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CN106399814A - Heat treatment method for phosphor-copper-titanium abrasion-resistant cast iron - Google Patents

Heat treatment method for phosphor-copper-titanium abrasion-resistant cast iron Download PDF

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CN106399814A
CN106399814A CN201610955301.9A CN201610955301A CN106399814A CN 106399814 A CN106399814 A CN 106399814A CN 201610955301 A CN201610955301 A CN 201610955301A CN 106399814 A CN106399814 A CN 106399814A
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iron
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molten iron
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cast iron
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周炳振
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys

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  • Crystallography & Structural Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

本发明公开了一种磷铜钛耐磨铸铁的热处理方法,所述的磷铜钛耐磨铸铁其成分的重量百分比为C2.9~3.3%、Si1.4~1.7%、Mn0.6~1%、P0.4~0.7%、Cu0.5~0.9%、Ti0.2~0.16%、S≤0.10%,余量为Fe。所述的方法包括配料、预热、熔炼、炉前快速分析、终脱氧、孕育处理、浇注、高温退火。该方法简单,通过严格控制磷、铜和钛的加入量,其耐磨性比HT300牌号铸铁高1.5倍,机械性能可达HT250牌号,同时改善机械性能及切削加工性能,特别适合铸造座标镗床床身。The invention discloses a heat treatment method of phosphorus copper titanium wear-resistant cast iron, the composition weight percentage of the phosphorus copper titanium wear-resistant cast iron is C2.9-3.3%, Si1.4-1.7%, Mn0.6-1 %, P0.4~0.7%, Cu0.5~0.9%, Ti0.2~0.16%, S≤0.10%, and the balance is Fe. The method includes batching, preheating, smelting, rapid analysis before furnace, final deoxidation, inoculation treatment, pouring and high temperature annealing. The method is simple, by strictly controlling the addition of phosphorus, copper and titanium, its wear resistance is 1.5 times higher than that of HT300 grade cast iron, and its mechanical properties can reach HT250 grade, while improving mechanical properties and cutting performance, especially suitable for casting jig boring machines bed frame.

Description

一种磷铜钛耐磨铸铁的热处理方法A kind of heat treatment method of phosphorus copper titanium wear-resistant cast iron

技术领域technical field

本发明涉及黑色金属的生产技术领域,尤其是一种磷铜钛耐磨铸铁的热处理方法。The invention relates to the technical field of ferrous metal production, in particular to a heat treatment method for phosphorus copper titanium wear-resistant cast iron.

背景技术Background technique

磷铜钛耐磨铸铁是一种性能优良的减磨材料,它具有很高的硬度和延长铸件的使用寿命的特点。磷铜钛铸铁只需在含磷铸铁中加入铜和少量钛,铜能促使形成并细化珠光体,从而提髙铸铁强度、硬度以及耐磨性,钛促使石墨细化,又由于钛可与碳、氮形成高硬度的化合物质点,因而可提高铸铁的耐磨性。另外为了消除自由渗碳体,降低硬度,改善机械性能及切削加工性能,需进行高温退火处理。Phosphor bronze titanium wear-resistant cast iron is an excellent wear-reducing material, which has the characteristics of high hardness and prolonging the service life of castings. Phosphor-bronze-titanium cast iron only needs to add copper and a small amount of titanium to phosphorus-containing cast iron. Copper can promote the formation and refinement of pearlite, thereby improving the strength, hardness and wear resistance of cast iron. Titanium promotes the refinement of graphite, and because titanium can be combined with Carbon and nitrogen form high-hardness compound particles, which can improve the wear resistance of cast iron. In addition, in order to eliminate free cementite, reduce hardness, improve mechanical properties and cutting performance, high temperature annealing treatment is required.

