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CN106246151A - A kind of method utilizing milk products waste to improve water-drive pool yield - Google Patents

A kind of method utilizing milk products waste to improve water-drive pool yield Download PDF

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Publication number
CN106246151A
CN106246151A CN201610710590.6A CN201610710590A CN106246151A CN 106246151 A CN106246151 A CN 106246151A CN 201610710590 A CN201610710590 A CN 201610710590A CN 106246151 A CN106246151 A CN 106246151A
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CN
China
Prior art keywords
milk products
products waste
water
test
waste
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610710590.6A
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Chinese (zh)
Inventor
刘琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yantai Zhiben Intellectual Property Operation and Management Co Ltd
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Yantai Zhiben Intellectual Property Operation and Management Co Ltd
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Priority to CN201610710590.6A priority Critical patent/CN106246151A/en
Publication of CN106246151A publication Critical patent/CN106246151A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/582Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of bacteria
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/594Compositions used in combination with injected gas, e.g. CO2 orcarbonated gas
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/166Injecting a gaseous medium; Injecting a gaseous medium and a liquid medium
    • E21B43/168Injecting a gaseous medium
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/20Displacing by water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/327Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from processes relating to the production of dairy products

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a kind of method utilizing milk products waste to improve water-drive pool yield, comprise the following steps: the suspended particle of particle diameter big in waste water is become the suspended particle of small particle, the pH of waste water is adjusted to 6.5~7.5, obtains pretreated milk products waste;The screening of test oil reservoir;On-the-spot injection technology determines, the ratio that zymocyte bacterium solution, pretreatment milk products waste, test reservoir flooding water and air are equal to 1:100~200:1000~2000:80~10 according to volume ratio is injected for a long time;On-the-spot test and the tracking of site test results and analysis.Construction technology of the present invention is simple, effectively reduce water-drive pool and improve the cost of oil recovery factor, and avoid and outside milk products waste, arrange the environmental pollution caused and the too high problem of processing cost, therefore, the composite can be widely applied to improve in the on-the-spot test of oil reservoir yield.

