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CN106252739B - A kind of integrated design high-power lithium ion storage battery - Google Patents

A kind of integrated design high-power lithium ion storage battery Download PDF

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CN106252739B
CN106252739B CN201610865833.3A CN201610865833A CN106252739B CN 106252739 B CN106252739 B CN 106252739B CN 201610865833 A CN201610865833 A CN 201610865833A CN 106252739 B CN106252739 B CN 106252739B
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pole
pair
integrated design
storage battery
power lithium
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CN106252739A (en
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顾洪汇
程广玉
高蕾
王可
徐冬梅
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Shanghai Academy of Spaceflight Technology SAST
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Secondary Cells (AREA)

Abstract

本发明公开了一种一体化设计高功率锂离子蓄电池,其包含:外壳;叠片式电芯,收容于外壳内,其包含一对多层引出端;盖板,安装于外壳顶部;一对极柱,设置在盖板上,其中一极柱构成正极柱,由铝材料制成,另一极柱构成负极柱,由铜材料制成;正极柱和负极柱各自包含一位于外壳内的集流部,且该一对集流部分别与所述叠片式电芯的一对多层引出端对应连接。其优点是:通过宽裕的极柱集流体面积设计以便短时通过超大电流密度,使锂离子电池具有超高的倍率性能和安全性能。

The invention discloses an integrated design high-power lithium-ion storage battery, which comprises: a casing; a laminated battery cell housed in the casing, which includes a pair of multi-layer lead-out ends; a cover plate installed on the top of the casing; a pair of The poles are arranged on the cover plate, one of which constitutes the positive pole, which is made of aluminum material, and the other pole constitutes the negative pole, which is made of copper material; the positive pole and the negative pole each contain a collector located in the shell A flow part, and the pair of current collecting parts are respectively correspondingly connected with a pair of multi-layer lead-out ends of the laminated battery cell. Its advantages are: through the design of the ample current collector area of the pole, the ultra-high current density can be passed in a short time, so that the lithium-ion battery has ultra-high rate performance and safety performance.

Description

一种一体化设计高功率锂离子蓄电池An integrated design high power lithium-ion battery

技术领域technical field

本发明涉及锂离子蓄电池技术领域,具体涉及一种一体化设计高功率锂离子蓄电池。The invention relates to the technical field of lithium-ion storage batteries, in particular to an integrated high-power lithium-ion storage battery.

背景技术Background technique

锂离子蓄电池相对于铅酸电池、镉镍电池、氢镍电池具有更高的能量密度、长循环寿命以及更低自放电率等优点,当前已广泛应用于各类电子产品以及新能源汽车领域。Compared with lead-acid batteries, nickel-cadmium batteries, and nickel-hydrogen batteries, lithium-ion batteries have the advantages of higher energy density, long cycle life, and lower self-discharge rate. They have been widely used in various electronic products and new energy vehicles.

目前商品化生产的高功率锂离子电池主要采用卷绕和叠层方式生产电芯,而卷绕工艺制备的圆柱形电芯存在电流密度分布不均匀,电池内阻高,发热量大等缺陷。而叠层方式生产的电芯具有内阻小,极化小等优势。At present, commercially produced high-power lithium-ion batteries mainly use winding and stacking methods to produce cells, while cylindrical cells prepared by the winding process have defects such as uneven current density distribution, high internal resistance of the battery, and large heat generation. The battery cells produced by stacking have the advantages of small internal resistance and small polarization.

许多应用场合,如纯电动汽车,在车辆启动时需要很大的启动电流,刹车时需要在很短的时间内回收能量,因此要求动力电池能够瞬时大电流工作。而此时传统锂离子电池受限于结构原因,内部极柱与极耳处导流面积狭窄,从而导致电流无法快速通过,限制了锂电池的倍率性能;同时,由于电池内阻很大,电极的极耳发热严重,导致电池温度不可控升高,会造成安全性以及循环寿命的重大隐患。Many applications, such as pure electric vehicles, require a large starting current when the vehicle is started, and energy needs to be recovered in a short time when braking, so the power battery is required to be able to work with a high current instantaneously. At this time, the traditional lithium-ion battery is limited by the structure, and the conduction area at the internal pole and tab is narrow, which leads to the inability of the current to pass through quickly, which limits the rate performance of the lithium battery; at the same time, due to the large internal resistance of the battery, the electrode The tabs of the battery are seriously heated, which leads to an uncontrollable increase in the battery temperature, which will cause a major hidden danger to safety and cycle life.

因此,需要提供一种能够极大提高锂离子电池的功率性能的一体化设计的电池结构,以进一步拓展其应用领域。Therefore, it is necessary to provide an integrated battery structure that can greatly improve the power performance of the lithium-ion battery, so as to further expand its application field.