发明内容Contents of the invention

本发明所需解决的技术问题是提供一种磷铜钛耐磨铸铁的热处理方法。通过控制铸铁中磷、铜和钛的加入量,铸造出耐磨铸铁,并进行高温退火改善机械性能及切削加工性能。The technical problem to be solved by the present invention is to provide a heat treatment method for phosphorus copper titanium wear-resistant cast iron. By controlling the addition of phosphorus, copper and titanium in cast iron, cast wear-resistant cast iron, and perform high-temperature annealing to improve mechanical properties and cutting performance.

本发明解决其技术问题所采用的技术方案是:包括下述几个步骤:The technical scheme that the present invention solves its technical problem adopts is: comprise following several steps:

第一步:配料:将废钢、回炉料、生铁、锰铁、硅铁按C2.9~3.3%、Si1.4~1.7%、Mn0.6~1%、P0.4~0.7%、Cu0.5~0.9%、Ti0.1~0.16%、S≤0.10%,余量为Fe重量百分比的方式进行配料;The first step: ingredients: steel scrap, recycled material, pig iron, ferromanganese, ferrosilicon according to C2.9~3.3%, Si1.4~1.7%, Mn0.6~1%, P0.4~0.7%, Cu0. 5~0.9%, Ti0.1~0.16%, S≤0.10%, and the balance is Fe weight percentage;

第二步:预热:将优化计算好的废钢、回炉料、生铁投入中频感应炉内进行预热;Step 2: Preheating: Put the optimized calculated steel scrap, recycled material and pig iron into the medium frequency induction furnace for preheating;

第三步:熔炼:将中频感应炉内的废钢、回炉料、生铁熔化后,投入其数量为炉料18~25%,成分为石灰70%+萤石30%的脱氧剂进行预脱氧,再投入烘烤处理的锰铁和硅铁得到铁液;The third step: smelting: After melting the steel scrap, recycled material, and pig iron in the intermediate frequency induction furnace, put in a deoxidizer whose amount is 18-25% of the furnace charge, and whose composition is 70% lime + 30% fluorite for pre-deoxidation, and then put in Ferromanganese and ferrosilicon processed by baking to obtain molten iron;

第四步:炉前快速分析:取铁液浇注试样进行快速分析,根据分析结果调整化学成分;Step 4: Quick analysis before the furnace: Take the molten iron pouring sample for quick analysis, and adjust the chemical composition according to the analysis results;

第五步:终脱氧:将铁液温度升温至1480~1600℃,投入其数量为铁液0.1~0.3%的铝进行终脱氧;Step 5: Final deoxidation: raise the temperature of the molten iron to 1480-1600°C, and put in 0.1-0.3% aluminum in the molten iron for final deoxidation;

第六步:孕育处理:铁液自中频感应炉流向浇包时进行孕育处理,加入其数量为铁液量的0.3~0.5%孕育剂,孕育剂的粒度为2~6mm,孕育剂为75硅铁;Step 6: Inoculation treatment: Inoculation treatment is carried out when the molten iron flows from the intermediate frequency induction furnace to the ladle, adding an inoculant whose amount is 0.3-0.5% of the molten iron, the particle size of the inoculant is 2-6 mm, and the inoculant is 75 silicon iron;

第七步:浇注:待铁液温度降至1400~1480℃时,进行浇注,得到铸件;Step 7: pouring: when the temperature of molten iron drops to 1400-1480°C, pouring is carried out to obtain castings;

第八步:高温退火。The eighth step: high temperature annealing.

所述的第八步高温退火中,铸件﹤200℃以下装入热处理炉中,以50~90℃/h的速度升温至780~830℃,保温1~3h进行快速冷却至550℃时,再将铸件放入热处理炉以40~80℃/h的速度冷至300℃以下出炉空冷,得到磷铜钛耐磨铸铁。In the eighth step of high-temperature annealing, the casting is loaded into a heat treatment furnace below 200°C, heated to 780-830°C at a rate of 50-90°C/h, kept for 1-3 hours and rapidly cooled to 550°C, and then The casting is put into a heat treatment furnace and cooled at a rate of 40-80°C/h to below 300°C, and then air-cooled to obtain phosphorus copper titanium wear-resistant cast iron.

