CN106400197A - Making method of comfortable polyester filament - Google Patents
Making method of comfortable polyester filament Download PDFInfo
- Publication number
- CN106400197A CN106400197A CN201610797235.7A CN201610797235A CN106400197A CN 106400197 A CN106400197 A CN 106400197A CN 201610797235 A CN201610797235 A CN 201610797235A CN 106400197 A CN106400197 A CN 106400197A
- Authority
- CN
- China
- Prior art keywords
- parts
- comfortableness
- comfortable
- ethylene glycol
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 32
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 106
- 229920001634 Copolyester Polymers 0.000 claims abstract description 24
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000009987 spinning Methods 0.000 claims abstract description 20
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000001476 alcoholic effect Effects 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 12
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000011858 nanopowder Substances 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 9
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940080314 sodium bentonite Drugs 0.000 claims abstract description 6
- 229910000280 sodium bentonite Inorganic materials 0.000 claims abstract description 6
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims abstract 3
- 229940047670 sodium acrylate Drugs 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 238000006068 polycondensation reaction Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 230000018044 dehydration Effects 0.000 claims description 16
- 238000006297 dehydration reaction Methods 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 238000004321 preservation Methods 0.000 claims description 14
- 208000005156 Dehydration Diseases 0.000 claims description 12
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 claims description 8
- 229920000615 alginic acid Polymers 0.000 claims description 8
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 238000010009 beating Methods 0.000 claims description 8
- 238000012512 characterization method Methods 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 8
- 238000005886 esterification reaction Methods 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000002074 melt spinning Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 206010067868 Skin mass Diseases 0.000 claims description 6
- 235000012216 bentonite Nutrition 0.000 claims description 6
- FNIHDXPFFIOGKL-UHFFFAOYSA-N disodium;dioxido(oxo)germane Chemical compound [Na+].[Na+].[O-][Ge]([O-])=O FNIHDXPFFIOGKL-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229940072056 alginate Drugs 0.000 claims description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims 2
- 230000008569 process Effects 0.000 abstract description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 238000007086 side reaction Methods 0.000 abstract description 2
- 235000010413 sodium alginate Nutrition 0.000 abstract description 2
- 239000000661 sodium alginate Substances 0.000 abstract description 2
- 229940005550 sodium alginate Drugs 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 6
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 abstract 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- WSXIMVDZMNWNRF-UHFFFAOYSA-N antimony;ethane-1,2-diol Chemical compound [Sb].OCCO WSXIMVDZMNWNRF-UHFFFAOYSA-N 0.000 abstract 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 229940093476 ethylene glycol Drugs 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229960004063 propylene glycol Drugs 0.000 abstract 1
- 230000005588 protonation Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 19
- 208000012886 Vertigo Diseases 0.000 description 16
- 239000004744 fabric Substances 0.000 description 12
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229920004934 Dacron® Polymers 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- -1 Polyethylene terephthalate Polymers 0.000 description 2
- 108010020346 Polyglutamic Acid Proteins 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229940092782 bentonite Drugs 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 108010064470 polyaspartate Proteins 0.000 description 2
- 229920002643 polyglutamic acid Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000036299 sexual function Effects 0.000 description 1
- 238000012799 strong cation exchange Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/08—Oxygen-containing compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to a making method of a comfortable polyester filament. The method comprises the steps of: 1) mixing organic conductive mica nano powder, organic sodium bentonite, sodium acrylate, ethylene glycol, propylene glycol, butanediol, p-hydroxybenzoic acid and sodium germinate to obtain a comfortable composite alcoholic solution; 2) mixing conductive potassium titanate whisker, ultrafine diatomite, sodium alginate, polyethylene glycol, propylene glycol, an antioxidant 168, lauroyl diethanolamide, ethylene glycol antimony, and a protonation agent phosphoric acid to obtain a comfortable composite promoter; 3) subjecting the comfortable composite multifunctional alcoholic solution, the comfortable composite promoter, pure terephthalic acid and ethylene glycol to copolycondensation to prepare a comfortable copolyester, and performing spinning to obtain the comfortable polyester filament. The comfortable modifier and composite promoter involved in the invention are prepared by a special process, have good dispersibility in polyester melt, and overcome the problems of uneven dispersion, increasing side reaction, spinning filament breaking and the like in a conventional modifying additive polymerization process.
Description
Technical field
The present invention relates to a kind of manufacture method of Comfortable Polyester long filament, belong to textile fabric manufacturing technology field.
