CN106397884A - Modified rubber and preparation method thereof, and application of modified rubber to clutch facing - Google Patents
Modified rubber and preparation method thereof, and application of modified rubber to clutch facing Download PDFInfo
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- CN106397884A CN106397884A CN201610766072.6A CN201610766072A CN106397884A CN 106397884 A CN106397884 A CN 106397884A CN 201610766072 A CN201610766072 A CN 201610766072A CN 106397884 A CN106397884 A CN 106397884A
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- rubber
- modified rubber
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 76
- 239000005060 rubber Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 18
- 239000005011 phenolic resin Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000006229 carbon black Substances 0.000 claims abstract description 9
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 32
- 239000002002 slurry Substances 0.000 claims description 31
- 238000007598 dipping method Methods 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 25
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 24
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 24
- 239000004744 fabric Substances 0.000 claims description 21
- 239000012467 final product Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 12
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 235000019359 magnesium stearate Nutrition 0.000 claims description 12
- 238000010074 rubber mixing Methods 0.000 claims description 12
- 239000007965 rubber solvent Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 8
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 239000002390 adhesive tape Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 238000007731 hot pressing Methods 0.000 claims description 6
- 210000001161 mammalian embryo Anatomy 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000013618 particulate matter Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 238000005299 abrasion Methods 0.000 abstract description 3
- -1 polyoxyethylene nonyl phenyl ether Polymers 0.000 abstract description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 5
- 239000004568 cement Substances 0.000 description 5
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002783 friction material Substances 0.000 description 2
- JEAHHRBTXZJYJU-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)(=O)OCCCCCCCC.[O] Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)OCCCCCCCC.[O] JEAHHRBTXZJYJU-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D13/00—Friction clutches
- F16D13/58—Details
- F16D13/60—Clutching elements
- F16D13/64—Clutch-plates; Clutch-lamellae
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Mechanical Operated Clutches (AREA)
Abstract
The invention discloses a modified rubber and a preparation method thereof, and application of the modified rubber to a clutch facing. The modified rubber is prepared from the following raw materials by weight: 35 to 55 parts of styrene butadiene rubber, 10 to 14 parts of phenolic resin, 40 to 50 parts of water, 6 to 8 parts of sodium hydroxide, 2 to 4 parts of carbon black, 0.6 to 0.8 part of methyltriethoxysilane, 1.4 to 1.6 parts of polyoxyethylene nonyl phenyl ether and 7 to 9 parts of nanometer mica powder. The modified rubber provided by the invention can be used for preparing the clutch facing; and the prepared clutch facing has a high and stable friction coefficient and low abrasion, and compared with the prior art, the clutch facing prepared in the invention has outstanding substantive features and makes substantial progress.
Description
Technical field
The invention belongs to friction material field, it is related to a kind of modified rubber and preparation method thereof and in clutch surface
Application.
Background technology
Automobile clutch is the key components and partss in automobile, and it is located in the bell housing between electromotor and change speed gear box,
Automobile plays transmitting torque, separates the multi-functionals such as transmission, damping and overload protection during exercising.Clutch surface is automobile
The core component of clutch, the performance of friction plate directly affects the performance of clutch and the serviceability of car load.This dough sheet is one
Plant the friction material with property, usual clutch surface is by bonding agent, frictional property regulator, fibrous skeleton material
Material, filler etc. form.One good clutch surface requires that stable friction factor, wear rate be low, light specific gravity, connects when using
Conjunction smooth-going, impact are little, and also are resistant to more than 300 DEG C of high temperature.
Directly affect the performance of clutch and the serviceability of car load due to the performance of clutch surface, Ge great producer from
Never slack in the research and development of clutch dough sheet, it is devoted to the exploitation of more high-quality clutch surface always.
Content of the invention
An object of the present disclosure is to provide a kind of modified rubber；
The present invention second purpose is to provide the preparation method of above-mentioned modified rubber；
The present invention the 3rd purpose is to provide application in clutch surface for the above-mentioned modified rubber, prepares clutch surface
Method.
The above-mentioned purpose of the present invention is achieved by techniques below scheme：
A kind of modified rubber, is prepared from by the raw material of following weight portion：Butadiene-styrene rubber, 35～55 parts；Phenolic resin,
10～14 parts；Water, 40～50 parts；Sodium hydroxide, 6～8 parts；White carbon black, 2～4 parts；MTES, 0.6～0.8 part；
NPE, 1.4～1.6 parts；Nano mica powder, 7～9 parts.
