CN106278186A - A kind of preparation method of blue and white with copper red colors pottery - Google Patents
A kind of preparation method of blue and white with copper red colors pottery Download PDFInfo
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- CN106278186A CN106278186A CN201610772920.4A CN201610772920A CN106278186A CN 106278186 A CN106278186 A CN 106278186A CN 201610772920 A CN201610772920 A CN 201610772920A CN 106278186 A CN106278186 A CN 106278186A
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- 239000003086 colorant Substances 0.000 title claims abstract description 42
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 40
- 239000010949 copper Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000005034 decoration Methods 0.000 claims abstract description 79
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 76
- 239000000919 ceramic Substances 0.000 claims abstract description 43
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 238000003825 pressing Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000009413 insulation Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 13
- 238000005245 sintering Methods 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 7
- 238000010304 firing Methods 0.000 description 6
- 238000001354 calcination Methods 0.000 description 5
- 239000004579 marble Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001062 red colorant Substances 0.000 description 2
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- ATSKDYKYMQVTGH-POBNKHOBSA-N amaranthin Chemical compound [N+]1([C@H](C([O-])=O)CC=2C=C(C(=CC=21)O)O[C@@H]1O[C@@H]([C@H]([C@H](O)[C@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@H](O1)C(O)=O)O)O)CO)=C\C=C1/C[C@@H](C(O)=O)NC(C(O)=O)=C1 ATSKDYKYMQVTGH-POBNKHOBSA-N 0.000 description 1
- HNGVOGUQLNOBKK-POBNKHOBSA-N amaranthine Natural products OC[C@H]1O[C@@H](Oc2cc3C[C@H](N(C=CC4=CC(=N[C@@H](C4)C(=O)O)C(=O)O)c3cc2O)C(=O)O)[C@H](O[C@@H]5O[C@@H]([C@@H](O)[C@H](O)[C@H]5O)C(=O)O)[C@@H](O)[C@@H]1O HNGVOGUQLNOBKK-POBNKHOBSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- OGGXGZAMXPVRFZ-UHFFFAOYSA-N dimethylarsinic acid Chemical compound C[As](C)(O)=O OGGXGZAMXPVRFZ-UHFFFAOYSA-N 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Adornments (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses the preparation method of a kind of blue and white with copper red colors pottery.The mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly by the method;After filter pressing, make mud cake, then through vacuum pugging, stand old, plasticity molding, prepare ceramic green;Ceramic green is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtains pottery biscuiting porcelain body;Pottery biscuiting porcelain body is carried out underglaze blue decoration, obtains underglaze blue decoration porcelain body;Underglaze blue decoration porcelain body is executed clear frit, obtains covering glaze underglaze blue decoration porcelain body;To carrying out in glaze under-glaze red decoration to covering glaze underglaze blue decoration porcelain body, obtain blue and white with copper red colors composite decoration porcelain body;Blue and white with copper red colors composite decoration porcelain body is burnt till at 1280 DEG C~1350 DEG C, is incubated 1~3 hour, natural cooling, prepare blue and white with copper red colors ceramic product.Under-glaze red color development respectively in the blue and white with copper red colors underglaze blue and glaze of pottery that the method prepares, bright in colour, it is to avoid in sintering process, two kinds of character difference color materials influences each other.
Description
Technical field
The present invention relates to ceramic standby, particularly relate to the preparation method of a kind of blue and white with copper red colors pottery.
Background technology
After porcelain is fired successfully by the mankind, the decoration of porcelain is just explored in improvement progressive, generally constantly
Can be summarized as " tire decoration ", " glaze decoration ", " color equipment decorations " three kinds of modes, three kinds of modes be combined with each other, and just constitute and are difficult to total number, many
The chinaware article that appearance is colorful.Tire decoration includes that moulding, heap are moulded, laminating, press back, to pick, draw, carve, engrave and twist tire, socket etc. right
Carcass beautify processing mode.Glaze decoration is the preparation with various different colours glaze and spreads, and reaches to hide carcass, beautify device
Thing, the decoration functions beneficially used.And color equipment decorations are the methods decorating porcelain that draws a design with shades of colour, its purpose exists entirely
In people, aesthstic pursuit, color equipment decorations porcelain are called for short faience, are the main flow of ceramic decoration.By color, glaze layer relation of plane, faience
Can be divided mainly into four big classes, the Doucai contrasting colors i.e. combined under underglaze colour, in-glaze decoration, overglaze color and glaze glazing.Wherein on underglaze colour, glaze
Color and Doucai contrasting colors all has the history of centuries, technology maturation, is widely used.In-glaze decoration is the one that 20 century 70s grow up
New decoration of porcelain material and skill and technique, impose on implements glaze by overglaze color method, and by high temperature rapid firing, glaze softens melted, makes
Pigment penetrates in glaze, glaze face closure after cooling.In-glaze decoration picture exquisiteness is sparkling and crystal-clear, anticorrosive, wear-resistant, has the effect of underglaze colour
Really.