Background technology
Polyethylene terephthalate belongs to macromolecular compound, is by p-phthalic acid (PTA) and ethylene glycol (EG)
Make through polycondensation, english abbreviation PET.Polyester has higher melt temperature (Tm) and glass transition temperature (Tg), and
And there is excellent combination property, it is widely used in the fields such as synthetic fibers, bottle piece, thin film.Due to nothing in PET resin structure
Hydrophilic radical, leads to its hygroscopicity very poor, and has when using as cloth textile that moisture absorbing and sweat releasing property is poor, and comfort is poor,
It is also easy to produce electrostatic, balling-up, easily adsorbs dust, the shortcomings of cloth cover is easily dirty, therefore limit its application on high-grade fabric.Institute
To carry out the research of comfortableness PET polyester, give its new characteristic, widen its application, the always focus of researcher research and development.
With the progressively expansion of polyester fiber range of application, from eighties of last century the seventies, developed country is directed to poly-
The above-mentioned deficiency of ester fiber, with the plurality of advantages of natural fiber as target, in terms of the wearing comfort of fiber, from three below
Aspect is started with, and improves the wearing comfort of polyester fiber：1) pass through the reform of spinning technique technology, produce fibre in differentiation, open
Send a series of differential spinning kind such as fine-denier, profiled fibre；2) by not allowing the co-blended spinning of component, with physics altogether
Mixed mode produces the various fiber species with specific function；3) pass through copolyreaction, improve polyester macromolecule this body structure of chain,
The permanent imparting various property of fiber.At present, including fire-retardant, cation-dyeable, high convergency, antistatic, uvioresistant etc.
Range of functional polyester fiber, creates far-reaching influence to the range of application of polyester fiber.
Through the development of decades, in normal polyester, convenient for production to have reached the world total for the polyester of China and chemical fibre market
The 70% about of yield, but the development and application field in functional polyester, China is at present more is limited to single function and fiber
Exploitation, and for having the exploitation of complex function, high added value functional polyester and fiber, then it is also highly desirable to have scientific research personnel multi-functional
Complex polyester and fiber art make a breakthrough.
Organic conductive Muscovitum has electric conductivity, and stable chemical performance, light specific gravity, possesses good dividing in ethylene glycol
Scattered property, is difficult to precipitate, as excellent modifying agent, PET polyester can be modified.Sodium bentonite have very strong hygroscopicity and
Dilatancy, the water yield of 8～15 times of adsorbable own vol, volumetric expansion can reach 30 times.In addition, bentonite is also relatively
Strong cation exchange capacity (CEC) and various gases, liquid, organic substance are had by certain absorbability, therefore have higher plasticity
Stronger caking property, because of bentonitic special nature, it has higher use value, is widely used in each industry neck
Domain.Diatomaceous density 1.9-2.3g/cm3, heap density 0.34-0.65g/cm3, specific surface area 40-65m2/g, pore volume
0.45-0.98m, water absorption rate is 2-4 times of own vol, has fine and smooth, loose, light weight, porous, water absorption and the strong property of permeability
Matter, adds adsorptivity and the hygroscopicity that a small amount of kieselguhr can significantly improve material in macromolecule polymer material, and can improve
The effect such as the heat-resisting, insulation of product, aging resistance.Sodium alginate has hygroscopicity, and during balance, the number of contained humidity is depending on phase
To humidity.
Whisker is with the diameter very little (0.1～10um) of single crystal form growth, atomic arrangement high-sequential, intensity
Close to the theoretical value of perfect crystal, have a kind of fibrous material of certain draw ratio (5-1000), have intensity high, heat-resisting, fire-retardant,
Antibacterial, conduction, inhale the function such as ripple, because its length be macromolecular material macromolecular chain length several times is to tens times, in macromolecule
Add a small amount of whisker in material, just can play enhancing, toughness reinforcing effect, also can improve material thermal resistance.Whisker is a kind of preferable
Polymer modification agent, have a wide range of applications field.
Retrieved by domestic literature, in existing technology report, after preparing the most employing of Comfort Polyester Fiber fabric
A kind of method arranging, such as patent of invention " utilization polyglutamic acid arranges the method improving comfort of polyester fabric " (CN
102587146 A) adopt with the following method：Dacron soaks 5～10 minutes in polyglutamic acid aqueous solution, soaks two with padding machine two
Roll, the pick-up making fabric is 80%～100%, and the fabric having padded is dried in 80 DEG C of baking ovens, and 100 DEG C of baker bakes 3
Minute.The regain of the dacron processing through the method is 1.75%；" one kind utilizes poly-aspartate to patent of invention
The method that finishing agent improves comfort of polyester fabric " (CN 102352542 A) discloses one kind and utilizes poly-aspartate finishing agent
The method improving comfort of polyester fabric.The method is the poly- Radix Asparagi using relative molecular mass between 100000-200000
Propylhomoserin is modified to dacron by spinning modification or arrangement modification, and the dacron moisture absorption poisture-penetrability of modified mistake is excellent
Different, antistatic behaviour is strong, good hand touch the advantages of, greatly improve the wearing comfort of terylene fabric, and human body and skin had very well
Affinity, stingless excitation, can be widely used for underwear, gym suit, bedding etc..Said method all makes to wash using finishing method
Synthetic fibre fabric possesses comfortable sexual function, and the method technique is loaded down with trivial details, high processing costs.
