CN106381042B - Water-in-water type antibacterial multi-color and preparation method thereof - Google Patents
Water-in-water type antibacterial multi-color and preparation method thereof Download PDFInfo
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- CN106381042B CN106381042B CN201610806939.6A CN201610806939A CN106381042B CN 106381042 B CN106381042 B CN 106381042B CN 201610806939 A CN201610806939 A CN 201610806939A CN 106381042 B CN106381042 B CN 106381042B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims abstract description 39
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 37
- 239000003973 paint Substances 0.000 claims abstract description 51
- 239000000839 emulsion Substances 0.000 claims abstract description 44
- 239000003292 glue Substances 0.000 claims abstract description 40
- 239000002966 varnish Substances 0.000 claims abstract description 39
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 22
- 238000004078 waterproofing Methods 0.000 claims abstract description 22
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 21
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 20
- 239000003755 preservative agent Substances 0.000 claims abstract description 20
- 230000002335 preservative effect Effects 0.000 claims abstract description 20
- 239000002562 thickening agent Substances 0.000 claims abstract description 20
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 14
- 125000005396 acrylic acid ester group Chemical group 0.000 claims abstract description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims description 42
- -1 poly (hexamethylene) hydrochloride Polymers 0.000 claims description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 239000006210 lotion Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229920002413 Polyhexanide Polymers 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- UMUXBDSQTCDPJZ-UHFFFAOYSA-N chromium titanium Chemical compound [Ti].[Cr] UMUXBDSQTCDPJZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 4
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 3
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- CZIRZNRQHFVCDZ-UHFFFAOYSA-L titan yellow Chemical compound [Na+].[Na+].C1=C(C)C(S([O-])(=O)=O)=C2SC(C3=CC=C(C=C3)/N=N/NC3=CC=C(C=C3)C3=NC4=CC=C(C(=C4S3)S([O-])(=O)=O)C)=NC2=C1 CZIRZNRQHFVCDZ-UHFFFAOYSA-L 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000003086 colorant Substances 0.000 abstract description 4
- 238000004900 laundering Methods 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 description 19
- 238000000576 coating method Methods 0.000 description 19
- 230000000694 effects Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000010276 construction Methods 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 5
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000012173 sealing wax Substances 0.000 description 3
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000009500 colour coating Methods 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 2
- 229940068984 polyvinyl alcohol Drugs 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SYRYCMSRILEZNI-UHFFFAOYSA-N 5-chloro-2-methyl-3h-1,2-thiazole Chemical class CN1CC=C(Cl)S1 SYRYCMSRILEZNI-UHFFFAOYSA-N 0.000 description 1
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- HEQBUZNAOJCRSL-UHFFFAOYSA-N iron(ii) chromite Chemical compound [O-2].[O-2].[O-2].[Cr+3].[Fe+3] HEQBUZNAOJCRSL-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of water-in-water type antibacterial multi-colors, are mixed by base paint, Protection glue and varnish；Base paint is made of following raw material：100 300 parts of 50 150 parts of aqueous elastic polyaminoester emulsion, 20 60 parts of kaolin, 10 30 parts of titanium dioxide, 0 30 parts of environment friendly inorganic pigment, 5 10 parts of antiseptic, 1 10 parts of antifoaming agent, 1 10 parts of coalescents and water；Protection glue is made of following raw material：100 300 parts of 30 80 parts of acrylic acid ester emulsion, 1 10 parts of preservative and water；Varnish is made of following raw material：30 80 parts of 20 100 parts of aqueous pure acrylate elastic emulsion, 10 30 parts of waterproofing agent, 0.5 5 parts of thickener and water.The present invention also provides the preparation method of multi-color, this multi-color mechanical performance is superior, while having the characteristics that antibacterial, waterproof, anti-pollution, uncomplicated laundering and scrubbable, and color is arbitrarily arranged in pairs or groups, and realizes perfect figure.
Description
Technical field
The present invention relates to a kind of preparation method of coating more particularly to a kind of water-in-water type antibacterial multi-color and its preparation sides
Method.
Background technology
As the improvement of people's living standards, interior decoration upsurge is quietly risen, decorative effect requirement of the people to coating
It is higher and higher.Multicolor finish with its bold design broken traditional single color, plane coating decorative effect, started more
Color, relief decorative cover, it is popular with consumers again.Currently, the wall multicolor finish in China mostly uses greatly the more of oil-in-water type
Color coating material not only contains organic solvent, production cost height but also repeatedly spraying is needed to lead to speed of application in the construction process
Slowly.