发明内容Contents of the invention

本发明的目的在于提供一种一体化设计高功率锂离子蓄电池,通过宽裕的极柱集流体面积设计以便短时通过超大电流密度,结合高能多点焊接方式与电芯芯体的多层引出端连接,并且左右端引出极耳采用电芯设计方式,使锂离子电池具有超高的倍率性能和安全性能。The purpose of the present invention is to provide a high-power lithium-ion battery with an integrated design, through the design of ample current collector area to pass a super large current density in a short time, combined with high-energy multi-point welding method and the multi-layer lead-out end of the battery core Connected, and the left and right ends of the tabs are designed with a cell design, so that the lithium-ion battery has ultra-high rate performance and safety performance.

为了达到上述目的,本发明通过以下技术方案实现:In order to achieve the above object, the present invention is achieved through the following technical solutions:

一种一体化设计高功率锂离子蓄电池,其特征是,包含:An integrated high-power lithium-ion storage battery is characterized in that it includes:

外壳;shell;

叠片式电芯,收容于外壳内,其包含一对多层引出端;A laminated battery cell is accommodated in the casing, which includes a pair of multi-layer terminals;

盖板,安装于外壳顶部;The cover plate is installed on the top of the shell;

一对极柱,设置在盖板上,其中一极柱构成正极柱,由铝材料制成,另一极柱构成负极柱,由铜材料制成;正极柱和负极柱各自包含一位于外壳内的集流部,且该一对集流部分别与所述叠片式电芯的一对多层引出端对应连接。A pair of poles are set on the cover plate, one of which constitutes the positive pole and is made of aluminum material, and the other pole constitutes the negative pole and is made of copper material; the positive pole and the negative pole each contain a The current collecting parts, and the pair of current collecting parts are correspondingly connected to the pair of multi-layer lead-out ends of the laminated cells.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

每个极柱还分别包含一螺纹部,螺纹部与集流部一体成型,各个极柱的螺纹部从盖板内侧穿出,并依次通过密封垫圈、平垫圈、弹簧垫圈以及铜螺母固定到盖板上。Each pole also includes a threaded part, the threaded part and the collector part are integrally formed, the threaded part of each pole passes through the inside of the cover plate, and is fixed to the cover by a sealing washer, a flat washer, a spring washer and a copper nut in turn. board.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

每个极柱的集流部分别由一对相对设置的导流片组成,该一对导流片将叠片式电芯上对应的一多层引出端夹紧。The current collecting part of each pole is composed of a pair of oppositely arranged guide pieces, and the pair of guide pieces clamp a corresponding multi-layer lead-out end on the laminated battery cell.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

每个导流片的集流面尺寸为100mm×10mm,每个导流片的厚度为1.2mm。The size of the collecting surface of each deflector is 100mm×10mm, and the thickness of each deflector is 1.2mm.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

所述外壳和盖板均采用铝材料制成。Both the shell and the cover are made of aluminum.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

采用激光焊接方式将外壳与盖板进行密封。The casing and the cover are sealed by laser welding.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

所述盖板上设有安全阀。A safety valve is provided on the cover.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

所述极柱的螺纹部直径为8mm。The diameter of the threaded portion of the pole is 8mm.

上述的一体化设计高功率锂离子蓄电池,其中:The above-mentioned integrated design high-power lithium-ion battery, wherein:

每个集流部的一对导流片分别通过多点焊接方式与叠片式电芯上对应的一多层引出端连接。A pair of guide fins of each current collecting part are respectively connected to a corresponding multi-layer lead-out terminal on the laminated electric core by means of multi-point welding.

本发明与现有技术相比具有以下优点:通过宽裕的极柱集流体面积设计以便短时通过超大电流密度,结合高能多点焊接方式与电芯芯体的多层引出端连接,并且左右端引出极耳设计方式,使锂离子电池具有超高的倍率性能和安全性能。Compared with the prior art, the present invention has the following advantages: through the design of ample pole current collector area to pass super large current density in a short time, combined with high-energy multi-point welding method to connect with the multi-layer lead-out end of the battery core body, and the left and right ends The lead-out tab design method makes the lithium-ion battery have ultra-high rate performance and safety performance.

附图说明Description of drawings

图1为本发明中的极柱的立体图;Fig. 1 is the perspective view of pole among the present invention;

图2为本发明中的一对极柱与盖板的连接关系示意图;Fig. 2 is a schematic diagram of the connection relationship between a pair of poles and a cover plate in the present invention;

图3为本发明的立体图。Fig. 3 is a perspective view of the present invention.

具体实施方式Detailed ways

以下结合附图,通过详细说明一个较佳的具体实施例,对本发明做进一步阐述。The present invention will be further elaborated below by describing a preferred specific embodiment in detail in conjunction with the accompanying drawings.