Blue-and-white porcelain is the high-grade porcelain with Typical Chinese characteristic, is a kind of underglaze colour porcelain, and it is with cobalt oxide for coloring
Agent, first describes decorative pattern on porcelain base, then executes layer of transparent glaze, enter kiln and form through about 1350 DEG C high-temperature firings.Although blue-and-white porcelain
Colouring single, but its more multicolored porcelain is the most aobvious luicd and elegant, graceful, is extensively liked by people, it is unleaded nontoxic, acid-proof wear-proof, complexion warp
Do not move back for a long time, have the title of " the most amaranthine blue and white ".Along with the development of science and technology, blue-and-white porcelain is changed by original pure handwritten drawings
Becoming applique process, production efficiency is greatly improved, and the market expansion is rapid.But blue-and-white porcelain decoration remains simple green grass or young crops at present
Color, the variation in market inevitably asks decoration and the variation of color, traditional blue and white on the basis of, other color compound,
Blue-and-white porcelain will be made to present more gorgeous decorative effect, wide market.
Under-glaze red porcelain is the another kind of high-grade under enamel colored porcelain having an Oriental character, and it is to describe on mold with copper red material
Decorative pattern back cover, with clear frit, burns till through high temperature reduction flame atmosphere, makes to present under glaze the porcelain of red decorative pattern.The compound of copper is not
Same base glaze and firing atmosphere present different colors, as taken on a red color in reducing atmosphere, in the face making solvent with lead
In green in material, in blueness in alkali or leadless glaze.Therefore, base glaze and firing atmosphere are required the tightest by under-glaze red porcelain
Lattice.Additionally, copper ion is the most sensitive to temperature, in kiln the duration and degree of heating less than, present dark red or bois de rose;The duration and degree of heating little over copper from
Son just volatilizees, and escapes, present distinctive crimson phenomenon or simply fade from glaze layer, and decorative pattern lines are common dizzy scattered, so in glaze
Braise into difficulty in soy sauce big.
The superfine product of " blue and white with copper red colors " Chinese pottery especially, " blue and white with copper red colors " is to burn, at blue and white and under-glaze red, the basis made
On make, this with cobalt oxide be coloring agent blue and white material and be coloring agent with copper oxide combining of being drawn of under-glaze red colorant
Box-like underglaze colour decoration, existing blue and white verdant product beautiful plain characteristic clear, deep and remote, have again magnificent and peaceful, gorgeous fawning of under-glaze red and
The most impetuous, ardent and implicit characteristic.Both strong points organically blend, the most plain but also gorgeous, define blue or green reddish tint, changes in temperature
The taste characteristic that phase contrast, sound are set each other off, this uses copper and the technique of cobalt colored drawing on implements simultaneously, is excellent magnificent
Extremely, be worth outstanding.Owing to blue and white material is different from under-glaze red colorant character, firing temperature and firing chamber's atmosphere requirements also have difference
Different, therefore both impose on a device and colour generation red, blue is just right, not a duck soup.Current works handed down from ancient times come from Qing Dynasty Qianrong more
The government porcelain kiln in period, after Qianrong, government porcelain kiln produces and the most constantly reduces, and the burning of blue and white with copper red colors is made quantity and started to reduce, and technique declines,
Carcass is gradually thick, and glaze juice is the dilutest, and under-glaze red is subduing, causes the works handed down from ancient times of blue and white with copper red colors now few.Beijing's Imperial Palace museum
It is the museum that domestic collection Chinese ancient porcelain historical relic quantity is most and kind is the abundantest, has collected more than 350,000 part ancient pottery and porcelain literary compositions altogether
Thing, blue and white with copper red colors collection only has about more than 130 parts, the most precious.
Summary of the invention
It is an object of the invention to, in conjunction with the demand that people are growing to all kinds of high-grade ceramics, it is provided that a kind of novel
Blue and white with copper red colors ceramic preparation.
The present invention uses new technical thought, modern times in-glaze decoration technology is applied to blue and white with copper red colors porcelain and produces, with glaze
In lower underglaze blue decoration and glaze, under-glaze red decoration combines, it is to avoid in sintering process, two kinds of character difference color materials influences each other;Logical
Cross the accurate control burnt till, make under-glaze red color development respectively in underglaze blue and glaze.
The purpose of the present invention is achieved through the following technical solutions:
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum
Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240~360 hours, make inside mud cake
Uniform moisture, obtains ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtain pottery unglazed porcelain
Tire;
(5) the ceramic biscuiting porcelain body that step (4) obtains is carried out blue and white color material decoration, obtain underglaze blue decoration porcelain body;
(6) the underglaze blue decoration porcelain body that step (5) obtains is executed clear frit, obtain covering glaze underglaze blue decoration porcelain body;
(7) the glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red decoration in glaze, obtains blue and white with copper red colors multiple
Attach together decorations porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1280 DEG C~1320 DEG C calcinings, is incubated 1~3
Hour, natural cooling, prepare blue and white with copper red colors ceramic product.
