3

本实施例中疏油亲水涂料的配方(质量百分比)如下:24%水性聚碳酸酯/聚氨酯混合乳液、24%滑石粉、20%乙醇,30%水、0.5%爽滑剂、0.5%防沉降剂、0.5%流平剂、0.5%消泡剂。The formula (mass percentage) of oleophobic hydrophilic coating in the present embodiment is as follows: 24% aqueous polycarbonate/polyurethane mixed emulsion, 24% talcum powder, 20% ethanol, 30% water, 0.5% smooth agent, 0.5% anti-corrosion Settling agent, 0.5% leveling agent, 0.5% defoamer.

所述疏油亲水涂料的制备方法如下:The preparation method of described oleophobic hydrophilic coating is as follows:

(1)将乙醇和水混合,搅拌均匀,得到一溶液;(1) Mix ethanol and water and stir evenly to obtain a solution;

(2)将水性聚碳酸酯/聚氨酯混合乳液加入上述溶液,搅拌均匀,得到一乳液;(2) adding the aqueous polycarbonate/polyurethane mixed emulsion to the above solution, stirring evenly to obtain an emulsion;

(3)将滑石粉加入到上述乳液中,搅拌均匀,得到一悬浊液;(3) Add talcum powder to the above-mentioned emulsion, stir evenly to obtain a suspension;

(4)将爽滑剂、防沉剂、消泡剂、流平剂加入到上述悬浊液中;(4) Add slip agent, anti-sedimentation agent, defoamer, and leveling agent to the above-mentioned suspension;

(5)将步骤(4)得到的悬浊液砂磨60min,得到细度为25μm、粘度在23s(24℃,英式3#查恩杯)的疏油亲水涂料。(5) Sand mill the suspension obtained in step (4) for 60 min to obtain an oleophobic and hydrophilic coating with a fineness of 25 μm and a viscosity of 23 s (24° C., British 3# Charn cup).

所述烟用接装纸的制备方法如下:The preparation method of the tipping paper for cigarettes is as follows:

(1)使用油性聚氨酯乳液,通过喷涂的方式在接装纸原纸上喷涂一层或多层防油层;(1) Use oily polyurethane emulsion to spray one or more oil-proof layers on the base paper of the tipping paper by spraying;

(2)使用上述疏油亲水涂料,通过喷涂的方式在防油层上喷涂一层或多层疏油亲水层,得到所述烟用接装纸。(2) Using the above-mentioned oleophobic and hydrophilic coating, one or more layers of oleophobic and hydrophilic layers are sprayed on the oil-repellent layer by spraying to obtain the tipping paper for cigarettes.

本实施例进一步在所述烟用接装纸的隔离层面或隔离层反面进行图文印刷。In this embodiment, graphics and text are further printed on the isolation layer or the reverse side of the isolation layer of the tipping paper for cigarettes.

实施例4Example 4

本实施例中疏油亲水涂料的配方(质量百分比)如下:20%水性聚碳酸酯、24%活性碳酸钙、30%乙醇、20%水、1%爽滑剂、1%防沉降剂、1%流平剂、1%消泡剂。The formula (mass percentage) of oleophobic hydrophilic coating in the present embodiment is as follows: 20% aqueous polycarbonate, 24% active calcium carbonate, 30% ethanol, 20% water, 1% smooth agent, 1% anti-settling agent, 1% leveling agent, 1% defoamer.

所述疏油亲水涂料的制备方法如下:The preparation method of described oleophobic hydrophilic coating is as follows:

(1)将乙醇和水混合,搅拌均匀,得到一溶液;(1) Mix ethanol and water and stir evenly to obtain a solution;

(2)将水性聚碳酸酯加入上述溶液,搅拌均匀,得到一乳液;(2) adding water-based polycarbonate to the above solution, stirring evenly to obtain an emulsion;

(3)将活性碳酸钙加入到上述乳液中,搅拌均匀,得到一悬浊液;(3) active calcium carbonate is added in the above-mentioned emulsion, stir evenly, obtain a suspension;

(4)将爽滑剂、防沉剂、消泡剂、流平剂加入到上述悬浊液中;(4) Add slip agent, anti-sedimentation agent, defoamer, and leveling agent to the above-mentioned suspension;

(5)将步骤(4)得到的悬浊液砂磨60min,得到细度为24μm、粘度在22s(25℃,英式3#查恩杯)的疏油亲水涂料。(5) Sand mill the suspension obtained in step (4) for 60 min to obtain an oleophobic and hydrophilic coating with a fineness of 24 μm and a viscosity of 22 s (25° C., British 3# Charn cup).

