CN106380220A - Novel water permeable brick processing method - Google Patents
Novel water permeable brick processing method Download PDFInfo
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- CN106380220A CN106380220A CN201610783023.3A CN201610783023A CN106380220A CN 106380220 A CN106380220 A CN 106380220A CN 201610783023 A CN201610783023 A CN 201610783023A CN 106380220 A CN106380220 A CN 106380220A
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- permeable brick
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0003—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof containing continuous channels, e.g. of the "dead-end" type or obtained by pushing bars in the green ceramic product
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1328—Waste materials; Refuse; Residues without additional clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Road Paving Structures (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a novel water permeable brick processing method. Ingredients involved in the method comprise an adhesive which is obtained after high-temperature melting and cooling and has an adhesion effect and a stone material used as a water permeable brick main body structure. Preprocessing of the ingredients comprises the following process: the adhesive is ground into powder, and the stone material is crushed into particles. Preform compacting comprises the following process: the adhesive material powder and the granular stone are mixed and compacted to obtain a preform. High-temperature sintering comprises the following process: the preform is sent into a high temperature kiln to be sintered. The sintered preform is cooled to prepare the water permeable brick finished product. The product has good water permeability performance. The method is very suitable for road-building bricks for sponge cities. The whole processing is simple, and production period is short. The method can be rapidly applied to large-scale batch production and meets the huge market requirement.
Description
Technical field
The present invention relates to building material field is and in particular to a kind of novel water permeable brick processing method.
Background technology
Industrial development, while promoting the well-being of mankind, also creates a lot of industrial refuses, and these industrial refuses have become as
The great puzzlement of impact people's living environment.Such as traditional Metallurgy Industry can produce substantial amounts of slag, traditional glass work
Substantial amounts of glass slag can be produced, if the slag of this enormous amount and glass slag are disposed not in time, threat people's life can be become
The major hidden danger of environment, therefore how to realize the industrial wastes such as slag, glass slag turns waste into wealth, and becomes current environmental protection, science and technology, society
Hot research topic etc. each ambit.
Meanwhile, current domestic city construction faces the problem of a very serious urban waterlogging, runs into rainy season, most of
City all can occur serious city's internal water accumulation, and this serious urban waterlogging can cause very big destruction to urban infrastructure,
On the one hand the roadbed of city public way can be destroyed, destroy the ground of urban architecture and expose wall, on the other hand can flood
The retail shop of low-rise building, house and automobile etc., cause the damage of resident's property.
In the face of such problem, people start to consider that the method using water-permeable brick quickly to discharge city in urban construction
Hydrops, that is, build sponge-type city.Existing water-permeable brick mainly includes common water-permeable brick, polymer fiber concrete permeable
Brick, colored stone composite concrete permeable brick, colored stone epoxy entire body water-permeable brick, concrete permeable brick and ecological sand base water-permeable brick, its
Using processing technology be usually compacting or in-situ casting method, its use raw material be generally granite, river sand, desert
Sand etc., and it is used cement, epoxy resin, polypropylene fibre or other raw materials to make the making of water-permeable brick as binding agent
With high costs, effectively do not use such as slag, the such industrial waste of glass slag simultaneously yet.
The patent of Publication No. CN105016642 A discloses a kind of environmental protection and energy saving slag water-permeable brick and preparation method thereof,
Described slag water-permeable brick includes basic unit：40～75 parts of slag, 5～25 parts of grain slag, 5～25 parts of stone powder, 0～10 part of flyash, water
8～25 parts of mud, 10 parts of water；Surface layer：0～80 part of slag, 0～80 part of sand, 15～30 parts of white cement, 0～5 part of toner, water 10
Part；Groundwork thickness is the 5%～20% of slag water-permeable brick gross thickness.Described preparation method includes：Weigh basic unit by formula respectively
And face stock；By basic unit and face stock mix homogeneously respectively, first raw material mixing in addition to water is added again during raw material mixing
Water, respectively obtains basic unit and surface layer material.Basic unit's material is sent in mould, by the one-shot forming that impulses；Again by surface layer material
Send into and be furnished with the mould of base material, by the post forming that impulses；By adobe natural curing 1～2 day at room temperature, dimensionally stable
Pile afterwards, then through room temperature natural curing in 28～30 days, the production cycle of the method at one month about, for large-scale
For building demand, such production cycle oversize it is impossible to meet growing market demand.
Content of the invention
For the deficiencies in the prior art, the present invention provides a kind of new as the water-permeable brick processing of raw material with common building stones
Technology, by mixing compressing by binding agent with common building stones and high-temperature firing forms water-permeable brick, water permeability is good, physics is strong
Degree is high, convenience of drawing materials, and can carry out large-scale production.