Description

A kind of method utilizing milk products waste to improve water-drive pool yield
Technical field
The invention belongs to technical field of sewage, be specifically related to one and utilize milk products waste to improve water drive oil The method hiding yield.
Background technology
Milk products waste is milk powder, fresh milk, modulation milk beverage, fermented yoghourt, yogurt blend, butter, ice cream, snow The waste water discharged during cake, cheese, lactose, condensed milk and milk product snack production, waste water is essentially from container and equipment Rinse water, main component contains goods raw material, pH value of waste water 6.5-7.0.Rich in saccharide, starch, protein in milk product waste With fatty acid etc., it is a kind of nutritious organic wastewater.
Milk products waste is frequently with materialization treatment process and biological filters such as oil removal, precipitation, coagulation air-float, electrochemistry flocculations The biochemical processing methods such as pond, catalytic oxidation, Aeration tank, oxidation ditch, biological pond process.But there is technique in above-mentioned processing method The shortcomings such as complicated, processing cost is high, treatment effect instability.
If these milk products waste are directly discharged, not only waste the resource of preciousness, and deal with improperly easily Putrefactive fermentation, makes water quality blackout foul, causes serious environmental pollution.
Summary of the invention
It is an object of the invention to provide one to turn waste into wealth, the nutrient substance made full use of in milk products waste carries The method of high water-drive pool yield, had both effectively reduced the cost of oil exploitation, solves again milk products waste and is processed into The problem that this height and discharge bring environmental pollution.
A kind of method utilizing milk products waste to improve water-drive pool yield, comprises the steps:
(1) filtration of milk products waste
Milk products waste is filtered, isolates the particle diameter float more than 100 μm, the breast system after being filtered Product industrial wastewater.
(2) process of float
First float after above-mentioned separation being crushed to particle diameter and is less than below 50 μm, the float after secondly pulverizing adds Enter in the milk products waste after above-mentioned filtration, obtain the milk products waste in microgranule footpath.
(3) waste water after filtering adjusts pH value
Utilize acid or alkali that the pH of the milk products waste in above-mentioned microgranule footpath is adjusted to 6.5~7.5, obtain pretreated Milk products waste.
(4) screening of oil reservoir is tested
The screening criteria of test oil reservoir is: reservoir temperature less than 90 DEG C, Reservoir Permeability is more than 50 × 10-3μm2, formation water Salinity is less than 4000mPa.s less than 100000mg/L and viscosity of crude.
(5) on-the-spot injection technology determines
Zymocyte bacterium solution, pretreated milk products waste, test reservoir flooding water and air are according to volume ratio etc. Ratio in 1:100~200:1000~2000:80~100 is injected for a long time.
(6) on-the-spot test
By the zymocyte bacterium solution of aforementioned proportion, pretreated milk products waste and the mixing of test reservoir flooding water Thing injects from the water injection well of test oil reservoir;Meanwhile, from the water injection well of test oil reservoir, air is injected;Divide after on-the-spot off-test Analysis field test results, calculates oil increment, improves gather value and input-output ratio.
Described acid is hydrochloric acid or acetic acid, and described alkali is sodium hydroxide or potassium hydroxide.
Described zymocyte bacterium solution is to produce biogas bacterium and the mixture of biosurfactant-producing microbe bacterium solution, and volume ratio is 1:8~10.
The mixture of described zymocyte bacterium solution, pretreated milk products waste and test reservoir flooding water is on-the-spot Injection rate is 8~10m3/ h, described air scene injection rate is (2~5) × 102Nm3/ h (mark side/hour).
The present invention utilizes nutrient substance carbon, nitrogen and phosphorus source abundant in milk products waste to activate the product injected in oil reservoir Biogas and the bacterium of biosurfactant, the biogas of generation reduces test oil reservoir Central Plains oil viscosity, the biological table of generation Face activating agent reduces oil water interfacial tension in test oil reservoir, thus reduces oil and water mobility ratio, the final crude oil improving test oil reservoir Recovery ratio.
The present invention compared with prior art has the advantage that and beneficial effect:
(1) present invention process is simple, easy and simple to handle, therefore, is conducive to on-the-spot popularization and application;
(2) present invention is effectively utilized milk products waste, it is to avoid environmental pollution that discharge of wastewater brings and useless The problem that cost of water treatment is high;
(3) present invention has small investment, low cost, advantage that field test results is good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in This:
Embodiment 1
Certain oil field block C1Reservoir temperature 65 DEG C, reservoir pressure is 12.8MPa, permeability 550 × 10-3μm2, porosity 32.5%, viscosity of crude is 3258mPa.s, and formation water salinity is 45860mg/L, recoverable reserves 7.0 × 104T, current block Comprehensive water cut is 93.5%.The milk products waste of row outside certain milk powder producing producer, pH value is 6.0.Utilize the side of the present invention Method improves this block recovery ratio, is embodied as step and is:
(1) filtration of milk products waste
Milk products waste is filtered, isolates the particle diameter float more than 100 μm, the breast system after being filtered Product industrial wastewater.
(2) process of float
Float after above-mentioned separation is crushed to particle diameter is below 50 μm, and the float after secondly pulverizing adds above-mentioned In milk products waste after filtration, obtain the milk products waste in microgranule footpath.
(3) waste water after filtering adjusts pH value
Utilize potassium hydroxide that the pH of the milk products waste in above-mentioned microgranule footpath is adjusted to 6.5 and obtain pretreated breast system Product industrial wastewater.