Content of the invention
It is an object of the invention to overcoming the shortcomings of that prior art exists, using the method for direct modified poly ester melt, profit
Prepare a kind of manufacture method of Comfortable Polyester long filament of Comfort Polyester Fiber with melt spinning technology.
A kind of manufacture method of Comfortable Polyester long filament that the present invention provides, it adopts following steps：
A) press mass fraction, by 1-2 part nanoscale organic conductive Muscovitum nano powder, the organic sodium bentonite of 1-2 part, 1-2
Part sodium polyacrylate, 65-75 part ethylene glycol, 5-8 part 1,3-PD, 5-8 part BDO, 4-6 part P-hydroxybenzoic acid,
0.1-0.3 part sodium germanate mixes, and mixed solution, in the airtight griding reaction 2-4 hour of 70 DEG C of agitating ball mills, obtains a kind of comfortable
Property compound alcoholic solution, 70 DEG C of heat preservation for standby use；
B) press mass fraction, a diameter of for 1-2 part characterization parameter 0.2-2um, length are the electric conductivity potassium titanate of 3-20um
Nano whisker, 1-2 part microfine diatomaceous, 1-2 part Na-alginate, 8-10 part molecular weight is 15000 ethylene glycol PEG, 8-10 part
1,3-PD, 0.3-0.5 part irgasfos 168,0.3-0.5 part lauric acid diethyl amide, 0.1-0.3 part antimony glycol,
0.1-0.3 part protonating agent phosphoric acid mixes, and under the conditions of 70 DEG C, airtight agitating ball mill griding reaction 1-2 hour, obtains one kind
Comfortableness compound accelerant, heat preservation for standby use when 70 DEG C of vacuum dehydration to water content are less than 1%；
C) press mass fraction, by step A prepare) 4-2 part comfortableness be combined alcoholic solution mix with 6-8 part ethylene glycol, then
Carry out proportioning with 15-18 part terephthalic acid component, and making beating is blended, be heated to 70 DEG C of vacuum dehydrations, when water content is less than 1%
When be added in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation
In the stage, be continuously added to 1-2 part and prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then
Evacuation, carries out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, and a kind of comfortableness copolyesters is obtained；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 30-
70：70-30, composite spinning is obtained the Comfortable Polyester long filament with skin-core structure；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester through one-component melt spinning long
Silk.
A kind of manufacture method of Comfortable Polyester long filament that the present invention provides, it adopts following steps：
A) press mass fraction, by 1.5 parts of nanoscale organic conductive Muscovitum nano powders, 1.5 parts of organic sodium bentonites, 1.5
Part sodium polyacrylate, 70 parts of ethylene glycol, 6 parts of 1,3-PDs, 6 parts of BDOs, 5 parts of P-hydroxybenzoic acid, 0.2 part of germanic acid
Sodium mixes, and mixed solution, in 70 DEG C of airtight griding reactions of agitating ball mill 3 hours, obtains a kind of comfortableness and is combined alcoholic solution, and 70
DEG C heat preservation for standby use；
B) press mass fraction, the electric conductivity potassium titanate that a diameter of for 1.5 parts of characterization parameters 1.1um, length are 11.5um is received
Meter Jing Xu, 1.5 parts of microfine diatomaceous, 1.5 parts of Na-alginates, the ethylene glycol PEG of 9 parts of molecular weight 15000,9 parts of 1,3-PDs,
0.4 part of irgasfos 168,0.4 part of lauric acid diethyl amide, 0.2 part of antimony glycol, 0.2 part of protonating agent phosphoric acid mixing, 70
Airtight agitating ball mill griding reaction 1.5 hours under the conditions of DEG C, obtain a kind of comfortableness compound accelerant, 70 DEG C of vacuum dehydrations are extremely
Heat preservation for standby use when water content is less than 1%；
C) press mass fraction, be prepared by step A) 3 parts of comfortablenesses be combined alcoholic solution and mix with 7 parts of ethylene glycol, then with 16
Part terephthalic acid component carries out proportioning, and making beating is blended, and is heated to 70 DEG C of vacuum dehydrations, adds when water content is less than 1%
To in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation phase,
Be continuously added to 1.5 parts to be prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C and react 50 minutes, then take out true
Sky, carries out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, and a kind of comfortableness copolyesters is obtained；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 50：
50, composite spinning is obtained the Comfortable Polyester long filament with skin-core structure；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester through one-component melt spinning long
Silk.
