CN106433313A - Preparation technology of salt anti-counterfeiting mark material - Google Patents
Preparation technology of salt anti-counterfeiting mark material Download PDFInfo
- Publication number
- CN106433313A CN106433313A CN201610863166.5A CN201610863166A CN106433313A CN 106433313 A CN106433313 A CN 106433313A CN 201610863166 A CN201610863166 A CN 201610863166A CN 106433313 A CN106433313 A CN 106433313A
- Authority
- CN
- China
- Prior art keywords
- counterfeiting mark
- polyamide resin
- preparation technology
- fulgide
- salt anti
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 150000003839 salts Chemical class 0.000 title claims abstract description 27
- 238000005516 engineering process Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 36
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 20
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 102000004895 Lipoproteins Human genes 0.000 claims description 23
- 108090001030 Lipoproteins Proteins 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 12
- 239000004952 Polyamide Substances 0.000 claims description 10
- 229920002647 polyamide Polymers 0.000 claims description 10
- 239000004576 sand Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 2
- 235000013339 cereals Nutrition 0.000 description 5
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wrappers (AREA)
Abstract
The invention relates to a preparation technology of a salt anti-counterfeiting mark material. The preparation technology comprises the following steps: mixing polyamide resin powder, isopropyl alcohol, dimethylbenzene and butyl alcohol, and stirring and heating into a polyamide resin solution; adding fulgide powder into the polyamide resin solution, and uniformly stirring; then adding a dispersing agent and an antioxidant; and then grinding, and uniformly stirring, so that the salt anti-counterfeiting mark material finished product is obtained. The preparation technology provided by the invention has the advantages that polyamide resin solution and fulgide are adopted as raw materials for preparing a photochromic salt anti-counterfeiting mark material, and the photochromic salt anti-counterfeiting mark material has good printing adaptability, can be better bonded with a salt packaging bag and is obvious in photochromic effect and better in wear resistance.
Description
Technical field
The present invention relates to anti-counterfeiting mark material, the specifically preparation technology of the anti-counterfeiting mark material in salt packaging bag.
Background technology
In recent years, with economic fast development, the life of people is enriched by more colourful things, but not
Good fortune, people are also stranded by various counterfeit and shoddy goods that flood market while enjoyment this part is convenient and colorful
Puzzled.Therefore, anti-counterfeiting technology in recent years is increasingly paid close attention to by people.Current anti-counterfeiting technology is mainly reflected in printing
The aspects such as packaging, chemical ink, material and computer network, and it has been widely used in every field.So that consumer
And the interests of businessman do not suffer damage, having, exclusivity is strong, the chemical material of good concealment is applied to anti-counterfeit field, constantly grinds
Study carefully and develop various anti-counterfeiting technology novel, efficient, it has also become the development trend of world's anti-counterfeiting technology.
With carrying out in a deep going way of market economy, trade mark, mark and packages printing are while pursuing high-grade fineness, also more next
More focusing on security, i.e. with anti-fake effect, the especially commodity such as tobacco and wine, diet, skin care item, medical supplies trend towards more
Use optical anti-counterfeiting.Optical anti-counterfeiting material not only usage is easy, with low cost, hiding is good, and typically also has bright-coloured
The features such as simple, the stronger reappearance of various color, inspection technique.But the anti-counterfeiting mark material in existing salt packaging bag
The processing preparation of material more bothers, and color changeable effect is inconspicuous, and relatively costly.
Content of the invention
For above-mentioned technical problem, the present invention provides a kind of color changeable effect preferable and wearability preferable salt anti-counterfeiting mark
The preparation technology of material.
The technical solution used in the present invention is：The preparation technology of a kind of salt anti-counterfeiting mark material, it comprises the following steps：
（1）Polyamide resin powders, isopropanol, dimethylbenzene and butanol mix and blend are heated into polyamide resin lipoprotein solution；
（2）Add fulgide powder in above-mentioned polyamide solution, and stir；
（3）It is subsequently adding dispersant and antioxidant；
（4）Stir after grinding again, obtain salt anti-counterfeiting mark finished material.
As preferably, in described polyamide resin lipoprotein solution, mass content is：20 30% polyamides, 30 35% isopropyls
Alcohol, 15 20% dimethylbenzene and 20 30% butanol.
As preferably, step（1）In heating-up temperature be 70 90 DEG C.
As preferably, step（2）Middle polyamide resin lipoprotein solution with the mass ratio of fulgide is（5-10）：1.
As preferably, described fulgide powder diameter is 200 400 mesh.
As preferably, described dispersant accounts for the 1 3% of polyamide resin lipoprotein solution and fulgide gross mass, and antioxidant accounts for
Polyamide resin lipoprotein solution and the 1 3% of fulgide gross mass.
As preferably, grinding and using rod pin-type sand mill, the finished product grain size after grinding is 30 60nm.
