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CN106350126A - Alcohol-based fuel with low tail gas emission load - Google Patents

Alcohol-based fuel with low tail gas emission load Download PDF

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Publication number
CN106350126A
CN106350126A CN201610869793.XA CN201610869793A CN106350126A CN 106350126 A CN106350126 A CN 106350126A CN 201610869793 A CN201610869793 A CN 201610869793A CN 106350126 A CN106350126 A CN 106350126A
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parts
weight portion
alcohol
based fuel
antioxidant
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CN201610869793.XA
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Inventor
蒙呈星
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Guangxi Tonki Energy Technology Co Ltd
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Guangxi Tonki Energy Technology Co Ltd
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Priority to CN201610869793.XA priority Critical patent/CN106350126A/en
Publication of CN106350126A publication Critical patent/CN106350126A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224Amides; Imides carboxylic acid amides, imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C10L1/233Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20Mixture of two components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention belongs to the technical field of fuels, and particularly relates to an alcohol-based fuel with low tail gas emission load. The alcohol-based fuel is prepared from the following raw materials in parts by weight: 68 to 92 parts of methyl alcohol, 16 to 34 parts of diesel oil, 0.7 to 1.9 parts of methacrylamide, 0.2 to 1.4 parts of 4-aza-benzo imidazole, 0.02 to 0.14 part of cyclohexyl nitrate, 0.3 to 1.5 parts of glycerin, 0.1 to 1.3 parts of aliphatic ester, 0.01 to 0.07 part of sodium dodecyl benzene sulfonate, 0.03 to 0.15 part of dimethyl carbonate, and 0.1 to 1.3 parts of antioxidant. The alcohol-based fuel with low tail gas emission load provided by the invention has the functions of purification, oxidation resistance, combustion supporting, corrosion resistance, freeze resistance, dispersion, lubrication and cetane number improvement, and the tail gas emission load can be remarkably reduced.

