[go: up one dir, main page]

CN106338351A - Negative-resistance-effect tension-sensitive sensor - Google Patents

Negative-resistance-effect tension-sensitive sensor Download PDF

Info

Publication number
CN106338351A
CN106338351A CN201510600916.5A CN201510600916A CN106338351A CN 106338351 A CN106338351 A CN 106338351A CN 201510600916 A CN201510600916 A CN 201510600916A CN 106338351 A CN106338351 A CN 106338351A
Authority
CN
China
Prior art keywords
stretching
sensitive
rubber
type sensor
sensitive type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510600916.5A
Other languages
Chinese (zh)
Other versions
CN106338351B (en
Inventor
李大军
李杨
徐行涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN HUIRUI ELECTRONIC MATERIALS Co Ltd
Original Assignee
SHENZHEN HUIRUI ELECTRONIC MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN HUIRUI ELECTRONIC MATERIALS Co Ltd filed Critical SHENZHEN HUIRUI ELECTRONIC MATERIALS Co Ltd
Publication of CN106338351A publication Critical patent/CN106338351A/en
Application granted granted Critical
Publication of CN106338351B publication Critical patent/CN106338351B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)
  • Measurement Of Length, Angles, Or The Like Using Electric Or Magnetic Means (AREA)

Abstract

The invention discloses a negative-resistance-effect tension-sensitive sensor. The tension-sensitive sensor comprises a tension-sensitive material and metal electrodes prepared on the surface of the tension-sensitive material. The tension-sensitive material is conductive rubber, which is prepared by compounding and filling conductive particles in a rubber material, and of which the resistivity is between 1.0*10<3>Omega.cm and 1.0*10<8>Omega.cm. The tension-sensitive sensor is simple in structure, large in mechanical quantity variation amplitude and good in flexibility, and the resistance variation intensity thereof cannot decrease after 1000 times of repetitive stretching. The conductive rubber of the tension-sensitive sensor is prepared by adopting the production process of ordinary rubber, and the tension-sensitive sensor has the advantages of high production efficiency and low manufacturing cost, so that the tension-sensitive sensor has wide application prospect in the fields of biomechanical detection, rehabilitation therapy, intelligent wearing and intelligent robot and the like.

