CN1064699A - Multifunctional concrete building material additive and its preparation process - Google Patents
Multifunctional concrete building material additive and its preparation process Download PDFInfo
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- CN1064699A CN1064699A CN 92101663 CN92101663A CN1064699A CN 1064699 A CN1064699 A CN 1064699A CN 92101663 CN92101663 CN 92101663 CN 92101663 A CN92101663 A CN 92101663A CN 1064699 A CN1064699 A CN 1064699A
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- residue
- alcohol
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- slag
- paraffin
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- 239000004567 concrete Substances 0.000 title claims abstract description 25
- 239000004566 building material Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000654 additive Substances 0.000 title claims abstract 7
- 230000000996 additive effect Effects 0.000 title claims abstract 5
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 19
- 239000002893 slag Substances 0.000 claims abstract description 18
- 239000012188 paraffin wax Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000007127 saponification reaction Methods 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 19
- 150000004665 fatty acids Chemical group 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 8
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- 238000005194 fractionation Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 238000000703 high-speed centrifugation Methods 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000003158 alcohol group Chemical group 0.000 claims 5
- 230000032798 delamination Effects 0.000 claims 2
- 239000010775 animal oil Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 239000000498 cooling water Substances 0.000 claims 1
- 230000004136 fatty acid synthesis Effects 0.000 claims 1
- 229940057995 liquid paraffin Drugs 0.000 claims 1
- 230000020477 pH reduction Effects 0.000 claims 1
- 239000000523 sample Substances 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 238000001816 cooling Methods 0.000 abstract description 5
- 238000004945 emulsification Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 239000002894 chemical waste Substances 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000010802 sludge Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 238000012423 maintenance Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 239000003513 alkali Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002362 mulch Substances 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000037 vitreous enamel Substances 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
多功能混凝土建材助剂及其制备工艺，助剂由成 膜物、乳化剂、铺助剂经加热、皂化、乳化、冷却配制而 成。成膜物采用酸渣、石蜡，乳化剂采用醇渣。本助 剂用化工废料为主要原料配制而成，具有脱模、养护、 防水多种功能。涂药一次，脱模2～3次，构件表面光 滑，膜层能耐水冲刷、围水浸泡。混凝土水分损失 0.030g/cm2，养护效果好。围水浸泡6个月，涂层无 变化，防水效果好。本助剂制备工艺简单生产成本 低，使用费用低，适合大面积推广。Multifunctional concrete building material additive and its preparation process, the additive is prepared by heating, saponification, emulsification, and cooling from film formers, emulsifiers, and paving aids. Acid slag and paraffin are used as film-forming materials, and alcohol slag is used as emulsifier. This additive is prepared with chemical waste as the main raw material, and has multiple functions of demoulding, curing and waterproofing. Apply the medicine once, demould 2-3 times, the surface of the component is smooth, and the film layer can withstand water washing and surrounding water immersion. The moisture loss of concrete is 0.030g/cm 2 , and the curing effect is good. Soaked in surrounding water for 6 months, the coating has no change, and the waterproof effect is good. The preparation process of the auxiliary agent is simple, the production cost is low, the use cost is low, and it is suitable for large-scale promotion.
Description
The invention belongs to the auxiliary class that is used for material of construction, be used for the building materials auxiliary agent of concrete construction specifically.
As the building materials chemical assistant of effects such as concrete demoulding, maintenance, waterproof, in concrete construction, be used widely.These auxiliary agents have its common ground, and promptly they all are the liquid membrane-forming agents of emulsion-type, and its main component is a filmogen, emulsifying agent, assistant medicament.Because of each agent role difference, also inequality to the selection of film forming matter.Select the oily material that frictional coefficient is little, intermolecular attraction is little as remover, curing agent is selected the not high temporary water-proof material of mechanicalness index, water-resisting agent is then selected to have the low molecule or the polymer of long-chain and is formed, film forming firmly, can the storage pore, block capillary channel, reduce the material of water-permeable.Therefore existing auxiliary agent only has simple function basically, can not three functions possess entirely.
In addition, present releasing agent mostly is fatty acid soaps class, seed fat foot soap class, emulsification oils greatly, cost height not only, the price height as 890 yuan of W-15 releasing agent prices per ton, and is coated with once, can only the demoulding once, easily be stained with ash, release agent coating can not water-fastly wash away.Curing agent has the RT175 of vinylchlorid, vinylidene chloride interpolymer, 5600 yuan/ton of its prices, and the solvent borne curing agent of emulsified olefin type, resene, its cost height, water retention property is poor.Water-resisting agent adopts emulsified bitumen basically, its construction cost height, contaminate environment.