Technical scheme is as follows：
A kind of novel water permeable brick processing method, comprises the following steps：
S1, dispensing：Described dispensing plays the binding agent of adhesion effect after including high temperature melting cooling, and as water-permeable brick
The building stones of main structure body；
S2, dispensing preprocessing：Binding agent is milled to powder, stone powder is broken into granule；
S3, compacting prefabricated component：Binder materials powder and the mixing of granular building stones are pressed into prefabricated component；
S4, high-temperature firing：Prefabricated component is sent in high temperature kiln and carries out calcination；
S5, cooling：Prefabricated component through calcination is carried out cooling down and makes water-permeable brick finished product.
In above-mentioned steps, binding agent selection principle is that heating can be melted, and can be attached to the industry on building stones after cooling
Waste material, bottom fusing point building stones etc., binding agent can be single substance or many kinds of substance mixture, only requires that it acts primarily as
The melting point substance of adhesive effect is less than the fusing point of building stones, can condense between irregular building stones granule i.e. after heating fusing cooling
Can, the selection of building stones can be the stone material of modal hardness is bigger, to reduce building stones cost, if binder materials are inherently
Powder, then can save grinding process.
Preferably, by weight, described adhesive is 8-20 part, and described building stones are 80-92 part, bonding
The effect of agent is that heating fusing cooling condenses between irregular building stones granule, plays reinforcement effect, unsuitable excessive, otherwise may lead
Cause all to block the permeable space between building stones granule.
Preferably, described building stones are granite and/or basalt, and granite and basalt are all that distributed pole is wide
Building stones, first take conveniently, cost is extremely low.
Preferably, described binding agent is one or more of slag, glass slag, feldspar powder, slag and glass slag
As industrial waste, cost is extremely low, can condense on building stones after heating, and viscous full effect is good, is preferable binder materials；Long
Stone is also the relatively low building stones distributed more widely of price, and its fusing point is lower than general building stones fusing point, is also preferable binder materials.
As preferably embodiment, described binding agent is slag, and by weight, described slag is 12-15 part,
Described building stones 85-88 part,
As preferably embodiment, described binding agent is glass slag, and by weight, described glass slag is 12-15 part,
Described building stones 85-88 part.
As preferably embodiment, described binding agent is slag and glass slag mixture, by weight, described slag
It is 12-15 part with glass slag, described building stones 85-88 part, wherein, slag is 1 with the weight proportion relation of glass slag:1.
Preferably, described building stones grain diameter is 1-6mm.
As preferably embodiment, in described building stones granule, building stones grain diameter is 1-4mm, and by weight,
Particle diameter is 15-30 part for 1-2mm；Particle diameter is 40-70 part for 2-3mm；Particle diameter is 15-30 part for 3-4mm；By different size
Building stones granule be distributed in proportion, can preferably reach permeable effect.
Preferably, described prefabricated component calcination step S4, also includes following step：
S41, by prefabricated component feeding preheating chamber preheated, wherein preheating temperature is gradually risen to 600 DEG C by 60 DEG C, preheating
Time is 4-8h.
S42, by prefabricated component feeding the room of burning till carry out high-temperature firing, the wherein temperature control of high-temperature firing at 800 DEG C extremely
1400 DEG C, the firing time is 4-8h, and high-temperature firing temperature is chosen different according to building stones and binding agent and can be set different temperature,
With higher than and binding agent fusing point and be advisable less than building stones fusing point, the high-temperature firing time is advisable with most of fusing of binding agent.
The beneficial effects of the present invention is：
1st, processing technique of the present invention is simple, and selection is convenient, cost the bottom of compared with, due to using building stones as brick main body, hardness is bigger,
The permeable effect of water-permeable brick preferably, is especially suitable for sponge urban pavement building brick.Whole process of the present invention is simple, consuming
With short production cycle, can quickly put into large-scale batch production process, meet huge market demand.
2nd, the present invention can take full advantage of the industrial waste such as slag and glass slag and makees binding agent, on the one hand achieve resource
Recycling, has the objective effect turned waste into wealth, on the other hand also solves the industrial wastes such as slag, glass slag to ecological environment
The threat causing, has positive environment protection significance.
3rd, water-permeable brick major ingredient involved in the present invention is based on the common building stones such as granite, basalt it is also possible to be selected to
, as binding agent, cost is low for the feldspar powder at this relatively bottom, has according to the water-permeable brick manufactured goods that the method for the present invention produces
Aqueouss can good, the high advantage of physical strength.
Figure of description
Fig. 1 is the overall flow figure of the present invention；
Fig. 2 is high-temperature firing detailed step of the present invention；
Fig. 3 is the permeable brick structure schematic diagram using present invention processing.