(4) screening of oil reservoir is tested
The temperature of test oil reservoir is 65 DEG C, Reservoir Permeability is 550 × 10-3μm2, formation water salinity be 45860mg/L, Viscosity of crude is 3258mPa.s, meets the standard of reservoir selection of the present invention.
(5) on-the-spot injection technology determines
Zymocyte bacterium solution, pretreated milk products waste, test reservoir flooding water and air are according to volume ratio etc. Ratio in 1:100:1000:80 is injected for a long time.
Zymocyte bacterium solution is to produce biogas bacterium and the mixture of biosurfactant-producing microbe bacterium solution, and volume ratio is 1:8.
(6) on-the-spot test
By aforementioned proportion zymocyte bacterium solution, pretreatment milk products waste and test reservoir flooding water mixture with 10m3/ h speed is injected from the water injection well of test oil reservoir;Meanwhile, with 5 × 10 from the water injection well of test oil reservoir2Nm3/ h speed Inject air.
On-the-spot off-test post analysis field test results, calculates oil increment, improves gather value and input-output ratio.Logical Cross and utilize the method scene test accumulative increasing oil 0.784 × 104T, improves oil recovery factor 11.2%, and input-output ratio is 1: 4.3。
Embodiment 2
Certain oil field block C2Reservoir temperature 70 DEG C, reservoir pressure is 15.2MPa, permeability 1120 × 10-3μm2, hole Degree 34.2%, viscosity of crude is 2235mPa.s, and formation water salinity is 21320mg/L, recoverable reserves 8.2 × 104T, current district Block comprehensive water cut is 94.5%.The milk products waste of row outside certain fresh milk, fermented yoghourt, yogurt blend, butter manufacturer, PH value is 6.3.The method utilizing the present invention improves this block recovery ratio, is embodied as step and is:
(1) filtration of milk products waste
Milk products waste is filtered, isolates the particle diameter float more than 100 μm, the breast system after being filtered Product industrial wastewater.
(2) process of float
Float after above-mentioned separation is crushed to particle diameter is below 50 μm, and the float after secondly pulverizing adds above-mentioned In milk products waste after filtration, obtain the milk products waste in microgranule footpath.
(3) waste water after filtering adjusts pH value
Utilize potassium hydroxide that the pH of the milk products waste in above-mentioned microgranule footpath is adjusted to 6.8 and obtain pretreated breast system Product industrial wastewater.
(4) screening of oil reservoir is tested
The temperature of test oil reservoir is 70 DEG C, Reservoir Permeability is 1120 × 10-3μm2, formation water salinity be 21320mg/ L, viscosity of crude is 2235mPa.s, meets the standard of reservoir selection of the present invention.
(5) on-the-spot injection technology determines
Zymocyte bacterium solution, pretreated milk products waste, test reservoir flooding water and air are according to volume ratio etc. Ratio in 1:200:1500:90 is injected for a long time.
Zymocyte bacterium solution is to produce biogas bacterium and the mixture of biosurfactant-producing microbe bacterium solution, and volume ratio is 1:9.
(6) on-the-spot test
By the zymocyte bacterium solution of aforementioned proportion, pretreated milk products waste and the mixing of test reservoir flooding water Thing is with 9m3/ h speed is injected from the water injection well of test oil reservoir;Meanwhile, with 3 × 10 from the water injection well of test oil reservoir2Nm3/ h speed Degree injects air.
On-the-spot off-test post analysis field test results, calculates oil increment, improves gather value and input-output ratio.Logical Cross and utilize the method scene test accumulative increasing oil 0.861 × 104T, improves oil recovery factor 10.5%, and input-output ratio is 1: 4.0。
Embodiment 3
Certain oil field block C3Reservoir temperature 78 DEG C, reservoir pressure is 14.7MPa, permeability 680 × 10-3μm2, porosity 33.2%, viscosity of crude is 1765mPa.s, and formation water salinity is 21120mg/L, recoverable reserves 5.6 × 104T, current block Comprehensive water cut is 92.8%.The milk products waste of row outside certain milk powder producing producer, pH value is 6.2.Utilize the side of the present invention Method improves this block recovery ratio, is embodied as step and is:
(1) filtration of milk products waste
Milk products waste is filtered, isolates the particle diameter float more than 100 μm, the breast system after being filtered Product industrial wastewater.
(2) process of float
Float after above-mentioned separation is crushed to particle diameter is below 50 μm, and the float after secondly pulverizing adds above-mentioned In milk products waste after filtration, obtain the milk products waste in microgranule footpath.
(3) waste water after filtering adjusts pH value
Utilize sodium hydroxide that the pH of the milk products waste in above-mentioned microgranule footpath is adjusted to 7.5 and obtain pretreated breast system Product industrial wastewater.
(4) screening of oil reservoir is tested
The temperature of test oil reservoir is 78 DEG C, Reservoir Permeability is 680 × 10-3μm2, formation water salinity be 21120mg/L, Viscosity of crude is 1765mPa.s, meets the standard of reservoir selection of the present invention.
(5) on-the-spot injection technology determines
Zymocyte bacterium solution, pretreated milk products waste, test reservoir flooding water and air are according to volume ratio etc. Ratio in 1:150:2000:100 is injected for a long time.
Zymocyte bacterium solution is to produce biogas bacterium and the mixture of biosurfactant-producing microbe bacterium solution, and volume ratio is 1:10.
(6) on-the-spot test
By the zymocyte bacterium solution of aforementioned proportion, pretreated milk products waste and the mixing of test reservoir flooding water Thing is with 8m3/ h speed is injected from the water injection well of test oil reservoir;Meanwhile, with 2 × 10 from the water injection well of test oil reservoir2Nm3/ h speed Degree injects air.
On-the-spot off-test post analysis field test results, calculates oil increment, improves gather value and input-output ratio.Logical Cross and utilize the method scene test accumulative increasing oil 0.756 × 104T, improves oil recovery factor 13.5%, and input-output ratio is 1: 4.5。