Description

A kind of stretching-sensitive type sensor of negative resistance effect
Technical field
The present invention relates to pulling force responsive type sensor field, particularly to a kind of stretching-sensitive type sensor of negative resistance effect.
Background technology
1885, English physicist Kelvin found that metal produces mechanical deformation afterwards bearing pressure (pulling force or torsion) Simultaneously as changed by scantling (length, sectional area) being affected, resistance value also there occurs that characteristic makes a variation, that is, strain Electricresistance effect.People just obtain feature and the value of material stress from the change of resistance value, develop pressure-sensitive respectively and draw The resistance strain sensor of power responsive type.The pulling force responsive type resistance strain type sensor being widely used at present, abbreviation stretching-sensitive resistance Sensor, mainly has metal strain resistance-type, semiconductor strain resistance-type, alloy strain resistance type etc..But due to sensing material The restriction of material elastic modelling quantity itself, these strain type resistive sensing elements have the disadvantage in that one is a lack of flexible and elasticity, no Can bend, thus the application in the field needing the complicated deformation such as bending, stretching is restricted;Two be mechanical quantity amplitude of variation relatively Little, thus cannot be used for the larger field of deformation quantity;Three is complex structure, and manufacturing cost is high.In biomethanics detection, rehabilitation It is desirable to sensor not only will possess during the labyrinth mechanical meaurement in the fields such as medical treatment, intelligent robot, wearable device Good stress-resistance characteristic, and require there is outstanding pliable and tough mechanical property.Therefore, metal type or half in these areas The application of conductor type resistance strain sensor just receives the restriction of natural resiliency modulus.It is, thus, sought for new pliability is excellent Good mechanics sensitive material manufactures flexible strain type pulling force sensor.
Content of the invention
It is an object of the invention to provide a kind of stretching-sensitive type sensor of negative resistance effect, strengthen flexibility and the elasticity of sensor, Increase the amplitude of variation of mechanical quantity, reduces cost.
To achieve these goals, the technical scheme is that a kind of stretching-sensitive type sensor of negative resistance effect, including stretching-sensitive Material and the metal electrode being produced on described stretching-sensitive material surface.Described stretching-sensitive material is filling conductive filler in elastomeric material The resistivity made is between 1.0 × 103ω .cm and 1.0 × 108A kind of conductive rubber between ω .cm, described metal electrode is selected from gold Belong to one of film, metal forming, sheet metal, by conductive glue bond, silver paste serigraphy, vacuum coating or mechanical crimp Mode is produced on stretching-sensitive material two ends.Described negative resistance effect stretching-sensitive type sensor resistance under tensile force effect constantly declines, and is in Reveal negative pulling force-electricresistance effect, 5-500 times of resistance variations can be produced when deformation quantity is 30%, and this stretching-sensitive type sensing The amplitude of variation of the mechanical quantity of device is big, and flexible and elasticity is fine, and after 1000 repeated stretchings, resistance variations intensity will not Decline.By the change of detection resistance value, or resistance signal is converted into electric current, voltage or capacitance signal, is obtained in that biography The information of external forces suffered by sensor, can be in necks such as biomethanics detection, rehabilitation medical, intelligence wearing, intelligent robots Domain carries out the measurement of mechanical quantity.
Conducting particles passes through the formation conductive path that contacts with each other of microcosmic in rubber matrix, thus when material is subject to extraneous pressure Or during pulling force effect, the spacing of material internal adjacent conductive particle changes, and results in relying on the contact of conducting particles and is formed Conductive path changes, and causes the resistance of macroscopically material to change, therefore can be used as a kind of mechanics sensing material.Rubber The excellent flexibility of matrix body itself and elasticity give the excellent flexibility of described stretching-sensitive type sensor and elasticity, and larger mechanical quantity Amplitude of variation, can overcome the shortcomings of metal type or semiconductor-type resistance strain sensor in terms of pliability and elasticity.
For realizing technique scheme, described stretching-sensitive material according to each component ratio of mass parts is: 100 parts of rubber matrix, protection System 0.1-3 part, vulcanizing system 1-15 part, conductive filler 20-100 part.Wherein, mass parts are industrial for calculating side Just using intuitively quality proportioning method, the mass ratio of digital directly proportion substance required for expression.
Further, described elastomeric material is natural rubber, nitrile rubber, ethylene propylene diene rubber, butadiene-styrene rubber, poly- isoamyl two At least one in alkene rubber, butadiene rubber.
Further, described protection system, including amines antioxidants and phenol antiager.
Further, described vulcanizing system, including vulcanizing agent, vulcanization accelerator and activating agent.
Further, described activating agent includes zinc oxide or stearic acid.
Further, described vulcanization accelerator includes thuriam acceserator, thiazole accelerator, guanidines or secondary sulphur Amide-type accelerator.
Further, described vulcanizing agent includes sulphur and organic peroxide.
Further, organic peroxide, including cumyl peroxide dcp, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene, 1,1- Double (t-butyl peroxy) n-butyl pentanoate of bis(t-butylperoxy) cyclohexane, tert butyl isopropyl benzene peroxide, 4,4-.