Description

The alcohol-based fuel of low exhaust gas discharge capacity
Technical field
The invention belongs to fuel technology field, particularly to a kind of alcohol-based fuel of low exhaust gas discharge capacity.
Background technology
Oil as a kind of non-renewable resources, excessive exploitation and use, the use especially on vehicle fuel, Cause the severe contamination of environment, if calculating with current depletion rate, petroleum resources can be depleted in the near future.? Under current severe situation, how to save diesel oil, reduce the pollution to environment for the diesel combustion emission, become the heat of this area Point.
At present, motor vehicle exhaust discharge has become each metropolitan primary pollution source in the world.And automobile engine with The continuous service of vehicle, can the department such as involuntary throttle body in engine interior, atomizer, cylinder produce greasy filth, Carbon distribution etc. affects the normal material running of automobile.If ignoring the presence of greasy filth and carbon distribution, they slowly swallow engine power, Reduce fuel economy, increase the material discharge of pollution environment, and may result in a series of engine failure.
With the raising of China's economic development and people's living standard, social, alcohol increasing to the demand of clean energy resource Base liquid fuel is because of its clean environment firendly, and progressively becomes novel alternative fuel.Alcohol-based fuel refer to alcohols (mainly methanol or Crude glycol) for main modulation liquid fuel, be a kind of cheap, clean energy resource of environmental protection.Because alcohol-based fuel itself is oxygen-containing, during burning Aerobic less, fuel combustion is abundant.In the market alcohol-based fuel title differ, composition numerous and diverse, mixed based on methanol or crude glycol Plus many petrochemical industry by-products, cause the smoke emissioning pollution thing after exhaust combustion alcohol-based fuel exceeded.Therefore, research and develop one kind Can reach diesel oil using standard and the alcohol-based fuel of exhaust emissions amount can be reduced become extremely important.
Content of the invention
The technical problem to be solved be provide low exhaust gas discharge capacity alcohol-based fuel, this fuel have peace and quiet, Antioxidation, combustion-supporting, anticorrosive, freeze proof, dispersion, lubrication, improves Cetane number effect, can significantly reduce exhaust emissions amount.
For achieving the above object, the present invention adopts the following technical scheme that
The present invention provides the alcohol-based fuel of low exhaust gas discharge capacity, is made up of the raw material of following weight portion: 68~92 parts of methanol, 16~34 parts of diesel oil, 0.7~1.9 part of Methacrylamide, 0.2~1.4 part of 4- azabenzimidazoles, cyclohexyl nitrate 0.02~ 0.14 part, 0.3~1.5 part of glycerol, 0.1~1.3 part of fatty acid ester, 0.01~0.07 part of dodecylbenzene sodium sulfonate, carbonic acid 0.03~0.15 part of dimethyl ester, 0.1~1.3 part of antioxidant.
Antioxidant of the present invention is 8~20 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 5~17 weight Part 2,4 dimethylanilines and the mixture of 1~7 weight portion ditertbutylparacresol.Antioxidant prevents diesel oil in storage process The colloid sediment that middle oxidation generates, the colloid being dissolved in use in fuel deposits suction system because of carburretion and atomization System, the normal operation of impact electromotor, improves the bin stability of fuel.
Preferably, the alcohol-based fuel of low exhaust gas discharge capacity of the present invention, is made up of the raw material of following weight portion: methanol 72~88 parts, 19~31 parts of diesel oil, 0.9~1.7 part of Methacrylamide, 0.4~1.2 part of 4- azabenzimidazoles, nitric acid ring 0.04~0.12 part of own ester, 0.5~1.3 part of glycerol, 0.3~1.1 part of fatty acid ester, dodecylbenzene sodium sulfonate 0.02~ 0.06 part, 0.05~0.13 part of dimethyl carbonate, 0.3~1.1 part of antioxidant.
It is highly preferred that the alcohol-based fuel of low exhaust gas discharge capacity of the present invention, it is made up of the raw material of following weight portion: first 80 parts of alcohol, 25 parts of diesel oil, 1.3 parts of Methacrylamide, 0.8 part of 4- azabenzimidazoles, 0.08 part of cyclohexyl nitrate, glycerol 0.9 part, 0.7 part of fatty acid ester, 0.04 part of dodecylbenzene sodium sulfonate, 0.09 part of dimethyl carbonate, 0.7 part of antioxidant.
Preferably, antioxidant of the present invention is 10~18 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 7 ~15 weight portion 2,4 dimethylaniline and the mixture of 2~6 weight portion ditertbutylparacresols.
It is highly preferred that antioxidant of the present invention is the 14 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 11 weights Amount part 2,4 dimethylaniline and the mixture of 4 weight portion ditertbutylparacresols.
The beneficial effects of the present invention is:
1st, the Methacrylamide of the present invention, 4- azabenzimidazoles and 2,4- dimethylaniline have the effect of quietness, Effectively nozzle deposit carbon can be removed it is ensured that good atomization, and keep engine performance and emission level.Detersive can have Effect removes nozzle deposit carbon it is ensured that good atomization, and keeps engine performance and emission level.
2nd, the cyclohexyl nitrate of the present invention and glycerol can put forward Cetane number, improve the Cetane number of fuel, improve fuel Fire behaviour, improve fuel cold start-up problem, reduce combustion noise, the noxious gas emission such as sox, nox reduces.
3rd, the glycerol of the present invention and dimethyl carbonate be as combustion improver, can promote that fuel is rapid, fully burn, Improve the thermal efficiency, thus reducing oil consumption, reducing the carbon deposit of burning interior and the coking of top piston ring.