Water type multicolor paint for water drum is full water-based system, only has the volatilization of water in film forming procedure, nontoxic, tasteless, to people
Body and environment do not cause any harm.The coating figure layer is also colorful three-dimensional sense decorative cover, does not crack, does not fall off, scrubbing resistance.
Water-water coating of multi-colour pattern is made color material with its two step of dispersion operation in continuous phase simultaneously of emulsification and anti-molten technology
The technical performance and decorative effect of product are improved to generate the strip decorative pattern of similar oil-in-water multicolor finish for a step, and
And it is more safer and environmentally friendly in the production and use process than oil-in-water type, simplifies production equipment, reduces product cost.Water
Packet water paint is substantially a kind of water paint, be in aqueous latex paint be added can gelation water soluble paint dispersion and
At by two-phase with opposite charge, in the life gelation of the contact surface of particle when two components mix.Water-in-water type multi-color
The paint energy finishing effect true to nature for restoring marble, granite is high-grade stone especially suitable for the interior/exterior decoration of all kinds of buildings
The economical alternative of material, not only can be to avoid the advantage for using organic solvent also to have production cost low.
Indoor coating also requires antibacterial, easy cleaning, wash resistant, waterproof and anti-pollution, to improve the neat and tidy of coating
And aesthetics, the superior mechanical performance such as strong adhesive force, abrasion-resistant is also also required, however in existing literature and data but almost
Such correlated performance of water-in-water multicolor coating is not addressed.Patent CN101429368A discloses a kind of water-in-water type multi-color painting
Material, production method is first to prepare the protection sol solution of 5% concentration, then prepares white basis paint again, then add by design requirement
Enter mill base to mix colours, finally carries out colored paint granulation.It needs to mix colours using mill base when the coating preparation, technique is not simple enough
Easily.Patent CN201410005877.X discloses a kind of preparation method of high durable artificial granite water-in-water multicolor coating, belongs to
Building coating material technical field, water-in-water multicolor coating uses aqueous high molecular synthetic emulsion as base-material, various water-soluble
Property substance as auxiliary agent, therefore odorlessness, pollution-free, its preparation process is simple, and production cost is low, and construction materials save, decoration effect
Fruit is unique, is a kind of ideal health type interior and exterior decoration material, and this product is more compared to other water-waters on the market
Color coating material has the advantages that color spot is not easy that bleeding, storage stabilizations, long shelf-life, to have Elastic anti-crack, weatherability good.The coating at
Product paint also discloses in preparing using water repellent auxiliary agent and water-proof emulsion, however the addition of the two is only for colorful after preventing film forming
Coating is not easy bleeding, does not consider antibiotic property, water proofing property, anti fouling performance and the easy cleaning of multicolor finish after film forming.Therefore it needs
A kind of polychrome, the mixing of multiphase particle is asked to coexist, three-dimensional sense good decorating effect, antibacterial, waterproof, anti-pollution and easy cleaning mechanicalness
The superior water type multicolor paint for water drum of energy extends the service life of coating to improve the aesthetics of coating.
Invention content
It is an object of the invention to：In view of the above problems, a kind of water-in-water type antibacterial multi-color and its system are provided
Preparation Method.Coating of the present invention does not have to organic solvent, multicolour also can be sprayed once, while this multi-color intensity is high, machine
Tool superior performance, while having the characteristics that antibacterial, waterproof, anti-pollution, uncomplicated laundering and scrubbable, construction is simple, color is arbitrarily taken
Match, realizes perfect figure.
In order to achieve the above-mentioned object of the invention, the technical solution adopted by the present invention is as follows：
A kind of water-in-water type antibacterial multi-color, is mixed by base paint, Protection glue and varnish；Wherein according to parts by weight
Meter,
The base paint is made of following raw material：50-150 parts of aqueous elastic polyaminoester emulsion, 20-60 parts of kaolin, titanium
10-30 parts of white powder, 0-30 parts of environment friendly inorganic pigment, 5-10 parts of antiseptic, 1-10 parts of antifoaming agent, 1-10 parts of coalescents and water
100-300 parts；
The Protection glue is made of following raw material：30-80 parts of acrylic acid ester emulsion, 1-10 parts of preservative and water 100-300
Part；
The varnish is made of following raw material：Aqueous pure acrylate elastic emulsion 20-100 parts, 10-30 parts of waterproofing agent, thickener
0.5-5 parts and 30-80 parts of water；
The weight ratio of the base paint, Protection glue and varnish is 50-80：40-60：10-30.