Further, described conductive filler is carbon black, and average grain diameter is 20-120nm, and oil factor is 40cm3/100g- 200cm3/100g.
Further, the resistivity of described conductive rubber material is between 1.0 × 103ω .cm and 1.0 × 108Between ω .cm.
Further, described metal electrode is selected from one of metal forming, sheet metal, metal film, special-shaped hardware, passes through Conductive glue bond, the mode of conductive silver paste serigraphy, vacuum coating or mechanical crimp are produced on stretching-sensitive material two ends.Described lead Electric silver paste is ultraviolet curing type.The method of described vacuum coating includes vacuum vapor plating, vacuum magnetron sputtering coating film, vacuum Ion film plating.
Further, the stretching-sensitive type sensor of described negative resistance effect, including the metal of stretching-sensitive material and making stretching-sensitive material surface Electrode.
Further, the resistance value of stretching-sensitive type sensor is between 50k ω and 50000k ω.
Described stretching-sensitive type sensor resistance value rapid decrease under tensile force effect, presents negative stretching-sensitive electricresistance effect, works as stretching 5-500 times of resistance variations can be produced when 30%.The change multiplying power of stretching-sensitive type electric resistance sensor resistance value before and after tensile deformation, The sensitivity of stretching-sensitive sensor can be characterized.
After under tension effect, stretching-sensitive length of material increases described stretching-sensitive sensor, and sectional area diminishes, and material internal The change in conducting particles gap leads to material conductive microstructure network change, thus causing the change of resistivity of material.Resistivity of material, The capacitance that between electrode, the comprehensive change of the factor such as length of material also simultaneously results between stretching-sensitive material two end electrodes becomes Change.
Further, the capacitance of the stretching-sensitive type sensor of the present invention increases with tensile deformation and increases, 30% tensile deformation model The capacitance variation multiplying power enclosing interior stretching-sensitive sensor is 5 to 500 times.
Present invention also offers a kind of negative resistance effect stretching-sensitive sensor manufacture method, comprise the following steps:
Step a: according to certain quality proportioning by rubber matrix, age resistor, conductive filler, vulcanizing agent, according to said sequence It is added sequentially to two-roll mill or banbury is kneaded, after each component mixes, thin pass-out piece, whole mixing process Temperature control below 80 DEG C.
Step b: conductive rubber sizing material will be kneaded and put in mould, sulfidization molding under certain temperature and pressure, led Electric rubber plate.Specific curing parameter determines according to different rubber matrixs.
Step c: conductive rubber sheet material cuts into the rubber batten of certain length and width, using conductive silver glue bonding, height The method of warm pressure, silver paste serigraphy or vacuum coating makes metal electrode it is also possible to connect thereon further at batten two ends Connect plain conductor, thus preparing the stretching-sensitive sensor of negative resistance effect.
Beneficial effect: the present invention provide the stretching-sensitive sensor of negative resistance effect resistance value between 50k ω and 50000k ω it Between.Stretching-sensitive sensor construction of the present invention is simple, and low cost of manufacture constantly declines in tensile force effect lower sensor resistance, presents Go out negative resistance effect, the capacitance simultaneously increasing with tensile deformation between the metal electrode of sensor two ends increases, when deformation quantity is 5-500 times of resistance and capacitance variations can be produced, the amplitude of variation of sensor mechanical quantity is big, and flexible and elasticity is fine when 30%, And this sensor is after 1000 repeated stretchings, resistance variations intensity will not decline.The excellent pliability of rubber itself gives institute State the excellent flexibility of sensor and elasticity, overcome metal type and semiconductor-type strain transducer elasticity and flexibility in terms of not Foot.By the change of detection resistance value, or resistance signal is converted into electric current, voltage or capacitance signal, is obtained in that sensing The information of external forces suffered by device, therefore has in fields such as biomethanics detection, instrument and meter, health medical treatment, artificial intelligence Have broad application prospects.
Brief description
Fig. 1-Fig. 7 is that the resistance value (capacitance) of the stretching-sensitive sensor of negative resistance effect of the present invention is bent with the change of tensile deformation Line chart.
Specific embodiment
In order to be more clearly understood that the technology contents of the present invention, especially exemplified by following examples, the present invention is elaborated:
Embodiment 1
The stretching-sensitive sensor of the negative resistance effect of the present embodiment adopts conductive rubber as stretching-sensitive material, and its preparation method is as follows:
The proportioning components of conductive rubber and preparation method are as follows:
In the following order by the natural rubber of 100 mass parts, the age resistor d of 1 mass parts, the zinc oxide of 5 mass parts, 2 The stearic acid of mass parts, the accelerator m of 1 mass parts, carbon black (raven520u, particle diameter 58nm, the oil suction of 110 mass parts Value 120m2/ g, Columbian Chemical), the sulphur of 2.5 mass parts, it is added sequentially to two-roll mill and kneaded, mill Machine temperature is set as 50 DEG C, after each component mixes, thin pass-out piece.The conductive natural rubber kneading is put in mould, At 140 DEG C, vulcanize 15 minutes under 15mpa pressure, obtain the conductive natural rubber sheet material of 1mm thickness.