Specific embodiment
In order to be more clearly understood from process, technical scheme and the beneficial effect of the present invention, below in conjunction with the accompanying drawings to this
Bright be described further, but not by protection scope of the present invention limit in the examples below, all bases in this method
The replacement made under present principles, modification all should fall into protection scope of the present invention.
It is the flow process of the present invention as shown in Figure 1 and Figure 2, concrete work flow is as follows：
Step S1, dispensing：Described dispensing plays the binding agent of adhesion effect after including high temperature melting cooling, and as thoroughly
The building stones of water brick structure main body；Binding agent selection principle is that heating can be melted, and can be attached to the Industry Waste on building stones after cooling
Material, bottom fusing point building stones etc., binding agent can be single substance or many kinds of substance mixture, only requires that it acts primarily as viscous
The melting point substance of cooperation is less than the fusing point of building stones, can condense between irregular building stones granule i.e. after heating fusing cooling
Can, such as slag, glass slag, feldspar powder, marble dust etc..Due in the present invention can be numerous with the raw material for binding agent, here be not
Illustrate one by one, every binding agent that can implement the present invention by the principle of the invention, belong to the scope of the present invention.Building stones select
It is taken as most common and hardness is bigger stone material, such as granite, basalt etc., to reduce building stones cost.The effect of binding agent is to add
Heat fusing cooling condenses between irregular building stones granule, plays reinforcement effect, unsuitable excessive, otherwise may lead to building stones granule
Between permeable space all block it is however generally that, by weight, by binding agent 8-20 part, building stones 80-92 part can be real
Apply, preferable proportioning is in binding agent 12-15 part, building stones 85-88 part.
Step S2, dispensing preprocessing：Binding agent is milled to powder, stone powder is broken into granule；If binder materials are originally
Body is exactly powder, then can save grinding process.Building stones grain diameter is advisable in 1-6mm, preferably 1-4mm, and building stones granule is
Well that size is all distributed, so to form permeable space, in specifically implementing ground journey, building stones can be smashed be divided into many
Class, the building stones granule of different-grain diameter is chosen in proportion, can make the water-permeable brick of different permeability rates.Because building stones granule is not advise
Then, when sieve takes the granule of different-grain diameter, top can be pressed by the circular hole sizer of different-diameter and sieve for large aperture, bottom is little
Aperture sieve, from top to bottom aperture be sequentially reduced order arrangement, the building stones granule staying between different layerings is corresponding particle diameter
Building stones granule, can not pass through the round sieve of 1mm diameter but can pass through the round sieve of 2mm diameter, then for 1-2mm particle diameter class
Building stones granule is it is impossible to by the round sieve of 2mm diameter but can pass through the round sieve of 3mm diameter, then for 2-3mm particle diameter class stone
Material granule, by that analogy.Should be noted when, finally need to screen out less than 1mm building stones powder, with prevent too small building stones powder block up
Fill in permeable space.The good water-permeable brick of water permeability all can be processed into by the following is several building stones grain mixture ratios：
Step S3, compacting prefabricated component：Binder materials powder and the mixing of granular building stones are pressed into prefabricated component；Will
Binder materials powder and building stones granule are mixed and are stirred, and then send binding agent and building stones granulate mixture
Enter press strength and be pressed into prefabricated component, prefabricated component by building brick size compacting it is also possible to according to market demand adjust
Preform sizes.
Step S4, high-temperature firing：Prefabricated component is sent in high temperature kiln and carries out calcination；Prefabricated component is put on chassis, in advance
Leave certain space between product, first, prefabricated component feeding preheating chamber is preheated, wherein preheating temperature is by 60 DEG C gradually
It is increased to 600 DEG C, preheating time is 4-8h；Secondly, the prefabricated component feeding room of burning till is carried out high-temperature firing, wherein high-temperature firing exists
Between 800 DEG C to 1400 DEG C, the firing time is 4-8h.Should be noted during high-temperature firing when, high-temperature firing temperature root
Choose different according to building stones and binding agent and different temperature can be set, with higher than and binding agent fusing point and be less than building stones fusing point
Preferably.In sintering procedure, adhesive melts, gradually permeate between the building stones granule as brick laying structure main body, and utilize
During cooling, building stones granule is bonded together.
Step S5, cooling：Prefabricated component through calcination is carried out cooling down and makes water-permeable brick finished product；After the completion of firing, so
Start chassis afterwards, cooled down firing the prefabricated component that completes and being sent into cooling chamber from the room of burning till, due to the binding agent of fusing
Can condense in cooling procedure around building stones granule and building stones grain contact point, play the effect of fixing building stones granule, meanwhile,
The non-contacting place of irregular building stones granule, can be formed with more lacunose permeable structure, thus it is preferable to make permeable effect
Water-permeable brick finished product.
