CN106350253A - 一种洗衣机清洁片及其制备方法 - Google Patents
一种洗衣机清洁片及其制备方法 Download PDFInfo
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- CN106350253A CN106350253A CN201610713238.8A CN201610713238A CN106350253A CN 106350253 A CN106350253 A CN 106350253A CN 201610713238 A CN201610713238 A CN 201610713238A CN 106350253 A CN106350253 A CN 106350253A
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- washing machine
- cleansing tablet
- acid
- tablet according
- water
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- 238000005406 washing Methods 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000004140 cleaning Methods 0.000 title abstract description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011976 maleic acid Substances 0.000 claims abstract description 9
- 239000011780 sodium chloride Substances 0.000 claims abstract description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 9
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 7
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011975 tartaric acid Substances 0.000 claims abstract description 7
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 13
- -1 polyoxyethylene Polymers 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
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- 239000008273 gelatin Substances 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 230000001788 irregular Effects 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 4
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920002257 Plurafac® Polymers 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 150000001241 acetals Chemical class 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 229940014259 gelatin Drugs 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 229940032147 starch Drugs 0.000 claims description 2
- 150000003509 tertiary alcohols Chemical group 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical class [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000008118 PEG 6000 Substances 0.000 abstract description 4
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 2
- 235000019832 sodium triphosphate Nutrition 0.000 abstract description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 abstract 1
- 235000015165 citric acid Nutrition 0.000 abstract 1
- 239000000686 essence Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- MSXHSNHNTORCAW-GGLLEASOSA-M sodium;(2s,3s,4s,5r,6s)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O MSXHSNHNTORCAW-GGLLEASOSA-M 0.000 abstract 1