Relative to prior art, modern times in-glaze decoration technology is applied to blue and white with copper red colors porcelain manufacture by the present invention, with under glaze
In underglaze blue decoration and glaze, copper red decoration combines, it is to avoid the influencing each other of two kinds of character difference color materials in sintering process, has fresh
Bright feature.
Detailed description of the invention
In order to be better understood from present disclosure, below in conjunction with case study on implementation to further instruction of the present invention, but this
The scope that invention claims not only is limited in listed example ranges.
Embodiment 1
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum
Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240 hours, make mud cake internal moisture equal
Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) carries out blue and white color material handwritten drawings decoration,Obtain underglaze blue decoration porcelain
Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red color material handwritten drawings decoration,Obtain blue and white
Under-glaze red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1280 DEG C of calcinings, is incubated 3 hours, the coldest
But, blue and white with copper red colors ceramic product is prepared.
Embodiment 2
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum
Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 300 hours, make mud cake internal moisture equal
Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 640 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) carries out blue and white color material handwritten drawings decoration,Obtain underglaze blue decoration porcelain
Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red marble paper applique decoration,Obtain in blue and white glaze
Red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1300 DEG C of calcinings, is incubated 2 hours, the coldest
But, blue and white with copper red colors ceramic product is prepared.
Embodiment 3
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum
Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 360 hours, make mud cake internal moisture equal
Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 700 DEG C, obtain pottery biscuiting porcelain body;
(5)The ceramic biscuiting carcass obtaining step (4) uses blue and white marble paper applique decoration technology,Obtain underglaze blue decoration porcelain
Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red color material handwritten drawings decoration,Obtain blue and white
Under-glaze red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1320 DEG C of calcinings, is incubated 1.5 hours, natural
Cooling, prepares blue and white with copper red colors ceramic product.
Embodiment 4
A kind of preparation method of blue and white with copper red colors pottery
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;After filter pressing, make mud cake, then practice through vacuum
Mud, air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 320 hours, make mud cake internal moisture equal
Even, obtain ceramic batch;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 680 DEG C, obtain pottery biscuiting porcelain body;
(5))The ceramic biscuiting carcass obtaining step (4) uses blue and white marble paper applique decoration technology,Obtain underglaze blue decoration
Porcelain body;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7)The glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out under-glaze red marble paper applique decoration,Obtain in blue and white glaze
Red composite decoration porcelain body;
(8) blue and white with copper red colors composite decoration porcelain body step (7) obtained is 1350 DEG C of calcinings, is incubated 1 hour, the coldest
But, blue and white with copper red colors ceramic product is prepared.
Claims (1)
1. a preparation method for blue and white with copper red colors pottery, is to comprise the steps of
(1) mode of ceramic material mix grinding in a wet process is pulverized and mixed uniformly;Mud cake is made after filter pressing, then through vacuum pugging,
Air in removing mud cake;
(2) mud cake perfected in step (1) is covered plastic sheeting, stand old 240~360 hours, make mud cake internal moisture
Uniformly, ceramic batch is obtained;
(3) by the ceramic batch in step (2) by plastic forming, ceramic green is prepared;
(4) ceramic green that step (3) obtains is carried out low temperature biscuiting at 600 DEG C~700 DEG C, obtain pottery biscuiting porcelain body;
(5) the ceramic biscuiting porcelain body that step (4) obtains is carried out the underglaze blue decoration such as manual drawing or applique, obtain underglaze blue decoration porcelain
Tire;
(6) carry out executing clear frit by the underglaze blue decoration porcelain body that step (5) obtains, obtain covering glaze underglaze blue decoration porcelain body;
(7) the glaze underglaze blue decoration porcelain body that covers step (6) obtained carries out the under-glaze red such as manual drawing or applique decoration in glaze, obtains
Blue and white with copper red colors composite decoration porcelain body;
(8) being burnt till at 1280 DEG C~1350 DEG C by the blue and white with copper red colors composite decoration porcelain body that step (7) obtains, insulation 1~3 is little
Time, natural cooling, prepare blue and white with copper red colors ceramic product.
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Cited By (4)
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CN106830687A (en) * | 2017-02-16 | 2017-06-13 | 内江师范学院 | A kind of ceramic sintering process that red glaze is fabricated to Chinese painting color ink effect |
CN106945149A (en) * | 2017-03-08 | 2017-07-14 | 龙泉市金宏瓷业有限公司 | A kind of ceramic body 3D printing technique |
CN114835476A (en) * | 2022-03-15 | 2022-08-02 | 福建省德化县豪发陶瓷有限公司 | High-strength blue-and-white five-color glazed porcelain and preparation method thereof |
CN114907148A (en) * | 2022-05-23 | 2022-08-16 | 孙赛华 | Formula and processing method of over-glaze blue and white pigment |
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