如图1~3所示,一种一体化设计高功率锂离子蓄电池,其包含:外壳4;叠片式电芯,收容于外壳4内,其包含一对多层引出端即极耳;盖板2,安装于外壳4顶部;一对极柱1,设置在盖板2上,其中一极柱1构成正极柱,另一极柱1构成负极柱,由于锂离子蓄电池是电位在4V左右的高电位电化学体系,不锈钢或镍极柱在高电位电化学体系中会发生电化学腐蚀和自放电等现象,因此正极柱设计采用纯铝材料,负极柱设计采用纯铜材料;正极柱和负极柱各自包含一位于外壳4内的集流部,且该一对集流部分别与所述叠片式电芯的一对多层引出端对应连接,通过设置集流部,以满足大电流密度支持以及提高散热性能。As shown in Figures 1 to 3, an integrated high-power lithium-ion battery includes: a casing 4; a stacked battery cell housed in the casing 4, which includes a pair of multi-layer lead-out ends, namely tabs; a cover The plate 2 is installed on the top of the shell 4; a pair of poles 1 is arranged on the cover plate 2, one pole 1 constitutes the positive pole, and the other pole 1 constitutes the negative pole. Since the lithium-ion battery has a potential of about 4V High-potential electrochemical system, stainless steel or nickel poles will undergo electrochemical corrosion and self-discharge in high-potential electrochemical systems, so the design of the positive pole is made of pure aluminum, and the design of the negative pole is made of pure copper; the positive pole and negative pole The pillars each include a current collecting part located in the casing 4, and the pair of current collecting parts are respectively connected to a pair of multi-layer lead-out ends of the laminated battery cell. By setting the current collecting part, the large current density Support and improve thermal performance.

每个极柱1还分别包含一螺纹部11,螺纹部11与集流部一体成型,各个极柱1的螺纹部11从盖板2内侧穿出,并依次通过密封垫圈31、平垫圈32、弹簧垫圈33以及铜螺母34固定到盖板2上,以增强电池的密封性能,防止电解液的泄露,提高电池使用安全性;同时可以提高电池的机械力学性能。。Each pole 1 also includes a threaded part 11, the threaded part 11 is integrally formed with the collector part, the threaded part 11 of each pole 1 passes through the inside of the cover plate 2, and passes through the sealing washer 31, flat washer 32, The spring washer 33 and the copper nut 34 are fixed on the cover plate 2 to enhance the sealing performance of the battery, prevent the leakage of the electrolyte, and improve the safety of the battery; meanwhile, the mechanical properties of the battery can be improved. .

每个极柱1的集流部分别由一对相对设置的导流片12组成,采用片式结构,使得集流部的比重轻,并且能够降低给电池比能量带来的负面影响,该一对导流片12将叠片式电芯上对应的一多层引出端夹紧;本实施例中,螺纹部11与一对导流片12之间通过一阻隔件13连接,阻隔件用于防止导流片12从盖板2内侧穿出以及便于连接件(密封垫圈31、平垫圈32、弹簧垫圈33以及铜螺母34)安装后极柱1的稳固。The current collecting part of each pole 1 is composed of a pair of oppositely arranged guide fins 12, which adopts a sheet structure, so that the specific gravity of the current collecting part is light, and the negative impact on the specific energy of the battery can be reduced. Clamp a corresponding multi-layer lead-out end on the laminated battery cell to the deflector 12; in this embodiment, the threaded part 11 and the pair of deflectors 12 are connected through a barrier 13, and the barrier is used for It prevents the deflector 12 from passing through the inner side of the cover plate 2 and facilitates the stability of the pole 1 after the connectors (seal washer 31 , flat washer 32 , spring washer 33 and copper nut 34 ) are installed.

本实施例中,每个导流片12的集流面尺寸为100 mm×10mm,每个导流片12的厚度为1.2mm,所述极柱1的螺纹部11直径为8mm,可以承载大电流脉冲放电。In this embodiment, the size of the collecting surface of each guide vane 12 is 100 mm×10 mm, the thickness of each guide vane 12 is 1.2 mm, and the diameter of the threaded part 11 of the pole 1 is 8 mm, which can carry large Current pulse discharge.

所述外壳4和盖板2均采用铝材料制成。Both the shell 4 and the cover plate 2 are made of aluminum.

采用激光焊接方式将外壳4与盖板2进行密封,具体的,通过焊接机配备的显微镜监视视频预焊接后,再进行环绕式一次性焊接,焊接完成后,将电池置于电解液溶剂中加压检漏。Laser welding is used to seal the shell 4 and the cover plate 2. Specifically, after pre-welding through the microscope monitoring video equipped with the welding machine, the surrounding one-time welding is carried out. After the welding is completed, the battery is placed in the electrolyte solvent and added Pressure leak detection.

