CN106424722A - Metal product manufacturing method - Google Patents
Metal product manufacturing method Download PDFInfo
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- CN106424722A CN106424722A CN201610575557.7A CN201610575557A CN106424722A CN 106424722 A CN106424722 A CN 106424722A CN 201610575557 A CN201610575557 A CN 201610575557A CN 106424722 A CN106424722 A CN 106424722A
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 83
- 239000002184 metal Substances 0.000 title claims abstract description 83
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 135
- 239000000463 material Substances 0.000 claims abstract description 116
- 238000005245 sintering Methods 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims description 45
- 238000011960 computer-aided design Methods 0.000 claims description 9
- 238000010586 diagram Methods 0.000 claims description 4
- 238000003723 Smelting Methods 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 92
- 239000011248 coating agent Substances 0.000 abstract description 91
- 230000008018 melting Effects 0.000 abstract description 19
- 238000002844 melting Methods 0.000 abstract description 19
- 238000003475 lamination Methods 0.000 description 24
- 239000012530 fluid Substances 0.000 description 17
- 238000005260 corrosion Methods 0.000 description 14
- 230000007797 corrosion Effects 0.000 description 14
- 238000000465 moulding Methods 0.000 description 12
- 239000010410 layer Substances 0.000 description 10
- 238000003466 welding Methods 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000012535 impurity Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 238000010276 construction Methods 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 229910000990 Ni alloy Inorganic materials 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 229910001039 duplex stainless steel Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 238000007751 thermal spraying Methods 0.000 description 3
- 229910001182 Mo alloy Inorganic materials 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002345 surface coating layer Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/36—Process control of energy beam parameters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/50—Means for feeding of material, e.g. heads
- B22F12/55—Two or more means for feeding material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Powder Metallurgy (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
本发明涉及金属制品制造方法。本发明的课题在于与形状的复杂性无关地、容易地制造由金属基材和表面涂覆材料构成的金属制品。本发明的金属制品制造方法中,关于金属制品,通过基于包含成为主体的金属基材和覆盖其表面的表面涂覆材料的各自的三维位置信息的三维CAD数据,作成层叠方向的每层的剖面图数据后,对每层基于剖面图数据,在造型台上配置金属基材粉末6和表面涂覆材料粉末7,利用激光熔化、烧结而进行固化。
The present invention relates to a method of manufacturing metal articles. The object of the present invention is to easily manufacture a metal product composed of a metal base material and a surface coating material regardless of the complexity of the shape. In the metal product manufacturing method of the present invention, with respect to the metal product, the cross-section of each layer in the stacking direction is prepared based on three-dimensional CAD data including the respective three-dimensional position information of the metal base material as the main body and the surface coating material covering the surface After the drawing data, based on the cross-sectional drawing data for each layer, the metal base material powder 6 and the surface coating material powder 7 are placed on the modeling table, and solidified by laser melting and sintering.
Description
技术领域technical field
本发明涉及制造由金属基材和表面涂覆材料(以下也称为“表面涂层”。)构成的金属制品的方法。The present invention relates to a method of manufacturing a metal product composed of a metal substrate and a surface coating material (hereinafter also referred to as "surface coating").
背景技术Background technique
目前为止,制造金属制品的情况下,有时在采用金属基材的成型体的表面被覆表面涂层。以下,作为金属制品,以使用叶轮(impeller)抽吸液体的流体(以下简称为“流体”)并排出的离心泵为例进行说明。Conventionally, when producing metal products, a surface coating layer was sometimes applied to the surface of a molded body using a metal base material. Hereinafter, as a metal product, a centrifugal pump that sucks and discharges liquid fluid (hereinafter simply referred to as "fluid") using an impeller will be described as an example.
就离心泵而言,根据用途多要求耐腐蚀性、耐磨损性等。例如,流体包含盐分、化学物质的情况下(海水、工业水等),对于离心泵要求耐腐蚀性。如果耐腐蚀性低,例如,有时在叶轮表面发生化学腐蚀(侵蚀)。Centrifugal pumps are often required to have corrosion resistance, wear resistance, etc. depending on the application. For example, when the fluid contains salt or chemical substances (sea water, industrial water, etc.), corrosion resistance is required for the centrifugal pump. If the corrosion resistance is low, for example, chemical corrosion (erosion) sometimes occurs on the surface of the impeller.
另外,流体包含泥砂等固体物的情况下(河流水等),对于离心泵要求耐磨损性。如果耐磨损性低,例如,有时在叶轮表面发生泥砂等固体物引起的磨损(泥浆冲蚀)。In addition, when the fluid contains solid matter such as mud and sand (river water, etc.), abrasion resistance is required for the centrifugal pump. If the wear resistance is low, for example, wear by solid matter such as mud and sand (slurry erosion) may occur on the surface of the impeller.
此外,与流体的种类无关,例如,有时在叶轮表面发生气蚀。气蚀是在流体中局部地与饱和蒸汽压相比成为了低压力的部分产生气穴(气泡),该气穴破裂消灭时的冲击力引起的损伤。Also, irrespective of the type of fluid, for example, cavitation may occur on the surface of the impeller. Cavitation is damage caused by the impact force when cavitation (bubbles) are locally generated in a part of the fluid where the pressure is lower than the saturated vapor pressure, and the cavitation is broken and eliminated.
例如,在离心泵的叶轮中多使用耐腐蚀性优异、可以以低价格获得的奥氏体系不锈钢。进而,作为提高耐腐蚀性的材料,也使用了双相不锈钢、镍基合金等。但是,由于只通过叶轮的材质难以提高耐腐蚀性和耐磨损性这两者,因此为了提高这两者,例如,有时在不锈钢的叶轮的表面被覆硬质的表面涂层。For example, austenitic stainless steel, which has excellent corrosion resistance and is available at low cost, is often used for impellers of centrifugal pumps. Furthermore, as materials for improving corrosion resistance, duplex stainless steel, nickel-based alloys, and the like are also used. However, since it is difficult to improve both corrosion resistance and wear resistance only by the material of the impeller, in order to improve both, for example, the surface of a stainless steel impeller may be coated with a hard surface coating.
