CN106349854A - Exterior wall coating - Google Patents
Exterior wall coating Download PDFInfo
- Publication number
- CN106349854A CN106349854A CN201610737094.XA CN201610737094A CN106349854A CN 106349854 A CN106349854 A CN 106349854A CN 201610737094 A CN201610737094 A CN 201610737094A CN 106349854 A CN106349854 A CN 106349854A
- Authority
- CN
- China
- Prior art keywords
- parts
- quinoline
- acid
- methylcellulose
- chlorobenzotriazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- -1 aldehyde ketone Chemical class 0.000 claims abstract description 32
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005639 Lauric acid Substances 0.000 claims abstract description 15
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 15
- 239000001923 methylcellulose Substances 0.000 claims abstract description 15
- 239000010445 mica Substances 0.000 claims abstract description 15
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 15
- 229940120693 copper naphthenate Drugs 0.000 claims abstract description 14
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 30
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 25
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 25
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 14
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 claims description 14
- 159000000000 sodium salts Chemical class 0.000 claims description 14
- 238000006277 sulfonation reaction Methods 0.000 claims description 14
- 229920002125 Sokalan® Polymers 0.000 claims description 13
- 229940008099 dimethicone Drugs 0.000 claims description 13
- 239000004584 polyacrylic acid Substances 0.000 claims description 13
- YAGMLECKUBJRNO-UHFFFAOYSA-N octyl 4-(dimethylamino)benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=C(N(C)C)C=C1 YAGMLECKUBJRNO-UHFFFAOYSA-N 0.000 claims description 11
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 10
- AVWWPFWBTLONRB-UHFFFAOYSA-N furan-2,5-dione;2-methylprop-1-ene Chemical compound CC(C)=C.CC(C)=C.O=C1OC(=O)C=C1 AVWWPFWBTLONRB-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 3
- 239000011575 calcium Substances 0.000 claims 3
- 229910052791 calcium Inorganic materials 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 2
- OKTJSMMVPCPJKN-IGMARMGPSA-N Carbon-12 Chemical group [12C] OKTJSMMVPCPJKN-IGMARMGPSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- VNWKTOKETHGBQD-AKLPVKDBSA-N carbane Chemical group [15CH4] VNWKTOKETHGBQD-AKLPVKDBSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-YPZZEJLDSA-N carbon-10 atom Chemical group [10C] OKTJSMMVPCPJKN-YPZZEJLDSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract description 6
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 241000238631 Hexapoda Species 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 238000009833 condensation Methods 0.000 abstract description 2
- 230000005494 condensation Effects 0.000 abstract description 2
- 230000000638 stimulation Effects 0.000 abstract description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract 1
- 229940112669 cuprous oxide Drugs 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 229920005573 silicon-containing polymer Polymers 0.000 abstract 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical class [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 6
- 238000005286 illumination Methods 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- AGGKHDYTKZAPRA-UHFFFAOYSA-N 2,4-ditert-butyl-6-(4-chlorophenyl)phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(C=2C=CC(Cl)=CC=2)=C1O AGGKHDYTKZAPRA-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010020741 Hyperpyrexia Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229940116364 hard fat Drugs 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002541 mycostatic Substances 0.000 description 1
- 230000001557 mycostatic effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
An exterior wall coating comprises acrylate emulsion, copolymer of diisobutylene and maleic anhydride, methylcellulose, mica powder, calcium carbonate, rutile type titanium white, a sulfonated aldehyde ketone condensation compound, sodium polyacrylate salt, copper naphthenate, 2-sulfaquinoxalinum, cuprous oxide, lauric acid, polydimethylsiloxane, dimethyl silicone polymer, methylene distearamide, 2-(2'-hydroxy-3',5'-ditert-butyl phenyl)-5-chlorobenzotriazole, polyvinyl chloride, solvent naphtha 200#, thickening agents, dimethyl para aminobenzoic octyl benzoate and water. The exterior wall coating has the advantages that through mutual synergistic effects of the raw materials, good antibacterial property and insect resistance property are achieved; in a humid environment, generation of mycete can be restrained, and influence from insect damage to the coating can be reduced; and in a strong-light high-temperature environment, high temperature can be resisted, adaption to stimulation from sunlight is realized, and service life is prolonged.