Further, described modified rubber is prepared from by the raw material of following weight portion：Butadiene-styrene rubber, 45 parts；Phenol
Urea formaldehyde, 12 parts；Water, 45 parts；Sodium hydroxide, 7 parts；White carbon black, 3 parts；MTES, 0.7 part；Polyoxyethylene nonyl phenyl second
Alkene ether, 1.5 parts；Nano mica powder, 8 parts.
The preparation method of above-mentioned modified rubber, comprises the steps：
Step S1, with water, NPE mix homogeneously after butadiene-styrene rubber is pulverized, is subsequently adding sodium hydroxide
Stir and be completely dissolved to sodium hydroxide, stand 2～3 hours；
Step S2, adds white carbon black, nano mica powder and MTES, is warming up to 50～60 DEG C, with 240～
The rotating speed of 260r/min stirs 6～10 minutes, the material obtaining is put in baking oven and dries, and 85～95 DEG C of drying temperature is dried
Time 1～2h；
Step S3, by the material dried in 155～165 DEG C of heat treatments 4～6 minutes, sends in banbury, adds phenolic aldehyde
Plasticate after resin and uniformly obtain final product described modified rubber, 65～75 DEG C of plasticating temperature.
Application in clutch surface for the above-mentioned modified rubber.
The method that clutch surface prepared by above-mentioned modified rubber, including step：
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 18～22%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:0.8～
1.2；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 20～30 parts；Lauxite, 6
～8 parts；Hexamethylenetetramine, 3～4 parts；Ethanol, 75～85 parts；
Described dipping rubber slurry is made by following raw material：Modified rubber as above, 35～45 parts；Sulfur
Sulphur powder, 5～7 parts；Accelerant CZ, 0.4～0.6 part；Antioxidant 1076,0.8～1.2 part；Magnesium stearate, 1.2～1.6 parts；Ring
Oxygen octyl stearate, 0.6～0.8 part；Semi-reinforcing hydrocarbon black, 8～10 parts；Graphite, 8～12 parts；Aluminium oxide, 7～9 parts；Poly- second two
Alcohol 400,6～8 parts；Nano silicon, 8～10 parts；Rubber solvent naphtha, 85～115 parts.
Further, the preparation method of impregnating resin is：By the mixing of phenolic resin, Lauxite and hexamethylenetetramine all
Pulverize after even, add ethanol and mix, put in blender and break into impregnating resin solution.
Further, the preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 1～2 minute, regulating roller away from 1～2mm, by load weighted modification
Rubber is placed on rubber mixing machine, plasticates 2～3 minutes, after bag roller, addition accelerant CZ, antioxidant 1076, aluminium oxide, and 80～85
After kneading uniformly at DEG C, beat triangle bag 2～3 times；
Step S2, after adjustment roll spacing 3～4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly,
The material cleaning in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 3～4 triangle bags；
Step S3, adjusts roll spacing 1～2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite
All pulverize in input beater with PEG400, obtain mixed material, be eventually adding rubber solvent naphtha, pull an oar 4～5 hours,
Treat in rubber cement, do not have particulate matter to obtain final product described dipping rubber slurry.
Further, described Compound Fabric is made up of glass fibre, chemical fibre, carbon fiber, copper wire.
Advantages of the present invention：
The modified rubber that the present invention provides can be used for preparing clutch surface, and prepared clutch surface friction is
Number is high and stable, and abrasion are low, compared with prior art have prominent substantive distinguishing features and significantly improve.
Specific embodiment
Further illustrate the essentiality content of the present invention with reference to embodiment, but present invention protection model is not limited with this
Enclose.Although being explained in detail to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be right
Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Modified rubber in following embodiments is prepared from by the raw material of following weight portion：Butadiene-styrene rubber, 45 parts；Phenolic aldehyde
Resin, 12 parts；Water, 45 parts；Sodium hydroxide, 7 parts；White carbon black, 3 parts；MTES, 0.7 part；Nonyl pheno
Ether, 1.5 parts；Nano mica powder, 8 parts.
Preparation method is：
Step S1, with water, NPE mix homogeneously after butadiene-styrene rubber is pulverized, is subsequently adding sodium hydroxide
Stir and be completely dissolved to sodium hydroxide, stand 2.5 hours；
Step S2, adds white carbon black, nano mica powder and MTES, is warming up to 55 DEG C, with 250r/min's
Rotating speed stirs 8 minutes, the material obtaining is put in baking oven and dries, 90 DEG C of drying temperature, drying time 1.5h；
Step S3, by the material dried in 160 DEG C of heat treatments 5 minutes, sends in banbury, moulds after adding phenolic resin
Refining uniformly obtains final product described modified rubber, 70 DEG C of plasticating temperature.