Further, the environment friendly inorganic pigment is titanium yellow, titanium chromium palm fibre, iron zinc chrome is brown, siderochrome is black, cobalt green, cobalt blue, copper
Chrome black, compound titan yellow and composite titanium are one or more of red.
Further, the antiseptic is 1 by mass ratio：The polyhexamethylene guanide phosphate and polyhexamethylene guanide of 2-3
Hydrochloride forms.
Further, the antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether or polypropylene glycerol aether, and the film forming helps
Agent is polyesterols, polyvinyl alcohol or xanthans.
Further, the preservative is 2-methyl-4-isothiazolin-3-one or 5- chloro-2-methyl -4- isothiazolines -
3- ketone.
Further, the waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion；The thickener is that ethoxy is fine
Dimension element or carboxymethyl cellulose.
The present invention also provides the preparation methods of above-mentioned water-in-water type antibacterial multi-color, comprise the steps of：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide in proportion, stirs to thin
Spend ＜ 50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment,
It stirs evenly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, obtain
It is spare to Protection glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirring is equal
It is even, it is spare to obtain varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；
It mixes, stirs evenly with varnish obtained above again, obtain the water-in-water type antibacterial multi-color.
The effect of each component of the present invention：
Antifoaming agent can prevent the later stage from generating bubble in base paint, make the lubricated with coating made；Kaolin have thickening and
In raising the effect of high shear, while the toughness of particle can be increased；Titanium dioxide is used for improving covering；Environment friendly inorganic pigment is used for
Toning, can according to client need recall multiple color；Antiseptic uses guanidine bactericides, is a kind of environment-friendly type antimildew and antibacterial
Agent has extremely strong killing microorganism ability, and bactericidal range is wide, and bactericidal effect is long, has extremely strong kill to bacterium and fungi
Effect；Aqueous elastic polyaminoester emulsion makes colorful sealing wax that there is certain elasticity, thickness not to crack when applying, and there is certain covering to split
The effect of seam.
The environment friendly inorganic pigment is respectively the B5302 titanium yellows for being selected from the production of Hunan Ju Fa Science and Technology Ltd.s, B2406
Titanium chromium palm fibre, B3301 iron zinc chrome is brown, A2901 siderochrome is black, B5003 cobalt greens, B2805 cobalt blues, A2854 copper-chrome blacks, Y1001 composite titaniums
One or more of Huang and R3012 composite titaniums are red.There is the serial pigment good compatibility, not bleeding not to migrate,
Strong covering power, light resistance, weatherability, heat-resisting quantity, acid-fast alkali-proof reach highest, to light, heat, weather and chemicals
With excellent fastness.
Acrylic acid ester emulsion in Protection glue can make the color grain not bleeding made, and color grain cohesive force is strong, while increasing anti-
Rotten agent makes color grain have preservative efficacy.
Thickener is hydroxyethyl cellulose or carboxymethyl cellulose in varnish, can reduce splashing effects with Protection glue reaction；
Use aqueous fluorine richness phosphoric acrylic ester lotion for waterproofing agent, except it is with good resistance to possessed by conventional propylene acid resin
Outside hot, weatherability, water resistance, resistance to salt water, strong adhesive force, the anti-sudden strain of a muscle corrosion also having, and its is flexible, bright plentiful, resistance to
Mill has good physical mechanical property.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
（1）Aqueous elastic polyaminoester emulsion is added in raw material of the present invention makes colorful sealing wax that there is certain elasticity, thickness to apply
When do not crack, have the function of certain covering crack；
（2）Antiseptic is added in raw material of the present invention, antiseptic uses guanidine bactericides, is that a kind of environment-friendly type is mould proof anti-
Microbial inoculum has effects that efficient and lasting bactericidal, mould proof and expelling parasite；
（3）Raw material of the present invention uses environment friendly inorganic pigment, and not bleeding does not migrate；And this multicolor finish is decorative strong, it can
According to customer demand, various colors and creative element are recalled, there is very strong DIY；
（4）Raw material of the present invention is added to waterproofing agent, has the characteristics that waterproof, anti-pollution, uncomplicated laundering and scrubbable；
（5）Good, the imitative stone material fidelity of the colorful sealing wax aqueous, environmental protective of the present invention, stability is high, construction adjustable extent is big, attachment
Power is strong, gloss retention is strong, resistance to ag(e)ing is excellent, water-tolerant, easy for construction；Non-ignitable, not quick-fried, nuisanceless, low tempertaure storage never degenerates；
Also have the characteristics that convenient and quick construction, paint film flat smooth, feel are all good；It is at low cost, proportion is low, more compared to stone material
Environmental protection will not hurt sb.'s feelings because stone material falls off.