As shown in figure 3, being the permeable brick structure schematic diagram being processed using the present invention, because building stones granule 1 is not advise
Then, in prefabricated component pressing process, more permeable space 2 can be formed between building stones granule 1, and when heating is fired,
Metal in slag or other fusible materials can melt, but due to building stones granule 1 fusing point higher moreover it is possible to keep original shape
Shape, in cooling procedure, slag molten metal or other fusible materials can contact local condensation in building stones granule 1, thus shape
Become ruggedized construction and in the more permeable space 2 of irregular building stones granule intermediate formation.Using glass slag and feldspar powder etc., other glue
The effect that mixture produces is similar with slag.
Claims (10)
1. a kind of novel water permeable brick processing method is it is characterised in that comprise the following steps：
S1, dispensing：Described dispensing plays the binding agent of adhesion effect after including high temperature melting cooling, and as permeable brick structure
The building stones of main body.
S2, dispensing preprocessing：Binding agent is milled to powder, stone powder is broken into granule；
S3, compacting prefabricated component：Binder materials powder and the mixing of granular building stones are pressed into prefabricated component；
S4, high-temperature firing：Prefabricated component is sent in high temperature kiln and carries out calcination；
S5, cooling：Prefabricated component through calcination is carried out cooling down and makes water-permeable brick finished product.
2. it is characterised in that by weight, described adhesive is 8- to water-permeable brick processing method according to claim 1
20 parts, described building stones are 80-92 part.
3. water-permeable brick processing method according to claim 2 is it is characterised in that described building stones are granite and/or profound
Wu Yan.
4. water-permeable brick processing method according to claim 3 is it is characterised in that described binding agent is slag, glass slag, length
One or more of stone powder.
5. water-permeable brick processing method according to claim 4 is it is characterised in that described binding agent is slag, by weight
Part meter, described slag is 12-15 part, described building stones 85-88 part.
6. water-permeable brick processing method according to claim 4 is it is characterised in that described binding agent is glass slag, by weight
Part meter, described glass slag is 12-15 part, described building stones 85-88 part.
7. water-permeable brick processing method according to claim 4 is it is characterised in that described binding agent is slag and glass slag mixes
Compound, by weight, described slag and glass slag are 12-15 part, described building stones 85-88 part, wherein, slag and glass slag
Weight proportion relation is 1:1.
8. water-permeable brick processing method according to claim 3 is it is characterised in that described building stones grain diameter is 1-6mm.
9. water-permeable brick processing method according to claim 3 is it is characterised in that described building stones grain diameter is 1-4mm,
In described building stones granule, by weight, particle diameter is 15-30 part for 1-2mm；Particle diameter is 40-70 part for 2-3mm；Particle diameter
It is 15-30 part for 3-4mm.
10. water-permeable brick processing method according to claim 3 is it is characterised in that described prefabricated component calcination step S4, also
Including following step：
S41, by prefabricated component feeding preheating chamber preheated, wherein preheating temperature is gradually risen to 600 DEG C by 60 DEG C, preheating time
For 4-8h.
S42, by prefabricated component feeding the room of burning till carry out high-temperature firing, the wherein temperature control of high-temperature firing at 800 DEG C to 1400 DEG C,
Firing time is 4-8h.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821758A (en) * | 2018-07-09 | 2018-11-16 | 山东理工大学 | The water-permeable brick and preparation method thereof prepared with granite building material waste material |
| CN110642595A (en) * | 2019-10-10 | 2020-01-03 | 郑州大学 | Ceramic water permeable brick and preparation method thereof |
| CN113716939A (en) * | 2021-09-30 | 2021-11-30 | 五莲宏邦资源循环科技有限公司 | Multi-mixing amount sawn mud square brick and preparation method thereof |
| CN114573353A (en) * | 2022-03-16 | 2022-06-03 | 正蓝旗祥升环保建材有限责任公司 | Method for manufacturing ceramic water-permeable sintered brick |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821758A (en) * | 2018-07-09 | 2018-11-16 | 山东理工大学 | The water-permeable brick and preparation method thereof prepared with granite building material waste material |
| CN108821758B (en) * | 2018-07-09 | 2021-05-07 | 山东理工大学 | Water permeable brick prepared from granite stone waste and preparation method thereof |
| CN110642595A (en) * | 2019-10-10 | 2020-01-03 | 郑州大学 | Ceramic water permeable brick and preparation method thereof |
| CN110642595B (en) * | 2019-10-10 | 2022-03-29 | 郑州大学 | Ceramic water permeable brick and preparation method thereof |
| CN113716939A (en) * | 2021-09-30 | 2021-11-30 | 五莲宏邦资源循环科技有限公司 | Multi-mixing amount sawn mud square brick and preparation method thereof |
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Application publication date: 20170208 |