另外,在离心泵中,除了叶轮的表面以外,为了提高耐磨损性等,也存在被覆表面涂层的部位。例如,在离心泵中,在旋转的叶轮、旋转轴与固定侧的壳体之间存在防止流体泄漏的密封部。该密封部为了尽可能减少流体泄漏,将旋转侧构件与固定侧构件的间隔设计得小。因此,在密封部中存在旋转侧构件与固定侧构件滑动的可能性。如果滑动的旋转侧构件、固定侧构件这两者为相同的表面材质,则存在咬住的可能性。另外,关于这样的滑动的部分,由于内部的流体的腐蚀性、泥砂等的状况,有可能滑动引起的磨损进一步发展,为了提高耐腐蚀性、耐磨损性等,也多在旋转侧构件与固定侧构件的一者的表面被覆表面涂层。In addition, in the centrifugal pump, in addition to the surface of the impeller, there are also portions that are coated with a surface coating for the purpose of improving wear resistance and the like. For example, in a centrifugal pump, there is a seal portion that prevents fluid leakage between the rotating impeller, the rotating shaft, and the housing on the fixed side. In order to reduce fluid leakage as much as possible in this seal portion, the interval between the rotating side member and the fixed side member is designed to be small. Therefore, there is a possibility that the rotation-side member and the fixed-side member slide in the seal portion. If both the sliding rotary side member and the fixed side member have the same surface material, there is a possibility of seizure. In addition, for such a sliding part, due to the corrosiveness of the internal fluid, the condition of mud and sand, etc., the wear caused by sliding may further develop. The surface of one of the fixed side members is covered with a surface coating.
与其相关联,例如,专利文献1中,在“用于解决课题的手段”中记载了“本发明的特征在于,作为要求耐磨损性、耐气蚀性等的部件的被覆构件,具备在由不锈钢构成的泵部件的母材的表面被覆了含有Cr、Mo、含有Si、B中的至少一种、余量由Ni和不可避免的杂质构成的Ni-Cr-Mo系合金、或者、余量由Co和不可避免的杂质构成的Co-Cr-Mo系合金的第1被膜,和被覆了含有Cr、Mo、Ni、Fe、Si、C、余量由Co和不可避免的杂质构成的Co基合金构成的硬质材料的第2被膜。”(参照)。即,在该技术中,通过对于叶轮表面、轴套形成这样的被膜,从而使耐磨损性、耐气蚀性提高。In connection with this, for example, in Patent Document 1, it is described in "Means for Solving the Problem" that "the present invention is characterized in that, as a covering member of a component requiring wear resistance, cavitation resistance, etc., The surface of the base material of the pump part made of stainless steel is coated with a Ni-Cr-Mo alloy containing at least one of Cr, Mo, Si, and B, and the balance consisting of Ni and unavoidable impurities, or, the remainder The first film of Co-Cr-Mo alloy composed of Co and unavoidable impurities, and Co containing Cr, Mo, Ni, Fe, Si, C, and the balance consisting of Co and unavoidable impurities. The second coating of a hard material composed of a base alloy." (Reference). That is, in this technique, wear resistance and cavitation resistance are improved by forming such a film on the surface of the impeller and the bushing.
另外,例如专利文献2中,权利要求1中记载了“在具备泵壳体和叶轮、在该泵壳体和该叶轮入口之间具备密封部的离心式泵中,在上述密封部中的上述叶轮侧的构件与上述泵壳体侧的构件的任一个的对置面,采用喷镀法或焊接法将比对方面材质软质的包含Cr、Mo的Ni合金堆焊为规定厚度,使与相对面的硬度差为HB(布氏硬度)=50以上,上述叶轮侧的构件与上述泵壳体侧的构件由相同材料的双相系不锈钢形成,上述堆焊了Ni合金的构件由PREN值为40以上的双相系不锈钢构成,上述Ni合金为Cr+Mo≥30%的Ni合金”。即,该技术中,通过在相当于叶轮密封部的叶轮口环或壳体密封环通过喷镀或焊接来堆焊高耐腐蚀性Ni合金,从而提高了耐腐蚀性。In addition, for example, in Patent Document 2, claim 1 states "In a centrifugal pump having a pump housing and an impeller, and a sealing portion between the pump housing and the impeller inlet, the sealing portion in the sealing portion The opposing surface of the member on the impeller side and any one of the above-mentioned members on the pump housing side is surfacing welded to a predetermined thickness with a Ni alloy containing Cr and Mo that is softer than the material of the opposing surface by spraying or welding, so that it is consistent with The hardness difference between the facing surfaces is HB (Brinell hardness) = 50 or more, the member on the impeller side and the member on the pump housing side are made of duplex stainless steel made of the same material, and the member on which the Ni alloy is overlaid is determined by PREN value It is composed of duplex stainless steel with 40 or more, and the above-mentioned Ni alloy is a Ni alloy with Cr+Mo≥30%. That is, in this technique, corrosion resistance is improved by overlaying a highly corrosion-resistant Ni alloy on the impeller lip ring or casing seal ring corresponding to the impeller seal portion by spraying or welding.
另外,特别是对于封闭式叶轮(带有侧板的叶轮),例如专利文献3中在“摘要”中记载了“硬质涂层在它们各自的中点具有最小低压涂层厚度和最小高压涂层厚度。最小低压涂层厚度以及最小高压涂层厚度分别为出口远位端的最大出口涂层厚度的、或者入口远位端的最大入口涂层厚度的任一个的约0.085~约0.8倍的范围。”。即,该技术中,根据封闭式叶轮的叶片的位置,考虑包覆(被覆)施工的容易性,调节了用于耐腐蚀性等的涂层的厚度。In addition, especially for closed impellers (impellers with side plates), for example, in Patent Document 3, it is described in the "Abstract" that "hard coatings have a minimum low-pressure coating thickness and a minimum high-pressure coating thickness at their respective midpoints. Layer Thickness. The minimum low pressure coating thickness and the minimum high pressure coating thickness are in the range of about 0.085 to about 0.8 times either the maximum outlet coating thickness at the outlet distal end or the maximum inlet coating thickness at the inlet distal end, respectively. ". That is, in this technique, the thickness of the coating layer for corrosion resistance and the like is adjusted in consideration of the ease of coating (coating) construction according to the position of the blades of the hermetic impeller.