Purpose of the present invention is intended to develop a kind of building materials auxiliary agent as multiple functions such as concrete demoulding, maintenance, waterproof, and this auxiliary agent raw material mainly adopts chemical spent material, and cost is low.The manufacturing process of design is simple, but this auxiliary agent is once brushed demoulding 2-3 time, and stripping result is good, water-fast the washing away of release coating energy, and the maintenance water conservation is effective, and water resistance is good.
The objective of the invention is to realize in the following manner, the multifunctional concrete auxiliary agent is made into by film forming matter, emulsifying agent, auxiliary, and film forming matter adopts acid sludge, paraffin, and emulsifying agent adopts pure slag, levelling agent 0(polyoxyethylene aliphatic alcohol ether), concrete weight proportion is:
Acid sludge paraffin alcohol slag caustic soda water
100～175 25～100 60～90 1.7～5.7 to add to concentration be 30～56%
Auxiliary agent outward appearance: pale brown look milk sap solid content: 30%-56%
Viscosity (being coated with-4 glasss): 12-13 second (30-35%) PH: about 7
Emulsion particle size: 3-4 micron
Stability of emulsion: 15 minutes not stratified or layering≤5% of 3000 rev/mins of high speed centrifugations, place not breakdown of emulsion of 2-3 under the good sample room temperature naturally.
The preparation technology of multifunctional assistant for concrete-containing building material is: earlier with more than the acid sludge heat fused to 90 ℃, under constantly stirring, the alkali lye that slowly adds the 5-10% of heat, continue to stir saponification 15-20 minute down at 85-90 ℃, after treating saponification fully, the mixed solution that adds the pure slag melted, paraffin, levelling agent 0 while hot, stir, the heating emulsifying water, in 85-95 ℃ of following insulated and stirred, after waiting to be incubated emulsification 30-40 minute emulsion, stir cooling with water coolant again, or being cooled to 40 ℃ naturally, discharging is product.
The multi-functional assistant for concrete-containing building material of preparation potion, the multiple material that need have various performances carries out compound preparation, and chemical spent material is formed complexity, it is the mixture of multiple composition, therefore to select to have hydrophobic nature structure and low molecule or the molecular chemical spent material of high score be the main composition of film forming matter to this auxiliary agent, through heating saponification, chemical modification, in addition other auxiliarys make film forming matter have multifrequency nature.Acid sludge as film forming matter has:
(1) synthetic fatty acid acid sludge: residue at the bottom of the still of paraffin oxidation synthetic fatty acid,
(2) natural fat acid sludge: the animals and plants oil foot extracts the acid sludge behind the lipid acid.
(3) residue behind stearic acid sludge (4) the soap system extraction glycerine
The main synthetic fat acid sludge of using, its acid value with 50-62 number for well.
No. 62 refining product of paraffin employing or semi-refined product.
Pure slag as emulsifying agent is
(1) higher alcohols slag: after the Fatty Alcohol(C12-C14 and C12-C18) fractionation, carbon number be higher than 16 after heat up in a steamer pure slag, be generally the mixture of 18-22 carbon number, its source has two: a kind of is the synthol slag that whiteruss makes after distillation with atmospheric oxidation in the presence of boric acid, or distills the synthol slag that makes from second unsaponifiables of producing synthetic fatty acid after the boric acid acidifying.Heat up in a steamer pure slag after after the fractionation of another kind Oleum Cocois hydrogenation system alcohol.
(2) the secondary unsaponifiables of synthetic fatty acid.
Water: tap water or soft water.
Auxiliary agent of the present invention is sprayed at the fresh concrete surface, forms fluid-tight polymolecular film, the unnecessary water that concrete mixing is used is closed in the concrete, suppresses and delayed the moisture loss in concrete premature cure stage, plays the water-preserving curing effect.Carry out relevant test with the ASTMC156 method of general in the world mensuration curing agent moisture loss amount, and compare with existing curing agent, it the results are shown in Table 1.
Table 1
This auxiliary agent water retention property is good as seen from the table.
When measuring the moisture loss amount, also carried out having blank correlated relative water retention test, blank comparative group is calculated as follows relative water retention for not being coated with the test specimen of curing agent:
Relative water retention=(blank test specimen moisture loss amount-test block moisture loss amount)/(blank test specimen moisture loss amount) * 100%,
After measured, the relative water retention that calculates this auxiliary agent is 90%.
The ultimate compression strength of the also available maintenance part of maintenance performance of curing agent is evaluated.The moisture loss amount is little, hydrated cementitious is abundant, and gain in strength is normal, otherwise then intensity is on the low side.Compare test with different curing agents, its comparing result sees Table 2.
Table 2
Good from the maintenance performance of table 2 also visible this auxiliary agent.