本发明的有益效果是:方法简单,通过严格控制磷、铜和钛的加入量,其耐磨性比HT300牌号铸铁高1.5倍,机械性能可达HT250牌号,同时改善机械性能及切削加工性能,特别适合铸造座标镗床床身。The beneficial effect of the present invention is: the method is simple, by strictly controlling the addition of phosphorus, copper and titanium, its wear resistance is 1.5 times higher than that of HT300 brand cast iron, and its mechanical properties can reach HT250 brand, while improving mechanical properties and cutting performance, Especially suitable for casting coordinate boring machine bed.

具体实施方式detailed description

实施例1:Example 1:

本例的一种磷铜钛耐磨铸铁的热处理方法,包括下述几个步骤:A kind of heat treatment method of phosphorus copper titanium wear-resistant cast iron of this example, comprises following several steps:

第一步:配料:将废钢、回炉料、生铁、锰铁、硅铁按C2.9%、Si1.4%、Mn0.6%、P0.4%、Cu0.5%、Ti0.1%、S≤0.10%,余量为Fe重量百分比的方式进行配料;The first step: ingredients: steel scrap, recycled material, pig iron, ferromanganese, ferrosilicon according to C2.9%, Si1.4%, Mn0.6%, P0.4%, Cu0.5%, Ti0.1%, S≤0.10%, and the balance is Fe weight percentage for batching;

第二步:预热:将优化计算好的废钢、回炉料、生铁投入中频感应炉内进行预热;Step 2: Preheating: Put the optimized calculated steel scrap, recycled material and pig iron into the medium frequency induction furnace for preheating;

第三步:熔炼:将中频感应炉内的废钢、回炉料、生铁熔化后,投入其数量为炉料18%,成分为石灰70%+萤石30%的脱氧剂进行预脱氧,再投入烘烤处理的锰铁和硅铁得到铁液;The third step: smelting: After melting the steel scrap, recycled materials, and pig iron in the intermediate frequency induction furnace, put in a deoxidizer whose amount is 18% of the furnace charge, and whose composition is 70% of lime + 30% of fluorite for pre-deoxidation, and then put into baking Treated ferromanganese and ferrosilicon to obtain molten iron;

第四步:炉前快速分析:取铁液浇注试样进行快速分析,根据分析结果调整化学成分;Step 4: Quick analysis before the furnace: Take the molten iron pouring sample for quick analysis, and adjust the chemical composition according to the analysis results;

第五步:终脱氧:将铁液温度升温至1480℃,投入其数量为铁液0.1%的铝进行终脱氧;Step 5: Final deoxidation: raise the temperature of the molten iron to 1480°C, and put in aluminum whose amount is 0.1% of the molten iron for final deoxidation;

第六步:孕育处理:铁液自中频感应炉流向浇包时进行孕育处理,加入其数量为铁液量的0.3%孕育剂,孕育剂的粒度为2mm,孕育剂为75硅铁;Step 6: Inoculation treatment: Inoculation treatment is carried out when the molten iron flows from the intermediate frequency induction furnace to the ladle, adding an inoculant whose amount is 0.3% of the molten iron, the particle size of the inoculant is 2 mm, and the inoculant is 75 ferrosilicon;

第七步:浇注:待铁液温度降至1400℃时,进行浇注,得到铸件;The seventh step: pouring: when the temperature of molten iron drops to 1400°C, pouring is carried out to obtain castings;

第八步:高温退火:铸件﹤200℃以下装入热处理炉中,以50℃/h的速度升温至780℃,保温1h进行快速冷却至550℃时,再将铸件放入热处理炉以40℃/h的速度冷至300℃以下出炉空冷,得到磷铜钛耐磨铸铁。Step 8: High-temperature annealing: Put the casting into the heat treatment furnace below 200°C, raise the temperature to 780°C at a rate of 50°C/h, keep it for 1 hour and quickly cool it to 550°C, then put the casting into the heat treatment furnace at 40°C /h speed cooling to below 300 ℃ out of the furnace and air cooling to obtain phosphorus copper titanium wear-resistant cast iron.