所述烟用接装纸的制备方法如下:The preparation method of the tipping paper for cigarettes is as follows:

(1)使用水性丙烯酸树脂类乳液,通过凹版印刷的方式在接装纸原纸上印刷一层或多层防油层;(1) Use water-based acrylic resin emulsion to print one or more oil-proof layers on the base paper of the tipping paper by gravure printing;

(2)使用上述疏油亲水涂料,通过凹版印刷的方式在防油层上印刷一层或多层疏油亲水层,得到所述烟用接装纸。(2) Using the above-mentioned oleophobic and hydrophilic coating, one or more layers of oleophobic and hydrophilic layers are printed on the oil-proof layer by gravure printing to obtain the tipping paper for cigarettes.

本实施例进一步在所述烟用接装纸的隔离层面或隔离层反面进行图文印刷。In this embodiment, graphics and text are further printed on the isolation layer or the reverse side of the isolation layer of the tipping paper for cigarettes.

以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only express several implementation modes of the present invention, and the description thereof is relatively specific and detailed, but should not be construed as limiting the patent scope of the present invention. It should be pointed out that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention should be based on the appended claims.

Claims (7)

1.一种烟用接装纸,包括接装纸原纸,其特征在于,所述接装纸原纸包括防油层和疏油亲水层,所述防油层和所述疏油亲水层依次层叠设置于所述接装纸原纸的至少一面上,所述防油层和所述疏油亲水层均具有树脂基体,且两者的树脂基体相容;1. A cigarette tipping paper, comprising tipping paper base paper, characterized in that, said tipping paper base paper comprises an oil-repellent layer and an oleophobic-hydrophilic layer, and said oil-repellent layer and said oleophobic-hydrophilic layer are stacked successively It is arranged on at least one side of the base paper of the tipping paper, the oil-repellent layer and the oleophobic and hydrophilic layer both have a resin matrix, and the resin matrix of the two is compatible; 所述防油层的树脂基体选自丙烯酸树脂类和聚氨酯类中的至少一种,或者选自聚苯丙氨酸、多聚苯丙氨酸、松香树脂、缩丁醛树脂和聚氨酯类中的至少一种;所述疏油亲水层的树脂基体选自聚碳酸酯和聚氨酯类中的至少一种;The resin matrix of the oil-proof layer is selected from at least one of acrylic resins and polyurethanes, or at least one selected from polyphenylalanine, polyphenylalanine, rosin resins, butyral resins and polyurethanes One; the resin matrix of the oleophobic and hydrophilic layer is selected from at least one of polycarbonate and polyurethane; 所述疏油亲水层进一步包括无机填料,所述无机填料选自活性碳酸钙和滑石粉中的至少一种,所述疏油亲水层的树脂基体与所述无机填料的质量比为1:1~2:1。The oleophobic and hydrophilic layer further includes an inorganic filler selected from at least one of activated calcium carbonate and talcum powder, and the mass ratio of the resin matrix of the oleophobic and hydrophilic layer to the inorganic filler is 1 :1~2:1. 2.根据权利要求1所述的烟用接装纸,其特征在于,所述烟用接装纸的两面均包括依次层叠设置的所述防油层和所述疏油亲水层。2 . The tipping paper for cigarettes according to claim 1 , wherein both sides of the tipping paper for cigarettes include the oil-repellent layer and the oleophobic and hydrophilic layer stacked in sequence. 3.根据权利要求1或2所述的烟用接装纸,其特征在于,所述烟用接装纸的至少一面上包括多个所述防油层和多个所述疏油亲水层交替设置。3. The tipping paper for cigarettes according to claim 1 or 2, characterized in that at least one side of the tipping paper for cigarettes comprises a plurality of said oil-repellent layers and a plurality of said oleophobic and hydrophilic layers alternately set up. 4.