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CN106278186A - A kind of preparation method of blue and white with copper red colors pottery - Google Patents

A kind of preparation method of blue and white with copper red colors pottery Download PDF

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Publication number
CN106278186A
CN106278186A CN201610772920.4A CN201610772920A CN106278186A CN 106278186 A CN106278186 A CN 106278186A CN 201610772920 A CN201610772920 A CN 201610772920A CN 106278186 A CN106278186 A CN 106278186A
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Prior art keywords
blue
decoration
glaze
white
porcelain body
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CN201610772920.4A
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张志杰
邓国舟
李涛
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Guangdong Changlong Ceramic Co Ltd
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Guangdong Changlong Ceramic Co Ltd
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Priority to CN201610772920.4A priority Critical patent/CN106278186A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Adornments (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses the preparation method of a kind of blue and white with copper red colors pottery.The mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly by the method;After filter pressing, make mud cake, then through vacuum pugging, stand old, plasticity molding, prepare ceramic green;Ceramic green is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtains pottery biscuiting porcelain body;Pottery biscuiting porcelain body is carried out underglaze blue decoration, obtains underglaze blue decoration porcelain body;Underglaze blue decoration porcelain body is executed clear frit, obtains covering glaze underglaze blue decoration porcelain body;To carrying out in glaze under-glaze red decoration to covering glaze underglaze blue decoration porcelain body, obtain blue and white with copper red colors composite decoration porcelain body;Blue and white with copper red colors composite decoration porcelain body is burnt till at 1280 DEG C~1350 DEG C, is incubated 1~3 hour, natural cooling, prepare blue and white with copper red colors ceramic product.Under-glaze red color development respectively in the blue and white with copper red colors underglaze blue and glaze of pottery that the method prepares, bright in colour, it is to avoid in sintering process, two kinds of character difference color materials influences each other.