By conductive rubber sheet material, cut into length 50mm, the batten of width 5mm, using conductive silver glue bonding method in sample Bar two ends are made metal foil electrode and are connected metal copper conductor thereon, and wherein metal forming is nickel plating Copper Foil, thickness 0.035mm, Length 10mm, width 5mm;Copper lines diameter 0.4mm.
As the stretching-sensitive material of the present invention, its resistivity is between 1.0 × 10 for conductive rubber material described in the present embodiment3ω .cm and 1.0×108Between ω .cm.Stretching-sensitive sensor manufactured in the present embodiment resistance value under tensile force effect constantly declines, and presents negative Electricresistance effect, and pliability and elasticity are good, and mechanical quantity amplitude of variation is big, and structure is simple, low cost of manufacture.
Flexibility stretching-sensitive material of the present invention is the conductive rubber material that filling conductive filler is made in elastomeric material, described gold Belong to electrode and be selected from one of metal film, metal forming, sheet metal, special-shaped hardware, by conductive glue bond, high temperature hot pressing, The mode of silver paste serigraphy or vacuum coating is produced on the surface at stretching-sensitive material two ends.The switching mode of the negative pulling sensitive effect of the present invention Electric resistance sensor structure is simple, and low cost of manufacture constantly declines in tensile force effect lower sensor resistance, presents negative stretching-sensitive electricity Inhibition effect, can produce 5-500 times of resistance variations when deformation quantity is 30%, and the amplitude of variation of mechanical quantity is big, flexible and elastic Very well, and this sensor is after 1000 repeated stretchings, resistance variations intensity will not decline.
Preferably, described stretching-sensitive material is grouped part ratio according to mass parts each group and is: 100 parts of elastomeric material, protection system 0.1 Part, 2 parts of vulcanizing system, 20 parts of conductive filler.
Preferably, according to mass parts each component ratio it is: 100 parts of elastomeric material, 1.5 parts of protection system, 7 parts of vulcanizing system, 70 parts of conductive filler.
Preferably, according to mass parts each component ratio it is: 100 parts of elastomeric material, 3 parts of protection system, 15 parts of vulcanizing system, 110 parts of conductive filler.
Preferably, described elastomeric material is natural rubber, nitrile rubber, ethylene propylene diene rubber, butadiene-styrene rubber, polyisoprene At least one in rubber, butadiene rubber.
Preferably, protection system includes amines antioxidants and phenol antiager.
Preferably, described vulcanizing system includes vulcanizing agent, vulcanization accelerator and activating agent.
Preferably, described activating agent includes zinc oxide or stearic acid.
Preferably, described vulcanization accelerator includes thuriam acceserator, thiazole accelerator, guanidines or secondary sulphonyl Amine type accelerator.
Preferably, described vulcanizing agent is sulphur and organic peroxide.
Preferably, described organic peroxide, including cumyl peroxide dcp, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene, Double (t-butyl peroxy) n-butyl pentanoate of 1,1-bis(t-butylperoxy)cyclohexane, tert butyl isopropyl benzene peroxide, 4,4-.
Preferably, described conductive filler is carbon black, and the average grain diameter of this carbon black is 20nm, and oil factor is 40cm3/100g.
Preferably, described conductive filler is carbon black, and the average grain diameter of this carbon black is 70nm, and oil factor is 120cm3/100g.
Preferably, described conductive filler is carbon black, and the average grain diameter of this carbon black is 120nm, and oil factor is 200cm3/100g.
Preferably, the resistivity of described conductive rubber material is 1.0 × 103ω.cm.
Preferably, the resistivity of described conductive rubber material is 1.0 × 105ω.cm.
Preferably, the resistivity of described conductive rubber material is 1.0 × 108ω.cm.
Preferably, described metal electrode is selected from one of metal forming, sheet metal, metal film, glues serigraphy by conducting resinl Or the mode of vacuum coating or mechanical crimp is produced on the surface at stretching-sensitive material two ends.
Preferably, the resistance value of described stretching-sensitive sensor is 50k ω.
Preferably, the resistance value of described stretching-sensitive sensor is 5000k ω.
Preferably, the resistance value of described stretching-sensitive sensor is 50000k ω.
Preferably, resistance value increases with deformation and declines described stretching-sensitive sensor under a stretching force, and shape is changed into resistance value when 30% Change multiplying power is 5 times.
Preferably, resistance value increases with deformation and declines described stretching-sensitive sensor under a stretching force, and shape is changed into resistance value when 30% Change multiplying power is 100 times.
Preferably, resistance value increases with deformation and declines described stretching-sensitive sensor under a stretching force, and shape is changed into resistance value when 30% Change multiplying power is 500 times.
Preferably, capacitance increases with deformation and increases described stretching-sensitive sensor under a stretching force, and shape is changed into capacitance when 30% Change multiplying power is 5 times.
Preferably, capacitance increases with deformation and increases described stretching-sensitive sensor under a stretching force, and shape is changed into capacitance when 30% Change multiplying power is 100 times.
Preferably, capacitance increases with deformation and increases described stretching-sensitive sensor under a stretching force, and shape is changed into capacitance when 30% Change multiplying power is 500 times.
Test the stretching-sensitive characteristic of the negative resistance effect stretching-sensitive sensor of the present embodiment according to following method of testing:
A () tests the Changing Pattern increasing its resistance value and capacitance with tensile deformation for the stretching-sensitive sensor, draw resistance value And the relation curve of capacitance and tensile deformation, as shown in Figure 1.