另一方面,有关对于使用采用3D(Dimensions)打印机、快速成型的三维层叠造型技术用树脂材料制造的叶轮的被覆技术,例如专利文献4中,在权利要求1中记载了“叶轮的制造方法,其特征在于,具有:采用迅速模型制造方法形成预先设计的形状的非金属制的基材的工序,和在上述基材的表面被覆表面金属层的工序”。即,该技术中,在采用迅速模型制造方法(三维层叠造型技术)制造的非金属树脂的叶轮的表面被覆金属层。On the other hand, regarding the coating technology for impellers made of resin materials using 3D (Dimensions) printers and rapid prototyping three-dimensional layered modeling technology, for example, in Patent Document 4, it is described in claim 1 that "the manufacturing method of the impeller, It is characterized in that it has: a step of forming a non-metallic base material of a pre-designed shape by a rapid prototyping method, and a step of coating the surface of the base material with a surface metal layer". That is, in this technique, a metal layer is coated on the surface of a non-metallic resin impeller manufactured by a rapid prototyping method (three-dimensional lamination technique).
如果使用三维层叠造型技术,即使复杂构造的制品也能够容易地制造。在此,例如,就离心泵中的叶轮而言,由于存在使流体升压时的负荷、通过旋转施加的离心力,因此,如果是树脂材料则多是强度不足。因此,对于叶轮,希望使用能够应用金属材料的三维层叠造型技术。If a three-dimensional layered molding technique is used, even a product with a complex structure can be easily manufactured. Here, for example, the impeller in a centrifugal pump often has insufficient strength if it is made of a resin material because there is a load when the fluid is pressurized and a centrifugal force is applied by rotation. Therefore, for the impeller, it is desirable to use a three-dimensional layered modeling technology that can apply metallic materials.
在能够应用金属材料的三维层叠造型技术中,有粉末供给法、粉末烧结层叠法。例如,专利文献4中记载的粉末供给法是边利用激光使粉末材料熔融边进行造型的手法。该粉末供给法中,由于凝固前的熔融材料有可能因自重而变形,因此可造型的形状存在限制。另一方面,如专利文献5中记载的那样,在粉末烧结层叠法中,在每一层铺设原料粉末,用激光使规定部分熔化、烧结。该粉末烧结层叠法中,由于用激光烧结的部分用位于其下部的粉末支承,因此在可造型的形状上限制少,可以对复杂的形状进行造型。Among the three-dimensional layered modeling techniques that can be applied to metal materials, there are powder supply method and powder sintered layering method. For example, the powder supply method described in Patent Document 4 is a method of performing molding while melting a powder material with a laser. In this powder supply method, since the molten material before solidification may deform due to its own weight, there is a limit to the shape that can be molded. On the other hand, as described in Patent Document 5, in the powder sintering lamination method, raw material powder is laid on each layer, and a predetermined portion is melted and sintered with a laser. In this powder sintering lamination method, since the part to be sintered by laser is supported by the powder located below it, there are few restrictions on the shapes that can be molded, and complex shapes can be molded.
现有技术文献prior art literature
专利文献patent documents
专利文献1:日本专利第3886394号Patent Document 1: Japanese Patent No. 3886394
专利文献2:日本专利第5096762号Patent Document 2: Japanese Patent No. 5096762
专利文献3:日本特开2014-1726号公报Patent Document 3: Japanese Patent Laid-Open No. 2014-1726
专利文献4:日本特开平11-82377号公报Patent Document 4: Japanese Patent Application Laid-Open No. 11-82377
专利文献5:日本特开2004-124200号公报Patent Document 5: Japanese Patent Laid-Open No. 2004-124200
发明内容Contents of the invention
发明要解决的课题The problem to be solved by the invention
但是,即使在使用粉末烧结层叠法对金属制品进行造型的情况下,在需要表面涂层的情形下必须另外进行被覆作业,存在作业烦杂的问题。进而,在金属制品的形状复杂的情况下,不仅表面涂层的被覆作业烦杂,而且对于喷镀、包覆焊接由于施工上的制约,有时表面涂层的被覆作业困难或者不可进行。However, even in the case of molding a metal product using the powder sintering lamination method, if a surface coating is required, a coating operation must be performed separately, and there is a problem that the operation is complicated. Furthermore, when the shape of the metal product is complex, not only the work of applying the surface coating is complicated, but also the work of applying the surface coating may be difficult or impossible due to constraints on the construction of spray plating and cladding welding.
例如,对于封闭式叶轮,由于在叶片的外侧存在侧板,因此叶片面的周围的空间狭窄,采用喷镀机、焊接机的作业不容易。另外,也有时使用能够插入狭窄的空间的喷镀机、焊接机,但是,也有时由于喷镀、焊接的方向而不能使表面涂覆材料充分地熔敷。另外,也有根据施工的困难性和品质,对叶片的每部分选择地进行电弧喷镀、火焰喷镀、HVOF(HighVelocity Oxygen Fuel)喷镀的方法。但是,如果因部位不同而改变施工方法,也要考虑到施工成本增大的同时施工部位的边界处的可靠性降低。For example, with a closed impeller, since side plates exist outside the blades, the space around the blade surface is narrow, making it difficult to work with a spraying machine or a welding machine. In addition, a thermal spraying machine and a welding machine that can be inserted into a narrow space may be used, but the surface coating material may not be sufficiently deposited depending on the direction of thermal spraying or welding. In addition, there is also a method of selectively performing arc spraying, flame spraying, and HVOF (High Velocity Oxygen Fuel) spraying on each part of the blade according to the difficulty and quality of construction. However, if the construction method is changed depending on the location, it is also considered that the reliability at the boundary of the construction location decreases while the construction cost increases.
因此,本发明的课题在于与形状的复杂性无关地容易地制造由金属基材和表面涂覆材料构成的金属制品。Therefore, an object of the present invention is to easily manufacture a metal product composed of a metal base material and a surface coating material regardless of the complexity of the shape.