Compared with prior art, the beneficial effects are mainly as follows：Organic conductive Muscovitum, potassium titanate crystal whisker and have
Machine bentonite has good dispersibility in ethylene glycol, can be uniformly dispersed in the polyester consistent, overcome typically inorganic interpolation
Component disperse in the polyester inequality problem, and can the requirement according to product purpose with to performance be properly added a certain proportion of
Modified component, gives the higher degree of crystallinity of product and preferably processes constancy；The addition of whisker, serves the effect of activeness and quietness
Really；Comfortableness modifying agent and compound accelerant adopt special process to prepare, and have good dispersibility, overcome in polyester fondant
After adding in conventional property-modifying additive polymerization process, dispersion is uneven, and side reaction increases, the problems such as spinning fracture of wire.
Specific embodiment
Below embodiments of the invention are further described.Following examples are only carried out furtherly to the application
Bright, should not be construed as the restriction to the application.
A kind of manufacture method of Comfortable Polyester long filament of the present invention, using following steps：
A) press mass fraction, by 1-2 part nanoscale organic conductive Muscovitum nano powder, the organic sodium bentonite of 1-2 part, 1-2
Part sodium polyacrylate, 65-75 part ethylene glycol, 5-8 part 1,3-PD, 5-8 part BDO, 4-6 part P-hydroxybenzoic acid,
0.1-0.3 part sodium germanate mixes, and mixed solution, in the airtight griding reaction 2-4 hour of 70 DEG C of agitating ball mills, obtains a kind of comfortable
Property compound alcoholic solution, 70 DEG C of heat preservation for standby use；
B) press mass fraction, a diameter of for 1-2 part characterization parameter 0.2-2um, length are the electric conductivity potassium titanate of 3-20um
Nano whisker, 1-2 part microfine diatomaceous, 1-2 part Na-alginate, 8-10 part molecular weight is 15000 ethylene glycol PEG, 8-10 part
1,3-PD, 0.3-0.5 part irgasfos 168,0.3-0.5 part lauric acid diethyl amide, 0.1-0.3 part antimony glycol,
0.1-0.3 part protonating agent phosphoric acid mixes, and under the conditions of 70 DEG C, airtight agitating ball mill griding reaction 1-2 hour, obtains one kind
Comfortableness compound accelerant, heat preservation for standby use when 70 DEG C of vacuum dehydration to water content are less than 1%；
C) press mass fraction, by step A prepare) 4-2 part comfortableness be combined alcoholic solution mix with 6-8 part ethylene glycol, then
Carry out proportioning with 15-18 part terephthalic acid component, and making beating is blended, be heated to 70 DEG C of vacuum dehydrations, when water content is less than 1%
When be added in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation
In the stage, be continuously added to 1-2 part and prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then
Evacuation, carries out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, and a kind of comfortableness copolyesters is obtained；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 30-
70：70-30, composite spinning is obtained the Comfortable Polyester long filament with skin-core structure；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester through one-component melt spinning long
Silk.