- 239000003826 tablet Substances 0.000 description 18
- 239000003599 detergent Substances 0.000 description 5
- 229920006243 acrylic copolymer Polymers 0.000 description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 3
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000000176 sodium gluconate Substances 0.000 description 3
- 235000012207 sodium gluconate Nutrition 0.000 description 3
- 229940005574 sodium gluconate Drugs 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- SBNFWQZLDJGRLK-UHFFFAOYSA-N phenothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
本发明涉及洗涤剂领域，特别是涉及一种洗衣机清洁片及其制备方法。一种洗衣机清洁片，该清洁片由以下的组分构成：柠檬酸、酒石酸、纯碱、STPP、低泡非离子表面活性剂、软水剂、葡糖糖酸钠、丙烯酸/马来酸共聚物、氨基磺酸、香精、氯化钠、PEG6000和元明粉。该产品去除油污、去除水垢好，除菌效果好，可用于自动洗衣机，以及其他容易形成水垢或碱性污垢领域的清洁。
Description
技术领域
本发明涉及洗涤剂领域，特别是涉及一种洗衣机清洁片及其制备方法。
背景技术
传统的洗衣液主要活性物质为直链十二烷基苯磺酸盐和其他助洗剂；直链十二烷基苯磺酸盐来源于石化产品，属于不可再生原料，且该原料不耐硬水，在自来水环境下去污力大大降低，不利于洗涤；其他助剂，4A沸石、如三聚磷酸钠含有磷、不利于环境保护；铝，纯碱、烧碱碱性较高，易使衣物褪色，损伤衣物；芒硝属于填充物，无效循环利用，会给运营带来不必要的浪费。此外，普通液体洗涤剂利用常规表面活性剂和碱性助剂，仅具有洗涤清洁作用。但是对于可用于自动洗衣机，以及其他容易形成水垢或碱性污垢则很难通过传统的洗衣液进行清洗。
发明内容
为了解决上述的技术问题，本发明的一个目的是提供一种洗衣机清洁片，该产品去除油污、去除水垢好，除菌效果好，可用于自动洗衣机，以及其他容易形成水垢或碱性污垢领域的清洁。本发明的另外一个目的是提供上述的洗衣机清洁片的制备方法。
为了实现上述的第一个目的，本发明采用了以下的技术方案：
一种洗衣机清洁片，该清洁片按质量百分比计由以下的组分构成：
本发明使用的时候采用柠檬酸、酒石酸、氨基磺酸和纯碱反应，释放出二氧化碳，使片体崩解。酸类含量增多，片体容易吸潮变软，不稳定；酸类含量减少，酸度过低，无法满足功能需求。
作为优选，该清洁片按质量百分比计由以下的组分构成：
作为优选，该清洁片中柠檬酸含量8-12％、酒石酸含量15-18％、氨基磺酸含量5-11％，纯碱含量5-7％，且纯碱中轻质纯碱：重质纯碱＝1：2-1:1。该技术方案效果最好，且容易压制成型。
作为优选，所述的低泡非离子表面活性剂选用脂肪醇聚氧乙烯醚和/或脂肪醇聚氧乙烯-聚氧丙烯醚；作为优选，所述的脂肪醇选用直链和支链的伯醇、仲醇、叔醇的单一构成或混合物，聚氧乙烯、聚氧丙烯的聚合为均聚或共聚；作为再优选，低泡非离子表面活性剂选用巴斯夫Plurafac LF系列、Lutensol XL系列、Lutensol AT系列，以及NIPPONSHOKUBAI公司SOFTNOL系列或克莱恩的GENAPL EP系列。
作为优选，所述的低泡非离子表面活性剂为液体类型成分时为1％-2％，低泡非离子表面活性剂为固体成分时为2％-4％。采用上述技术方案，泡沫适中，效果满意。固体表面活性剂增多，泡沫过多，容易损伤自动洗碗机循环泵；液体表面活性剂超过2％，粉体流动性极差，不利压制成片，且产品容易受潮。
作为优选，所述的软水剂选用EDTA钠盐或有机膦酸盐。
作为优选，所述的香精选用柠檬、橙或橘子香型。
为了实现上述的第二个目的，本发明采用了以下的技术方案：
一种制备上述任意一个技术方案所述的洗衣机清洁片的方法，该方法包括以下的步骤：
1)纯碱、STPP、氯化钠和元明粉先进行混匀，加入表面活性剂和香精，其他原料最后加入，pH值控制在1.5-4.0；
2)经过压片，形成规则或不规则几何体；
3)然后用水溶性膜进行包装。
作为优选，形成的几何体为长方体、正方体、圆柱体、圆锥体、橄榄型或球型。
作为优选，包装方式选用水封或热封；水溶选用聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
本发明由于采用了上述的技术方案，该产品去除油污、去除水垢好，除菌效果好，可用于自动洗衣机，以及其他容易形成水垢或碱性污垢领域的清洁。该产品是新一代紧密型洗涤产品，定量包装，可以防止传统的添加方式(用勺子舀或直接倒出)可能造成量太少降低清洁能力，或者添加量过大造成浪费，甚至对清洗对象腐蚀。水溶膜包装，外包装水溶膜可直接溶解于水，无需拆开，方便环保，不伤手。使用过程不直接接触产品，减少产品对皮肤的刺激，更安全卫生。
具体实施方式
实施例1
一种洗衣机清洁片，该清洁片按质量百分比计有以下的组分构成：
| 柠檬酸 | 8 |
| 酒石酸 | 16 |
| 纯碱 | 5 |
| STPP | 4 |
| 低泡非离子表面活性剂 | 4 |
| 软水剂 | 0.5 |
| 葡糖糖酸钠 | 4 |
| 丙烯酸/马来酸共聚物 | 0.5 |
| 氨基磺酸 | 10 |
| 香精 | 0.2 |
| 氯化钠 | 25 |
| PEG 6000 | 2.8 |
| 元明粉 | 20 |
一种制备上述的洗衣机清洁片的方法，该方法包括以下的步骤：