Description
Technical field
The invention belongs to paint field, specifically a kind of exterior coating.
Background technology
At present, existing exterior coating use environment requires higher, such as natural environment requirement cleaning, and humidity temperature is difficult
In fungus growth, outdoor temperature and illumination can not require high.Coating is narrow in range, even if coating by force, uses
Life-span is shorter.
Content of the invention
The present invention provides a kind of exterior coating, in order to solve defect of the prior art.
The present invention is achieved by the following technical programs:
A kind of exterior coating, in parts by weight, composed of the following components: acrylic acid ester emulsion 10-30 part, diisobutylene maleic
Anhydride multipolymer 0.8-1.2 part, methylcellulose 0.1-0.4 part, mica powder 10-15 part, Calcium Carbonate 10-15 part, rutile
Type titanium white 10-20 part, sulfonation aldehyde-ketone condensate 0.2-0.5 part, polyacrylic acid sodium salt 0.2-0.6 part, copper naphthenate 0.2-1 part,
2- sulfanilamide quinoline uh quinoline 0.1-0.3 part, Red copper oxide 0.2-0.8 part, lauric acid 0.3-0.5 part, Dimethicone 0.3-0.5
Part, polydimethylsiloxane 0.1-0.4 part, methylene bis stearamide 0.1-0.4 part, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary fourths
Base phenyl) -5- chlorobenzotriazole 0.1-0.5 part, polrvinyl chloride 1-5 part, 200# solvent naphtha 2-5 part, thickening agent 0.2-1.5 part,
Octyl dimethyl p-aminobenzoic acid 0.2-0.5 part, water 30-60 part.
A kind of exterior coating as above, in parts by weight, composed of the following components: 10 parts of acrylic acid ester emulsion, two
1.0 parts of isobutylene maleic anhydride copolymers, 0.4 part of methylcellulose, 10 parts of mica powder, 12 parts of Calcium Carbonate, rutile-type
20 parts of titanium white, 0.2 part of sulfonation aldehyde-ketone condensate, 0.4 part of polyacrylic acid sodium salt, 1 part of copper naphthenate, 0.1 part of 2- sulfanilamide quinoline uh quinoline,
0.5 part of Red copper oxide, 0.5 part of lauric acid, 0.3 part of Dimethicone, 0.4 part of polydimethylsiloxane, di-2-ethylhexylphosphine oxide Hard Fat
0.1 part of amide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) 0.3 part of -5- chlorobenzotriazole, 5 parts of polrvinyl chloride, 200# are molten
2 parts of agent oil, 1.0 parts of thickening agent, 0.5 part of octyl dimethyl p-aminobenzoic acid, 60 parts of water.
A kind of exterior coating as above, in parts by weight, composed of the following components: 20 parts of acrylic acid ester emulsion, two
1.2 parts of isobutylene maleic anhydride copolymers, 0.1 part of methylcellulose, 12 parts of mica powder, 15 parts of Calcium Carbonate, rutile-type
10 parts of titanium white, 0.3 part of sulfonation aldehyde-ketone condensate, 0.6 part of polyacrylic acid sodium salt, 0.2 part of copper naphthenate, 2- sulfanilamide quinoline uh quinoline 0.2
Part, 0.8 part of Red copper oxide, 0.3 part of lauric acid, 0.4 part of Dimethicone, 0.1 part of polydimethylsiloxane, di-2-ethylhexylphosphine oxide are hard
0.3 part of acyl amine, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) 0.5 part of -5- chlorobenzotriazole, 1 part of polrvinyl chloride, 200#
4 parts of solvent naphtha, 1.5 parts of thickening agent, 0.2 part of octyl dimethyl p-aminobenzoic acid, 30 parts of water.
