CN106417361A - 一种高效祛霉抑霉剂及其制备方法 - Google Patents
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Abstract
本发明属于建材防霉防腐技术领域,具体涉及一种高效祛霉抑霉剂及其制备方法。该高效祛霉抑霉剂包括广谱杀菌剂、氧化抑菌剂、乳化剂和去离子水,按重量比,广谱杀菌剂:氧化抑菌剂:乳化剂:去离子水=23~32:5~10:1~6:58~70。本发明所提供的高效祛霉抑霉剂具有极短的作用时间,短时间的作用后祛霉率即可高达99.8%以上。并且,祛霉后具有长效的抑霉效果。
Description
技术领域
本发明属于建材防霉防腐技术领域,具体涉及一种高效祛霉抑霉剂及其制备方法。
背景技术
《2016年中国建材行业发展调研与发展趋势分析报告》指出,目前中国已经是世界上最大的建筑材料生产国和消费国。主要建材产品水泥、平板玻璃、建筑卫生陶瓷、石材和墙体的材料等产量多年居世界第一位。随着我国经济结构的战略性调整及战略性新兴产业、绿色建筑产业的发展,未来产品需求的绿色化、多功能化和高品质化发展趋势将更加突出,兼具绿色、节能、环保等多种功能的高品质建材产品将成为未来新的发展主体,其市场空间也将随之进一步扩大,而健康环保防霉抗菌现已成为建材市场的新宠。
建筑物长霉现象一直是令人苦恼的问题。各种节能新型材料的使用及房屋的气密性加强、建筑结构中的湿度积累及其引发的霉菌生长,对建筑结构的使用性能和人们的居住环境构成巨大的威胁。霉菌的存在影响了建筑的美观性的同时又时刻在损坏建筑结构,使建筑的使用年限降低。据报道,我国平均每年仅用于整修因发霉对建筑物所造成损坏的费用就高达68000万美元。建筑物霉菌在损坏建筑物的同时对人类的健康也带来极大的危害。霉菌会造成呼吸道感染,产生流行性感冒、鼻粘膜炎、过敏反应、结核等症状。因此,建筑材料防霉已经成为现在建筑装修的首要选择之一。
进入夏季,特别是在南方逐渐进入雨季的时候,许多家庭的墙面都容易出现受潮、发霉的现象。不仅影响墙面的美观,还会致使室内长期处于潮湿、霉味的困扰。同样在南方等雨水充沛地域的建筑工程,特别是建筑工程的一楼、地下商场、地铁等低海拔设施,在建筑墙体、梁柱、装饰结构等地方更容易出现生菌发霉的现象。日常生活中我们除了保持室内墙壁及家具等物品的清洁卫生,并注意室内通风换气来减少霉菌滋生外,进行建筑装修时使用具有抗菌防霉功能的材料已成为必须解决的问题。
发明内容
为解决现有技术的不足,本发明提供了一种高效祛霉抑霉剂及其制备方法。
一种高效祛霉抑霉剂,包括广谱杀菌剂、氧化抑菌剂、乳化剂和去离子水,按重量比,广谱杀菌剂:氧化抑菌剂:乳化剂:去离子水=23~32:5~10:1~6:58~70。
具体的,所述广谱杀菌剂选自5-氯-2-甲基-4-异噻唑-3-酮、乙内酰脲(DMDM)、四氯间苯二甲腈或山梨酸钾中的任意一种或多种的混合。
具体的,所述氧化抑菌剂选自三氯异氰尿酸、二氯异氰尿酸钠或次氯酸钙中的任意一种或多种的混合。
具体的,所述乳化剂选自烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵(SE-10)、烯丙氧基羟丙磺酸钠(AHPS)或甲基丙烯酸羟丙磺酸钠(HMPS)中的任意一种或多种的混合。
本发明还提供了一种高效祛霉抑霉剂的制备方法,包括以下步骤:
1)将广谱杀菌剂、氧化抑菌剂、乳化剂和去离子水混合,得到混合溶液,其中,按重量比,广谱杀菌剂:氧化抑菌剂:乳化剂:去离子水=23~32:5~10:1~6:58~70;
2)将步骤1)得到的混合溶液乳化,得到高效祛霉抑霉剂。
具体的,所述广谱杀菌剂选自5-氯-2-甲基-4-异噻唑-3-酮、乙内酰脲(DMDM)、四氯间苯二甲腈或山梨酸钾中的任意一种或多种的混合。
具体的,所述氧化抑菌剂选自三氯异氰尿酸、二氯异氰尿酸钠或次氯酸钙中的任意一种或多种的混合。
具体的,所述乳化剂选自烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵(SE-10)、烯丙氧基羟丙磺酸钠(AHPS)或甲基丙烯酸羟丙磺酸钠(HMPS)中的任意一种或多种的混合。
具体的,乳化机乳化,乳化时间12~24小时。
本发明所提供的高效祛霉抑霉剂具有极短的作用时间,短时间的作用后祛霉率即可高达99.8%以上。并且,祛霉后具有长效的抑霉效果。
附图说明
图1是各实验样品的光学照片。
图2是为各实验样品分别经过产品1、产品2和产品3的短时间作用后的光学照片。
图3是为经过产品1、产品2和产品3处理后的各实验样品置于高温髙湿试验环境下6个月后的光学照片。
图4是本发明所提供的高效祛霉抑霉剂的制备流程图。