实施例2:Example 2:

本例的一种磷铜钛耐磨铸铁的热处理方法,包括下述几个步骤:A kind of heat treatment method of phosphorus copper titanium wear-resistant cast iron of this example, comprises following several steps:

第一步:配料:将废钢、回炉料、生铁、锰铁、硅铁按C3.1%、Si1.55%、Mn0.8%、P0.55%、Cu0.7%、Ti0.13%、S≤0.10%,余量为Fe重量百分比的方式进行配料;The first step: ingredients: steel scrap, recycled materials, pig iron, ferromanganese, ferrosilicon according to C3.1%, Si1.55%, Mn0.8%, P0.55%, Cu0.7%, Ti0.13%, S≤0.10%, and the balance is Fe weight percentage for batching;

第二步:预热:将优化计算好的废钢、回炉料、生铁投入中频感应炉内进行预热;Step 2: Preheating: Put the optimized calculated steel scrap, recycled material and pig iron into the medium frequency induction furnace for preheating;

第三步:熔炼:将中频感应炉内的废钢、回炉料、生铁熔化后,投入其数量为炉料21%,成分为石灰70%+萤石30%的脱氧剂进行预脱氧,再投入烘烤处理的锰铁和硅铁得到铁液;The third step: smelting: After melting the scrap steel, recycled materials, and pig iron in the intermediate frequency induction furnace, put in a deoxidizer whose amount is 21% of the furnace charge, and whose composition is 70% lime + 30% fluorite for pre-deoxidation, and then put into baking Treated ferromanganese and ferrosilicon to obtain molten iron;

第四步:炉前快速分析:取铁液浇注试样进行快速分析,根据分析结果调整化学成分;Step 4: Quick analysis before the furnace: Take the molten iron pouring sample for quick analysis, and adjust the chemical composition according to the analysis results;

第五步:终脱氧:将铁液温度升温至1540℃,投入其数量为铁液0.2%的铝进行终脱氧;Step 5: Final deoxidation: raise the temperature of the molten iron to 1540°C, and put in aluminum whose amount is 0.2% of the molten iron for final deoxidation;

第六步:孕育处理:铁液自中频感应炉流向浇包时进行孕育处理,加入其数量为铁液量的0.4%孕育剂,孕育剂的粒度为4mm,孕育剂为75硅铁;Step 6: Inoculation treatment: Inoculation treatment is carried out when the molten iron flows from the intermediate frequency induction furnace to the ladle, adding an inoculant whose amount is 0.4% of the molten iron, the particle size of the inoculant is 4 mm, and the inoculant is 75 ferrosilicon;

第七步:浇注:待铁液温度降至1440℃时,进行浇注,得到铸件;Step 7: pouring: when the temperature of molten iron drops to 1440°C, pouring is carried out to obtain castings;

第八步:高温退火:铸件﹤200℃以下装入热处理炉中,以70℃/h的速度升温至805℃,保温2h进行快速冷却至550℃时,再将铸件放入热处理炉以60℃/h的速度冷至300℃以下出炉空冷,得到磷铜钛耐磨铸铁。Step 8: High-temperature annealing: Put the casting into the heat treatment furnace below 200°C, raise the temperature to 805°C at a rate of 70°C/h, keep it warm for 2 hours and cool it rapidly to 550°C, then put the casting into the heat treatment furnace at 60°C /h speed cooling to below 300 ℃ out of the furnace and air cooling to obtain phosphorus copper titanium wear-resistant cast iron.