Embodiment 1：The preparation of clutch surface
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 20%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:1；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described Compound Fabric is made up of glass fibre, chemical fibre, carbon fiber, copper wire, or known to those of ordinary skill in the art
Other equivalents.
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 25 parts；Lauxite, 7 parts；
Hexamethylenetetramine, 3.5 parts；Ethanol, 80 parts；
Dipping rubber slurry is made by following raw material：Modified rubber, 40 parts；Cosan, 6 parts；Accelerant CZ,
0.5 part；Antioxidant 1076,1 part；Magnesium stearate, 1.4 parts；Octyl epoxy stearate, 0.7 part；Semi-reinforcing hydrocarbon black, 9 parts；Graphite,
10 parts；Aluminium oxide, 8 parts；PEG400,7 parts；Nano silicon, 9 parts；Rubber solvent naphtha, 100 parts.
The preparation method of impregnating resin is：To pulverize after phenolic resin, Lauxite and hexamethylenetetramine mix homogeneously,
Add ethanol to mix, put in blender and break into impregnating resin solution, obtain final product.
The preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 2 minutes, regulating roller, away from 2mm, load weighted modified rubber is put
On rubber mixing machine, plasticate 3 minutes, after bag roller, add accelerant CZ, antioxidant 1076, aluminium oxide, knead uniformly at 85 DEG C
Afterwards, beat triangle bag 3 times；
Step S2, after adjustment roll spacing 4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly, clearly
The material swept in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 4 triangle bags；
Step S3, adjusts roll spacing 2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite
All pulverize in input beater with PEG400, obtain mixed material, be eventually adding rubber solvent naphtha, pull an oar 5 hours, treat
Particulate matter is not had to obtain final product described dipping rubber slurry in rubber cement.
Embodiment 2：The preparation of clutch surface
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 20%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:0.8；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 20 parts；Lauxite, 6 parts；
Hexamethylenetetramine, 3 parts；Ethanol, 75 parts.
Dipping rubber slurry is made by following raw material：Modified rubber, 35 parts；Cosan, 5 parts；Accelerant CZ,
0.4 part；Antioxidant 1076,0.8 part；Magnesium stearate, 1.2 parts；Octyl epoxy stearate, 0.6 part；Semi-reinforcing hydrocarbon black, 8 parts；Stone
Ink, 8 parts；Aluminium oxide, 7 parts；PEG400,6 parts；Nano silicon, 8 parts；Rubber solvent naphtha, 85 parts.
The preparation method of impregnating resin is：To pulverize after phenolic resin, Lauxite and hexamethylenetetramine mix homogeneously,
Add ethanol to mix, put in blender and break into impregnating resin solution, obtain final product.
The preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 2 minutes, regulating roller, away from 2mm, load weighted modified rubber is put
On rubber mixing machine, plasticate 3 minutes, after bag roller, add accelerant CZ, antioxidant 1076, aluminium oxide, knead uniformly at 85 DEG C
Afterwards, beat triangle bag 3 times；
Step S2, after adjustment roll spacing 4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly, clearly
The material swept in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 4 triangle bags；
Step S3, adjusts roll spacing 2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite
All pulverize in input beater with PEG400, obtain mixed material, be eventually adding rubber solvent naphtha, pull an oar 5 hours, treat
Particulate matter is not had to obtain final product described dipping rubber slurry in rubber cement.
Embodiment 3：The preparation of clutch surface
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 20%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:1.2；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 30 parts；Lauxite, 8 parts；
Hexamethylenetetramine, 4 parts；Ethanol, 85 parts；
Dipping rubber slurry is made by following weight raw material：Modified rubber, 45 parts；Cosan, 7 parts；Accelerant CZ,
0.6 part；Antioxidant 1076,1.2 parts；Magnesium stearate, 1.6 parts；Octyl epoxy stearate, 0.8 part；Semi-reinforcing hydrocarbon black, 10 parts；Stone
Ink, 12 parts；Aluminium oxide, 9 parts；PEG400,8 parts；Nano silicon, 10 parts；Rubber solvent naphtha, 115 parts.
The preparation method of impregnating resin is：To pulverize after phenolic resin, Lauxite and hexamethylenetetramine mix homogeneously,
Add ethanol to mix, put in blender and break into impregnating resin solution, obtain final product.
The preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 2 minutes, regulating roller, away from 2mm, load weighted modified rubber is put
On rubber mixing machine, plasticate 3 minutes, after bag roller, add accelerant CZ, antioxidant 1076, aluminium oxide, knead uniformly at 85 DEG C
Afterwards, beat triangle bag 3 times；
Step S2, after adjustment roll spacing 4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly, clearly
The material swept in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 4 triangle bags；
Step S3, adjusts roll spacing 2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite
All pulverize in input beater with PEG400, obtain mixed material, be eventually adding rubber solvent naphtha, pull an oar 5 hours, treat
Particulate matter is not had to obtain final product described dipping rubber slurry in rubber cement.