具体实施方式
以下对本发明的原理和特征进行描述,所举实施例只用于解释本发明,并非用于限定本发明的范围。
实施例1
本实施例组分按重量百分比计,优选的:
DMDM乙内酰脲30份;
三氯异氰尿酸8份;
甲基丙烯酸羟丙磺酸钠4份;
去离子水58份;
置于乳化机内乳化24小时即制得产品1。
实施例2
本实施例组分按重量百分比计,优选的:
5-氯-2-甲基-4-异噻唑-3-酮55%,四氯间苯二甲腈45%混合,27份;
次氯酸钙7份;
烯丙氧基羟丙磺酸钠(AHPS)2份;
去离子水64份;
置于乳化机内乳化24小时即制得产品2。
实施例3
本实施例组分按重量百分比计,优选的:
5-氯-2-甲基-4-异噻唑-3-酮65%,山梨酸钾35%混合,31份;
二氯异氰尿酸钠5份;
烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵(SE-10)3份;
去离子水61份;
置于乳化机内乳化24小时即制得产品3。
效果例
效果实验方案
1)取三组已经发霉的建筑材料板,板面发霉清晰可见;
2)将产品1、产品2和产品3的高效祛霉抑霉剂均匀喷涂于板面,形成一层液膜即可;
3)将喷涂好的试验板置于常温条件下,开始计时,分别记录霉痕祛除时间;
4)将已经完全祛除霉菌的板材经过干燥养护后,置于模拟高温髙湿试验房内,长期记录观察,分别收集祛霉防霉效果数据。
表1
项目 | 祛霉时间(min) | 有效祛霉率(%) |
产品1 | 15-20 | 99.8% |
产品2 | 10-15 | 99.8% |
产品3 | 15-20 | 99.8% |
如表1所示,为产品1、产品2和产品3的早起作用效果数据。从表1的内容可以看出,三个实施例的产品均能在10-20分钟的极短的时间内发挥效力进行祛霉,且在短时间的作用后,祛霉率即可达到99.8%。而目前现有的建筑材料板祛霉剂,作用时间通常在4小时以上,显效时间大大缩短。
如图1所述,为各实验样品的光学照片。
如图2所示,为各实验样品分别经过产品1、产品2和产品3的短时间作用后的光学照片。
从图2可以看出,各实验样品表面的霉菌得到有效的祛除。
如图3所示,为经过产品1、产品2和产品3处理后的各实验样品置于高温髙湿试验环境下6个月后的光学照片。模拟条件为:温度在45~50℃,湿度为95~99RH。
从图3可以看出,各实验样品在长达6个月的时间内,表面霉菌得到稳定抑制。
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (9)
1.一种高效祛霉抑霉剂,其特征在于,包括广谱杀菌剂、氧化抑菌剂、乳化剂和去离子水,按重量比,广谱杀菌剂:氧化抑菌剂:乳化剂:去离子水=23~32:5~10:1~6:58~70。
2.根据权利要求1所述的高效祛霉抑霉剂,其特征在于:所述广谱杀菌剂选自5-氯-2-甲基-4-异噻唑-3-酮、乙内酰脲、四氯间苯二甲腈或山梨酸钾中的任意一种或多种的混合。
3.根据权利要求1所述的高效祛霉抑霉剂,其特征在于:所述氧化抑菌剂选自三氯异氰尿酸、二氯异氰尿酸钠或次氯酸钙中的任意一种或多种的混合。
4.根据权利要求1所述的高效祛霉抑霉剂,其特征在于:所述乳化剂选自烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵、烯丙氧基羟丙磺酸钠或甲基丙烯酸羟丙磺酸钠中的任意一种或多种的混合。
5.一种高效祛霉抑霉剂的制备方法,其特征在于,包括以下步骤:
1)将广谱杀菌剂、氧化抑菌剂、乳化剂和去离子水混合,得到混合溶液,其中,按重量比,广谱杀菌剂:氧化抑菌剂:乳化剂:去离子水=23~32:5~10:1~6:58~70;
2)将步骤1)得到的混合溶液乳化,得到高效祛霉抑霉剂。
6.根据权利要求5所述的高效祛霉抑霉剂的制备方法,其特征在于:所述广谱杀菌剂选自5-氯-2-甲基-4-异噻唑-3-酮、乙内酰脲、四氯间苯二甲腈或山梨酸钾中的任意一种或多种的混合。
7.根据权利要求5所述的高效祛霉抑霉剂的制备方法,其特征在于:所述氧化抑菌剂选自三氯异氰尿酸、二氯异氰尿酸钠或次氯酸钙中的任意一种或多种的混合。
8.根据权利要求5所述的高效祛霉抑霉剂的制备方法,其特征在于:所述乳化剂选自烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵、烯丙氧基羟丙磺酸钠或甲基丙烯酸羟丙磺酸钠中的任意一种或多种的混合。
9.根据权利要求5所述的高效祛霉抑霉剂的制备方法,其特征在于:所述混合溶液的乳化采用乳化机进行乳化,乳化时间12~24小时。
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