B () tests stretching-sensitive the sensor repeatable performance of resistance variations and stability under surely stretching deformation: set tensile deformation 30%, set sample and be stretched to the retention time determining elongation as 5 seconds, after unloading pulling force, the turnaround time of sample is 30 seconds, The number of times of repeated stretching is 1000 times, resistance and the resistance value being stretched to during tensile deformation 30% before each stretching of record, and data arranges In table 2.
Embodiment 2
In conjunction with Fig. 2, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but the charcoal of 90 mass parts Black (raven520u, particle diameter 58nm, oil factor 120m2/ g, Columbian Chemical) 110 mass parts in alternate embodiment 1 Carbon black (raven520u, particle diameter 58nm, oil factor 120m2/ g, Columbian Chemical).According to institute in embodiment 1 State the properties that identical mode tests stretching-sensitive sensor, the results are shown in Table 2.
Embodiment 3
In conjunction with Fig. 3, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but with 80 mass parts Carbon black (raven520u, particle diameter 58nm, oil factor 120m2/ g, Columbian Chemical) 110 mass in alternate embodiment 1 Carbon black (raven520u, particle diameter 58nm, oil factor 120m of part2/ g, Columbian Chemical).According to embodiment 1 Described in identical mode test the properties of stretching-sensitive sensor, the results are shown in Table 2.
Embodiment 4
In conjunction with Fig. 4, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but with 70 mass parts Carbon black (raven520u, particle diameter 58nm, oil factor 120m2/ g, Columbian Chemical) 110 mass in alternate embodiment 1 Carbon black (raven520u, particle diameter 58nm, oil factor 120m of part2/ g, Columbian Chemical).According to embodiment 1 Described in identical mode test the properties of stretching-sensitive sensor, the results are shown in Table 2.
Embodiment 5
In conjunction with Fig. 5, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but with 50 mass parts Carbon black (raven520u, particle diameter 58nm, oil factor 120m2/ g, Columbian Chemical) 110 mass in alternate embodiment 1 Carbon black (raven520u, particle diameter 58nm, oil factor 120m of part2/ g, Columbian Chemical).According to embodiment 1 Described in identical mode test the properties of stretching-sensitive sensor, the results are shown in Table 2.
Embodiment 6
In conjunction with Fig. 6, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but replaced with nitrile rubber Natural rubber in embodiment 1, with carbon black (vxc72, particle diameter 30nm, oil factor 174m of 30 mass parts2/ g, card is rich Special) carbon black (raven520u, particle diameter 58nm, oil factor 120m of 110 mass parts in alternate embodiment 12/ g, brother's rival Sub- chemistry), with the age resistor d of 1 mass parts in the age resistor d alternate embodiment 1 of 0.5 mass parts.According to embodiment 1 Described in identical mode test the properties of stretching-sensitive sensor, the results are shown in Table 2.
Embodiment 7
In conjunction with Fig. 7, according to the stretching-sensitive sensor manufacturing negative resistance effect with embodiment 1 same procedure, but use ethylene propylene diene rubber Replace the natural rubber in embodiment 1, with carbon black (raven430, particle diameter 82nm, oil factor 75m of 100 mass parts2/ g, Columbian Chemical) carbon black (raven520u, particle diameter 58nm, oil factor 120m of 110 mass parts in alternate embodiment 12/ g, Columbian Chemical), with the age resistor d of 1 mass parts in the age resistor d alternate embodiment 1 of 2 mass parts.According to and implement Described in example 1, identical mode tests the properties of stretching-sensitive sensor, and the results are shown in Table 2.
Table 1
Note: material composition unit: mass parts
Initial resistance and resistivity are mean value
Table 2
By resistance or electric capacity and the stretching of the stretching-sensitive sensor of the negative resistance effect to embodiment 7 for the embodiment in Fig. 1 to Fig. 71 The relation curve of deformation can be seen that the present invention offer stretching-sensitive sensor, its resistance value with tensile deformation increase continuous under Fall, capacitance is continuously increased with tensile deformation increase.
By the data in table 2 it can be seen that the stretching-sensitive type sensor of the negative resistance effect of the present invention has good resistance weight Renaturation can be with pulling sensitive effect Repeatability, and stretching-sensitive type resistor still has excellent pulling sensitive effect after 1000 stretchings.
The stretching-sensitive type sensor construction of the negative resistance effect that the present invention provides is simple, low cost of manufacture, senses under tensile force effect Device resistance constantly declines, and presents negative resistance effect, increases the electricity between the metal electrode of sensor two ends with tensile deformation simultaneously Capacitance increases, and can produce 5-500 times of resistance and capacitance variations, the stretching-sensitive sensor mechanics of the present invention when deformation quantity is 30% The amplitude of variation of amount is big, and very well, and this sensor is after 1000 repeated stretchings for flexible and elasticity, and resistance variations multiplying power is not Can decline.By detect drawing process sensor resistance change, or by the resistance signal of change be converted into voltage, electric current or Capacitance signal, can carry out the measurement of power, have in fields such as biomethanics, rehabilitation medical, intelligence wearing and artificial intelligence Wide application prospect.
Above content is to further describe it is impossible to assert the present invention with reference to specific preferred embodiment is made for the present invention Be embodied as be confined to these explanations.For general technical staff of the technical field of the invention, without departing from this On the premise of inventive concept, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.

