CN106381096A - Water-based plastic product label adhesive - Google Patents
Water-based plastic product label adhesive Download PDFInfo
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- CN106381096A CN106381096A CN201610941616.8A CN201610941616A CN106381096A CN 106381096 A CN106381096 A CN 106381096A CN 201610941616 A CN201610941616 A CN 201610941616A CN 106381096 A CN106381096 A CN 106381096A
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- plastic product
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based plastic product label adhesive, relating to the technical field of plastic product processing. The water-based plastic product label adhesive is prepared from the following raw materials in parts by weight: 10-15 parts of polyvinyl alcohol resin, 8-12 parts of hydrogenated rosin pentaerythritol ester, 4-8 parts of hydroxyethyl methacrylate, 3-6 parts of sodium bentonite, 3-6 parts of water-soluble chitosan, 2-4 parts of polymaliec acid anhydride, 2-4 parts of polyoxytetramethylene glycol, 2-4 parts of aid, 1-2 parts of tea seed powder, 1-2 parts of polyaluminum chloride, 1-2 parts of diisooctyl maleate, 0.5-1 part of polyoxyethylene abietate, 0.5-1 part of polyquaternary amine salt-7, 0.5-1 part of sodium glycinate, 0.5-1 part of sodium pyrophosphate and 100-150 parts of water. The adhesive has high binding property, and can firmly attach the label to the plastic product, thereby achieving the goal of identifying the product information. The label can be easily peeled off, and the residual adhesive on the plastic product after the label is peeled off can be washed off by water.
Description
Technical field：
The present invention relates to plastic processing technique field is and in particular to a kind of water-based plastic product label adhesive.
Background technology：
The general designation of the articles for use such as life that plastic is is main Raw material processing using plastics, industry.Including to mould
Expect the product of all techniques such as injection for raw material, plastic uptake.Label is for marking the name of an article of plastic, manufacturer, life
The carrier of place of production location, production time and bar code, is easy to consumer and identifies the relevant information of bought plastic and be easy to
Plastic is peddled in supermarket and shop.Want label to be attached on plastic, label adhesive is usually used.At present, greatly
Its label can not be removed completely by most plastics when using, even if also can glue attachment portion on plastic after removing
Patch, and these alite pastes easily adsorb dust and blackening, and washing cannot remove.For this problem, our company develops
When label is pasted, a kind of water-based plastic product label adhesive, has the characteristics that caking property is strong, the energy when plastic uses
It is easy to remove label, and the alite paste remaining on plastic after removing can completely remove through washing, thus not shadow
Ring the presentation quality of plastic and normal use.
Content of the invention：
The technical problem to be solved is to provide a kind of caking property strong and label is easily removed, remains alite paste
The water-based plastic product label adhesive of removing can be washed with water.
The technical problem to be solved to be realized using following technical scheme：
A kind of water-based plastic product label adhesive, is made up of the raw material of following parts by weight：
Polyvinyl alcohol resin 10-15 part, hydrogenated rosin pentaerythritol ester 8-12 part, hydroxyethyl methylacrylate 4-8 part, sodium
Base bentonite 3-6 part, water-soluble chitosan 3-6 part, polymaleic anhydride 2-4 part, PTMG 2-4 part, pliable and tough help
Agent 2-4 part, camellia oleosa seed powder 1-2 part, aluminium polychlorid 1-2 part, diisooctyl maleate 1-2 part, polyoxylethylene abietate 0.5-1
Part, polyquaternary ammonium salt -70.5-1 part, Glycine sodium 0.5-1 part, sodium pyrophosphate 0.5-1 part, water 100-150 part.
Its preparation method comprises the steps：
(1) add polyvinyl alcohol resin and polyoxylethylene abietate in water, be heated to reflux state insulation mixing
15min, adds hydrogenated rosin pentaerythritol ester and PTMG, continues backflow insulation mixing 15min, obtains final product thing
Material I；
(2) add sodium bentonite and water-soluble chitosan in hydroxyethyl methylacrylate, be heated to 110-120 DEG C of guarantor
Temperature mixing 10min, is subsequently adding pliable and tough auxiliary agent, camellia oleosa seed powder, diisooctyl maleate and sodium pyrophosphate, continues at 110-120 DEG C
Insulation mixing 10min, obtains final product material II；
(3) add polymaleic anhydride and aluminium polychlorid in material I, stand 30min after being sufficiently mixed, add material
II, polyquaternary ammonium salt -7 and Glycine sodium, are heated to reflux state insulation mixing 10min, obtain final product alite paste.