用于解决课题的手段means to solve the problem
为了解决上述课题,本发明为金属制品制造方法,是使用金属基材粉末和表面涂覆材料粉末利用粉末烧结层叠法制造由金属基材和表面涂覆材料构成的金属制品的金属制品制造方法,其特征在于,进行了基于关于上述金属制品的三维CAD(计算机辅助设计)数据作成层叠方向的每层的剖面图数据的步骤后,对上述每层基于上述剖面图数据反复进行下述步骤:在造型台上在上述金属基材的位置配置上述金属基材粉末,在其以外的位置配置上述表面涂覆材料粉末的步骤;和通过利用激光将上述配置的金属基材粉末和位于上述剖面图数据中的上述表面涂覆材料的位置的上述表面涂覆材料粉末熔化、烧结而进行固化的步骤。In order to solve the above-mentioned problems, the present invention is a metal product manufacturing method, which is a metal product manufacturing method for manufacturing a metal product composed of a metal base material and a surface coating material by a powder sintering lamination method using a metal base material powder and a surface coating material powder, It is characterized in that, after performing the step of creating cross-sectional view data for each layer in the stacking direction based on three-dimensional CAD (computer-aided design) data about the metal product, the following steps are repeated based on the cross-sectional view data for each layer: arranging the above-mentioned metal base powder on the position of the above-mentioned metal base material on the modeling table, and arranging the above-mentioned surface coating material powder at other positions; A step of melting and sintering the powder of the above-mentioned surface-coating material at the position of the above-mentioned surface-coating material to solidify.
对于其他手段将后述。Other means will be described later.
发明的效果The effect of the invention
根据本发明,能够与形状的复杂性无关地容易地制造由金属基材和表面涂覆材料构成的金属制品。According to the present invention, a metal product composed of a metal base material and a surface coating material can be easily manufactured regardless of the complexity of the shape.
附图说明Description of drawings
图1为用于说明粉末烧结层叠法的示意图。FIG. 1 is a schematic diagram for explaining the powder sintering lamination method.
图2为表示采用本实施方式中的粉末烧结层叠法的金属制品制造方法的处理流程的流程图。FIG. 2 is a flowchart showing a process flow of a metal product manufacturing method using the powder sintering lamination method in this embodiment.
图3为表示封闭式叶轮的构造例的立体图。Fig. 3 is a perspective view showing a structural example of a closed impeller.
图4(a)为封闭式叶轮的侧面图。(b)为(a)的A-A向视剖面图。(c)为(a)的B-B向视剖面图。Figure 4(a) is a side view of the closed impeller. (b) is the A-A sectional view of (a). (c) is the B-B arrow sectional view of (a).
图5(a)为表示为了采用粉末烧结层叠法制造封闭式叶轮而将金属基材粉末和表面涂覆材料粉末配置在造型台上的状态的图。(b)为表示(a)的状态下进行了激光烧结后的状态的图。Fig. 5(a) is a view showing a state in which metal base material powder and surface coating material powder are arranged on a molding table for manufacturing a hermetic impeller by the powder sintering lamination method. (b) is a figure which shows the state after performing laser sintering in the state of (a).
图6为表示横轴多段泵的构造例的剖面图。Fig. 6 is a sectional view showing a structural example of a horizontal axis multi-stage pump.
图7(a)为图6的区域C的放大图。(b)为(a)的区域D的放大图。FIG. 7( a ) is an enlarged view of area C in FIG. 6 . (b) is an enlarged view of the region D of (a).
图8为表示立轴泵的构造例的剖面图。Fig. 8 is a cross-sectional view showing a structural example of a vertical shaft pump.
图9为图8的区域E的放大图。FIG. 9 is an enlarged view of area E of FIG. 8 .
图10为表示为了采用粉末烧结层叠法制造封闭式叶轮而将金属基材粉末和表面涂覆材料粉末和高熔点粉末配置在造型台上的状态的图。Fig. 10 is a view showing a state in which metal base powder, surface coating material powder, and high melting point powder are arranged on a molding table for manufacturing a closed impeller by the powder sintering lamination method.
附图标记的说明Explanation of reference signs
1 叶片1 blade
2 芯板2 core board
3 侧板3 side panels
4 轴孔4 shaft holes
6 金属基材粉末6 Metal base powder
6a 金属基材6a Metal Substrates
7 表面涂覆材料粉末7 Surface coating material powder
7a 表面涂覆材料7a Surface coating materials
8 高熔点粉末8 high melting point powder
10 横轴多段泵10 horizontal axis multi-stage pump
11 壳体11 housing
12 吸入口12 Suction port
13 旋转轴13 axis of rotation
14 叶轮14 impeller
17 排出口17 outlet
20a、20b 轴封装置20a, 20b shaft seal device
21 轴承21 bearings
31 叶轮口环31 Impeller mouth ring
32 壳体密封环32 Housing sealing ring
33 表面涂层33 surface coating
41 轴承壳体41 Bearing housing
43 轴承垫材43 Bearing pads
44 轴套44 bushing
45 轴套45 bushing
46 表面涂层46 surface coating
50 封闭式叶轮50 enclosed impeller
60 立轴泵60 vertical shaft pump
101 造型台101 modeling table
102 喷嘴102 nozzles
103 喷嘴103 Nozzles
104 激光装置104 laser device
105 控制装置105 Controls
具体实施方式detailed description
以下参照附图对本发明的实施方式进行说明。首先,参照图1、图2对采用本实施方式中的粉末烧结层叠法的金属制品制造方法的概要进行说明。在此,使用金属基材粉末和表面涂覆材料粉末,通过作为三维层叠造型技术的一种的粉末烧结层叠法制造由金属基材和表面涂覆材料构成的金属制品。图1为用于说明粉末烧结层叠法的示意图,作为主要的构成,具备造型台101、用于配置粉末的喷嘴102、103、用于将粉末熔化、烧结的激光装置104、控制制造的控制装置105。另外,图2为表示采用本实施方式中的粉末烧结层叠法的金属制品制造方法的处理流程的流程图。Embodiments of the present invention will be described below with reference to the drawings. First, the outline of a metal product manufacturing method using the powder sintering lamination method in this embodiment will be described with reference to FIGS. 1 and 2 . Here, a metal product composed of a metal base material and a surface coating material is produced by using a metal base material powder and a surface coating material powder by a powder sintering lamination method, which is one type of three-dimensional lamination modeling technology. Fig. 1 is a schematic diagram for explaining the powder sintering lamination method. As the main components, it includes a molding table 101, nozzles 102 and 103 for arranging powder, a laser device 104 for melting and sintering the powder, and a control device for controlling manufacturing. 105. In addition, FIG. 2 is a flow chart showing the processing flow of the metal product manufacturing method using the powder sintering lamination method in this embodiment.