Specific implementation mode
All features disclosed in this specification or disclosed all methods or in the process the step of, in addition to mutually exclusive
Feature and/or step other than, can combine in any way.
This specification（Including any accessory claim, abstract）Disclosed in any feature, unless specifically stated,
It is replaced by other equivalent or with similar purpose alternative features.That is, unless specifically stated, each feature is a series of
An example in equivalent or similar characteristics.
The raw material of the present invention used can be commercially available on the market, and wherein environment friendly inorganic pigment is selected from Hunan Ju Fa sections
Skill Co., Ltd, aqueous fluorine richness phosphoric acrylic ester lotion are purchased from Xi'an Jialong Painting New Technology Development Co., Ltd..
Embodiment 1
A kind of water-in-water type antibacterial multi-color, is mixed by base paint, Protection glue and varnish；Wherein according to parts by weight
Meter,
The base paint is made of following raw material：150 parts of aqueous elastic polyaminoester emulsion, 20 parts of kaolin, titanium dioxide 30
Part, 5 parts of antiseptic, 10 parts of antifoaming agent, 1 part of coalescents and 300 parts of water；
Antiseptic is 1 by mass ratio：2 polyhexamethylene guanide phosphate and poly (hexamethylene) hydrochloride composition；Defoaming
Agent is polyoxyethylene polyoxy propyl alcohol amidogen ether；Coalescents are polyesterols；
The Protection glue is made of following raw material：100 parts of 30 parts of acrylic acid ester emulsion, 10 parts of preservative and water；Preservative
For 2-methyl-4-isothiazolin-3-one；
The varnish is made of following raw material：100 parts of aqueous pure acrylate elastic emulsion, 10 parts of waterproofing agent, 5 parts of thickener and water
30 parts；Waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion, and thickener is hydroxyethyl cellulose；
The weight ratio of the base paint, Protection glue and varnish is 80：40：30.
The preparation method of above-mentioned water-in-water type antibacterial multi-color, comprises the steps of：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide in proportion, stirs to thin
Spend ＜ 50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment,
It stirs evenly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, obtain
It is spare to Protection glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirring is equal
It is even, it is spare to obtain varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；
It mixes, stirs evenly with varnish obtained above again, obtain the water-in-water type antibacterial multi-color.
Embodiment 2
A kind of water-in-water type antibacterial multi-color, is mixed by base paint, Protection glue and varnish；Wherein according to parts by weight
Meter,
The base paint is made of following raw material：50 parts of aqueous elastic polyaminoester emulsion, 60 parts of kaolin, titanium dioxide 10
Part, 30 parts of environment friendly inorganic pigment, 10 parts of antiseptic, 1 part of antifoaming agent, 10 parts of coalescents and 100 parts of water；
It is 1 that environment friendly inorganic pigment, which has weight ratio,：1 titanium yellow and titanium chromium palm fibre composition；Antiseptic is 1 by mass ratio：3 it is poly-
Hexa-methylene guanidine phosphate and poly (hexamethylene) hydrochloride composition；Antifoaming agent is polypropylene glycerol aether；Coalescents are poly-
Vinyl alcohol；
The Protection glue is made of following raw material：100 parts of 30 parts of acrylic acid ester emulsion, 10 parts of preservative and water；Preservative
For 5-Chloro-2-methyl-4-isothiazolin-3-one；
The varnish is made of following raw material：100 parts of aqueous pure acrylate elastic emulsion, 10 parts of waterproofing agent, 5 parts of thickener and water
30 parts；Waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion, and thickener is carboxymethyl cellulose；
The weight ratio of the base paint, Protection glue and varnish is 50：60：10.
