CN106314002B - Pearly-lustre embossment firework paper and production method on pearly-lustre embossment pigment and ceramic glaze on ceramic glaze - Google Patents
Pearly-lustre embossment firework paper and production method on pearly-lustre embossment pigment and ceramic glaze on ceramic glaze Download PDFInfo
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- CN106314002B CN106314002B CN201610747641.2A CN201610747641A CN106314002B CN 106314002 B CN106314002 B CN 106314002B CN 201610747641 A CN201610747641 A CN 201610747641A CN 106314002 B CN106314002 B CN 106314002B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 63
- 239000000049 pigment Substances 0.000 title claims abstract description 46
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000004579 marble Substances 0.000 claims abstract description 36
- 239000010433 feldspar Substances 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 229910021538 borax Inorganic materials 0.000 claims abstract description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 11
- 238000007639 printing Methods 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 23
- 238000000498 ball milling Methods 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 10
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 7
- 238000005476 soldering Methods 0.000 claims description 6
- 239000001030 cadmium pigment Substances 0.000 claims description 5
- 238000004049 embossing Methods 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 238000013518 transcription Methods 0.000 claims description 5
- 230000035897 transcription Effects 0.000 claims description 5
- 229910052656 albite Inorganic materials 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229910052657 oligoclase Inorganic materials 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 229910000846 In alloy Inorganic materials 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 abstract description 2
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- CXLUIRPQSBYREP-WDSKDSINSA-N (3s)-3-[[(2s)-2-amino-4,4-dicarboxybutanoyl]amino]propane-1,1,3-tricarboxylic acid Chemical compound OC(=O)C(C(O)=O)C[C@H](N)C(=O)N[C@@H](CC(C(O)=O)C(O)=O)C(O)=O CXLUIRPQSBYREP-WDSKDSINSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 108010004609 gamma-carboxyglutamyl-gamma-carboxyglutamic acid Proteins 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052652 orthoclase Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
Landscapes
- Decoration By Transfer Pictures (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to pearly-lustre embossment firework paper and production method on pearly-lustre embossment pigment on a kind of ceramic glaze and ceramic glaze, belong to color printing technology on ceramic glaze.Pearly-lustre embossment pigment includes the following component according to mass percent meter on the ceramic glaze: feldspar 30%-40%, borax 15%-25%, kaolin 5%-15%, low-temperature lead-free frit 20%-50%, wherein each component percentage adds up to 100%.After pearly-lustre embossment firework paper carries out applique to ceramic on glaze produced by the present invention, pearly-lustre embossment has stronger adhesive force and good glossiness on glaze, and assign the excellent resistance to soiling of ceramic, scrub resistance and wear resistence, also impart the excellent metal pearly-lustre colouring effect of ceramic, and under the light of different angle, ceramic can show different degrees of pearly-lustre metal effect, furthermore, marble paper obtained is beautiful and environment-friendly, its lead-indium alloy is extremely low, meets the standard of China and European and American countries.
Description
Technical field
The invention belongs to printing technologies color on ceramic glaze, and in particular to pearly-lustre embossment pigment and pottery on a kind of ceramic glaze
Pearly-lustre embossment firework paper and production method on enamel.
Background technique
Ceramic pearly-lustre embossment pigment is the embossment cap layer pigment for being exclusively used in marble paper on ceramic glaze, its main feature is that being burnt into production
After can achieve stronger metal sense, and different metal effects can be shown under the light of different angle, it is color transformed
It is abundant, substantially close to the color development of organic pigment.Traditional its ingredient of pearly-lustre embossment pigment is mainly artificial synthesized titanium oxide cloud
Master slice, firing fusing point are 1500 DEG C or so, although cost is relatively low for titanium oxide mica sheet, have the disadvantage that first, attached
Put forth effort poor；Second, five gloss of rough surface；Third, resistance to soiling are poor and not wash resistant；Current solution is to print
Add the bright cap layer of printthrough on the pearly-lustre pattern finished again, so that the glossiness and wear resistence of surface of ceramic products are improved, but due to
Pearlescent pigment and the matching of transparent cap layer are poor, while bringing new problem again: surface of ceramic products not only loses pearl
The due metal sense of delustering pigment, also affects the color of pearlescent pigment itself.