Embodiment 4：Comparative example, modified rubber is replaced with common mixed rubber
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 20%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:1；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 25 parts；Lauxite, 7 parts；
Hexamethylenetetramine, 3.5 parts；Ethanol, 80 parts；
Dipping rubber slurry is made by following raw material：Common 40 parts of butadiene-styrene rubber；Cosan, 6 parts；Accelerator
CZ, 0.5 part；Antioxidant 1076,1 part；Magnesium stearate, 1.4 parts；Octyl epoxy stearate, 0.7 part；Semi-reinforcing hydrocarbon black, 9 parts；Stone
Ink, 10 parts；Aluminium oxide, 8 parts；PEG400,7 parts；Nano silicon, 9 parts；Rubber solvent naphtha, 100 parts.
The preparation method of impregnating resin is：To pulverize after phenolic resin, Lauxite and hexamethylenetetramine mix homogeneously,
Add ethanol to mix, put in blender and break into impregnating resin solution.
The preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 2 minutes, regulating roller away from 2mm, by load weighted common mixing rubber
Glue is placed on rubber mixing machine, plasticates 3 minutes, after bag roller, adds accelerant CZ, antioxidant 1076, aluminium oxide, kneads all at 85 DEG C
After even, beat triangle bag 3 times；
Step S2, after adjustment roll spacing 4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly, clearly
The material swept in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 4 triangle bags；
Step S3, adjusts roll spacing 2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite
All pulverize in input beater with PEG400, obtain mixed material, be eventually adding rubber solvent naphtha, pull an oar 5 hours, treat
Particulate matter is not had to obtain final product described dipping rubber slurry in rubber cement.
Embodiment 5：Effect example
Enter using constant speed formula testing machine, according to the clutch surface that GB/T5764-1998 standard is prepared to embodiment 1～4
Row test, has the friction and wear behavior of following Tables 1 and 2.Wherein, the clutch surface of embodiment 2,3 preparation and embodiment 1
Basically identical, no longer individually enumerate its test data.
The friction and wear behavior of table 1 embodiment 1 clutch surface
The friction and wear behavior of table 2 embodiment 4 (comparative example) clutch surface
Result shows, the modified rubber that the present invention provides can be used for preparing clutch surface, prepared clutch
Dough sheet coefficient of friction is high and stable, and abrasion are low, compared with prior art have prominent substantive distinguishing features and significantly improve.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this
Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent,
Essence without deviating from technical solution of the present invention and protection domain.
Claims (8)
1. a kind of modified rubber is it is characterised in that be prepared from by the raw material of following weight portion：Butadiene-styrene rubber, 35～55 parts；
Phenolic resin, 10～14 parts；Water, 40～50 parts；Sodium hydroxide, 6～8 parts；White carbon black, 2～4 parts；MTES,
0.6～0.8 part；NPE, 1.4～1.6 parts；Nano mica powder, 7～9 parts.
2. modified rubber according to claim 1 is it is characterised in that be prepared from by the raw material of following weight portion：Fourth
Benzene rubber, 45 parts；Phenolic resin, 12 parts；Water, 45 parts；Sodium hydroxide, 7 parts；White carbon black, 3 parts；MTES, 0.7
Part；NPE, 1.5 parts；Nano mica powder, 8 parts.
3. the preparation method of modified rubber described in claim 1 or 2 is it is characterised in that comprise the steps：
Step S1, with water, NPE mix homogeneously after butadiene-styrene rubber is pulverized, is subsequently adding sodium hydroxide stirring
It is completely dissolved to sodium hydroxide, stand 2～3 hours；
Step S2, adds white carbon black, nano mica powder and MTES, is warming up to 50～60 DEG C, with 240～260r/
The rotating speed of min stirs 6～10 minutes, the material obtaining is put in baking oven and dries, 85～95 DEG C of drying temperature, drying time 1
～2h；
Step S3, by the material dried in 155～165 DEG C of heat treatments 4～6 minutes, sends in banbury, adds phenolic resin
After plasticate and uniformly obtain final product described modified rubber, 65～75 DEG C of plasticating temperature.
4. application in clutch surface for the modified rubber described in claim 1 or 2.