A kind of exterior coating as above, in parts by weight, composed of the following components: 30 parts of acrylic acid ester emulsion, two
0.8 part of isobutylene maleic anhydride copolymers, 0.2 part of methylcellulose, 15 parts of mica powder, 10 parts of Calcium Carbonate, rutile-type
15 parts of titanium white, 0.5 part of sulfonation aldehyde-ketone condensate, 0.2 part of polyacrylic acid sodium salt, 0.6 part of copper naphthenate, 2- sulfanilamide quinoline uh quinoline 0.3
Part, 0.2 part of Red copper oxide, 0.4 part of lauric acid, 0.5 part of Dimethicone, 0.2 part of polydimethylsiloxane, di-2-ethylhexylphosphine oxide are hard
0.4 part of acyl amine, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) 0.1 part of -5- chlorobenzotriazole, 3 parts of polrvinyl chloride, 200#
5 parts of solvent naphtha, 0.2 part of thickening agent, 0.3 part of octyl dimethyl p-aminobenzoic acid, 45 parts of water.
The invention has the advantage that in the present invention, acrylic acid ester emulsion, diisobutylene maleic anhydride multipolymer are as base
Material, as filler, rutile titanium dioxide is as pigment for methylcellulose, mica powder, Calcium Carbonate.Sulfonation aldehyde-ketone condensate, poly- third
Olefin(e) acid sodium salt as dispersant, two kinds of dispersant synergism, it is possible to increase the various filler of homogeneous dispersion, prevent each raw material from sinking
Fall and cohesion.Copper naphthenate has anti-mold effect, reduces mycete and grows；2- sulfanilamide quinoline uh quinoline has bactericidal action, works in coordination with and reduces
Mycete grows；Avoid breed bacteria in coating, Red copper oxide has insecticidal effect.Lauric acid and Dimethicone are as froth breaking
Agent, both synergism effectively reduce the generation of foam, can eliminate as early as possible for the foam producing.Polydimethylsiloxane and
Methylene bis stearamide is lubricant, improves the synergism between various raw materials, reinforced effects.2- (2 '-hydroxyl -3 ',
5 '-di-tert-butyl-phenyl) -5- chlorobenzotriazole can make sunlight to invention impact weaken, reduce because illumination cause aging,
Improve service life.Polrvinyl chloride can increase the present invention and resist impact in high temperature, make the present invention be applied to the high temperature of China
Area.200# solvent naphtha is coalescents.The mutual synergism of each raw material in the present invention, has good antibiotic property and pest-resistant
Property, in wet condition, can press down mycostatic grow, reduce the impact to coating for the insect pest.In the environment of high light, hyperpyrexia,
High temperature can be resisted, adapt to the stimulation of illumination, improve service life.
Specific embodiment
Purpose, technical scheme and advantage for making the embodiment of the present invention are clearer, below will be in the embodiment of the present invention
Technical scheme be clearly and completely described it is clear that described embodiment a part of embodiment that is the present invention, rather than
Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative work premise
Lower obtained every other embodiment, broadly falls into the scope of protection of the invention.