The preparation method of above-mentioned water-in-water type antibacterial multi-color, comprises the steps of：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide in proportion, stirs to thin
Spend ＜ 50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment,
It stirs evenly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, obtain
It is spare to Protection glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirring is equal
It is even, it is spare to obtain varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；
It mixes, stirs evenly with varnish obtained above again, obtain the water-in-water type antibacterial multi-color.
Embodiment 3
A kind of water-in-water type antibacterial multi-color, is mixed by base paint, Protection glue and varnish；Wherein according to parts by weight
Meter,
The base paint is made of following raw material：100 parts of aqueous elastic polyaminoester emulsion, 30 parts of kaolin, titanium dioxide 20
Part, 15 parts of environment friendly inorganic pigment, 8 parts of antiseptic, 6 parts of antifoaming agent, 8 parts of coalescents and 200 parts of water；
It is 1 that environment friendly inorganic pigment, which has weight ratio,：1：1：1 cobalt green, titanium chromium palm fibre, cobalt blue and copper-chrome black composition；Antiseptic by
Mass ratio is 1：2.5 polyhexamethylene guanide phosphate and poly (hexamethylene) hydrochloride composition；Antifoaming agent is that polyoxypropylene is sweet
Oily ether；Coalescents are xanthans；
The Protection glue is made of following raw material：200 parts of 50 parts of acrylic acid ester emulsion, 6 parts of preservative and water；Preservative is
2-methyl-4-isothiazolin-3-one；
The varnish is made of following raw material：80 parts of aqueous pure acrylate elastic emulsion, 20 parts of waterproofing agent, 2 parts of thickener and water
50 parts；Waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion, and thickener is carboxymethyl cellulose；
The weight ratio of the base paint, Protection glue and varnish is 70：50：20.
The preparation method of above-mentioned water-in-water type antibacterial multi-color, comprises the steps of：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide in proportion, stirs to thin
Spend ＜ 50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment,
It stirs evenly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, obtain
It is spare to Protection glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirring is equal
It is even, it is spare to obtain varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；
It mixes, stirs evenly with varnish obtained above again, obtain the water-in-water type antibacterial multi-color.
Embodiment 4
A kind of water-in-water type antibacterial multi-color, is mixed by base paint, Protection glue and varnish；Wherein according to parts by weight
Meter,
The base paint is made of following raw material：100 parts of aqueous elastic polyaminoester emulsion, 30 parts of kaolin, titanium dioxide 20
Part, 15 parts of environment friendly inorganic pigment, 8 parts of antiseptic, 6 parts of antifoaming agent, 8 parts of coalescents and 200 parts of water；
It is 1 that environment friendly inorganic pigment, which has weight ratio,：1 cobalt green and compound titan yellow composition；Antiseptic is 1 by mass ratio：2.5
Polyhexamethylene guanide phosphate and poly (hexamethylene) hydrochloride composition；Antifoaming agent is polypropylene glycerol aether；Coalescents are
Polyesterols；
The Protection glue is made of following raw material：200 parts of 50 parts of acrylic acid ester emulsion, 6 parts of preservative and water；Preservative is
5-Chloro-2-methyl-4-isothiazolin-3-one；
The varnish is made of following raw material：80 parts of aqueous pure acrylate elastic emulsion, 20 parts of waterproofing agent, 2 parts of thickener and water
50 parts；Waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion, and thickener is hydroxyethyl cellulose；
The weight ratio of the base paint, Protection glue and varnish is 60：55：25.
The preparation method of above-mentioned water-in-water type antibacterial multi-color, comprises the steps of：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide in proportion, stirs to thin
Spend ＜ 50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment,
It stirs evenly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, obtain
It is spare to Protection glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirring is equal
It is even, it is spare to obtain varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；
It mixes, stirs evenly with varnish obtained above again, obtain the water-in-water type antibacterial multi-color.
The water-in-water type antibacterial multi-color that embodiment 1-4 is prepared is carried out direct spraying construction or is sprayed using air
It applies, and according to national standard HG/T4343-2012《Aqueous water-water building coating》It is right with HG/T3950-2007 antibiotic paints
It carries out the detection of technical performance, and testing result is shown in Table 1.