Although and have many reports of embossment on associated ceramic glaze in the prior art, there are no the report of pearly-lustre embossment
Road, and embossment marble paper only has the single colour system such as transparent and milky white at present, limitation is larger, and it is above-mentioned it is many it is insufficient mainly by
Caused by the limitation of embossment pigment formula and manufacture craft, and the embossment pigment of many marble papers is on being pasted onto ceramic
It will appear that pigment distribution is uneven after drying, the appearance of ceramic influenced, because of composition of the embossment to embossment pigment on glaze
And manufacture craft requirement is higher compared with pigment in glaze.Applicant submitted in 2014 application No. is the China of 201410243698.X
Patent discloses a kind of manufacture craft of famille-rose embossment printed matter on glaze, although it has filled up on glaze embossment on colour system
Blank, but applicant found in subsequent research the marble paper in actual use its famille-rose embossment color effect not
Obviously, firing temperature is higher, mixes colours also cumbersome, is still further improved.
Summary of the invention
The purpose of the present invention is to solve the deficiencies in the prior art, and provide on a kind of ceramic glaze pearly-lustre embossment pigment and
Pearly-lustre embossment firework paper and production method on ceramic glaze, this method is easy to operate, and the firing temperature of embossment pigment is lower, and pearly-lustre is floating
The adhesive force of carving is stronger, and resistance to soiling and washing fastness are preferable, and glossiness and wear resistence are preferable, and it is excellent can to assign ceramic
Pearly-lustre anaglyph.
The present invention adopts the following technical scheme:
Pearly-lustre embossment pigment on ceramic glaze, including the following component according to mass percent meter: feldspar 30%-40%, borax
15%-25%, kaolin 5%-15%, low-temperature lead-free frit 20%-50%, wherein each component percentage adds up to 100%.
Further, pearly-lustre embossment pigment on the ceramic glaze, wherein the feldspar is in orthoclase or plagioclase
One kind.
Further, pearly-lustre embossment pigment on the ceramic glaze, wherein the feldspar is potassium feldspar, albite or Austria
One of feldspar.
The production method of pearly-lustre embossment firework paper, includes the following steps: on ceramic glaze
Step 1, the preparation of pearl powder: according to mass percent meter, by the low temperature of the pearl powder of 70%-90% and 10%-30%
The ethyl alcohol ball milling 2-4h of phase homogenous quantities is added after lead free soldering mixing, it is spare to crushed 200 meshes after drying；
Step 2, the preparation of pearly-lustre embossment pigment: according to the mass percent, by feldspar, borax, kaolin and low temperature
Lead free soldering is uniformly mixed, and by calcining, ball milling, drying and is crushed up to the pearly-lustre embossment pigment, wherein the calcining has
Body is to be gradually heated to 1050 DEG C, keeps the temperature 20-30min；The ball milling is specially that ethyl alcohol identical with raw material gross weight is added, in
Ball milling 120h under the revolving speed of ball milling 1000r/min；The drying is specially to dry at 50-60 DEG C, described to smash it through 350 mesh
Sieve；
Step 3, printing:
A: the unleaded cadmium pigment of background color is screen printed on transcription base stock with 250 mesh, and dry 6h or more obtains background color marble paper；
B: the pearl powder is stirred evenly with ink, and the mass ratio of pearl powder and ink is 1:1-1:2, rolls Mo Houyong
200 mesh are screen printed on the background color of background color marble paper obtained by step a, and naturally dry 4h or more obtains pearly-lustre marble paper；
C: the pearly-lustre embossment pigment is uniformly mixed with ink, and the mass ratio of pearly-lustre embossment pigment and ink is 10:6-
10:8 is screen printed on the pearly-lustre color of step b gained pearly-lustre marble paper after rolling ink with 120 mesh, and print pass is as needed for 1-3
Secondary, naturally dry 12h or more obtains pearly-lustre embossment marble paper；
D: cover glue is screen printed on the pearly-lustre embossing pattern of step c gained pearly-lustre embossment marble paper with 80 mesh, dry
Up to pearly-lustre embossment firework paper on the ceramic glaze.
Further, on the ceramic glaze pearly-lustre embossment firework paper production method, wherein ball described in step 1
Grind the ball milling 2-4h under 1500r/min revolving speed.