Embodiment 1：A kind of manufacture method of Comfortable Polyester long filament, using following steps：
A) press mass fraction, by 2 parts of nanoscale organic conductive Muscovitum nano powders, 2 parts of organic sodium bentonites, 2 parts poly- third
Olefin(e) acid sodium, 70 parts of ethylene glycol, 8 parts of 1,3-PDs, 6 parts of BDOs, 6 parts of P-hydroxybenzoic acid, 0.3 part of sodium germanate mixes
Close, mixed solution, in 70 DEG C of airtight griding reactions of agitating ball mill 4 hours, obtains a kind of comfortableness and is combined alcoholic solution, 70 DEG C of guarantors
Temperature is stand-by；
B) pressing mass fraction by a diameter of for 2 parts of characterization parameters 0.2um, length is the electric conductivity potassium titanate nano whisker of 3um,
2 parts of microfine diatomaceous, 2 parts of Na-alginates, 10 parts of molecular weight are 15000 ethylene glycol PEG, 10 parts of 1,3-PDs, and 0.5 part resists
168,0.5 part of lauric acid diethyl amide of oxygen agent, 0.3 part of antimony glycol, 0.2 part of protonating agent phosphoric acid mixing, in 70 DEG C of conditions
Under airtight agitating ball mill griding reaction 2 hours, obtain a kind of comfortableness compound accelerant, 70 DEG C of vacuum dehydrations are little to water content
Heat preservation for standby use when 1%；
C) press mass fraction, be prepared by step A) 4 parts of comfortablenesses be combined alcoholic solution and mix with 6 parts of ethylene glycol, then with 16
Part terephthalic acid component carries out proportioning, and making beating is blended, and is heated to 70 DEG C of vacuum dehydrations, adds when water content is less than 1%
To in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation phase,
Be continuously added to 2 parts to be prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then evacuation,
Carry out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, go out after the technological requirement of processing after meeting to melt viscosity
Material, is obtained a kind of comfortableness copolyesters；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by cortex and sandwich layer quality
Ratio 40：60 composite spinnings, as cortex comfortableness copolyesters melt and the conventional polyester melt as sandwich layer respectively through each
Enter manifold after self-measuring pump-metered, then through core-skin composite spining module, after cooling, winding, skin-core structure comfortable is obtained
Property polyester filament；The present embodiment spinning technology parameter：238dtex/48f fiber dimensious, 286 DEG C of spinning temperatures, 2800m/min
POY winding speed, 21.5 DEG C of ring blowing temperature, 45Pa ring blow pressure, 85% ring blowing humidity.
Embodiment 2：A kind of manufacture method of Comfortable Polyester long filament, using following steps：
A) press mass fraction, by 1.5 parts of nanoscale organic conductive Muscovitum nano powders, 1.5 parts of organic sodium bentonites, 1.5
Part sodium polyacrylate, 70 parts of ethylene glycol, 6 parts of 1,3-PDs, 6 parts of BDOs, 5 parts of P-hydroxybenzoic acid, 0.2 part of germanic acid
Sodium mixes, and mixed solution, in 70 DEG C of airtight griding reactions of agitating ball mill 3 hours, obtains a kind of comfortableness and is combined alcoholic solution, and 70
DEG C heat preservation for standby use；
B) press mass fraction, the electric conductivity potassium titanate that a diameter of for 1.5 parts of characterization parameters 1.1um, length are 11.5um is received
Meter Jing Xu, 1.5 parts of microfine diatomaceous, 1.5 parts of Na-alginates, the ethylene glycol PEG of 9 parts of molecular weight 15000,9 parts of 1,3-PDs,
0.4 part of irgasfos 168,0.4 part of lauric acid diethyl amide, 0.2 part of antimony glycol, 0.2 part of protonating agent phosphoric acid mixing, 70
Airtight agitating ball mill griding reaction 1.5 hours under the conditions of DEG C, obtain a kind of comfortableness compound accelerant, 70 DEG C of vacuum dehydrations are extremely
Heat preservation for standby use when water content is less than 1%；
C) press mass fraction, be prepared by step A) 3 parts of comfortablenesses be combined alcoholic solution and mix with 7 parts of ethylene glycol, then with 16
Part terephthalic acid component carries out proportioning, and making beating is blended, and is heated to 70 DEG C of vacuum dehydrations, adds when water content is less than 1%
To in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation phase,
Be continuously added to 1.5 parts to be prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C and react 50 minutes, then take out true
Sky, carries out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, after the technological requirement of processing after meeting to melt viscosity
Discharging, is obtained a kind of comfortableness copolyesters；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 50：
50, composite spinning is obtained the Comfortable Polyester long filament with skin-core structure；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester through one-component melt spinning long
Silk.