Described pliable and tough auxiliary agent is made up of the raw material of following parts by weight：C9 Petropols 5-8 part, polyvinyl butyral resin 3-
5 parts, polyethylene glycol oxide 3-5 part, hydrogenated palm oil 2-3 part, lanonol 2-3 part, PAMA 1-2 part, gas phase two
Silicon oxide 1-2 part, ultra-fine polytetrafluorethylepowder powder 0.5-1 part, sulfurized lard 0.5-1 part, its preparation method is：By hydrogenated palm
Oil and lanonol are heated to molten condition insulation mixing 5min, add C9 Petropols and polyvinyl butyral resin, fully mixed
Close microwave treatment 5min under microwave frequency 2450MHz, power 700W, be subsequently adding polyethylene glycol oxide and ultra-fine polytetrafluoroethyl-ne
Alkene powder, continues microwave treatment 5min after mix homogeneously, gained mixture proceeds in 0-5 DEG C of environment standing 3h, be subsequently heated to
120-130 DEG C of insulation mixing 15min, and add PAMA, aerosil and sulfurized lard, continue
120-130 DEG C of insulation mixing 10min, is finally lowered the temperature with the rate of cooling of 10-15 DEG C/min, treats that temperature is down to room temperature.
The interpolation of this pliable and tough auxiliary agent can effectively strengthen the pliability of made alite paste, improves sticking effect.
Using front through modification, its processing method is described aerosil：To 10-15 part aerosil
Middle addition 0.5-1 part DMI and 0.5-1 part triethylene tetramine, and it is heated to 80-90 DEG C of insulation mixing
10min, adds 0.5-1 part terpene resin and 1-2 part emulsified silicone oil, continues to be heated to 110-120 DEG C of insulation mixing 10min,
Gained mixture proceeds to sealing and standing 3h in -5-0 DEG C of environment, after make powder through super micron mill.
Aerosil, through above-mentioned process, strengthens its lipotropy, thus being beneficial to improve itself and high molecular polymer
Blending property.
The invention has the beneficial effects as follows：The made alite paste of the present invention belongs to aqueouss alite paste it is adaptable to the mark of plastic
Sign and paste, have the characteristics that caking property is strong, label can be firmly attached on plastic, to play the mesh of mark product information
's；And label is easily removed, the alite paste that label remains in after removing on plastic can be washed with water removing, to avoid remaining
Alite paste affects the normal use of plastic, is also beneficial to the recycling of plastic simultaneously, is easy to plastic and label
Separation.
Specific embodiment：
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are easy to understand, tie below
Close specific embodiment, the present invention is expanded on further.
Embodiment 1
(1) add 10 parts of polyvinyl alcohol resins and 1 part of polyoxylethylene abietate in 100 parts of water, be heated to the shape that flows back
State insulation mixing 15min, adds 8 parts of hydrogenated rosin pentaerythritol esters and 2 parts of PTMG, continues backflow insulation
Mixing 15min, obtains final product material I；
(2) add 5 parts of sodium bentonites and 3 parts of water-soluble chitosans in 6 parts of hydroxyethyl methylacrylates, be heated to
110-120 DEG C of insulation mixing 10min, is subsequently adding 3 parts of pliable and tough auxiliary agents, 1 part of camellia oleosa seed powder, 1 part of diisooctyl maleate and 0.5 part
Sodium pyrophosphate, continues, in 110-120 DEG C of insulation mixing 10min, to obtain final product material II；
(3) add 2 parts of polymaleic anhydride and 1 part of aluminium polychlorid in material I, after being sufficiently mixed, stand 30min, then plus
Enter material II, 1 part of polyquaternary ammonium salt -7 and 0.5 part of Glycine sodium, be heated to reflux state insulation mixing 10min, obtain final product alite paste.