A kind of exterior coating, in parts by weight, composed of the following components: acrylic acid ester emulsion 10-30 part, diisobutylene are suitable
Maleic anhydride copolymer 0.8-1.2 part, methylcellulose 0.1-0.4 part, mica powder 10-15 part, Calcium Carbonate 10-15 part, gold
Red stone-type titanium white 10-20 part, sulfonation aldehyde-ketone condensate 0.2-0.5 part, polyacrylic acid sodium salt 0.2-0.6 part, copper naphthenate 0.2-1
Part, 2- sulfanilamide quinoline uh quinoline 0.1-0.3 part, Red copper oxide 0.2-0.8 part, lauric acid 0.3-0.5 part, Dimethicone 0.3-
0.5 part, polydimethylsiloxane 0.1-0.4 part, methylene bis stearamide 0.1-0.4 part, 2- (2 '-hydroxyl -3 ', 5 '-two uncles
Butyl phenyl) -5- chlorobenzotriazole 0.1-0.5 part, polrvinyl chloride 1-5 part, 200# solvent naphtha 2-5 part, thickening agent 0.2-1.5
Part, octyl dimethyl p-aminobenzoic acid 0.2-0.5 part, water 30-60 part.
The present invention in parts by weight, is grouped into by following examples group
Embodiment 1: 10 parts of acrylic acid ester emulsion, 1.0 parts of diisobutylene maleic anhydride multipolymer, 0.4 part of methylcellulose,
10 parts of mica powder, 12 parts of Calcium Carbonate, 20 parts of rutile titanium dioxide, 0.2 part of sulfonation aldehyde-ketone condensate, 0.4 part of polyacrylic acid sodium salt,
1 part of copper naphthenate, 0.1 part of 2- sulfanilamide quinoline uh quinoline, 0.5 part of Red copper oxide, 0.5 part of lauric acid, 0.3 part of Dimethicone, poly-
0.4 part of dimethyl siloxane, 0.1 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) -5- chlorobenzene
And 0.3 part of triazole, 5 parts of polrvinyl chloride, 2 parts of 200# solvent naphtha, 1.0 parts of thickening agent, octyl dimethyl p-aminobenzoic acid 0.5
Part, 60 parts of water.
Embodiment 2: 20 parts of acrylic acid ester emulsion, 1.2 parts of diisobutylene maleic anhydride multipolymer, methylcellulose
0.1 part, 12 parts of mica powder, 15 parts of Calcium Carbonate, 10 parts of rutile titanium dioxide, 0.3 part of sulfonation aldehyde-ketone condensate, polyacrylic acid sodium salt
0.6 part, 0.2 part of copper naphthenate, 0.2 part of 2- sulfanilamide quinoline uh quinoline, 0.8 part of Red copper oxide, 0.3 part of lauric acid, Dimethicone
0.4 part, 0.1 part of polydimethylsiloxane, 0.3 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl
Base) 0.5 part of -5- chlorobenzotriazole, 1 part of polrvinyl chloride, 4 parts of 200# solvent naphtha, 1.5 parts of thickening agent, dimethyl p-aminophenyl first
0.2 part of misery ester, 30 parts of water.
Embodiment 3: 30 parts of acrylic acid ester emulsion, 0.8 part of diisobutylene maleic anhydride multipolymer, methylcellulose
0.2 part, 15 parts of mica powder, 10 parts of Calcium Carbonate, 15 parts of rutile titanium dioxide, 0.5 part of sulfonation aldehyde-ketone condensate, polyacrylic acid sodium salt
0.2 part, 0.6 part of copper naphthenate, 0.3 part of 2- sulfanilamide quinoline uh quinoline, 0.2 part of Red copper oxide, 0.4 part of lauric acid, Dimethicone
0.5 part, 0.2 part of polydimethylsiloxane, 0.4 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl
Base) 0.1 part of -5- chlorobenzotriazole, 3 parts of polrvinyl chloride, 5 parts of 200# solvent naphtha, 0.2 part of thickening agent, dimethyl p-aminophenyl first
0.3 part of misery ester, 45 parts of water.