Embodiment 3：A kind of manufacture method of Comfortable Polyester long filament, using following steps：
A) press mass fraction, by 1 part of nanoscale organic conductive Muscovitum nano powder, 1 part of organic sodium bentonite, 1 part poly- third
Olefin(e) acid sodium, 65 parts of ethylene glycol, 8 parts of 1,3-PDs, 8 parts of BDOs, 4 parts of P-hydroxybenzoic acid, 0.1 part of sodium germanate mixes
Close, mixed solution, in 70 DEG C of airtight griding reactions of agitating ball mill 2.5 hours, obtains a kind of comfortableness and is combined alcoholic solution, 70 DEG C
Heat preservation for standby use；
B) press mass fraction, a diameter of for 1 part of characterization parameter 2um, length be the electric conductivity potassium titanate nano whisker of 20um,
1 part of microfine diatomaceous, 1 part of Na-alginate, 8 parts of molecular weight are 15000 ethylene glycol PEG, 8 parts of 1,3-PDs, 0.3 part of antioxygen
Agent 168,0.3 part of lauric acid diethyl amide, 0.1 part of antimony glycol, 0.1 part of protonating agent phosphoric acid mixing, under the conditions of 70 DEG C
Airtight agitating ball mill griding reaction 1.5 hours, obtains a kind of comfortableness compound accelerant, and 70 DEG C of vacuum dehydrations are little to water content
Heat preservation for standby use when 1%；
C) press mass fraction, be prepared by step A) 2 parts of comfortablenesses be combined alcoholic solution and mix with 8 parts of ethylene glycol, then with 16
Part terephthalic acid component carries out proportioning, and making beating is blended, and is heated to 70 DEG C of vacuum dehydrations, adds when water content is less than 1%
To in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation phase,
Be continuously added to 1 part to be prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then evacuation,
Carry out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, go out after the technological requirement of processing after meeting to melt viscosity
Material, is obtained a kind of comfortableness copolyesters；
D) prepared with step C) comfortableness copolyesters as raw material, one-component melt by polycondensation vessel through pipeline, through counting
Amount pump, filament spinning component, cooling, after winding spinning make Comfortable Polyester long filament；The present embodiment spinning technology parameter：275dtex/
48f fiber dimensious, 285 DEG C of spinning temperatures, 4750m/min FDY winding speed, 3.2 draw ratios, 21 DEG C of side-blown air temperatures,
The side-blown wind velocity of 0.65m/min, 80% cross air blasting humidity.
Embodiment of the present invention is not limited to embodiment described above, by aforementioned disclosed numerical range, just
Arbitrarily replaced in specific embodiment, such that it is able to obtain numerous embodiment, this is not enumerated.
Claims (2)
1. a kind of manufacture method of Comfortable Polyester long filament is it is characterised in that this manufacture method adopts following steps：
A) press mass fraction, by 1-2 part nanoscale organic conductive Muscovitum nano powder, the organic sodium bentonite of 1-2 part, 1-2 part is gathered
Sodium acrylate, 65-75 part ethylene glycol, 5-8 part 1,3-PD, 5-8 part BDO, 4-6 part P-hydroxybenzoic acid, 0.1-
The mixing of 0.3 part of sodium germanate, mixed solution, in the airtight griding reaction 2-4 hour of 70 DEG C of agitating ball mills, obtains a kind of comfortableness multiple
Close alcoholic solution, 70 DEG C of heat preservation for standby use；
B) press mass fraction, a diameter of for 1-2 part characterization parameter 0.2-2um, length are the electric conductivity potassium titanate nanometer of 3-20um
Whisker, 1-2 part microfine diatomaceous, 1-2 part Na-alginate, 8-10 part molecular weight is 15000 ethylene glycol PEG, 8-10 part 1,3-
Propylene glycol, 0.3-0.5 part irgasfos 168,0.3-0.5 part lauric acid diethyl amide, 0.1-0.3 part antimony glycol, 0.1-0.3
Part protonating agent phosphoric acid mixing, airtight agitating ball mill griding reaction 1-2 hour under the conditions of 70 DEG C, obtain a kind of comfortableness multiple
Close accelerator, heat preservation for standby use when 70 DEG C of vacuum dehydration to water content are less than 1%；
C) press mass fraction, by step A prepare) 4-2 part comfortableness be combined alcoholic solution mix with 6-8 part ethylene glycol, then with 15-
18 parts of terephthalic acid component carry out proportioning, and making beating is blended, and are heated to 70 DEG C of vacuum dehydrations, add when water content is less than 1%
Enter in polyplant, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation rank
Section, be continuously added to 1-2 part and prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then take out
Vacuum, carries out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, and a kind of comfortableness copolyesters is obtained；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 30-70：70-
30, composite spinning is obtained the Comfortable Polyester long filament with skin-core structure；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester long filament through one-component melt spinning.