The preparation of pliable and tough auxiliary agent：3 parts of hydrogenated palm oil and 2 parts of lanonols are heated to molten condition insulation mixing 5min,
Add 5 parts of C9 Petropols and 5 parts of polyvinyl butyral resins, be sufficiently mixed under microwave frequency 2450MHz, power 700W
Microwave treatment 5min, is subsequently adding 3 parts of polyethylene glycol oxides and 0.5 part of ultra-fine polytetrafluorethylepowder powder, continues micro- after mix homogeneously
Ripple processes 5min, and gained mixture proceeds to standing 3h in 0-5 DEG C of environment, is subsequently heated to 120-130 DEG C of insulation mixing 15min,
And add 1 part of PAMA, 1 part of aerosil and 1 part of sulfurized lard, continue mixed in 120-130 DEG C of insulation
Close 10min, finally lowered the temperature with the rate of cooling of 10-15 DEG C/min, treat that temperature is down to room temperature.
The modification of aerosil：0.5 part of 1,3- dimethyl -2- imidazoles is added in 15 parts of aerosils
Quinoline ketone and 0.5 part of triethylene tetramine, and it is heated to 80-90 DEG C of insulation mixing 10min, add 1 part of terpene resin and 1 part of emulsifying
Silicone oil, continues to be heated to 110-120 DEG C of insulation mixing 10min, gained mixture proceeds to sealing and standing 3h in -5-0 DEG C of environment,
Make powder by super micron mill.
Embodiment 2
(1) add 15 parts of polyvinyl alcohol resins and 0.5 part of polyoxylethylene abietate in 100 parts of water, be heated to flowing back
State insulation mixing 15min, adds 8 parts of hydrogenated rosin pentaerythritol esters and 3 parts of PTMG, continues backflow and protect
Temperature mixing 15min, obtains final product material I；
(2) add 5 parts of sodium bentonites and 5 parts of water-soluble chitosans in 8 parts of hydroxyethyl methylacrylates, be heated to
110-120 DEG C of insulation mixing 10min, is subsequently adding 3 parts of pliable and tough auxiliary agents, 1 part of camellia oleosa seed powder, 1 part of diisooctyl maleate and 0.5 part
Sodium pyrophosphate, continues, in 110-120 DEG C of insulation mixing 10min, to obtain final product material II；
(3) add 3 parts of polymaleic anhydride and 1 part of aluminium polychlorid in material I, after being sufficiently mixed, stand 30min, then plus
Enter material II, 0.5 part of polyquaternary ammonium salt -7 and 0.5 part of Glycine sodium, be heated to reflux state insulation mixing 10min, obtain final product stickup
Agent.
The preparation of pliable and tough auxiliary agent：2 parts of hydrogenated palm oil and 3 parts of lanonols are heated to molten condition insulation mixing 5min,
Add 8 parts of C9 Petropols and 3 parts of polyvinyl butyral resins, be sufficiently mixed under microwave frequency 2450MHz, power 700W
Microwave treatment 5min, is subsequently adding 5 parts of polyethylene glycol oxides and 0.5 part of ultra-fine polytetrafluorethylepowder powder, continues micro- after mix homogeneously
Ripple processes 5min, and gained mixture proceeds to standing 3h in 0-5 DEG C of environment, is subsequently heated to 120-130 DEG C of insulation mixing 15min,
And add 2 parts of PAMAs, 1 part of aerosil and 0.5 part of sulfurized lard, continue to be incubated at 120-130 DEG C
Mixing 10min, is finally lowered the temperature with the rate of cooling of 10-15 DEG C/min, treats that temperature is down to room temperature.
The modification of aerosil：0.5 part of 1,3- dimethyl -2- imidazoles is added in 15 parts of aerosils
Quinoline ketone and 0.5 part of triethylene tetramine, and it is heated to 80-90 DEG C of insulation mixing 10min, add 0.5 part of terpene resin and 1 part of breast
SiClx oil, continues to be heated to 110-120 DEG C of insulation mixing 10min, gained mixture proceeds to sealing and standing 3h in -5-0 DEG C of environment,
Powder is made through super micron mill after.