首先,控制装置105输入预先作成的、有关金属制品的三维CAD(Computer AidedDesign)数据(步骤S1)。金属制品为例如叶轮的情况下,三维CAD数据包含成为叶轮主体的金属基材和覆盖其表面的表面涂覆材料的各自的三维位置信息。First, the control device 105 inputs three-dimensional CAD (Computer Aided Design) data on metal products created in advance (step S1). When the metal product is, for example, an impeller, the three-dimensional CAD data includes respective three-dimensional positional information of the metal base material serving as the main body of the impeller and the surface coating material covering the surface.
接下来,控制装置105基于三维CAD数据作成层叠方向的每层的剖面图数据(步骤S2)。Next, the control device 105 creates cross-sectional view data for each layer in the stacking direction based on the three-dimensional CAD data (step S2).
接下来,控制装置105对每层反复进行步骤S4~S6的处理(步骤S3~S7)。Next, the control device 105 repeats the processing of steps S4 to S6 for each layer (steps S3 to S7).
控制装置105基于剖面图数据在造型台101(以下也有时没有符号,称为“造型台”)上按1层的量在金属基材的位置使用喷嘴102配置金属基材粉末,在其以外的位置使用喷嘴103配置表面涂覆材料粉末(步骤S4)。The control device 105 arranges the metal base material powder at the position of the metal base material by using the nozzle 102 in the amount of one layer on the build table 101 (hereinafter sometimes referred to as "build table" without a symbol) based on the cross-sectional view data, and the other The surface coating material powder is placed using the nozzle 103 (step S4).
接下来,控制装置105基于剖面图数据,通过采用激光装置104的激光照射,将金属基材的位置的金属基材粉末、位于表面涂覆材料的位置的表面涂覆材料粉末熔化、烧结,从而固化(步骤S5)。应予说明,此时,位于表面涂覆材料的位置以外的位置的表面涂覆材料粉末以粉末的状态残留,最后被回收。Next, the control device 105 melts and sinters the metal base material powder at the position of the metal base material and the surface coating material powder at the position of the surface coating material by irradiating laser light from the laser device 104 based on the cross-sectional view data, thereby Curing (step S5). It should be noted that at this time, the surface-coating material powder located at a position other than the position of the surface-coating material remains in a powder state and is finally recovered.
接下来,控制装置105使造型台101下降一层(步骤S6)。Next, the control device 105 lowers the modeling table 101 by one stage (step S6).
这样,通过对每层反复进行步骤S4~S6的处理,使用金属基材粉末和表面涂覆材料粉末,采用粉末烧结层叠法能够与形状的复杂性无关地容易地制造由金属基材和表面涂覆材料构成的金属制品。以下作为金属制品,以封闭式叶轮、壳体密封环、轴套为例,具体地进行说明。In this way, by repeating the processing of steps S4 to S6 for each layer, using the metal base material powder and the surface coating material powder, the metal base material and the surface coating material powder can be easily manufactured by using the powder sintering lamination method regardless of the complexity of the shape. Metal products made of covered materials. Hereinafter, as metal products, a closed impeller, a casing seal ring, and a shaft sleeve are taken as examples to describe in detail.
图3为表示封闭式叶轮的构造例的立体图。图4中,(a)为图3的封闭式叶轮的侧面图,(b)为(a)的A-A向视剖面图,(c)为(a)的B-B向视剖面图。Fig. 3 is a perspective view showing a structural example of a closed impeller. Among Fig. 4, (a) is the side view of the enclosed impeller of Fig. 3, (b) is the A-A arrow sectional view of (a), and (c) is the B-B arrow sectional view of (a).
如图3、图4中所示那样,封闭式叶轮50具备:5个叶片1、与插入中心轴的轴孔4成为一体的芯板2、和覆盖外周侧的侧板3。应予说明,将这样具有侧板的叶轮称为封闭式叶轮,另一方面,将不具有侧板的叶轮称为开放式叶轮。As shown in FIGS. 3 and 4 , the hermetic impeller 50 includes five blades 1 , a core plate 2 integrated with a shaft hole 4 inserted into a central shaft, and a side plate 3 covering the outer peripheral side. It should be noted that an impeller having such a side plate is called a closed impeller, while an impeller without a side plate is called an open impeller.
封闭式叶轮50中,为了提高流体的性能(高效率、宽运转范围),叶片1成为复杂的曲面。因此,采用以往的喷镀机、焊接机的表面涂层被覆作业不容易。另外,在图4(a)的A-A向视剖面图(图4(b))中没有侧板3,在图4(a)的B-B向视剖面图(图4(c))中有侧板3。另外,在A-A向视剖面图(图4(b))和B-B向视剖面图(图4(c))中叶片1自身的曲面的形状也不同。即,封闭式叶轮50在铅直方向上并不是一样的结构,因此如果采用粉末供给法制造,造型中途的金属有可能因自重而变形,因此本实施方式中采用粉末烧结层叠法制造。In the closed impeller 50, the blade 1 has a complicated curved surface in order to improve fluid performance (high efficiency, wide operating range). Therefore, it is not easy to perform surface coating work using conventional spraying machines and welding machines. In addition, there is no side plate 3 in the A-A arrow sectional view of Fig. 4 (a) (Fig. 4 (b)), and there is a side plate 3 in the B-B arrow sectional view of Fig. 4 (a) (Fig. 4 (c)). 3. In addition, the shape of the curved surface of the blade 1 itself is also different in the A-A cross-sectional view ( FIG. 4( b )) and the B-B arrow cross-sectional view ( FIG. 4( c )). That is, the closed impeller 50 is not uniform in the vertical direction, so if it is manufactured by the powder supply method, the metal in the middle of the molding may be deformed by its own weight, so it is manufactured by the powder sintering lamination method in this embodiment.