A kind of preparation method of exterior coating, comprises the steps: 1. to add in reactor water, sulfonation condensation
Thing, polyacrylic acid sodium salt, lauric acid, stir 5min, rotating speed 150rpm；2. methylcellulose, mica powder, Calcium Carbonate are added
And rutile titanium dioxide, stir 5min, rotating speed 800rpm；3. add polydimethylsiloxane, methylene bis stearamide,
200# solvent naphtha, thickening agent, octyl dimethyl p-aminobenzoic acid, stir 20min, rotating speed 1500rpm；4. add propylene
Acid esters emulsion, diisobutylene maleic anhydride multipolymer, stir 15min, rotating speed 1000rpm；5. add copper naphthenate,
2- sulfanilamide quinoline uh quinoline, Red copper oxide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) -5- chlorobenzotriazole, polrvinyl chloride 1-
5, stir 3min, rotating speed 300rpm；6. add Dimethicone and carry out froth breaking, get product after stirring.
High temperature resistant test: take ground, use sand papering surface, the present invention is uniformly applied to surface of bottom material, smear smooth
Densification, dries.Respectively the ground scribbling the present invention is inserted baking box, be respectively provided with temperature be 40 DEG C, 60 DEG C, 80 DEG C, 100 DEG C,
150 DEG C and 200 DEG C, observe at set intervals once, result is as shown in the table.
Above-mentioned test shows, the heat stability of the present invention is higher, can be applied to general outdoor high temperature environment.
Through overtesting, the present invention meets the limits of harmful substances of antibiotic paint；Meet technical requirements regulation in gb18582,
Meet technical requirements regulation in gb18581.
Finally it is noted that above example, only in order to technical scheme to be described, is not intended to limit；Although
With reference to the foregoing embodiments the present invention is described in detail, it will be understood by those within the art that: it still may be used
To modify to the technical scheme described in foregoing embodiments, or equivalent is carried out to wherein some technical characteristics；
And these modification or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.
Claims (4)
1. a kind of exterior coating it is characterised in that: in parts by weight, composed of the following components: acrylic acid ester emulsion 10-30 part,
Diisobutylene maleic anhydride multipolymer 0.8-1.2 part, methylcellulose 0.1-0.4 part, mica powder 10-15 part, Calcium Carbonate
10-15 part, rutile titanium dioxide 10-20 part, sulfonation aldehyde-ketone condensate 0.2-0.5 part, polyacrylic acid sodium salt 0.2-0.6 part, ring
Alkanoic acid copper 0.2-1 part, 2- sulfanilamide quinoline uh quinoline 0.1-0.3 part, Red copper oxide 0.2-0.8 part, lauric acid 0.3-0.5 part, poly- diformazan
Base silicon ether 0.3-0.5 part, polydimethylsiloxane 0.1-0.4 part, methylene bis stearamide 0.1-0.4 part, 2- (2 '-hydroxyl-
3 ', 5 '-di-tert-butyl-phenyl) -5- chlorobenzotriazole 0.1-0.5 part, polrvinyl chloride 1-5 part, 200# solvent naphtha 2-5 part, thickening
Agent 0.2-1.5 part, octyl dimethyl p-aminobenzoic acid 0.2-0.5 part, water 30-60 part.
2. a kind of exterior coating according to claim 1 it is characterised in that: in parts by weight, composed of the following components: third
10 parts of olefin(e) acid ester emulsion, 1.0 parts of diisobutylene maleic anhydride multipolymer, 0.4 part of methylcellulose, 10 parts of mica powder, carbon
12 parts of sour calcium, 20 parts of rutile titanium dioxide, 0.2 part of sulfonation aldehyde-ketone condensate, 0.4 part of polyacrylic acid sodium salt, 1 part of copper naphthenate,
0.1 part of 2- sulfanilamide quinoline uh quinoline, 0.5 part of Red copper oxide, 0.5 part of lauric acid, 0.3 part of Dimethicone, polydimethylsiloxane
0.4 part, 0.1 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) 0.3 part of -5- chlorobenzotriazole,
5 parts of polrvinyl chloride, 2 parts of 200# solvent naphtha, 1.0 parts of thickening agent, 0.5 part of octyl dimethyl p-aminobenzoic acid, 60 parts of water.