根据权利要求1或2所述的烟用接装纸,其特征在于,所述防油层或所述疏油亲水层为多层结构。4. The tipping paper for cigarettes according to claim 1 or 2, characterized in that the oil-repellent layer or the oleophobic and hydrophilic layer has a multi-layer structure. 5.一种烟用接装纸的制备方法,其特征在于,包括:5. A preparation method for cigarette tipping paper, characterized in that it comprises: S11,提供一接装纸原纸,所述接装纸原纸具有相对的第一面和第二面;S11, providing a base paper for tipping paper, the base paper for tipping paper has opposite first and second sides; S12,提供防油涂料,在所述第一面上印刷或涂布所述防油涂料,制得第一防油层;S12, providing an oil-repellent coating, printing or coating the oil-repellent coating on the first surface to obtain a first oil-repellent layer; S13,提供疏油亲水涂料,该疏油亲水涂料与上述防油涂料分别具有相容的树脂基体;S13, providing an oleophobic and hydrophilic coating, the oleophobic and hydrophilic coating and the above-mentioned oil-repellent coating respectively have a compatible resin matrix; S14,在所述第一防油层上印刷或涂布所述疏油亲水涂料,制得第一疏油亲水层,获得所述烟用接装纸,其中:S14, printing or coating the oleophobic and hydrophilic coating on the first oil-repellent layer to obtain the first oleophobic and hydrophilic layer, and obtaining the tipping paper for cigarettes, wherein: 所述防油涂料为水性丙烯酸树脂类和水性聚氨酯类中的至少一种,或油性聚苯丙氨酸、松香树脂、缩丁醛树脂、多聚苯丙氨酸和油性聚氨酯类中的至少一种;所述疏油亲水涂料包括连接料、无机填料、乙醇和水,所述连接料为水性聚碳酸酯、水性聚氨酯类中的至少一种,所述无机填料为活性碳酸钙和滑石粉中的至少一种,其中,所述连接料的质量百分比为15~30%,所述无机填料的质量百分比为15~30%,所述乙醇的质量百分比为20~30%,所述水的质量百分比为20~30%。The oil-proof coating is at least one of water-based acrylic resins and water-based polyurethanes, or at least one of oily polyphenylalanine, rosin resin, butyral resin, polyphenylalanine and oily polyurethanes A kind; Described oleophobic hydrophilic coating comprises linking material, inorganic filler, ethanol and water, and described linking material is at least one in water-based polycarbonate, water-based polyurethane, and described inorganic filler is active calcium carbonate and talcum powder At least one of, wherein, the mass percentage of the binder is 15-30%, the mass percentage of the inorganic filler is 15-30%, the mass percentage of the ethanol is 20-30%, and the water The mass percentage is 20-30%. 6.根据权利要求5所述的烟用接装纸的制备方法,其特征在于,所述疏油亲水涂料的细度小于30μm。6. The method for preparing cigarette tipping paper according to claim 5, characterized in that the fineness of the oleophobic and hydrophilic coating is less than 30 μm. 7.根据权利要求5所述的烟用接装纸的制备方法,其特征在于,所述烟用接装纸的制备方法进一步包括在所述接装纸原纸的第二面依次印刷或涂布所述防油涂料和所述疏油亲水涂料,得到第二防油层和第二疏油亲水层的步骤。7. The method for preparing tipping paper for cigarettes according to claim 5, characterized in that, the method for preparing tipping paper for cigarettes further comprises sequentially printing or coating on the second side of the base paper for tipping paper The step of obtaining a second oil-repellent layer and a second oleophobic-hydrophilic layer for the oil-repellent coating and the oleophobic-hydrophilic coating.
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