图5(a)为表示为了采用粉末烧结层叠法制造封闭式叶轮50而将金属基材粉末和表面涂覆材料粉末配置在造型台上的状态的图。在造型台上,将金属基材粉末6配置在封闭式叶轮50的叶片1、芯板2和侧板3的位置(参照图4(c)),在其以外的位置配置表面涂覆材料粉末7(图2的步骤S4)。然后,通过采用激光装置104(图1)的激光照射,将叶片1、芯板2和侧板3的位置的金属基材粉末6、和位于表面涂覆材料的位置的表面涂覆材料粉末7熔化、烧结,从而固化(图2的步骤S5)。由此,如图5(b)中所示那样,能够形成在金属基材6a的表面被覆了表面涂覆材料7a的状态。FIG. 5( a ) is a view showing a state in which metal base powder and surface coating material powder are arranged on a molding table in order to manufacture a hermetic impeller 50 by the powder sintering lamination method. On the molding table, the metal base powder 6 is arranged at the position of the blade 1, the core plate 2, and the side plate 3 of the closed impeller 50 (see FIG. 4(c)), and the surface coating material powder is arranged at other positions. 7 (step S4 of FIG. 2). Then, by laser irradiation using the laser device 104 (FIG. 1), the metal base material powder 6 at the position of the blade 1, the core plate 2, and the side plate 3, and the surface coating material powder 7 at the position of the surface coating material Melting, sintering, and solidification (step S5 in FIG. 2 ). Thereby, as shown in FIG.5(b), the surface coating material 7a can be formed in the state coated on the surface of the metal base material 6a.
这样,能够将金属基材和表面涂覆材料一体成型,制造封闭式叶轮50。而且,由于能够将金属基材和表面涂覆材料一体成型,因此具有它们之间的接合强度比焊接、熔敷的情形高的优点。另外,通常,通过焊接、喷镀被覆的表面涂层的厚度为数百μm至数mm左右,但粉末烧结层叠法的情况下,能够自由地改变表面涂层的厚度,进而还具有能够根据所要求的耐腐蚀性、耐磨损性来分布涂层厚度的优点。In this way, the metal base material and the surface coating material can be integrally molded to manufacture the hermetic impeller 50 . Furthermore, since the metal base material and the surface coating material can be integrally molded, there is an advantage that the joint strength between them is higher than welding or welding. In addition, generally, the thickness of the surface coating applied by welding and thermal spraying is about several hundred μm to several mm, but in the case of the powder sintering lamination method, the thickness of the surface coating can be freely changed, and further has The required corrosion resistance, wear resistance to distribute the advantages of coating thickness.
再有,作为金属基材粉末6,可列举出低合金钢、不锈钢、铝合金等的粉末。另外,作为表面涂覆材料粉末7,可列举出镍基合金、钴基合金、高耐腐蚀性不锈钢(双相不锈钢)等的合金、在碳化钨中混合了钴和/或镍、铬等的粘结剂的产物等。不过,这里所示的材料表示示例,并不限定于这些材料。In addition, as the metal base material powder 6, powders of low-alloy steel, stainless steel, aluminum alloy, etc. are mentioned. In addition, examples of the surface coating material powder 7 include alloys such as nickel-based alloys, cobalt-based alloys, high corrosion-resistant stainless steel (duplex stainless steel), and tungsten carbide mixed with cobalt and/or nickel, chromium, etc. Adhesive products, etc. However, the materials shown here are examples and are not limited to these materials.
接下来,参照图6、图7,对制造壳体密封环的情形进行说明。如图6中所示那样,横轴多段泵10具有5段的叶轮14。横轴多段泵10中,从吸入口12吸入流体,从排出口17将加压的流体排出。将5段的叶轮14安装于旋转轴13,旋转轴13被两端的轴承21支承。Next, referring to FIG. 6 and FIG. 7 , the state of manufacturing the case seal ring will be described. As shown in FIG. 6 , the horizontal axis multi-stage pump 10 has five-stage impellers 14 . In the horizontal axis multi-stage pump 10 , fluid is sucked in from the suction port 12 and the pressurized fluid is discharged from the discharge port 17 . Five-stage impellers 14 are attached to a rotating shaft 13 , and the rotating shaft 13 is supported by bearings 21 at both ends.
为了使来自壳体11和旋转轴13的间隙的流体泄漏为最小限度,将轴封装置20a、20b(密封部)分别安装于旋转轴13和壳体11。轴封装置20a、20b由于成为滑动部位,因此多用硬质的表面涂层被覆任一者。In order to minimize fluid leakage from the gap between the housing 11 and the rotating shaft 13 , shaft sealing devices 20 a and 20 b (seal portions) are attached to the rotating shaft 13 and the housing 11 , respectively. Since the shaft sealing devices 20a and 20b serve as sliding parts, either one is often coated with a hard surface coating.
在此,图7(a)为图6的区域C的放大图。另外,图7(b)为图7(a)的区域D的放大图。在叶轮14的入口部分,为了将叶轮14的吸入侧和排出侧密封,安装有叶轮口环31和壳体密封环32。该叶轮口环31和壳体密封环32,为了提高密封性能,如图7(b)中所示那样,有时在任一者或两者的表面设置复杂的凹凸。图7(b)中,示出了在叶轮口环31和壳体密封环32的两者的表面设置了复杂的凹凸的构造。Here, FIG. 7( a ) is an enlarged view of region C in FIG. 6 . In addition, FIG. 7( b ) is an enlarged view of a region D in FIG. 7( a ). At the inlet portion of the impeller 14 , an impeller mouth ring 31 and a casing seal ring 32 are attached to seal the suction side and the discharge side of the impeller 14 . In order to improve the sealing performance of the impeller ring 31 and the casing seal ring 32 , as shown in FIG. 7( b ), complex irregularities may be provided on the surfaces of either one or both of them. FIG. 7( b ) shows a structure in which complex unevenness is provided on both surfaces of the impeller ring 31 and the casing seal ring 32 .