实施例3:Example 3:

本例的一种磷铜钛耐磨铸铁的热处理方法,包括下述几个步骤:A kind of heat treatment method of phosphorus copper titanium wear-resistant cast iron of this example, comprises following several steps:

第一步:配料:将废钢、回炉料、生铁、锰铁、硅铁按C3.3%、Si1.7%、Mn1%、P0.7%、Cu0.9%、Ti0.16%、S≤0.10%,余量为Fe重量百分比的方式进行配料;The first step: ingredients: steel scrap, recycled materials, pig iron, ferromanganese, ferrosilicon according to C3.3%, Si1.7%, Mn1%, P0.7%, Cu0.9%, Ti0.16%, S≤ 0.10%, and the balance is batched in the form of Fe weight percentage;

第二步:预热:将优化计算好的废钢、回炉料、生铁投入中频感应炉内进行预热;Step 2: Preheating: Put the optimized calculated steel scrap, recycled material and pig iron into the medium frequency induction furnace for preheating;

第三步:熔炼:将中频感应炉内的废钢、回炉料、生铁熔化后,投入其数量为炉料25%,成分为石灰70%+萤石30%的脱氧剂进行预脱氧,再投入烘烤处理的锰铁和硅铁得到铁液;The third step: smelting: After melting the steel scrap, recycled material, and pig iron in the intermediate frequency induction furnace, put in a deoxidizer whose amount is 25% of the furnace charge, and whose composition is 70% of lime + 30% of fluorite for pre-deoxidation, and then put into baking Treated ferromanganese and ferrosilicon to obtain molten iron;

第四步:炉前快速分析:取铁液浇注试样进行快速分析,根据分析结果调整化学成分;Step 4: Quick analysis before the furnace: Take the molten iron pouring sample for quick analysis, and adjust the chemical composition according to the analysis results;

第五步:终脱氧:将铁液温度升温至1600℃,投入其数量为铁液0.3%的铝进行终脱氧;Step 5: Final deoxidation: raise the temperature of molten iron to 1600°C, and put in aluminum whose amount is 0.3% of molten iron for final deoxidation;

第六步:孕育处理:铁液自中频感应炉流向浇包时进行孕育处理,加入其数量为铁液量的0.5%孕育剂,孕育剂的粒度为6mm,孕育剂为75硅铁;Step 6: Inoculation treatment: Inoculation treatment is carried out when the molten iron flows from the intermediate frequency induction furnace to the ladle, adding an inoculant whose amount is 0.5% of the molten iron, the particle size of the inoculant is 6 mm, and the inoculant is 75 ferrosilicon;

第七步:浇注:待铁液温度降至1480℃时,进行浇注,得到铸件;Step 7: pouring: when the temperature of molten iron drops to 1480°C, pouring is carried out to obtain castings;

第八步:高温退火:铸件﹤200℃以下装入热处理炉中,以90℃/h的速度升温至830℃,保温3h进行快速冷却至550℃时,再将铸件放入热处理炉以80℃/h的速度冷至300℃以下出炉空冷,得到磷铜钛耐磨铸铁。Step 8: High-temperature annealing: Put the casting into the heat treatment furnace below 200°C, raise the temperature to 830°C at a rate of 90°C/h, keep it warm for 3 hours and cool it rapidly to 550°C, then put the casting into the heat treatment furnace at 80°C /h speed cooling to below 300 ℃ out of the furnace and air cooling to obtain phosphorus copper titanium wear-resistant cast iron.

以上对本发明的具体实施方式作了说明,但这些说明不能被理解为限制了本发明的范围,本发明的保护范围由随附的权利要求书限定,仼何在本发明权利要求基础上的任何修改、等同替换和改进等,均落入本发明的保护范围之內。The specific embodiments of the present invention have been described above, but these descriptions can not be interpreted as limiting the scope of the present invention, and the protection scope of the present invention is defined by the appended claims, and any modification on the basis of the claims of the present invention , equivalent replacements and improvements, etc., all fall within the protection scope of the present invention.