4th, the fatty acid ester of the present invention, dimethyl carbonate and ditertbutylparacresol have anticorrosive effect, with metal watch Face strong effect, produces chemically and physically adsorption, forms good protecting film, has isolated corrosive deposit to a certain extent Contact with metalwork, reaches the purpose of suppression corrosion, protects engine fuel system, the extended probationary period, prevented also from generation Rust grain block fuel filter strainer and nozzle etc., impact electromotor normal operation.
5th, the dodecylbenzene sodium sulfonate of the present invention has scattered effect, makes insoluble substance keep disperseing in fuel Suspended state, in order to avoid the key position row in electromotor becomes lacquer deposit, also can guarantee that combustibility is good simultaneously, reduces row Tolerance, reduces pollution.
6th, the raw material synergism of the present invention, fuel also has freeze proof, lubrication effect, protects engine apparatus, saves Engine fuel, is simultaneously also beneficial to full combustion of fuel and reduces exhaust emissions amount, improve fuel cold start-up problem, under low temperature not Layering, and can normally use.
7th, the alcohol-based fuel of the low exhaust gas discharge capacity of the present invention, after tested, deposit at least 18 months not stratified, never degenerate, Even if not also being layered at -40 DEG C, can normally use;Fuel value relatively diesel oil raising 700~1050 kilocalories/kilogram;Copper It is 1a level that piece corrodes (50 DEG C, 3h);Cetane number improves 6~9 units compared with diesel oil;Co, hc, no in tail gasxAnd particulate matter Relatively reduce by 41~61%, 32~61%, 40~74%, 59~88% respectively using Diesel Emissions, be computed, cost-saved 25.6%~34.7%, water-resistance reaches 32%~47%.
Specific embodiment
The invention will be further described with reference to embodiments, but the invention is not limited in these embodiments.
Embodiment 1
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 68 parts of alcohol, 34 parts of diesel oil, 0.7 part of Methacrylamide, 1.4 parts of 4- azabenzimidazoles, 0.02 part of cyclohexyl nitrate, glycerol 1.5 parts, 0.1 part of fatty acid ester, 0.07 part of dodecylbenzene sodium sulfonate, 0.03 part of dimethyl carbonate, 1.3 parts of antioxidant;Institute The antioxidant stated is the 8 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 17 weight portion 2,4 dimethylaniline and 1 weight portion The mixture of ditertbutylparacresol.
Embodiment 2
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 72 parts of alcohol, 31 parts of diesel oil, 0.9 part of Methacrylamide, 1.2 parts of 4- azabenzimidazoles, 0.04 part of cyclohexyl nitrate, glycerol 1.3 parts, 0.3 part of fatty acid ester, 0.06 part of dodecylbenzene sodium sulfonate, 0.05 part of dimethyl carbonate, 1.1 parts of antioxidant;Institute The antioxidant stated is the 10 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 15 weight portion 2,4 dimethylaniline and 2 weight The mixture of part ditertbutylparacresol.
Embodiment 3
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 76 parts of alcohol, 28 parts of diesel oil, 1.1 parts of Methacrylamide, 1 part of 4- azabenzimidazoles, 0.06 part of cyclohexyl nitrate, glycerol 1.1 parts, 0.5 part of fatty acid ester, 0.05 part of dodecylbenzene sodium sulfonate, 0.07 part of dimethyl carbonate, 0.9 part of antioxidant;Institute The antioxidant stated is the 12 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 13 weight portion 2,4 dimethylaniline and 3 weight The mixture of part ditertbutylparacresol.
Embodiment 4
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 80 parts of alcohol, 25 parts of diesel oil, 1.3 parts of Methacrylamide, 0.8 part of 4- azabenzimidazoles, 0.08 part of cyclohexyl nitrate, glycerol 0.9 part, 0.7 part of fatty acid ester, 0.04 part of dodecylbenzene sodium sulfonate, 0.09 part of dimethyl carbonate, 0.7 part of antioxidant;Institute The antioxidant stated is the 14 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 11 weight portion 2,4 dimethylaniline and 4 weight The mixture of part ditertbutylparacresol.
Embodiment 5
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 84 parts of alcohol, 22 parts of diesel oil, 1.5 parts of Methacrylamide, 0.6 part of 4- azabenzimidazoles, 0.1 part of cyclohexyl nitrate, glycerol 0.7 part, 0.9 part of fatty acid ester, 0.03 part of dodecylbenzene sodium sulfonate, 0.11 part of dimethyl carbonate, 0.5 part of antioxidant;Institute The antioxidant stated is the 16 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 9 weight portion 2,4 dimethylaniline and 5 weight portions The mixture of ditertbutylparacresol.
Embodiment 6
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 88 parts of alcohol, 19 parts of diesel oil, 1.7 parts of Methacrylamide, 0.4 part of 4- azabenzimidazoles, 0.12 part of cyclohexyl nitrate, glycerol 0.5 part, 1.1 parts of fatty acid ester, 0.02 part of dodecylbenzene sodium sulfonate, 0.13 part of dimethyl carbonate, 0.3 part of antioxidant;Institute The antioxidant stated is the 18 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 7 weight portion 2,4 dimethylaniline and 6 weight portions The mixture of ditertbutylparacresol.
Embodiment 7
The alcohol-based fuel of low exhaust gas discharge capacity, makes (under room temperature, stirring): first by the raw material of following weight portion 92 parts of alcohol, 16 parts of diesel oil, 1.9 parts of Methacrylamide, 0.2 part of 4- azabenzimidazoles, 0.14 part of cyclohexyl nitrate, glycerol 0.3 part, 1.3 parts of fatty acid ester, 0.01 part of dodecylbenzene sodium sulfonate, 0.15 part of dimethyl carbonate, 0.1 part of antioxidant;Institute The antioxidant stated is the 20 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 5 weight portion 2,4 dimethylaniline and 7 weight portions The mixture of ditertbutylparacresol.