对于这些叶轮口环31和壳体密封环32,由于边卷入工作流体中的泥砂边滑动,因此必须在叶轮口环31的滑动面或壳体密封环32的滑动面的一者上被覆硬质的表面涂层。在此,在壳体密封环32的滑动面被覆了表面涂层33。For these impeller mouth rings 31 and casing seal rings 32, since the mud and sand involved in the working fluid slide while sliding, it is necessary to coat the sliding surface of the impeller mouth ring 31 or the sliding surface of the casing seal ring 32 with hard coating. quality surface coating. Here, a surface coating 33 is applied to the sliding surface of the case seal ring 32 .
再有,虽然省略了图5那样的图示,但对于壳体密封环32,也与上述的封闭式叶轮50的情形同样地,能够采用粉末烧结层叠法利用金属基材粉末和表面涂覆材料粉末来制造。具体地,壳体密封环32由于为圆筒构件,因此如果是粉末烧结层叠法,则在轴方向上层叠。于是,在造型台上,将金属基材粉末配置在壳体密封环基材部分,将表面涂覆材料粉末配置在其以外的位置,用激光将金属基材粉末和其附近的表面涂覆材料粉末熔化、烧结,从而能够与表面涂层33一起容易地制造具有凹凸的壳体密封环32。In addition, although the illustration as in FIG. 5 is omitted, the casing seal ring 32 can be formed by using the metal base powder and the surface coating material by the powder sintering lamination method as in the case of the above-mentioned closed impeller 50. powder to manufacture. Specifically, since the case seal ring 32 is a cylindrical member, it is laminated in the axial direction by the powder sintering lamination method. Then, on the molding table, the metal base powder is arranged on the base part of the casing seal ring, the surface coating material powder is placed on a position other than it, and the metal base powder and the surface coating material in the vicinity are laser-coated. The powder is melted and sintered, so that the case seal ring 32 having unevenness can be easily produced together with the surface coating 33 .
接下来,参照图8、图9,对制造轴套的情形进行说明。如图8中所示那样,立轴泵60成为从图的下方吸入流体、用叶轮14升压、从图的上方向右排出的构造。在叶轮14的上部配置着支承旋转轴13的轴承21。图9为将包含该轴承21的区域E放大的图。Next, referring to FIG. 8 and FIG. 9 , the state of manufacturing the boss will be described. As shown in FIG. 8 , the vertical shaft pump 60 has a structure in which fluid is sucked in from the bottom of the figure, boosted by the impeller 14 , and discharged to the right from the top of the figure. A bearing 21 for supporting the rotating shaft 13 is disposed on the upper portion of the impeller 14 . FIG. 9 is an enlarged view of a region E including the bearing 21 .
如图9所示,对于旋转轴13,在滑动部位通过冷缩配合等固定着轴套44。在轴套44的表面被覆着硬质的表面涂层46。另一方面,轴承21具备:轴承壳体41、固定于轴承壳体41的轴套45、安装于轴套45的表面的轴承垫材43。由于轴承垫材43与表面涂层46滑动,因此在轴承垫材43中使用了滑动性良好的PTFE(聚四氟乙烯)、PEEK(聚醚醚酮)等的树脂、陶瓷材料。轴套44由于表面的表面涂层46,即使边卷入工作流体中的泥砂边与轴承垫材43滑动也不磨损。As shown in FIG. 9 , with respect to the rotating shaft 13 , a sleeve 44 is fixed to the sliding portion by shrink fitting or the like. The surface of the sleeve 44 is covered with a hard surface coating 46 . On the other hand, the bearing 21 includes a bearing housing 41 , a boss 45 fixed to the bearing housing 41 , and a bearing pad 43 attached to the surface of the boss 45 . Since the bearing pad 43 and the surface coating 46 slide, resins such as PTFE (polytetrafluoroethylene) and PEEK (polyether ether ketone) or ceramic materials having good sliding properties are used for the bearing pad 43 . The bushing 44 is not abraded by the surface coating 46 on the surface even when mud and sand involved in the working fluid slides against the bearing pad 43 .
再有,虽然省略了图5那样的图示,但对于轴套44,也与上述的封闭式叶轮50的情形同样地,能够采用粉末烧结层叠法利用金属基材粉末和表面涂覆材料粉末来制造。具体地,轴套44由于为圆筒构件,因此如果是粉末烧结层叠法,则在轴方向上层叠。于是,在造型台上,将金属基材粉末配置在轴套基材部分,将表面涂覆材料粉末配置在其以外的位置,用激光将金属基材粉末和其附近的表面涂覆材料粉末熔化、烧结,从而能够与表面涂层46一起容易地制造轴套44。In addition, although the illustration as in FIG. 5 is omitted, the sleeve 44 can be formed by using the metal base powder and the surface coating material powder by the powder sintering lamination method similarly to the case of the above-mentioned closed impeller 50. manufacture. Specifically, since the sleeve 44 is a cylindrical member, it is laminated in the axial direction by the powder sintering lamination method. Then, on the molding table, the metal base powder is arranged on the bush base part, the surface coating material powder is placed outside it, and the metal base powder and the surface coating material powder near it are melted by laser. , sintering, so that the sleeve 44 can be easily manufactured together with the surface coating 46 .
接下来,对于将图5中说明的封闭式叶轮50的制造方法进行了部分改变的实施方式进行说明。图5中说明的制造方法中,将没有熔化、烧结的表面涂覆材料粉末7大量地作为残留材料回收,但是,一般地由于该残留材料中含有杂质,因此如果不进行杂质的分离处理,则难以再利用。而且,表面涂覆材料粉末7通常价格高,因此表面涂覆材料粉末7的残留材料多,不进行杂质的分离处理而不再利用的情况下,具有制造成本升高的一面。另外,即使进行杂质的分离处理,也存在其成本高企的问题。Next, an embodiment in which the method of manufacturing the hermetic impeller 50 described in FIG. 5 is partially modified will be described. In the manufacturing method illustrated in FIG. 5 , a large amount of surface coating material powder 7 that has not been melted and sintered is recovered as a residual material, but generally, since the residual material contains impurities, if the separation of impurities is not performed, the Difficult to reuse. Furthermore, the surface coating material powder 7 is generally expensive, so the surface coating material powder 7 has a large amount of residual material, and if it is not reused without separating impurities, the production cost will increase. In addition, even if the separation treatment of impurities is performed, there is a problem that the cost is high.