Table 1
As shown in Table 1, this water-in-water type antibacterial multi-color intensity is high, mechanical performance is superior, also has antibacterial, waterproof, prevents
Pollution, uncomplicated laundering and scrubbable feature are suitble to promote and apply.
The invention is not limited in specific implementation modes above-mentioned.The present invention, which expands to, any in the present specification to be disclosed
New feature or any new combination, and disclose any new method or process the step of or any new combination.
Claims (4)
1. a kind of water-in-water type antibacterial multi-color, it is characterised in that：It is mixed by base paint, Protection glue and varnish；Wherein press
According to parts by weight meter,
The base paint is made of following raw material：50-150 parts of aqueous elastic polyaminoester emulsion, 20-60 parts of kaolin, titanium dioxide
10-30 parts, 0-30 parts of environment friendly inorganic pigment, 5-10 parts of antiseptic, 1-10 parts of antifoaming agent, 1-10 parts of coalescents and water 100-
300 parts；
The Protection glue is made of following raw material：100-300 parts of 30-80 parts of acrylic acid ester emulsion, 1-10 parts of preservative and water；
The varnish is made of following raw material：Aqueous pure acrylate elastic emulsion 20-100 parts, 10-30 parts of waterproofing agent, thickener 0.5-5
30-80 parts of part and water；
The weight ratio of the base paint, Protection glue and varnish is 50-80：40-60：10-30；
The environment friendly inorganic pigment is titanium yellow, titanium chromium palm fibre, iron zinc chrome is brown, siderochrome is black, cobalt green, cobalt blue, copper-chrome black, compound titan yellow
And composite titanium is one or more of red；
The antiseptic is 1 by mass ratio：The polyhexamethylene guanide phosphate and poly (hexamethylene) hydrochloride of 2-3 forms；
The waterproofing agent is aqueous fluorine richness phosphoric acrylic ester lotion；The thickener is hydroxyethyl cellulose or carboxymethyl
Cellulose.
2. water-in-water type antibacterial multi-color according to claim 1, it is characterised in that：The antifoaming agent is poly- for polyoxyethylene
Oxygen propyl alcohol amidogen ether or polypropylene glycerol aether, the coalescents are polyesterols, polyvinyl alcohol or xanthans.
3. water-in-water type antibacterial multi-color according to claim 2, it is characterised in that：The preservative is 2- methyl -4-
Isothiazoline -3- ketone or 5-Chloro-2-methyl-4-isothiazolin-3-one.
4. the preparation method of water-in-water type antibacterial multi-color according to any one of claims 1 to 3, it is characterised in that：By
Following steps form：
（1）The preparation of base paint：Stirring sequentially adds water, antifoaming agent, kaolin and titanium dioxide, stirring to fineness ＜ in proportion
50um；It is stirred for that aqueous elastic polyaminoester emulsion, antiseptic and coalescents are added, is eventually adding environment friendly inorganic pigment, stir
Uniformly, it is spare to obtain base paint；
（2）The preparation of Protection glue：Water is first added in proportion, adds acrylic acid ester emulsion and preservative, stirs evenly, protected
It is spare to protect glue；
（3）The preparation of varnish：Water, aqueous pure acrylate elastic emulsion, waterproofing agent and thickener are mixed in proportion, stirs evenly, obtains
It is spare to varnish；
（4）The preparation of multi-color：In proportion, base paint obtained above is mixed with Protection glue, is granulated after stirring evenly；Again with
Varnish mixing obtained above, stirs evenly, obtains the water-in-water type antibacterial multi-color.
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| CN110330832A (en) * | 2019-07-31 | 2019-10-15 | 龚卫伟 | A kind of graphene multicolor finish |
| CN111171614A (en) * | 2020-01-21 | 2020-05-19 | 南京双善节能科技有限公司 | Batch-scraping type marble-imitated paint and preparation method and application thereof |
| CN111978801B (en) * | 2020-08-19 | 2021-09-21 | 嘉宝莉化工集团股份有限公司 | Scraping type sand-in-water multicolor paint and preparation method thereof |
| CN112680079A (en) * | 2020-12-16 | 2021-04-20 | 北京三棵树新材料科技有限公司 | Exposable high-strength high-toughness water-in-water multicolor paint |
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