As can be known from the above technical solutions, the present invention uses polyamide resin lipoprotein solution and fulgide is that light-induced variable prepared by raw material
The salt anti-counterfeiting mark material of look, it not only has good printing adaptability, can be combined with salt packaging bag preferably, Er Qiebian
Chromatic effect is obvious, and anti-wear performance is preferable.
Detailed description of the invention
The present invention is described more detail below, and illustrative examples and explanation in this present invention are used for explaining the present invention,
But it is not as a limitation of the invention.
The preparation technology of a kind of salt anti-counterfeiting mark material, it comprises the following steps：
First polyamide resin powders, isopropanol, dimethylbenzene and butanol mix and blend are heated into polyamide resin lipoprotein solution；Its
In, in polyamide resin lipoprotein solution, mass content is：20 30% polyamides, 30 35% isopropanols, 15 20% dimethylbenzene and
20 30% butanol；This polyamide is tough and tensile, flexibility good, adhesion is strong, wear-resisting, and oil resistant is water-fast, antienzyme bacterium；During heating,
Heating-up temperature is advisable with 70 90 DEG C, and component can be made to be sufficiently mixed, and keeps internal temperature uniform, and prevents hot-spot from consolidating
Change.
Then in above-mentioned polyamide solution, add fulgide powder, and stir；Fulgide is photic
Off-color material, after being irradiated by light, color changes, and after removing light, can return to original state, thus realizes false proof
Purpose；Fulgide powder diameter is advisable with 200 400 mesh, and it can be made preferably to be dispersed in binder polyamide resin liposoluble
In liquid, and polyamide resin lipoprotein solution with the mass ratio of fulgide is（5-10）：1, finished product can be made to reach better performance.
Being subsequently adding dispersant and antioxidant, dispersant accounts for the 1 of polyamide resin lipoprotein solution and fulgide gross mass
3%, antioxidant accounts for the 1 3% of polyamide resin lipoprotein solution and fulgide gross mass, thus ensures the preparation quality of finished product；?
Rear employing rod pin-type sand mill grinds, and makes finished product grain size reach 30 60nm, it is thus achieved that salt anti-counterfeiting mark nano material.
Embodiment 1
First mass fraction is pressed by 30% polyamide resin powders, 30% isopropanol, 20% dimethylbenzene and 20% butanol mix and blend, and
It is heated into polyamide resin lipoprotein solution with 90 DEG C；Then in above-mentioned polyamide solution, add the fulgide powder of 400 mesh,
And polyamide resin lipoprotein solution is 10 with the mass ratio of fulgide：1；It is subsequently adding that to account for polyamide resin lipoprotein solution total with fulgide
3% dispersant of quality and 1% antioxidant, finally use rod pin-type sand mill to grind, make finished product grain size reach 60nm, it is thus achieved that to receive
Rice material, prints to salt packaging bag this material as anti-counterfeiting mark, and this anti-counterfeiting mark is at 20 °--under 85 ° of lighting angles
Variable color is obvious, and the glossiness of anti-counterfeiting mark reaches 60, abrasion index about 0.43.
Embodiment 2
First mass fraction is pressed by 20% polyamide resin powders, 35% isopropanol, 15% dimethylbenzene and 30% butanol mix and blend, and
It is heated into polyamide resin lipoprotein solution with 70 DEG C；Then in above-mentioned polyamide solution, add the fulgide powder of 200 mesh,
And polyamide resin lipoprotein solution is 5 with the mass ratio of fulgide：1；It is subsequently adding that to account for polyamide resin lipoprotein solution total with fulgide
1% dispersant of quality and 2% antioxidant, finally use rod pin-type sand mill to grind, make finished product grain size reach 30nm, it is thus achieved that to receive
Rice material, prints to salt packaging bag this material as anti-counterfeiting mark, and this anti-counterfeiting mark is at 20 °--under 85 ° of lighting angles
Variable color is obvious, and the glossiness of anti-counterfeiting mark reaches 56, abrasion index about 0.48.
Embodiment 3
First mass fraction is pressed by 26% polyamide resin powders, 33% isopropanol, 17% dimethylbenzene and 24% butanol mix and blend, and
It is heated into polyamide resin lipoprotein solution with 80 DEG C；Then in above-mentioned polyamide solution, add the fulgide powder of 300 mesh,
And polyamide resin lipoprotein solution is 8 with the mass ratio of fulgide：1；It is subsequently adding that to account for polyamide resin lipoprotein solution total with fulgide
2% dispersant of quality and 3% antioxidant, finally use rod pin-type sand mill to grind, make finished product grain size reach 40nm, it is thus achieved that to receive
Rice material, prints to salt packaging bag this material as anti-counterfeiting mark, and this anti-counterfeiting mark is at 20 °--under 85 ° of lighting angles
Variable color is obvious, and the glossiness of anti-counterfeiting mark reaches 63, abrasion index about 0.41.