Embodiment 3
The label that the made alite paste of embodiment 1 and 2 is used for plastic is pasted, and finds through actual production, this alite paste
Will not inconsistent phenomenon because of friction in label after making the stickup success rate of label reach 100%, and stickup, in transport, sells
With the phenomenon that label peeling does not occur during use yet, after removing label, the alite paste remaining on plastic is entered
Row washing, you can fully erased clean.
Ultimate principle and principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry
, it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description is originally for personnel
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and its
Equivalent thereof.
Claims (4)
1. a kind of water-based plastic product label adhesive is it is characterised in that be made up of the raw material of following parts by weight：
Polyvinyl alcohol resin 10-15 part, hydrogenated rosin pentaerythritol ester 8-12 part, hydroxyethyl methylacrylate 4-8 part, sodio are swollen
The native 3-6 part of profit, water-soluble chitosan 3-6 part, polymaleic anhydride 2-4 part, PTMG 2-4 part, pliable and tough auxiliary agent 2-4
Part, camellia oleosa seed powder 1-2 part, aluminium polychlorid 1-2 part, diisooctyl maleate 1-2 part, polyoxylethylene abietate 0.5-1 part, poly-
Quaternary ammonium salt -70.5-1 part, Glycine sodium 0.5-1 part, sodium pyrophosphate 0.5-1 part, water 100-150 part.
2. water-based plastic product label adhesive according to claim 1 it is characterised in that its preparation method include as follows
Step：
(1) add polyvinyl alcohol resin and polyoxylethylene abietate in water, be heated to reflux state insulation mixing 15min,
Add hydrogenated rosin pentaerythritol ester and PTMG, continue backflow insulation mixing 15min, obtain final product material I；
(2) add sodium bentonite and water-soluble chitosan in hydroxyethyl methylacrylate, be heated to 110-120 DEG C of insulation mixed
Close 10min, be subsequently adding pliable and tough auxiliary agent, camellia oleosa seed powder, diisooctyl maleate and sodium pyrophosphate, continue to be incubated at 110-120 DEG C
Mixing 10min, obtains final product material II；
(3) add polymaleic anhydride and aluminium polychlorid in material I, after being sufficiently mixed, stand 30min, add material II,
Polyquaternary ammonium salt -7 and Glycine sodium, are heated to reflux state insulation mixing 10min, obtain final product alite paste.
3. water-based plastic product label adhesive according to claim 1 and 2 it is characterised in that described pliable and tough auxiliary agent by
The raw material of following parts by weight is made：C9 Petropols 5-8 part, polyvinyl butyral resin 3-5 part, polyethylene glycol oxide 3-5 part, hydrogen
Change Petiolus Trachycarpi oil 2-3 part, lanonol 2-3 part, PAMA 1-2 part, aerosil 1-2 part, ultra-fine polytetrafluoro
Ethylene powder 0.5-1 part, sulfurized lard 0.5-1 part, its preparation method is：Hydrogenated palm oil and lanonol are heated to molten
State insulation mixing 5min, add C9 Petropols and polyvinyl butyral resin, be sufficiently mixed after microwave frequency 2450MHz,
Microwave treatment 5min under power 700W, is subsequently adding polyethylene glycol oxide and ultra-fine polytetrafluorethylepowder powder, continues after mix homogeneously
Microwave treatment 5min, gained mixture proceeds to standing 3h in 0-5 DEG C of environment, is subsequently heated to 120-130 DEG C of insulation mixing
15min, and add PAMA, aerosil and sulfurized lard, continue in 120-130 DEG C of insulation mixing
10min, is finally lowered the temperature with the rate of cooling of 10-15 DEG C/min, treats that temperature is down to room temperature.