Claims (8)

1. a kind of negative resistance effect stretching-sensitive type sensor it is characterised in that: include stretching-sensitive material and the metal electrode that is produced on described stretching-sensitive material surface;Described stretching-sensitive resistance material is that conducting particles is dispersed in the resistivity made in elastomeric material between 1.0 × 103ω .cm and 1.0 × 108A kind of conductive rubber material between ω .cm, each constituent mass part ratio is: 100 parts of rubber matrix, protection system 0.1-5 part, vulcanizing system 1-15 part, conducting particles 20-100 part.
2. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: described elastomeric material is selected from natural rubber, nitrile rubber, ethylene propylene diene rubber, butadiene-styrene rubber, neoprene, polyisoprene rubber, at least one in butadiene rubber.
3. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: described conducting particles be selected from carbon black, average grain diameter be 20-120nm, oil factor be 40cm3/100g - 200cm3/100g.
4. the stretching-sensitive type sensor of negative resistance effect as claimed in claim 1 is it is characterised in that described conductive rubber material is to carry out vulcanization crosslinking using sulphur or organic peroxide.
5. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: described metal electrode is selected from one of metal film, metal forming, sheet metal or profiled metal part.
6. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: the resistance value of described stretching-sensitive type sensor is between 50k ω and 50000k ω.
7. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: described stretching-sensitive type sensor under tensile force effect with tensile deformation increase resistance value decline, during tensile deformation 30% resistance variations multiplying power be 5-500 times.
8. negative resistance effect as claimed in claim 1 stretching-sensitive type sensor it is characterised in that: described stretching-sensitive type sensor under tensile force effect with tensile deformation increase capacitance increase, during tensile deformation 30% capacitance variation multiplying power be 5-500 times.
CN201510600916.5A 2015-07-15 2015-09-18 A kind of stretching-sensitive type sensor of negative resistance effect Expired - Fee Related CN106338351B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2015104173729 2015-07-15
CN201510417372 2015-07-15