Claims (5)

1. the alcohol-based fuel of low exhaust gas discharge capacity is it is characterised in that be made up of the raw material of following weight portion: 68~92 parts of methanol, 16~34 parts of diesel oil, 0.7~1.9 part of Methacrylamide, 0.2~1.4 part of 4- azabenzimidazoles, cyclohexyl nitrate 0.02~ 0.14 part, 0.3~1.5 part of glycerol, 0.1~1.3 part of fatty acid ester, 0.01~0.07 part of dodecylbenzene sodium sulfonate, carbonic acid 0.03~0.15 part of dimethyl ester, 0.1~1.3 part of antioxidant;
Described antioxidant is 8~20 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 5~17 weight portion 2,4 dimethyl Aniline and the mixture of 1~7 weight portion ditertbutylparacresol.
2. the alcohol-based fuel of low exhaust gas discharge capacity according to claim 1 is it is characterised in that raw material by following weight portion Make: 72~88 parts of methanol, 19~31 parts of diesel oil, 0.9~1.7 part of Methacrylamide, 4- azabenzimidazoles 0.4~1.2 Part, 0.04~0.12 part of cyclohexyl nitrate, 0.5~1.3 part of glycerol, 0.3~1.1 part of fatty acid ester, DBSA 0.02~0.06 part of sodium, 0.05~0.13 part of dimethyl carbonate, 0.3~1.1 part of antioxidant.
3. the alcohol-based fuel of low exhaust gas discharge capacity according to claim 2 is it is characterised in that raw material by following weight portion Make: 80 parts of methanol, 25 parts of diesel oil, 1.3 parts of Methacrylamide, 0.8 part of 4- azabenzimidazoles, cyclohexyl nitrate 0.08 Part, 0.9 part of glycerol, 0.7 part of fatty acid ester, 0.04 part of dodecylbenzene sodium sulfonate, 0.09 part of dimethyl carbonate, antioxidant 0.7 part.
4. low exhaust gas discharge capacity according to claim 1 alcohol-based fuel it is characterised in that: described antioxidant be 10 ~18 weight portion 4- tert-butyl groups -2,6-Bis(1-methylethyl)phenol, 7~15 weight portion 2,4 dimethylaniline and 2~6 weight portion two uncle The mixture of butyl paracresol.
5. low exhaust gas discharge capacity according to claim 4 alcohol-based fuel it is characterised in that: described antioxidant be 14 The weight portion 4- tert-butyl group -2,6-Bis(1-methylethyl)phenol, 11 weight portion 2,4 dimethylaniline and 4 weight portion ditertbutylparacresols Mixture.
CN201610869793.XA 2016-09-30 2016-09-30 Alcohol-based fuel with low tail gas emission load Pending CN106350126A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109868165A (en) * 2019-03-26 2019-06-11 林国兵 A kind of high heating value alcohol radical environment protection oil being mainly used for Industrial Boiler kiln automobile and synthetic method
CN113355139A (en) * 2021-05-06 2021-09-07 东奇能源技术有限公司 Alcohol-based fuel with high combustion value for vehicle

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109868165A (en) * 2019-03-26 2019-06-11 林国兵 A kind of high heating value alcohol radical environment protection oil being mainly used for Industrial Boiler kiln automobile and synthetic method
CN113355139A (en) * 2021-05-06 2021-09-07 东奇能源技术有限公司 Alcohol-based fuel with high combustion value for vehicle

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Application publication date: 20170125