Claims (2)

1.一种磷铜钛耐磨铸铁的热处理方法,其特征在于:包括下述几个步骤:1. a heat treatment method of phosphorus copper titanium wear-resistant cast iron is characterized in that: comprise following several steps: 第一步:配料:将废钢、回炉料、生铁、锰铁、硅铁按C2.9~3.3%、Si1.4~1.7%、Mn0.6~1%、P0.4~0.7%、Cu0.5~0.9%、Ti0.1~0.16%、S≤0.10%,余量为Fe重量百分比的方式进行配料;The first step: ingredients: steel scrap, recycled material, pig iron, ferromanganese, ferrosilicon according to C2.9~3.3%, Si1.4~1.7%, Mn0.6~1%, P0.4~0.7%, Cu0. 5~0.9%, Ti0.1~0.16%, S≤0.10%, and the balance is Fe weight percentage; 第二步:预热:将优化计算好的废钢、回炉料、生铁投入中频感应炉内进行预热;Step 2: Preheating: Put the optimized calculated steel scrap, recycled material and pig iron into the medium frequency induction furnace for preheating; 第三步:熔炼:将中频感应炉内的废钢、回炉料、生铁熔化后,投入其数量为炉料18~25%,成分为石灰70%+萤石30%的脱氧剂进行预脱氧,再投入烘烤处理的锰铁和硅铁得到铁液;The third step: smelting: After melting the steel scrap, recycled material, and pig iron in the intermediate frequency induction furnace, put in a deoxidizer whose amount is 18-25% of the furnace charge, and whose composition is 70% lime + 30% fluorite for pre-deoxidation, and then put in Ferromanganese and ferrosilicon processed by baking to obtain molten iron; 第四步:炉前快速分析:取铁液浇注试样进行快速分析,根据分析结果调整化学成分;Step 4: Quick analysis before the furnace: Take the molten iron pouring sample for quick analysis, and adjust the chemical composition according to the analysis results; 第五步:终脱氧:将铁液温度升温至1480~1600℃,投入其数量为铁液0.1~0.3%的铝进行终脱氧;Step 5: Final deoxidation: raise the temperature of the molten iron to 1480-1600°C, and put in 0.1-0.3% aluminum in the molten iron for final deoxidation; 第六步:孕育处理:铁液自中频感应炉流向浇包时进行孕育处理,加入其数量为铁液量的0.3~0.5%孕育剂,孕育剂的粒度为2~6mm,孕育剂为75硅铁;Step 6: Inoculation treatment: Inoculation treatment is carried out when the molten iron flows from the intermediate frequency induction furnace to the ladle, adding an inoculant whose amount is 0.3-0.5% of the molten iron, the particle size of the inoculant is 2-6 mm, and the inoculant is 75 silicon iron; 第七步:浇注:待铁液温度降至1400~1480℃时,进行浇注,得到铸件;Step 7: pouring: when the temperature of molten iron drops to 1400-1480°C, pouring is carried out to obtain castings; 第八步:高温退火。The eighth step: high temperature annealing. 2.根据权利要求1所述的一种磷铜钛耐磨铸铁的热处理方法,其特征在于:在所述的第八步高温退火中,铸件﹤200℃以下装入热处理炉中,以50~90℃/h的速度升温至780~830℃,保温1~3h进行快速冷却至550℃时,再将铸件放入热处理炉以40~80℃/h的速度冷至300℃以下出炉空冷,得到磷铜钛耐磨铸铁。2. The heat treatment method of a kind of phosphor copper titanium wear-resistant cast iron according to claim 1, characterized in that: in the eighth step high-temperature annealing, the casting is loaded into the heat treatment furnace below 200 ° C, and the temperature is 50 ~ Heat up to 780-830°C at a rate of 90°C/h, hold for 1-3 hours for rapid cooling to 550°C, then put the casting into a heat treatment furnace and cool it down to below 300°C at a rate of 40-80°C/h, and leave the furnace for air cooling to obtain Phosphor bronze titanium wear-resistant cast iron.
CN201610955301.9A 2016-11-03 2016-11-03 Heat treatment method for phosphor-copper-titanium abrasion-resistant cast iron Pending CN106399814A (en)

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CN107012386A (en) * 2017-04-20 2017-08-04 龙邹 A kind of machining center lathe bed and preparation method thereof
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