Publications (2)

Publication Number Publication Date
CN106338351A true CN106338351A (en) 2017-01-18
CN106338351B CN106338351B (en) 2019-08-06

Family

ID=57826273

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510600916.5A Expired - Fee Related CN106338351B (en) 2015-07-15 2015-09-18 A kind of stretching-sensitive type sensor of negative resistance effect

Country Status (1)

Country Link
CN (1) CN106338351B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5095756A (en) * 1988-05-19 1992-03-17 Edwards Eric F R Linear movement sensors
CN101260237A (en) * 2008-04-11 2008-09-10 合肥工业大学 Pressure sensitive material for flexible tactile sensor and preparation method thereof
CN101464126A (en) * 2009-01-09 2009-06-24 清华大学 Production method of integrated submissive sensor for measuring curve clearance and force
CN103131187A (en) * 2013-03-28 2013-06-05 武汉大学 Composite pressure sensor and preparation method thereof
CN103808437A (en) * 2014-03-04 2014-05-21 东北大学 Differential type flexible piezoresistive device based on conductive polymer composite

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5095756A (en) * 1988-05-19 1992-03-17 Edwards Eric F R Linear movement sensors
CN101260237A (en) * 2008-04-11 2008-09-10 合肥工业大学 Pressure sensitive material for flexible tactile sensor and preparation method thereof
CN101464126A (en) * 2009-01-09 2009-06-24 清华大学 Production method of integrated submissive sensor for measuring curve clearance and force
CN103131187A (en) * 2013-03-28 2013-06-05 武汉大学 Composite pressure sensor and preparation method thereof
CN103808437A (en) * 2014-03-04 2014-05-21 东北大学 Differential type flexible piezoresistive device based on conductive polymer composite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘顺华 等: "炭黑填充复合型硅橡胶屏蔽性能及拉敏特性研究", 《大连理工大学学报》 *

Also Published As

Publication number Publication date
CN106338351B (en) 2019-08-06

Similar Documents

Publication Publication Date Title
CN105157891B (en) The stretching-sensitive sensor and its manufacture method of a kind of negative resistance effect
CN106338350B (en) A kind of pulling force responsive type sensor of positive electricity inhibition effect
CN105606270B (en) A kind of Grazing condition touch-pressure sensation sensor based on capacitance resistance combined type
CN108701505B (en) Stretchable conductor sheet, stretchable conductor sheet having adhesive property, and method for forming wiring composed of stretchable conductor on fabric
JP5166714B2 (en) Cross-linked elastomer for sensor and method for producing the same
CN105136369B (en) A kind of Grazing condition resistance-type touch-pressure sensation detecting sensor and preparation method thereof
CN111253751B (en) A kind of carbon nanotube polydimethylsiloxane composite material and its preparation method and application
US10591272B2 (en) Strain sensor with improved sensitivity
CN102770742A (en) Flexible pressure sensor and flexible pressure sensing array
CN105482176A (en) Conductive rubber material for flexible sensor and preparation method and application of conductive rubber material
CN105670297A (en) Conductive rubber material for flexible sensors as well as preparation method and application of conductive rubber material
CN111512705A (en) Retractable conductive wiring material and retractable conductive wiring module with retractable conductive wiring material
Baloda et al. A flexible pressure sensor based on multiwalled carbon nanotubes/polydimethylosiloxane composite for wearable electronic-skin application
JP6165002B2 (en) Elastic flexible sensor
WO2011098869A2 (en) An electrolyte sensor using conductive elastomer
Liu et al. Superstretchable and Linear-Response Strain Sensors With Carbon Nanotubes Ultrasonically Assembled on Silicone Rubber Film
Azhari et al. Toward automated tomato harvesting system: Integration of haptic based piezoresistive nanocomposite and machine learning
JP2013232293A (en) Tactile sensor
US20240167898A1 (en) Flexible strain sensor based on same conductive material, and method for preparing same
Khaanghah et al. Silicone/carbon black-filled elastomer-based self-healing strain sensor
Kundu et al. Elastomeric Sensor-Triboelectric Nanogenerator Coupled System for Multimodal Strain Sensing and Organic Vapor Detection
CN106338351A (en) Negative-resistance-effect tension-sensitive sensor
Momin et al. Development of compact load cell using multiwall carbon nanotube/cotton composites and its application to human health and activity monitoring
CN105542246A (en) Conductive rubber material used for flexible sensor as well as preparation method and application of conductive rubber material
JP6770743B2 (en) Pressure sensor

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20190806

CF01 Termination of patent right due to non-payment of annual fee