因此,为了改善这点,除了金属基材粉末、表面涂覆材料粉末以外,对于还使用熔点比表面涂覆材料粉末高的高熔点粉末的方法进行说明。Therefore, in order to improve this point, a method of using a high melting point powder having a melting point higher than that of the surface coating material powder in addition to the metal base material powder and the surface coating material powder will be described.
在造型台上,如图10所示,将金属基材粉末6配置在封闭式叶轮50的叶片1、芯板2和侧板3的位置(参照图4(c)),在它们的附近配置表面涂覆材料粉末7,在其以外的位置配置高熔点粉末8。然后,用激光将金属基材粉末6和表面涂覆材料粉末7熔化、烧结时,调节激光的强度以使高熔点粉末8不熔化、烧结。烧结后的状态与图5(b)相同。On the molding table, as shown in FIG. 10, the metal base powder 6 is arranged at the position of the blade 1, the core plate 2, and the side plate 3 of the closed impeller 50 (refer to FIG. 4(c)), and is arranged near them. The surface coating material powder 7 is provided with a high melting point powder 8 at a position other than that. Then, when the metal base material powder 6 and the surface coating material powder 7 are melted and sintered with a laser, the intensity of the laser is adjusted so that the high melting point powder 8 is not melted and sintered. The state after sintering is the same as in Fig. 5(b).
使用2种以上的粉末采用粉末烧结层叠法制作形状的情况下,如果相邻的2种粉末都熔化、烧结,则这些粉末的成分会相互混合。虽然在表面涂覆材料粉末7中使用了耐腐蚀性、耐磨损性高的材料,但是,如果在其中混合高熔点粉末8的成分,则它们的功能降低。When two or more types of powders are used to form a shape by powder sintering lamination, if adjacent two types of powders are melted and sintered, the components of these powders will mix with each other. Although a material with high corrosion resistance and wear resistance is used for the surface coating material powder 7, if the components of the high melting point powder 8 are mixed therein, their functions will be reduced.
使用了图5中所示的金属基材粉末6和表面涂覆材料粉末7这2种的情况下,在这2者的边界处成分混合,但通过将涂层厚度设置为某一程度,能够使表面涂覆材料7a的表层仅由该成分构成。即,耐腐蚀性、耐磨损性只要在表面涂覆材料7a的表层维持即可,因此图5的构成中,金属基材粉末6和表面涂覆材料粉末7的成分的混合不会成为问题。In the case of using two types of metal base powder 6 and surface coating material powder 7 shown in FIG. The surface layer of the surface coating material 7a is composed only of this component. That is, the corrosion resistance and wear resistance should only be maintained on the surface layer of the surface coating material 7a, so in the configuration of FIG. .
另一方面,使用图10中所示的3种粉末的情况下,在表面涂覆材料粉末7和高熔点粉末8也产生粉末间的边界。因此,必须使得不熔化高熔点粉末8,表面涂覆材料粉末7与高熔点粉末8的成分不混合。不过,表面涂覆材料粉末7熔化、烧结时,也有时高熔点粉末8不熔化但附着,因此在该采用粉末烧结层叠法的封闭式叶轮50的制造后可以对表面进行磨削,将高熔点粉末8的成分除去。On the other hand, in the case of using the three types of powders shown in FIG. 10 , a boundary between the powders also occurs between the surface coating material powder 7 and the high melting point powder 8 . Therefore, it is necessary not to melt the high-melting-point powder 8 , and not to mix the components of the surface-coating material powder 7 and the high-melting-point powder 8 . However, when the surface coating material powder 7 is melted and sintered, sometimes the high melting point powder 8 adheres without melting. Therefore, the surface can be ground after the production of the enclosed impeller 50 using the powder sintering lamination method, and the high melting point powder 8 can be ground. The components of powder 8 were removed.
再有,作为高熔点粉末8,需要熔点比表面涂覆材料粉末7高,另外,希望价格低,例如可列举出氧化铝等,但并不限定于此。In addition, the high melting point powder 8 needs to have a melting point higher than that of the surface coating material powder 7, and it is desired to be low in price. Examples thereof include alumina, but are not limited thereto.
另外,不仅是封闭式叶轮50,对于壳体密封环32、轴套44,除了金属基材粉末和表面涂覆材料粉末以外,也可使用高熔点粉末制造。In addition, not only the closed impeller 50 but also the casing seal ring 32 and the bushing 44 can be manufactured using high melting point powders in addition to metal base powder and surface coating material powder.
这样,根据本实施方式,通过使用金属基材粉末和表面涂覆材料粉末采用粉末烧结层叠法制造由金属基材和表面涂覆材料构成的金属制品(封闭式叶轮50、壳体密封环32、轴套44),能够与形状的复杂性无关地容易地制造。Thus, according to this embodiment, metal products (closed impeller 50, casing seal ring 32, The bushing 44) can be easily manufactured regardless of the complexity of the shape.
另外,通过除了金属粉末基材和表面涂覆材料粉末以外还使用高熔点粉末,能够降低制造成本。In addition, manufacturing costs can be reduced by using high-melting-point powders in addition to the metal powder base material and the surface-coating material powder.
以上对实施方式的说明结束,但本发明的方式并不限定于这些。例如,上述的实施方式为了容易理解地说明本发明而详细地进行了说明,但并不限定于必须具备说明的全部构成的实施方式。The above is the end of the description of the embodiment, but the aspects of the present invention are not limited to these. For example, the above-mentioned embodiment has been described in detail to explain the present invention in an easy-to-understand manner, but it is not limited to the embodiment that must include all the configurations described.
另外,也可以将某实施方式的构成的一部分替换为其他实施方式的构成,另外,也可以在某实施方式的构成中加入其他实施方式的构成。In addition, a part of the configuration of a certain embodiment may be replaced with a configuration of another embodiment, and the configuration of another embodiment may be added to the configuration of a certain embodiment.
此外,对于具体的构成,可以在不脱离本发明的主旨的范围内进行适当的改变。In addition, specific configurations can be appropriately changed within a range not departing from the gist of the present invention.
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