1)纯碱、STPP、氯化钠和元明粉先进行混匀，加入表面活性剂和香精，其他原料最后加入，pH值控制在1.5-4.0；
2)经过压片，形成规则或不规则几何体；形成的几何体为长方体、正方体、圆柱体、圆锥体、橄榄型或球型；
3)然后用水溶性膜进行包装；包装方式选用水封或热封；水溶选用聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
效果验证：
1.去除油污
分别对人为沾染同一批粘土-油污污渍的陶瓷片进行洗涤，称量洗前和洗后污渍的重量，计算污渍去除率。
洗涤浓度：每13升水放一片机洗片。对照组：每次用120Ml清洁剂。
洗涤次数：分别5次
使用机洗片，可以更好的清洁机器内隐藏的污垢，达到清洁的目的，而且使用量是普通清洁剂的20％。
2.去除水垢
相同时间内(2小时)，清洁剂对水垢的溶解率为1.37％，加入机洗片，溶解率可达2.24％。具有明显的除垢效果。
3.除菌
杀菌挑战性试验证明：在自动洗碗机常用的洗涤温度下(65℃)，加入洗碗片(1片/10L水)，半小时内可使金黄色葡萄球菌(ATCC 6538)含量从7.8×106CFU/ml(Log10＝6.89)下降到＜100CFU/ml(Log10＝2.0)，杀菌率超过99.99％；可使大肠杆菌(ATCC 10536)含量从4.4×106CFU/ml(Log10＝6.64)下降到＜100CFU/ml(Log10＝2.0)，杀菌率超过99.99％。
4.同类产品对比
*满意度测评有测试者评感官打分，每种试验样品选用十组测试者，满分10分，求平均值。
实施例2
一种洗衣机清洁片，该清洁片按质量百分比计有以下的组分构成：
| 柠檬酸 | 10 |
| 酒石酸 | 12 |
| 纯碱 | 7 |
| STPP | 3 |
| 低泡非离子表面活性剂 | 5 |
| 软水剂 | 0.5 |
| 葡糖糖酸钠 | 3 |
| 丙烯酸/马来酸共聚物 | 0.5 |
| 氨基磺酸 | 14 |
| 香精 | 0.2 |
| 氯化钠 | 24 |
| PEG 6000 | 1.8 |
| 元明粉 | 19 |
一种制备上述的洗衣机清洁片的方法，该方法包括以下的步骤：
1)纯碱、STPP、氯化钠和元明粉先进行混匀，加入表面活性剂和香精，其他原料最后加入，pH值控制在1.5-4.0；
2)经过压片，形成规则或不规则几何体；形成的几何体为长方体、正方体、圆柱体、圆锥体、橄榄型或球型；
3)然后用水溶性膜进行包装；包装方式选用水封或热封；水溶选用聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
实施例3
一种洗衣机清洁片，该清洁片按质量百分比计有以下的组分构成：
| 柠檬酸 | 12 |
| 酒石酸 | 14 |
| 纯碱 | 6 |
| STPP | 5 |
| 低泡非离子表面活性剂 | 3 |
| 软水剂 | 0.5 |
| 葡糖糖酸钠 | 5 |
| 丙烯酸/马来酸共聚物 | 0.5 |
| 氨基磺酸 | 12 |
| 香精 | 0.2 |
| 氯化钠 | 26 |
| PEG 6000 | 1.8 |
| 元明粉 | 14 |
一种制备上述的洗衣机清洁片的方法，该方法包括以下的步骤：
1)纯碱、STPP、氯化钠和元明粉先进行混匀，加入表面活性剂和香精，其他原料最后加入，pH值控制在1.5-4.0；
2)经过压片，形成规则或不规则几何体；形成的几何体为长方体、正方体、圆柱体、圆锥体、橄榄型或球型；
3)然后用水溶性膜进行包装；包装方式选用水封或热封；水溶选用聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
Claims (10)
1.一种洗衣机清洁片，其特征在于该清洁片按质量百分比计由以下的组分构成：
2.根据权利要求1所述的一种洗衣机清洁片，其特征在于该清洁片按质量百分比计由以下的组分构成：
3.根据权利要求1所述的一种洗衣机清洁片，其特征在于该清洁片中柠檬酸含量8-12％、酒石酸含量15-18％、氨基磺酸含量5-11％，纯碱含量5-7％，且纯碱中轻质纯碱：重质纯碱＝1：2-1:1。
4.根据权利要求1所述的一种洗衣机清洁片，其特征在于低泡非离子表面活性剂选用脂肪醇聚氧乙烯醚和/或脂肪醇聚氧乙烯-聚氧丙烯醚；作为优选，所述的脂肪醇选用直链和支链的伯醇、仲醇、叔醇的单一构成或混合物，聚氧乙烯、聚氧丙烯的聚合为均聚或共聚；作为再优选，低泡非离子表面活性剂选用巴斯夫Plurafac LF系列、Lutensol XL系列、Lutensol AT系列，以及NIPPON SHOKUBAI公司SOFTNOL系列或克莱恩的GENAPL EP系列。
5.根据权利要求4或5或6所述的一种洗衣机清洁片，其特征在于低泡非离子表面活性剂为液体类型成分时为1％-2％，低泡非离子表面活性剂为固体成分时为2％-4％。
6.根据权利要求1或2所述的一种洗衣机清洁片，其特征在于软水剂选用EDTA钠盐或有机膦酸盐。
7.根据权利要求1或2所述的一种洗衣机清洁片，其特征在于香精选用柠檬、橙或橘子香型。
8.一种制备权利要求1～7任意一项权利要求所述的洗衣机清洁片的方法，其特征在于该方法包括以下的步骤：
1)纯碱、STPP、氯化钠和元明粉先进行混匀，加入表面活性剂和香精，其他原料最后加入，pH值控制在1.5-4.0；
2)经过压片，形成规则或不规则几何体；
3)然后用水溶性膜进行包装。
9.根据权利要求8所述的洗衣机清洁片的制备方法，其特征在于形成的几何体为长方体、正方体、圆柱体、圆锥体、橄榄型或球型。
10.根据权利要求8所述的洗衣机清洁片的制备方法，其特征在于包装方式选用水封或热封；
水溶选用聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
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