Claims (7)

1. the method utilizing milk products waste to improve water-drive pool yield, comprises the steps:
(1) filtration of milk products waste
Milk products waste is filtered, isolates the particle diameter float more than 100 μm, the milk product work after being filtered Industry waste water;
(2) process of float
First float after above-mentioned separation being crushed to particle diameter and is less than below 50 μm, the float after secondly pulverizing adds State in the milk products waste after filtration, obtain the milk products waste in microgranule footpath;
(3) waste water after filtering adjusts pH value
Utilize acid or alkali that the pH of the milk products waste in above-mentioned microgranule footpath is adjusted to 6.5~7.5, obtain pretreated breast system Product industrial wastewater;
(4) screening of oil reservoir is tested
The screening criteria of test oil reservoir is: reservoir temperature less than 90 DEG C, Reservoir Permeability is more than 50 × 10-3μm2, formation water mineralising Degree is less than 4000mPa.s less than 100000mg/L and viscosity of crude;
(5) on-the-spot injection technology determines
Zymocyte bacterium solution, pretreated milk products waste, test reservoir flooding water and air according to volume ratio equal to 1: The ratio of 100~200:1000~2000:80~100 is injected for a long time;
(6) on-the-spot test
By the zymocyte bacterium solution of aforementioned proportion, pretreated milk products waste and test reservoir flooding water mixture from The water injection well of test oil reservoir injects;Meanwhile, from the water injection well of test oil reservoir, air is injected;On-the-spot off-test post analysis is existing Field test effect, calculates oil increment, improves gather value and input-output ratio.
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 1, it is characterised in that Described acid is hydrochloric acid or acetic acid.
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 1 and 2, its feature exists In, described alkali is sodium hydroxide or potassium hydroxide.
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 1 and 2, its feature exists In, described zymocyte bacterium solution is to produce biogas bacterium and the mixture of biosurfactant-producing microbe bacterium solution.
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 4, it is characterised in that Described product biogas bacterium and biosurfactant-producing microbe bacterium solution volume ratio are 1:8~10.
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 1, it is characterised in that Described zymocyte bacterium solution, pretreated milk products waste and the mixture scene injection rate of test reservoir flooding water It is 8~10m3/h。
The method utilizing milk products waste to improve water-drive pool yield the most according to claim 6, it is characterised in that Described air scene injection rate is (2~5) × 102Nm3/h。
CN201610710590.6A 2016-08-24 2016-08-24 A kind of method utilizing milk products waste to improve water-drive pool yield Pending CN106246151A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610710590.6A CN106246151A (en) 2016-08-24 2016-08-24 A kind of method utilizing milk products waste to improve water-drive pool yield

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2004118325A (en) * 2004-06-16 2005-11-20 Общество с ограниченной ответственностью "АРМ ГАРАНТ" (RU) METHOD OF PROTECTION AGAINST CORROSION OF OIL-PRODUCING EQUIPMENT AND PIPELINES UNDER CONDITIONS OF MICROBIOLOGICAL INFECTION OF OIL LAYERS OF DEPOSITS
CN101195652A (en) * 2007-12-03 2008-06-11 内蒙古工业大学 A method for recovering protein and lactose from dairy wastewater
CN101503956A (en) * 2009-01-21 2009-08-12 中国石油化工股份有限公司胜利油田分公司采油工艺研究院 Method for improving crude oil recovery ratio by utilization of industrial sewage and waste gas
US20100059226A1 (en) * 2008-09-09 2010-03-11 Tetra Technologies, Inc. Method of Delivering Frac Fluid and Additives
CN102966341A (en) * 2012-11-13 2013-03-13 常州大学 Method for increasing stratum layer oil recovery factor by utilizing wastewater
CN103147730A (en) * 2013-03-22 2013-06-12 中国石油化工股份有限公司 Method for improving crude oil recovery ratio by using organic solid waste
CN104213887A (en) * 2014-09-09 2014-12-17 中国石油化工股份有限公司 Method for improving producible oil index by use of starch wastewater
CN105156087A (en) * 2015-09-28 2015-12-16 中国石油化工股份有限公司 Method for improving crude oil recovery ratio by using guanidine gum fracturing backflow liquid

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2004118325A (en) * 2004-06-16 2005-11-20 Общество с ограниченной ответственностью "АРМ ГАРАНТ" (RU) METHOD OF PROTECTION AGAINST CORROSION OF OIL-PRODUCING EQUIPMENT AND PIPELINES UNDER CONDITIONS OF MICROBIOLOGICAL INFECTION OF OIL LAYERS OF DEPOSITS
CN101195652A (en) * 2007-12-03 2008-06-11 内蒙古工业大学 A method for recovering protein and lactose from dairy wastewater
US20100059226A1 (en) * 2008-09-09 2010-03-11 Tetra Technologies, Inc. Method of Delivering Frac Fluid and Additives
CN101503956A (en) * 2009-01-21 2009-08-12 中国石油化工股份有限公司胜利油田分公司采油工艺研究院 Method for improving crude oil recovery ratio by utilization of industrial sewage and waste gas
CN102966341A (en) * 2012-11-13 2013-03-13 常州大学 Method for increasing stratum layer oil recovery factor by utilizing wastewater
CN103147730A (en) * 2013-03-22 2013-06-12 中国石油化工股份有限公司 Method for improving crude oil recovery ratio by using organic solid waste
CN104213887A (en) * 2014-09-09 2014-12-17 中国石油化工股份有限公司 Method for improving producible oil index by use of starch wastewater
CN105156087A (en) * 2015-09-28 2015-12-16 中国石油化工股份有限公司 Method for improving crude oil recovery ratio by using guanidine gum fracturing backflow liquid

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Application publication date: 20161221