3. a kind of exterior coating according to claim 1 it is characterised in that: in parts by weight, composed of the following components: third
20 parts of olefin(e) acid ester emulsion, 1.2 parts of diisobutylene maleic anhydride multipolymer, 0.1 part of methylcellulose, 12 parts of mica powder, carbon
15 parts of sour calcium, 10 parts of rutile titanium dioxide, 0.3 part of sulfonation aldehyde-ketone condensate, 0.6 part of polyacrylic acid sodium salt, copper naphthenate 0.2
Part, 0.2 part of 2- sulfanilamide quinoline uh quinoline, 0.8 part of Red copper oxide, 0.3 part of lauric acid, 0.4 part of Dimethicone, polydimethylsiloxanes
0.1 part of alkane, 0.3 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) -5- chlorobenzotriazole 0.5
Part, 1 part of polrvinyl chloride, 4 parts of 200# solvent naphtha, 1.5 parts of thickening agent, 0.2 part of octyl dimethyl p-aminobenzoic acid, 30 parts of water.
4. a kind of exterior coating according to claim 1 it is characterised in that: in parts by weight, composed of the following components: third
30 parts of olefin(e) acid ester emulsion, 0.8 part of diisobutylene maleic anhydride multipolymer, 0.2 part of methylcellulose, 15 parts of mica powder, carbon
10 parts of sour calcium, 15 parts of rutile titanium dioxide, 0.5 part of sulfonation aldehyde-ketone condensate, 0.2 part of polyacrylic acid sodium salt, copper naphthenate 0.6
Part, 0.3 part of 2- sulfanilamide quinoline uh quinoline, 0.2 part of Red copper oxide, 0.4 part of lauric acid, 0.5 part of Dimethicone, polydimethylsiloxanes
0.2 part of alkane, 0.4 part of methylene bis stearamide, 2- (2 '-hydroxyl -3 ', 5 '-di-tert-butyl-phenyl) -5- chlorobenzotriazole 0.1
Part, 3 parts of polrvinyl chloride, 5 parts of 200# solvent naphtha, 0.2 part of thickening agent, 0.3 part of octyl dimethyl p-aminobenzoic acid, 45 parts of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737094.XA CN106349854A (en) | 2016-08-29 | 2016-08-29 | Exterior wall coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737094.XA CN106349854A (en) | 2016-08-29 | 2016-08-29 | Exterior wall coating |
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| Publication Number | Publication Date |
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| CN106349854A true CN106349854A (en) | 2017-01-25 |
Family
ID=57856059
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|---|---|---|---|---|
| CN1712479A (en) * | 2004-06-25 | 2005-12-28 | 闫俊杰 | Modified paint |
| CN102153924A (en) * | 2011-05-13 | 2011-08-17 | 中山市丽莎涂料有限公司 | Inner wall latex paint |
| JP2013023611A (en) * | 2011-07-22 | 2013-02-04 | Adeka Corp | Aqueous polyurethane resin composition and easily adhesive polyester film applied with the same |
| CN102993861A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Flame-retardant acrylic acid veneer coating and preparation method thereof |
| CN105462406A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Exterior wall coating and preparation method thereof |
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2016
- 2016-08-29 CN CN201610737094.XA patent/CN106349854A/en active Pending
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| CN1712479A (en) * | 2004-06-25 | 2005-12-28 | 闫俊杰 | Modified paint |
| CN102153924A (en) * | 2011-05-13 | 2011-08-17 | 中山市丽莎涂料有限公司 | Inner wall latex paint |
| JP2013023611A (en) * | 2011-07-22 | 2013-02-04 | Adeka Corp | Aqueous polyurethane resin composition and easily adhesive polyester film applied with the same |
| CN102993861A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Flame-retardant acrylic acid veneer coating and preparation method thereof |
| CN105462406A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Exterior wall coating and preparation method thereof |
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Application publication date: 20170125 |