5. prepare the method for clutch surface it is characterised in that including step using modified rubber described in claim 1 or 2：
Step S1, Compound Fabric is dried process, makes absorption water content≤1.5%；
Step S2, Compound Fabric impregnates in impregnating resin so as to resinous amount controls 18～22%；
Step S3, impregnates in dipping rubber slurry, and weight proportion is Compound Fabric:Dipping rubber slurry=1:0.8～1.2；
Step S4, then through around embryo, hot pressing, heat treatment, mill processing, obtaining final product；
Described impregnating resin is prepared from by the raw material of following weight portion：Phenolic resin, 20～30 parts；Lauxite, 6～8
Part；Hexamethylenetetramine, 3～4 parts；Ethanol, 75～85 parts；
Described dipping rubber slurry is made by following raw material：Modified rubber as claimed in claim 1 or 2,35～
45 parts；Cosan, 5～7 parts；Accelerant CZ, 0.4～0.6 part；Antioxidant 1076,0.8～1.2 part；Magnesium stearate, 1.2～
1.6 part；Octyl epoxy stearate, 0.6～0.8 part；Semi-reinforcing hydrocarbon black, 8～10 parts；Graphite, 8～12 parts；Aluminium oxide, 7～9
Part；PEG400,6～8 parts；Nano silicon, 8～10 parts；Rubber solvent naphtha, 85～115 parts.
6. method according to claim 5 is it is characterised in that the preparation method of impregnating resin is：By phenolic resin, ureaformaldehyde
Pulverize after resin and hexamethylenetetramine mix homogeneously, add ethanol and mix, put in blender and break into impregnating resin solution.
7. method according to claim 5 is it is characterised in that the preparation method of dipping rubber slurry comprises the steps：
Step S1, starts opening rubber mixing machine, trial operation 1～2 minute, regulating roller away from 1～2mm, by load weighted modified rubber
It is placed on rubber mixing machine, plasticates 2～3 minutes, after bag roller, add accelerant CZ, antioxidant 1076, aluminium oxide, at 80～85 DEG C
After mixing uniformly, beat triangle bag 2～3 times；
Step S2, after adjustment roll spacing 3～4mm, adds semi-reinforcing hydrocarbon black, nano titanium oxide, after material mixing uniformly, cleans
Material in receiver adds in elastomeric compound, is eventually adding Cosan, continuously makes a call to 3～4 triangle bags；
Step S3, adjusts roll spacing 1～2mm, thin for sizing material roller blanking controls 70 DEG C of roller temperature ＜, cuts out bar standby；
Step S4, the adhesive tape cutting out is measured and puts in beater, then by magnesium stearate, octyl epoxy stearate, graphite and gathers
Ethylene glycol 400 is all pulverized in input beater, obtains mixed material, is eventually adding rubber solvent naphtha, pulls an oar 4～5 hours, treats glue
Particulate matter is not had to obtain final product described dipping rubber slurry in slurry.
8. method according to claim 5 is it is characterised in that described Compound Fabric is by glass fibre, chemical fibre, carbon fiber, copper
Silk composition.
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| CN103029231A (en) * | 2011-09-29 | 2013-04-10 | 浙江科马摩擦材料股份有限公司 | Preparation method of clutch facing blank |
| CN103351574A (en) * | 2013-06-03 | 2013-10-16 | 海盐华强树脂有限公司 | Method for preparing short fiber reinforced friction material through adopting long fibers |
| CN103483646A (en) * | 2013-08-20 | 2014-01-01 | 来安县隆华摩擦材料有限公司 | Temperature-resistant rubber paste for impregnating clutch facets |
| CN105114498A (en) * | 2015-08-06 | 2015-12-02 | 杭州科瑞特摩擦材料有限公司 | Poly-p-phenylene terephthamide composite fiber dry clutch facing and preparation method thereof |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103029231A (en) * | 2011-09-29 | 2013-04-10 | 浙江科马摩擦材料股份有限公司 | Preparation method of clutch facing blank |
| CN102993635A (en) * | 2012-12-03 | 2013-03-27 | 浙江科马摩擦材料股份有限公司 | Method for preparing clutch facing through taking water soluble phenol-formaldehyde resin as adhesion agent |
| CN103351574A (en) * | 2013-06-03 | 2013-10-16 | 海盐华强树脂有限公司 | Method for preparing short fiber reinforced friction material through adopting long fibers |
| CN103483646A (en) * | 2013-08-20 | 2014-01-01 | 来安县隆华摩擦材料有限公司 | Temperature-resistant rubber paste for impregnating clutch facets |
| CN105114498A (en) * | 2015-08-06 | 2015-12-02 | 杭州科瑞特摩擦材料有限公司 | Poly-p-phenylene terephthamide composite fiber dry clutch facing and preparation method thereof |
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