Description

A kind of preparation method of blue and white with copper red colors pottery
Technical field
The present invention relates to ceramic standby, particularly relate to the preparation method of a kind of blue and white with copper red colors pottery.
Background technology
After porcelain is fired successfully by the mankind, the decoration of porcelain is just explored in improvement progressive, generally constantly Can be summarized as " tire decoration ", " glaze decoration ", " color equipment decorations " three kinds of modes, three kinds of modes be combined with each other, and just constitute and are difficult to total number, many The chinaware article that appearance is colorful.Tire decoration includes that moulding, heap are moulded, laminating, press back, to pick, draw, carve, engrave and twist tire, socket etc. right Carcass beautify processing mode.Glaze decoration is the preparation with various different colours glaze and spreads, and reaches to hide carcass, beautify device Thing, the decoration functions beneficially used.And color equipment decorations are the methods decorating porcelain that draws a design with shades of colour, its purpose exists entirely In people, aesthstic pursuit, color equipment decorations porcelain are called for short faience, are the main flow of ceramic decoration.By color, glaze layer relation of plane, faience Can be divided mainly into four big classes, the Doucai contrasting colors i.e. combined under underglaze colour, in-glaze decoration, overglaze color and glaze glazing.Wherein on underglaze colour, glaze Color and Doucai contrasting colors all has the history of centuries, technology maturation, is widely used.In-glaze decoration is the one that 20 century 70s grow up New decoration of porcelain material and skill and technique, impose on implements glaze by overglaze color method, and by high temperature rapid firing, glaze softens melted, makes Pigment penetrates in glaze, glaze face closure after cooling.In-glaze decoration picture exquisiteness is sparkling and crystal-clear, anticorrosive, wear-resistant, has the effect of underglaze colour Really.
Blue-and-white porcelain is the high-grade porcelain with Typical Chinese characteristic, is a kind of underglaze colour porcelain, and it is with cobalt oxide for coloring Agent, first describes decorative pattern on porcelain base, then executes layer of transparent glaze, enter kiln and form through about 1350 DEG C high-temperature firings.Although blue-and-white porcelain Colouring single, but its more multicolored porcelain is the most aobvious luicd and elegant, graceful, is extensively liked by people, it is unleaded nontoxic, acid-proof wear-proof, complexion warp Do not move back for a long time, have the title of " the most amaranthine blue and white ".Along with the development of science and technology, blue-and-white porcelain is changed by original pure handwritten drawings Becoming applique process, production efficiency is greatly improved, and the market expansion is rapid.But blue-and-white porcelain decoration remains simple green grass or young crops at present Color, the variation in market inevitably asks decoration and the variation of color, traditional blue and white on the basis of, other color compound, Blue-and-white porcelain will be made to present more gorgeous decorative effect, wide market.
Under-glaze red porcelain is the another kind of high-grade under enamel colored porcelain having an Oriental character, and it is to describe on mold with copper red material Decorative pattern back cover, with clear frit, burns till through high temperature reduction flame atmosphere, makes to present under glaze the porcelain of red decorative pattern.The compound of copper is not Same base glaze and firing atmosphere present different colors, as taken on a red color in reducing atmosphere, in the face making solvent with lead In green in material, in blueness in alkali or leadless glaze.Therefore, base glaze and firing atmosphere are required the tightest by under-glaze red porcelain Lattice.Additionally, copper ion is the most sensitive to temperature, in kiln the duration and degree of heating less than, present dark red or bois de rose;The duration and degree of heating little over copper from Son just volatilizees, and escapes, present distinctive crimson phenomenon or simply fade from glaze layer, and decorative pattern lines are common dizzy scattered, so in glaze Braise into difficulty in soy sauce big.
The superfine product of " blue and white with copper red colors " Chinese pottery especially, " blue and white with copper red colors " is to burn, at blue and white and under-glaze red, the basis made On make, this with cobalt oxide be coloring agent blue and white material and be coloring agent with copper oxide combining of being drawn of under-glaze red colorant Box-like underglaze colour decoration, existing blue and white verdant product beautiful plain characteristic clear, deep and remote, have again magnificent and peaceful, gorgeous fawning of under-glaze red and The most impetuous, ardent and implicit characteristic.Both strong points organically blend, the most plain but also gorgeous, define blue or green reddish tint, changes in temperature The taste characteristic that phase contrast, sound are set each other off, this uses copper and the technique of cobalt colored drawing on implements simultaneously, is excellent magnificent Extremely, be worth outstanding.Owing to blue and white material is different from under-glaze red colorant character, firing temperature and firing chamber's atmosphere requirements also have difference Different, therefore both impose on a device and colour generation red, blue is just right, not a duck soup.Current works handed down from ancient times come from Qing Dynasty Qianrong more The government porcelain kiln in period, after Qianrong, government porcelain kiln produces and the most constantly reduces, and the burning of blue and white with copper red colors is made quantity and started to reduce, and technique declines, Carcass is gradually thick, and glaze juice is the dilutest, and under-glaze red is subduing, causes the works handed down from ancient times of blue and white with copper red colors now few.Beijing's Imperial Palace museum It is the museum that domestic collection Chinese ancient porcelain historical relic quantity is most and kind is the abundantest, has collected more than 350,000 part ancient pottery and porcelain literary compositions altogether Thing, blue and white with copper red colors collection only has about more than 130 parts, the most precious.
Summary of the invention
It is an object of the invention to, in conjunction with the demand that people are growing to all kinds of high-grade ceramics, it is provided that a kind of novel Blue and white with copper red colors ceramic preparation.
The present invention uses new technical thought, modern times in-glaze decoration technology is applied to blue and white with copper red colors porcelain and produces, with glaze In lower underglaze blue decoration and glaze, under-glaze red decoration combines, it is to avoid in sintering process, two kinds of character difference color materials influences each other;Logical Cross the accurate control burnt till, make under-glaze red color development respectively in underglaze blue and glaze.
The purpose of the present invention is achieved through the following technical solutions:
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240~360 hours, make inside mud cake Uniform moisture, obtains ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtain pottery unglazed porcelain Tire;
(5) the ceramic biscuiting porcelain body that step (4) obtains is carried out blue and white color material decoration, obtain underglaze blue decoration porcelain body;
(6) the underglaze blue decoration porcelain body that step (5) obtains is executed clear frit, obtain covering glaze underglaze blue decoration porcelain body;
(7) the glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red decoration in glaze, obtains blue and white with copper red colors multiple Attach together decorations porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1280 DEG C~1320 DEG C calcinings, is incubated 1~3 Hour, natural cooling, prepare blue and white with copper red colors ceramic product.
Relative to prior art, modern times in-glaze decoration technology is applied to blue and white with copper red colors porcelain manufacture by the present invention, with under glaze In underglaze blue decoration and glaze, copper red decoration combines, it is to avoid the influencing each other of two kinds of character difference color materials in sintering process, has fresh Bright feature.
Detailed description of the invention
In order to be better understood from present disclosure, below in conjunction with case study on implementation to further instruction of the present invention, but this The scope that invention claims not only is limited in listed example ranges.
Embodiment 1
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240 hours, make mud cake internal moisture equal Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) carries out blue and white color material handwritten drawings decoration,Obtain underglaze blue decoration porcelain Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red color material handwritten drawings decoration,Obtain blue and white Under-glaze red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1280 DEG C of calcinings, is incubated 3 hours, the coldest But, blue and white with copper red colors ceramic product is prepared.
Embodiment 2
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 300 hours, make mud cake internal moisture equal Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 640 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) carries out blue and white color material handwritten drawings decoration,Obtain underglaze blue decoration porcelain Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red marble paper applique decoration,Obtain in blue and white glaze Red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1300 DEG C of calcinings, is incubated 2 hours, the coldest But, blue and white with copper red colors ceramic product is prepared.
Embodiment 3
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 360 hours, make mud cake internal moisture equal Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 700 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) uses blue and white marble paper applique decoration technology,Obtain underglaze blue decoration porcelain Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red color material handwritten drawings decoration,Obtain blue and white Under-glaze red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1320 DEG C of calcinings, is incubated 1.5 hours, natural Cooling, prepares blue and white with copper red colors ceramic product.
Embodiment 4
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 320 hours, make mud cake internal moisture equal Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 680 DEG C, obtain pottery biscuiting porcelain body;
(5))The ceramic biscuiting carcass obtaining step (4) uses blue and white marble paper applique decoration technology,Obtain underglaze blue decoration Porcelain body;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red marble paper applique decoration,Obtain in blue and white glaze Red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1350 DEG C of calcinings, is incubated 1 hour, the coldest But, blue and white with copper red colors ceramic product is prepared.