Further, on the ceramic glaze pearly-lustre embossment firework paper production method, wherein forged described in step 2
Burning is specially to be gradually heated to 1050 DEG C, keeps the temperature 20-30min；The ball milling is specially that second identical with raw material gross weight is added
Alcohol, the ball milling 120h under the revolving speed of ball milling 1000r/min；The drying is specially to dry at 50-60 DEG C, described to smash it through
350 meshes.
Further, on the ceramic glaze pearly-lustre embossment firework paper production method, wherein institute in step 3 b and c
Stating dry is naturally dry.
The present invention also provides a kind of ceramic glazes as made from the production method of pearly-lustre embossment firework paper on the ceramic glaze
Upper pearly-lustre embossment firework paper.
Pearly-lustre embossment firework paper applique is after ceramic surface on ceramic glaze produced by the present invention, and first dry in the air 6h or more naturally, then
30-40min is baked at 1100-1150 DEG C can assign pearly-lustre anaglyph on the excellent glaze of ceramic.
Compared with prior art, the present invention has the advantages that:
After pearly-lustre embossment firework paper carries out applique to ceramic on glaze produced by the present invention, pearly-lustre embossment has on glaze
Stronger adhesive force and good glossiness, and the excellent resistance to soiling of ceramic, scrub resistance and wear resistence are assigned, also assign
Ceramic excellent metal pearly-lustre colouring effect, and under the light of different angle, ceramic can be shown not
With the pearly-lustre metal effect of degree, in addition, marble paper obtained is beautiful and environment-friendly, lead-indium alloy is extremely low, respectively less than 0.005mg/
L meets the standard of China and European and American countries.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
It will be understood to those of skill in the art that the following example is merely to illustrate the present invention, and it should not be regarded as limiting this hair
Bright range.Pearl powder used in the present invention is the pearl powder of Merck KGaA production, and the low-temperature lead-free frit used is purchased from English
The rich company of state Zhuan Xinwan.
Embodiment 1
Pearly-lustre embossment pigment on ceramic glaze, including the following component according to mass percent meter: potassium feldspar 35%, borax
20%, kaolin 10%, low-temperature lead-free frit 35%, wherein each component percentage adds up to 100%.
The production method of pearly-lustre embossment firework paper, includes the following steps: on ceramic glaze
Step 1, the preparation of pearl powder: according to mass percent meter, by 80% pearl powder and 20% low-temperature lead-free frit
The ethyl alcohol of addition phase homogenous quantities ball milling 3h under 1500r/min revolving speed, it is spare to crushed 200 meshes after mixing after drying；
Step 2, the preparation of pearly-lustre embossment pigment: according to the mass percent, by feldspar, borax, kaolin and low temperature
Lead free soldering is uniformly mixed, and by calcining, ball milling, drying and is crushed up to the pearly-lustre embossment pigment；
Step 3, printing:
A: the unleaded cadmium pigment of background color is screen printed on transcription base stock with 250 mesh, and dry 6h or more obtains background color marble paper；
B: the pearl powder is stirred evenly with ink, and the mass ratio of pearl powder and ink is 1:1, is rolled after ink with 200 mesh
It is screen printed on the background color of background color marble paper obtained by step a, dry 4h or more obtains pearly-lustre marble paper；
C: the pearly-lustre embossment pigment is uniformly mixed with ink, and the mass ratio of pearly-lustre embossment pigment and ink is 10:7,
It is screen printed into 120 mesh on the pearly-lustre color of step b gained pearly-lustre marble paper after rolling ink, print pass is done as needed for 1-3 times
Dry 12h or more obtains pearly-lustre embossment marble paper；
D: cover glue is screen printed on the pearly-lustre embossing pattern of step c gained pearly-lustre embossment marble paper with 80 mesh, dry
Up to pearly-lustre embossment firework paper on the ceramic glaze.
Embodiment 2
Pearly-lustre embossment pigment on ceramic glaze, including the following component according to mass percent meter: albite 30%, borax
15%, kaolin 5%, low-temperature lead-free frit 50%, wherein each component percentage adds up to 100%.