所述盖板2上设有安全阀21,能避免锂离子电池的壳体爆裂,可靠性好。The cover plate 2 is provided with a safety valve 21, which can prevent the casing of the lithium-ion battery from bursting and has good reliability.

本实施例中,每个集流部的一对导流片12分别通过多点焊接方式与叠片式电芯上对应的一多层引出端连接。为进一步提高空间利用率以及电池性能,叠片式电芯的一对极耳设置在外壳内部左右两侧,相应的,一对极柱1的集流部对应位于外壳的内部两侧,其螺纹部11则位于盖板2的左右两侧位置。In this embodiment, a pair of deflectors 12 of each collector are respectively connected to a corresponding multi-layer lead-out terminal on the laminated cell by means of multi-point welding. In order to further improve the space utilization rate and battery performance, a pair of tabs of the laminated battery cell are arranged on the left and right sides inside the casing, and correspondingly, the collectors of a pair of poles 1 are located on both sides of the inside of the casing, and the threads The portion 11 is located on the left and right sides of the cover plate 2 .

本发明通过设计新型的电池内部结构,使得锂离子蓄电池的功率性能得到显著提升,采用这种结构设计的10Ah锂离子蓄电池,功率性能可以达到5000W/kg及以上,循环寿命1000次,同时能够通过车用动力电池等相关安全试验要求,极大地拓宽了锂离子电池的使用范围。The present invention significantly improves the power performance of the lithium-ion battery by designing a new battery internal structure. The power performance of the 10Ah lithium-ion battery designed with this structure can reach 5000W/kg and above, and the cycle life is 1000 times. At the same time, it can pass Relevant safety test requirements for automotive power batteries have greatly expanded the scope of use of lithium-ion batteries.

尽管本发明的内容已经通过上述优选实施例作了详细介绍,但应当认识到上述的描述不应被认为是对本发明的限制。在本领域技术人员阅读了上述内容后,对于本发明的多种修改和替代都将是显而易见的。因此,本发明的保护范围应由所附的权利要求来限定。Although the content of the present invention has been described in detail through the above preferred embodiments, it should be understood that the above description should not be considered as limiting the present invention. Various modifications and alterations to the present invention will become apparent to those skilled in the art upon reading the above disclosure. Therefore, the protection scope of the present invention should be defined by the appended claims.

Claims (7)

1. a kind of integrated design high-power lithium ion storage battery, which is characterized in that include:
Shell (4);
Lamination type electric core is contained in shell (4), and it includes a pair of of multilayer exits;
Cover board (2) is installed at the top of shell (4);
A pair of of pole (1) is arranged on cover board (2), wherein a pole (1) constitutes positive terminal, is made of aluminum material, another pole (1) negative terminal is constituted, is made of copper product;Positive terminal and negative terminal respectively contain an afflux portion being located in shell (4), and should A pair of collection stream part is not correspondingly connected with a pair of of multilayer exit of the lamination type electric core;The collection stream part of each pole (1) It is not made of the flow deflector of a pair of opposing (12), which draws a corresponding multilayer on lamination type electric core Outlet clamps;A pair of of flow deflector (12) in each afflux portion passes through multi-point welding mode corresponding on lamination type electric core one respectively Multilayer exit connects.
2. integrated design high-power lithium ion storage battery as described in claim 1, it is characterised in that:
Each pole (1) also separately includes a threaded portion (11), and threaded portion (11) are integrally formed with afflux portion, each pole (1) Threaded portion (11) be pierced by the inside of the cover board (2), and pass sequentially through seal washer (31), plain washer (32), spring washer (33) And copper nut (34) is fixed on cover board (2).
3. integrated design high-power lithium ion storage battery as described in claim 1, it is characterised in that:
The Colony culture size of each flow deflector (12) is 100mm × 10mm, and the thickness of each flow deflector (12) is 1.2mm.
4. integrated design high-power lithium ion storage battery as described in claim 1, it is characterised in that:
The shell (4) and cover board (2) are all made of aluminum material and are made.
5. integrated design high-power lithium ion storage battery as described in claim 1, it is characterised in that:
Shell (4) and cover board (2) are sealed using laser welding mode.
6. integrated design high-power lithium ion storage battery as described in claim 1, it is characterised in that:
The cover board (2) is equipped with safety valve (21).
7. integrated design high-power lithium ion storage battery as claimed in claim 2, it is characterised in that:
Threaded portion (11) a diameter of 8mm of the pole (1).
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CN101174681A (en) * 2006-10-30 2008-05-07 比亚迪股份有限公司 Pole piece complex body, electric core and lithium ion battery
CN102315409A (en) * 2011-08-29 2012-01-11 潍坊威能环保电源有限公司 Lithium ion power cell
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CN101174681A (en) * 2006-10-30 2008-05-07 比亚迪股份有限公司 Pole piece complex body, electric core and lithium ion battery
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