This auxiliary agent is coated on the concrete formation template, forms one deck sealing coat on the surface, so stripping result is good, to concrete bottom die, the loose tool particularly suitable that is difficult to the demoulding.With the test method of 0.4 * 0.2 * 0.05 meter concrete slab of moulding, the RH releasing agent of W-15, Wanrong, Shanxi that detects this auxiliary agent and Wuhan chemical industry two factories is to the demolding performace of metal pattern, concrete bottom die, and its detection, comparing result see Table 3.
Table 3
As seen from the table, it is many that this auxiliary agent and other releasing agents are compared release times, and film forming is firm, and the water logging bubble can water-fastly be washed away or enclose to the demoulding coating of releasing agent.
This auxiliary agent is sprayed at concrete surface, and the energy water-proof is at autumn in summer high temperature season, even soaked 6 months surperficial no change in water.
Hubei Province building slab factory is sprayed at this auxiliary agent on the bed die of concrete floor, and the cast prestressed hollow slab is coated with once, and the demoulding is twice continuously.When playing plate, cut off compressor wire, floor can break away from the mulch film terrace automatically.The simulation heavy rain wash away with rain after accumulated water, penetrate high pressure water with 5 meters and washed away 10 minutes or enclosed water logging bubble 48 hours, release agent coating stands intact, and soaks six days, the face color does not take off.
Wuhan Iron and Steel Plant foreign trade harbour is with 1 * 0.5 * 0.06 meter Steel Concrete trench cover of this auxiliary agent maintenance, and the film forming fast drying can effectively prevent the generation of desciccation crack.
This auxiliary agent is a main raw material with chemical spent material, has multiple functions such as the demoulding, maintenance, waterproof.As releasing agent, a coating, but demoulding 2-3 time, demoulding component surface is smooth, and release agent coating can water-fast washing away, and encloses water logging and steep.As curing agent, moisture loss is 0.030g/cm
2, film forming 0.5-1 time of drying hour.As waterproof paint, enclose water logging bubble coating no change after June.This auxiliary agent production cost is low, and cost of use is low, suits large area to popularize.
Enumerate embodiments of the invention below:
Example 1,75 gram acid sludge places little porcelain enamel barrel, is heated in oil bath more than 90 ℃, and 5% the caustic soda soln 34ml that stirs on one side that slow adding boils adds alkali lye in 88-92 ℃ of saponification 25 minutes.In another beaker, with the secondary unsaponifiables of 43 gram synthetic fatty acids, 25 restrain No. 62 paraffin of full refinings simultaneously, 1.5 gram levelling agent 0 mixes, after the fusing, it is joined in the above-mentioned saponification material while hot in boiling water bath, temperature is controlled at 85-90 ℃, stir after 5-10 minute, slowly add 200ml hot water, stirred 40 minutes in 85 ℃ of left and right sides constant temperature, cooling is stirred to 40 ℃ naturally, get product 260 grams, working substance content 56%.
Example 2,100 gram acid sludges are heated in oil bath more than 90 ℃, slowly add 5% the alkali lye 46ml that boils under constantly stirring, in 85-90 ℃ of saponification about 15 minutes, and moisturizing frequently, treat that saponification adds the pure slag of 86 grams fully while hot, semi-refined No. 62 paraffin of 100 grams, the consolute thing of 3 gram leveling agent ds after 10 minutes, slowly adds hot water emulsification in 89-91 ℃ of stirring, after 85 ℃ of left and right sides constant temperature stir 30 minutes, naturally cooling is stirred to 40 ℃ of dischargings, gets product 799 grams, working substance content 36%.
Example 3,175 gram acid sludges are heated to more than 90 ℃, stir to add 5% alkali lye 64ml down, in 85-90 ℃ of saponification, complete to saponification, add No. 62 paraffin of 25 grams, the melts of the pure slag of 70 grams, 3 gram leveling agent ds, stirred 10 minutes in 85-90 ℃, add boiling water emulsification, after 85 ℃ of left and right sides constant temperature stirred 40 minutes, cooling was stirred to 40 ℃ naturally, get product 920 grams, working substance content 30%.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92101663 CN1024681C (en) | 1992-03-11 | 1992-03-11 | Multifunctional concrete building material additive and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92101663 CN1024681C (en) | 1992-03-11 | 1992-03-11 | Multifunctional concrete building material additive and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1064699A true CN1064699A (en) | 1992-09-23 |
| CN1024681C CN1024681C (en) | 1994-05-25 |
Family
ID=4939227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92101663 Expired - Fee Related CN1024681C (en) | 1992-03-11 | 1992-03-11 | Multifunctional concrete building material additive and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1024681C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104276792A (en) * | 2014-09-10 | 2015-01-14 | 解波 | Moistureproof concrete and preparation method thereof |
-
1992
- 1992-03-11 CN CN 92101663 patent/CN1024681C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104276792A (en) * | 2014-09-10 | 2015-01-14 | 解波 | Moistureproof concrete and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1024681C (en) | 1994-05-25 |
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