The production method of pearly-lustre embossment firework paper, includes the following steps: on ceramic glaze
Step 1, the preparation of pearl powder: according to mass percent meter, by 70% pearl powder and 30% low-temperature lead-free frit
The ethyl alcohol of addition phase homogenous quantities ball milling 2h under 1500r/min revolving speed, it is spare to crushed 200 meshes after mixing after drying；
Step 2, the preparation of pearly-lustre embossment pigment: according to the mass percent, by feldspar, borax, kaolin and low temperature
Lead free soldering is uniformly mixed, and by calcining, ball milling, drying and is crushed up to the pearly-lustre embossment pigment；
Step 3, printing:
A: the unleaded cadmium pigment of background color is screen printed on transcription base stock with 250 mesh, and dry 6h or more obtains background color marble paper；
B: the pearl powder is stirred evenly with ink, and the mass ratio of pearl powder and ink is 1:1.5, is rolled after ink with 200
Mesh is screen printed on the background color of background color marble paper obtained by step a, and dry 4h or more obtains pearly-lustre marble paper；
C: the pearly-lustre embossment pigment is uniformly mixed with ink, and the mass ratio of pearly-lustre embossment pigment and ink is 10:6,
It is screen printed into 120 mesh on the pearly-lustre color of step b gained pearly-lustre marble paper after rolling ink, print pass is done as needed for 1-3 times
Dry 12h or more obtains pearly-lustre embossment marble paper；
D: cover glue is screen printed on the pearly-lustre embossing pattern of step c gained pearly-lustre embossment marble paper with 80 mesh, dry
Up to pearly-lustre embossment firework paper on the ceramic glaze.
Embodiment 3
Pearly-lustre embossment pigment on ceramic glaze, including the following component according to mass percent meter: oligoclase 40%, borax
25%, kaolin 15%, low-temperature lead-free frit 20%, wherein each component percentage adds up to 100%.
The production method of pearly-lustre embossment firework paper, includes the following steps: on ceramic glaze
Step 1, the preparation of pearl powder: according to mass percent meter, by 90% pearl powder and 10% low-temperature lead-free frit
The ethyl alcohol of addition phase homogenous quantities ball milling 4h under 1500r/min revolving speed, it is spare to crushed 200 meshes after mixing after drying；
Step 2, the preparation of pearly-lustre embossment pigment: according to the mass percent, by feldspar, borax, kaolin and low temperature
Lead free soldering frit is uniformly mixed, and by calcining, ball milling, drying and is crushed up to the pearly-lustre embossment pigment；
Step 3, printing:
A: the unleaded cadmium pigment of background color is screen printed on transcription base stock with 250 mesh, and dry 6h or more obtains background color marble paper；
B: the pearl powder is stirred evenly with ink, and the mass ratio of pearl powder and ink is 1:2, is rolled after ink with 200 mesh
It is screen printed on the background color of background color marble paper obtained by step a, dry 4h or more obtains pearly-lustre marble paper；
C: the pearly-lustre embossment pigment is uniformly mixed with ink, and the mass ratio of pearly-lustre embossment pigment and ink is 10:8,
It is screen printed into 120 mesh on the pearly-lustre color of step b gained pearly-lustre marble paper after rolling ink, print pass is done as needed for 1-3 times
Dry 12h or more obtains pearly-lustre embossment marble paper；
D: cover glue is screen printed on the pearly-lustre embossing pattern of step c gained pearly-lustre embossment marble paper with 80 mesh, dry
Up to pearly-lustre embossment firework paper on the ceramic glaze.
By pearly-lustre embossment firework paper applique on ceramic glaze made from the embodiment of the present invention 1 to 3 behind ceramic surface, first
Naturally dry in the air 6h or more, and 6h is baked at 780-820 DEG C, tests the performance of ceramic, test result see the table below 1:
1 performance test data of table
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Resistance to soiling (resistance to low concentration acid) | GLA | GLA | GLA |
| Scrub resistance (wet rubbing), it is secondary | 10000 | 10000 | 10000 |
| Wear resistence | 6000 turns, level Four | 6000 turns, level Four | 6000 turns, level Four |
| Adhesive force (cross-hatching) | 4B | 4B | 4B |
As seen from the above table, it can assign ceramics excellent resistant according to pearly-lustre embossment firework paper on glaze produced by the present invention
Property, scrub resistance, wear resistence, and pearly-lustre embossment pigment and ceramics adhesive force it is stronger, can reach 4B grades.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation
It is merely illustrated the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also has
Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention
It is defined by the appending claims and its equivalent thereof.