2. a kind of manufacture method of Comfortable Polyester long filament is it is characterised in that this manufacture method adopts following steps：
A) press mass fraction, by 1.5 parts of nanoscale organic conductive Muscovitum nano powders, 1.5 parts of organic sodium bentonites, 1.5 parts are gathered
Sodium acrylate, 70 parts of ethylene glycol, 6 parts of 1,3-PDs, 6 parts of BDOs, 5 parts of P-hydroxybenzoic acid, 0.2 part of sodium germanate mixes
Close, mixed solution, in 70 DEG C of airtight griding reactions of agitating ball mill 3 hours, obtains a kind of comfortableness and is combined alcoholic solution, 70 DEG C of guarantors
Temperature is stand-by；
B) press mass fraction, the electric conductivity potassium titanate that a diameter of for 1.5 parts of characterization parameters 1.1um, length are 11.5um is nanocrystalline
Must, 1.5 parts of microfine diatomaceous, 1.5 parts of Na-alginates, the ethylene glycol PEG of 9 parts of molecular weight 15000,9 parts of 1,3-PDs, 0.4
Part irgasfos 168,0.4 part of lauric acid diethyl amide, 0.2 part of antimony glycol, 0.2 part of protonating agent phosphoric acid mixing, at 70 DEG C
Under the conditions of airtight agitating ball mill griding reaction 1.5 hours, obtain a kind of comfortableness compound accelerant, 70 DEG C of vacuum dehydration is to containing
The heat preservation for standby use when water yield is less than 1%；
C) press mass fraction, be prepared by step A) 3 parts of comfortablenesses be combined alcoholic solution and mix with 7 parts of ethylene glycol, more right with 16 parts
Terephthalic acid component carries out proportioning, and making beating is blended, and is heated to 70 DEG C of vacuum dehydrations, is added to poly- when water content is less than 1%
Attach together in putting, in 250 DEG C of temperature, carry out esterification under pressure 0.15MPa 2 hours, in normal pressure esterification-polycondensation phase, continuously
Add 1.5 parts prepared by step B) comfortableness compound accelerant, and be warming up to 270 DEG C react 50 minutes, then evacuation,
Carry out polycondensation reaction below 283 DEG C of temperature, absolute pressure 100Pa, a kind of comfortableness copolyesters is obtained；
D) with step C prepare) comfortableness copolyesters as cortex, with conventional polyester as sandwich layer, by core-skin mass ratio 50：50, multiple
Close spinning and the Comfortable Polyester long filament with skin-core structure is obtained；
Or E) with step C preparation) comfortableness copolyesters as raw material, make Comfortable Polyester long filament through one-component melt spinning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610797235.7A CN106400197A (en) | 2016-08-31 | 2016-08-31 | Making method of comfortable polyester filament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610797235.7A CN106400197A (en) | 2016-08-31 | 2016-08-31 | Making method of comfortable polyester filament |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106400197A true CN106400197A (en) | 2017-02-15 |
Family
ID=58002020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610797235.7A Pending CN106400197A (en) | 2016-08-31 | 2016-08-31 | Making method of comfortable polyester filament |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106400197A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106894102A (en) * | 2017-04-12 | 2017-06-27 | 江苏江南高纤股份有限公司 | Efficient polyolefin/polyester sheath core is combined direct spinning system and method |
| CN108383985A (en) * | 2018-01-23 | 2018-08-10 | 浙江省现代纺织工业研究院 | A kind of modified PTA, modified poly ester and its antibiotic health care polyester fiber of preparation |
| CN109763191A (en) * | 2018-12-19 | 2019-05-17 | 中科纺织研究院（青岛）有限公司 | A kind of seaweed polyester fiber and preparation method thereof |
| CN115559014A (en) * | 2022-09-15 | 2023-01-03 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filament yarn |
| CN115584567A (en) * | 2022-08-29 | 2023-01-10 | 浙江盛元化纤有限公司 | Preparation method of copolymerization modified linen-like polyester filament yarn |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63159523A (en) * | 1986-12-18 | 1988-07-02 | Toray Ind Inc | Composite fiber |
| CN102400245A (en) * | 2011-08-24 | 2012-04-04 | 杭州泛林科技有限公司 | Preparation method of water-absorbing antibacterial modified polyester fiber |
| CN102978743A (en) * | 2012-11-26 | 2013-03-20 | 浙江理工大学 | Method for manufacturing various-modulus flame-retardant anti-molten-drop polyester fibers |
| CN102978744A (en) * | 2012-11-26 | 2013-03-20 | 浙江理工大学 | Method for manufacturing conductive polyester fibers |
| CN103668536A (en) * | 2012-09-13 | 2014-03-26 | 东丽纤维研究所（中国）有限公司 | Moisture-absorbing fiber and preparation method thereof |