Claims (1)

1. a preparation method for blue and white with copper red colors pottery, is to comprise the steps of
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;Mud cake is made after filter pressing, then through vacuum pugging, Air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240~360 hours, make mud cake internal moisture Uniformly, ceramic batch is obtained;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtain pottery biscuiting porcelain body;
(5) the ceramic biscuiting porcelain body that step (4) obtains is carried out the underglaze blue decoration such as manual drawing or applique, obtain underglaze blue decoration porcelain Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7) the glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out the under-glaze red such as manual drawing or applique decoration in glaze, obtains Blue and white with copper red colors composite decoration porcelain body;
(8) being burnt till at 1280 DEG C~1350 DEG C by the blue and white with copper red colors composite decoration porcelain body that step (7) obtains, insulation 1~3 is little Time, natural cooling, prepare blue and white with copper red colors ceramic product.
CN201610772920.4A 2016-08-30 2016-08-30 A kind of preparation method of blue and white with copper red colors pottery Pending CN106278186A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106830687A (en) * 2017-02-16 2017-06-13 内江师范学院 A kind of ceramic sintering process that red glaze is fabricated to Chinese painting color ink effect
CN106945149A (en) * 2017-03-08 2017-07-14 龙泉市金宏瓷业有限公司 A kind of ceramic body 3D printing technique
CN114835476A (en) * 2022-03-15 2022-08-02 福建省德化县豪发陶瓷有限公司 High-strength blue-and-white five-color glazed porcelain and preparation method thereof
CN114907148A (en) * 2022-05-23 2022-08-16 孙赛华 Formula and processing method of over-glaze blue and white pigment

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898119A (en) * 2012-10-10 2013-01-30 福建省德化县永德信陶瓷有限责任公司 Low-temperature once-fired environment-friendly ceramic
CN103833423A (en) * 2014-01-14 2014-06-04 佛山市东鹏陶瓷有限公司 Ceramic tile preparation method and product thereof
CN104108956A (en) * 2014-08-01 2014-10-22 佛山市东鹏陶瓷有限公司 Manufacturing method of ceramic tile and product of ceramic tile
CN203999394U (en) * 2014-05-09 2014-12-10 佛山市东鹏陶瓷有限公司 A kind of glazed brick of throwing
CN104744078A (en) * 2015-03-31 2015-07-01 马健 Firing technique of blue-and-white underglaze red
CN104860647A (en) * 2015-04-13 2015-08-26 广东昌隆陶瓷股份有限公司 Method for manufacturing high-strength egg-shell china
CN104944915A (en) * 2015-05-29 2015-09-30 苏州拓科仪器设备有限公司 Underglazered blue and white porcelain

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898119A (en) * 2012-10-10 2013-01-30 福建省德化县永德信陶瓷有限责任公司 Low-temperature once-fired environment-friendly ceramic
CN103833423A (en) * 2014-01-14 2014-06-04 佛山市东鹏陶瓷有限公司 Ceramic tile preparation method and product thereof
CN203999394U (en) * 2014-05-09 2014-12-10 佛山市东鹏陶瓷有限公司 A kind of glazed brick of throwing
CN104108956A (en) * 2014-08-01 2014-10-22 佛山市东鹏陶瓷有限公司 Manufacturing method of ceramic tile and product of ceramic tile
CN104744078A (en) * 2015-03-31 2015-07-01 马健 Firing technique of blue-and-white underglaze red
CN104860647A (en) * 2015-04-13 2015-08-26 广东昌隆陶瓷股份有限公司 Method for manufacturing high-strength egg-shell china
CN104944915A (en) * 2015-05-29 2015-09-30 苏州拓科仪器设备有限公司 Underglazered blue and white porcelain

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106830687A (en) * 2017-02-16 2017-06-13 内江师范学院 A kind of ceramic sintering process that red glaze is fabricated to Chinese painting color ink effect
CN106945149A (en) * 2017-03-08 2017-07-14 龙泉市金宏瓷业有限公司 A kind of ceramic body 3D printing technique
CN114835476A (en) * 2022-03-15 2022-08-02 福建省德化县豪发陶瓷有限公司 High-strength blue-and-white five-color glazed porcelain and preparation method thereof
CN114907148A (en) * 2022-05-23 2022-08-16 孙赛华 Formula and processing method of over-glaze blue and white pigment

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Application publication date: 20170104