The technical scheme being provided the embodiment of the present invention above is described in detail, specific case used herein
Being set forth the principle and embodiment of the embodiment of the present invention, the explanation of above example is only applicable to help to understand this
The principle of inventive embodiments；Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, in specific embodiment party
All will change in formula and range of application, in sum, this specification content should not be construed as limitation of the present invention.
Claims (7)
1. a preparation technology for salt anti-counterfeiting mark material, it comprises the following steps：
（1）Polyamide resin powders, isopropanol, dimethylbenzene and butanol mix and blend are heated into polyamide resin lipoprotein solution；
（2）Add fulgide powder in above-mentioned polyamide solution, and stir；
（3）It is subsequently adding dispersant and antioxidant；
（4）Stir after grinding again, obtain salt anti-counterfeiting mark finished material.
2. the preparation technology of salt anti-counterfeiting mark material according to claim 1, it is characterised in that：Described polyamide resin liposoluble
In liquid, mass content is：20 30% polyamides, 30 35% isopropanols, 15 20% dimethylbenzene and 20 30% butanol.
3. the preparation technology of salt anti-counterfeiting mark material as claimed in claim 2, it is characterised in that：Step（1）In heating temperature
Degree is 70 90 DEG C.
4. the preparation technology of salt anti-counterfeiting mark material as claimed in claim 1, it is characterised in that：Step（2）Middle polyamide resin
Lipoprotein solution with the mass ratio of fulgide is（5-10）：1.
5. the preparation technology of salt anti-counterfeiting mark material as claimed in claim 4, it is characterised in that：Described fulgide powder grain
Footpath is 200 400 mesh.
6. the preparation technology of salt anti-counterfeiting mark material as claimed in claim 1, it is characterised in that：Described dispersant accounts for polyamide
Resin solution and the 1 3% of fulgide gross mass, antioxidant accounts for the 1 of polyamide resin lipoprotein solution and fulgide gross mass
3%.
7. the preparation technology of salt anti-counterfeiting mark material as claimed in claim 1, it is characterised in that：Grind and use rod pin sand milling
Machine, the finished product grain size after grinding is 30 60nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610863166.5A CN106433313A (en) | 2016-09-29 | 2016-09-29 | Preparation technology of salt anti-counterfeiting mark material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610863166.5A CN106433313A (en) | 2016-09-29 | 2016-09-29 | Preparation technology of salt anti-counterfeiting mark material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106433313A true CN106433313A (en) | 2017-02-22 |
Family
ID=58170945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610863166.5A Pending CN106433313A (en) | 2016-09-29 | 2016-09-29 | Preparation technology of salt anti-counterfeiting mark material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106433313A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113232181A (en) * | 2021-03-26 | 2021-08-10 | 殷开情 | Laminated raw material premixing method for salt packaging bag anti-counterfeiting mark material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1180708A (en) * | 1997-11-12 | 1998-05-06 | 南开大学戈德防伪技术公司 | Photochemistry gene recognition material and its preparing method and use |
| CN1375528A (en) * | 2001-03-19 | 2002-10-23 | 樊官保 | Photochromic ink compound and its application |
| CN102382453A (en) * | 2011-09-28 | 2012-03-21 | 深圳市科聚新材料有限公司 | Antistatic nylon material and preparation method thereof |
| US20130305947A1 (en) * | 2012-05-17 | 2013-11-21 | Xerox Corporation | Photochromic security enabled ink for digital offset printing applications |
| CN104610811A (en) * | 2014-12-24 | 2015-05-13 | 中钞油墨有限公司 | Anti-counterfeit ink composition for judicial expertise and application of anti-counterfeit ink composition |
-
2016
- 2016-09-29 CN CN201610863166.5A patent/CN106433313A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1180708A (en) * | 1997-11-12 | 1998-05-06 | 南开大学戈德防伪技术公司 | Photochemistry gene recognition material and its preparing method and use |
| CN1375528A (en) * | 2001-03-19 | 2002-10-23 | 樊官保 | Photochromic ink compound and its application |
| CN102382453A (en) * | 2011-09-28 | 2012-03-21 | 深圳市科聚新材料有限公司 | Antistatic nylon material and preparation method thereof |
| US20130305947A1 (en) * | 2012-05-17 | 2013-11-21 | Xerox Corporation | Photochromic security enabled ink for digital offset printing applications |
| CN104610811A (en) * | 2014-12-24 | 2015-05-13 | 中钞油墨有限公司 | Anti-counterfeit ink composition for judicial expertise and application of anti-counterfeit ink composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113232181A (en) * | 2021-03-26 | 2021-08-10 | 殷开情 | Laminated raw material premixing method for salt packaging bag anti-counterfeiting mark material |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170222 |
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| RJ01 | Rejection of invention patent application after publication |