Claims (5)
1. the production method of pearly-lustre embossment firework paper on ceramic glaze, which comprises the steps of:
Step 1, the preparation of pearl powder: according to mass percent meter, by the low temperature of the pearl powder of 70%-90% and 10%-30%
The ethyl alcohol ball milling 2-4h of phase homogenous quantities is added after lead free soldering mixing, it is spare to crushed 200 meshes after drying；
Step 2, the preparation of pearly-lustre embossment pigment: pearly-lustre embossment pigment includes according to mass percent meter on the ceramic glaze
Following component: feldspar 30%-40%, borax 15%-25%, kaolin 5%-15%, low-temperature lead-free frit 20%-50%,
Described in each component percentage add up to 100%, according to the mass percent, by feldspar, borax, kaolin and low-temperature lead-free
Frit is uniformly mixed, and by calcining, ball milling, drying and is crushed up to the pearly-lustre embossment pigment；Wherein the feldspar is that potassium is long
One of stone, albite or oligoclase；
Step 3, printing:
A: the unleaded cadmium pigment of background color is screen printed on transcription base stock with 250 mesh, and dry 6h or more obtains background color marble paper；
B: the pearl powder is stirred evenly with ink, and the mass ratio of pearl powder and ink is 1:1-1:2, is rolled after ink with 200 mesh
It is screen printed on the background color of background color marble paper obtained by step a, dry 4h or more obtains pearly-lustre marble paper；
C: the pearly-lustre embossment pigment is uniformly mixed with ink, and the mass ratio of pearly-lustre embossment pigment and ink is 10:6-10:8,
It is screen printed into 120 mesh on the pearly-lustre color of step b gained pearly-lustre marble paper after rolling ink, print pass is done as needed for 1-3 times
Dry 12h or more obtains pearly-lustre embossment marble paper；
D: cover glue is screen printed on the pearly-lustre embossing pattern of step c gained pearly-lustre embossment marble paper with 80 mesh, is drying to obtain
Pearly-lustre embossment firework paper on the ceramic glaze.
2. according to the production method of pearly-lustre embossment firework paper on ceramic glaze described in right 1, which is characterized in that described in step 1
Ball milling ball milling 2-4h under 1500r/min revolving speed.
3. the production method of pearly-lustre embossment firework paper on ceramic glaze according to claim 1, which is characterized in that in step 2
The calcining is specially to be gradually heated to 1050 DEG C, keeps the temperature 20-30min；The ball milling is specially to be added and raw material gross weight phase
Same ethyl alcohol, the ball milling 120h under the revolving speed of ball milling 1000r/min；The drying is specially to dry at 50-60 DEG C, the powder
350 meshes are crossed after broken.
4. the production method of pearly-lustre embossment firework paper on ceramic glaze according to claim 1, which is characterized in that step 3 b
It is naturally dry with drying described in c.
5. pearly-lustre embossment on the ceramic glaze as made from the production method of pearly-lustre embossment firework paper on ceramic glaze described in claim 1
Firework paper.
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| CN201610747641.2A CN106314002B (en) | 2016-08-30 | 2016-08-30 | Pearly-lustre embossment firework paper and production method on pearly-lustre embossment pigment and ceramic glaze on ceramic glaze |
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| CN201610747641.2A CN106314002B (en) | 2016-08-30 | 2016-08-30 | Pearly-lustre embossment firework paper and production method on pearly-lustre embossment pigment and ceramic glaze on ceramic glaze |
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| CN111070952A (en) * | 2019-12-28 | 2020-04-28 | 福建省德化县华兴陶瓷有限公司 | Ceramic-glazed pearlescent relief color paper and manufacturing method thereof |
| CN111675936A (en) * | 2020-05-11 | 2020-09-18 | 醴陵市精陶瓷业有限公司 | Ceramic three-dimensional stained paper and preparation method and application thereof |
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| ES2423321T3 (en) * | 2003-11-17 | 2013-09-19 | Microban Products Company | Procedure for the preparation of cement slab products that have antimicrobial properties |
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Denomination of invention: Ceramic overglazed pearlescent relief pigment, ceramic overglazed pearlescent relief color decal paper and manufacturing method thereof Effective date of registration: 20190820 Granted publication date: 20190409 Pledgee: Industrial Commercial Bank of China Ltd Dehua branch Pledgor: Dehua, Fujian Province Ming Fengjin marble paper company limited Registration number: Y2019990000098 |