| CN105088388A (en) * | 2015-07-30 | 2015-11-25 | 浙江恒逸高新材料有限公司 | Preparation method for hydrophilic antibacterial polyester chips and fibers |
-
2016
- 2016-08-31 CN CN201610797235.7A patent/CN106400197A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63159523A (en) * | 1986-12-18 | 1988-07-02 | Toray Ind Inc | Composite fiber |
| CN102400245A (en) * | 2011-08-24 | 2012-04-04 | 杭州泛林科技有限公司 | Preparation method of water-absorbing antibacterial modified polyester fiber |
| CN103668536A (en) * | 2012-09-13 | 2014-03-26 | 东丽纤维研究所（中国）有限公司 | Moisture-absorbing fiber and preparation method thereof |
| CN102978743A (en) * | 2012-11-26 | 2013-03-20 | 浙江理工大学 | Method for manufacturing various-modulus flame-retardant anti-molten-drop polyester fibers |
| CN102978744A (en) * | 2012-11-26 | 2013-03-20 | 浙江理工大学 | Method for manufacturing conductive polyester fibers |
| CN105088388A (en) * | 2015-07-30 | 2015-11-25 | 浙江恒逸高新材料有限公司 | Preparation method for hydrophilic antibacterial polyester chips and fibers |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106894102A (en) * | 2017-04-12 | 2017-06-27 | 江苏江南高纤股份有限公司 | Efficient polyolefin/polyester sheath core is combined direct spinning system and method |
| CN108383985A (en) * | 2018-01-23 | 2018-08-10 | 浙江省现代纺织工业研究院 | A kind of modified PTA, modified poly ester and its antibiotic health care polyester fiber of preparation |
| CN109763191A (en) * | 2018-12-19 | 2019-05-17 | 中科纺织研究院（青岛）有限公司 | A kind of seaweed polyester fiber and preparation method thereof |
| CN115584567A (en) * | 2022-08-29 | 2023-01-10 | 浙江盛元化纤有限公司 | Preparation method of copolymerization modified linen-like polyester filament yarn |
| CN115584567B (en) * | 2022-08-29 | 2024-04-16 | 浙江盛元化纤有限公司 | Preparation method of copolymerization modified linen-like polyester filaments |
| CN115559014A (en) * | 2022-09-15 | 2023-01-03 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filament yarn |
| CN115559014B (en) * | 2022-09-15 | 2024-03-08 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filaments |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106400197A (en) | Making method of comfortable polyester filament | |
| CN105504341B (en) | A kind of compound and preparation method thereof and a kind of macromolecular material and preparation method thereof | |
| CN107312166A (en) | A kind of modified PET polyester and its preparation method and application | |
| CN104153035B (en) | Fire-retardant nice and cool recycled polyester filament fiber and production method thereof | |
| CN107245230B (en) | A kind of PET polyester slices and its preparation method and application with air-cleaning function | |
| CN103541039A (en) | Multifunctional modified polyester staple fiber and preparation method of same | |
| CN110685025A (en) | Production process of porous polyester staple fibers | |
| CN101363143B (en) | Nylon 6/ultrafine calcium carbonate particle composite fiber and its preparation method | |
| CN106567192A (en) | Method for preparing multifunctional health-care nanofiber membrane | |
| CN107794591A (en) | A kind of preparation method and spinning process of the Anti-radiation polyester fiber based on mechanical stripping graphene | |
| CN106398129A (en) | Self-adjusting and hygroscopic modified polyester synthesis method | |
| CN113417026B (en) | Graphene high-thermal-insulation fiber and preparation method thereof | |
| CN106948171A (en) | A kind of post-processing approach of fibre, obtained modified fibre product and application thereof | |
| CN114351279A (en) | Preparation method of aerogel-containing special-shaped polyester staple fibers | |
| CN101381904A (en) | A kind of preparation method of hygroscopic blend fiber | |
| CN114292441B (en) | Spiral carbon nano tube-hollow glass bead composite filler and preparation method and application thereof | |
| CN106397751A (en) | Method for synthesis of comfortable copolyester | |
| CN110670167A (en) | Preparation method of antibacterial polyester staple fibers | |
| CN118065001B (en) | Preparation method of polyester special-shaped fiber | |
| CN109440223A (en) | A kind of wet fiber material preparation method of spiral porous structure | |
| CN105002588A (en) | Preparation method for imitating cotton polyester-PET/PA6 copolymer fiber | |
| CN111733477A (en) | High-performance nano ceramic uvioresistant high-cold-insulation fiber and preparation method thereof | |
| CN117845365A (en) | Preparation method of modified regenerated polyester fiber fabric | |
| CN106400181A (en) | Manufacturing method of moisture-balance polyester fibers | |
| CN118029002A (en) | Hydrophobic polyester fiber and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |
|
| RJ01 | Rejection of invention patent application after publication |