4. water-based plastic product label adhesive according to claim 3 it is characterised in that：Described aerosil makes
With front through modification, its processing method is：0.5-1 part 1,3- dimethyl -2- is added in 10-15 part aerosil
Imidazolone and 0.5-1 part triethylene tetramine, and it is heated to 80-90 DEG C of insulation mixing 10min, add 0.5-1 part terpenes tree
Fat and 1-2 part emulsified silicone oil, continue to be heated to 110-120 DEG C of insulation mixing 10min, gained mixture proceeds in -5-0 DEG C of environment
Sealing and standing 3h, after make powder through super micron mill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610941616.8A CN106381096A (en) | 2016-11-01 | 2016-11-01 | Water-based plastic product label adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610941616.8A CN106381096A (en) | 2016-11-01 | 2016-11-01 | Water-based plastic product label adhesive |
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| CN106381096A true CN106381096A (en) | 2017-02-08 |
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| CN201610941616.8A Pending CN106381096A (en) | 2016-11-01 | 2016-11-01 | Water-based plastic product label adhesive |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022324A (en) * | 2017-05-03 | 2017-08-08 | 安徽太阳体育用品有限公司 | A kind of shuttlecock colour band pastes glue and preparation method thereof |
| CN107057614A (en) * | 2017-05-03 | 2017-08-18 | 安徽太阳体育用品有限公司 | A kind of shuttlecock binding is with aqueous line glue |
| CN107118739A (en) * | 2017-06-23 | 2017-09-01 | 界首市众鑫科技服务有限公司 | A kind of bookbinding modified rosin PUR and preparation method thereof |
| CN107675559A (en) * | 2017-08-30 | 2018-02-09 | 安徽省德邦瓷业有限公司 | A kind of domestic ceramic product label paper gum layer processing unit (plant) |
| CN107697385A (en) * | 2017-08-30 | 2018-02-16 | 安徽省德邦瓷业有限公司 | A kind of barbola work of domestic ceramic product label paper |
| CN107964388A (en) * | 2017-08-30 | 2018-04-27 | 安徽省德邦瓷业有限公司 | A kind of domestic ceramic product sale label adhesive |
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| CN102757747A (en) * | 2012-08-06 | 2012-10-31 | 河南中医学院 | Aldehyde-free odorless environment-friendly and transparent polyvinyl alcohol (PVA) glue and preparation method thereof |
| CN104327793A (en) * | 2014-08-06 | 2015-02-04 | 桐乡嘉力丰实业股份有限公司 | Inorganic-powder-modified mould-proof wallpaper adhesive and preparation method thereof |
| CN104845582A (en) * | 2015-05-28 | 2015-08-19 | 句容市茂源织造厂 | Adhesive for plastic flexible packaging and preparation method thereof |
| CN105647441A (en) * | 2016-04-14 | 2016-06-08 | 苏州市丛岭胶粘剂有限公司 | Plastic label adhesive and preparation method thereof |
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| CN1222553A (en) * | 1997-10-05 | 1999-07-14 | 翟广玉 | Aqueous glue for sticking paper label onto plastic bottle |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022324A (en) * | 2017-05-03 | 2017-08-08 | 安徽太阳体育用品有限公司 | A kind of shuttlecock colour band pastes glue and preparation method thereof |
| CN107057614A (en) * | 2017-05-03 | 2017-08-18 | 安徽太阳体育用品有限公司 | A kind of shuttlecock binding is with aqueous line glue |
| CN107118739A (en) * | 2017-06-23 | 2017-09-01 | 界首市众鑫科技服务有限公司 | A kind of bookbinding modified rosin PUR and preparation method thereof |
| CN107118739B (en) * | 2017-06-23 | 2019-01-01 | 界首市众鑫科技服务有限公司 | A kind of bookbinding modified rosin hot melt adhesive and preparation method thereof |
| CN107675559A (en) * | 2017-08-30 | 2018-02-09 | 安徽省德邦瓷业有限公司 | A kind of domestic ceramic product label paper gum layer processing unit (plant) |
| CN107697385A (en) * | 2017-08-30 | 2018-02-16 | 安徽省德邦瓷业有限公司 | A kind of barbola work of domestic ceramic product label paper |
| CN107964388A (en) * | 2017-08-30 | 2018-04-27 | 安徽省德邦瓷业有限公司 | A kind of domestic ceramic product sale label adhesive |
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Application publication date: 20170208 |