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CN106245415A - A kind of manufacture method of glassine paper - Google Patents

A kind of manufacture method of glassine paper Download PDF

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Publication number
CN106245415A
CN106245415A CN201610725022.3A CN201610725022A CN106245415A CN 106245415 A CN106245415 A CN 106245415A CN 201610725022 A CN201610725022 A CN 201610725022A CN 106245415 A CN106245415 A CN 106245415A
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China
Prior art keywords
paper
pulp
applying glue
slurry
page
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Granted
Application number
CN201610725022.3A
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Chinese (zh)
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CN106245415B (en
Inventor
朱宏伟
李树林
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Yueyang Forest & Paper Co Ltd
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Yueyang Forest & Paper Co Ltd
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Priority to CN201610725022.3A priority Critical patent/CN106245415B/en
Publication of CN106245415A publication Critical patent/CN106245415A/en
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Publication of CN106245415B publication Critical patent/CN106245415B/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/04Kraft or sulfate pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • D21H17/29Starch cationic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001Release paper

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

The invention discloses the manufacture method of a kind of glassine paper, including use softwood pulp, hardwood pulp through making beating respectively, with slurry and adjuvant adds, l Water Paper page is manufactured paper with pulp, front be dried, coating applying glue (PVA), the rear processing step such as dry.The present invention, by studying the functionalized chemical auxiliary agent etc. added in slurry selection, wet end furnish, beating process, slurry, uses film transitional surface applying glue to process, and performs to produce qualified glassine paper with reference to relevant paper machine parameter.

Description

A kind of manufacture method of glassine paper
Technical field
The present invention relates to the manufacture method of a kind of glassine paper, belong to pulp technology for making paper.
Background technology
Glassine paper is a kind of industrial paper, makes Ge Laxin after the operations such as rewetting, supercalendering and painting silicone oil Paper.Lattice Racine paper (GLASSINE) quality is fine and close, uniform, has good internal intensity and transparency.Be make bar coded sticker, Adhesive sticker, adhesive tape or the common used material of toughness industrial goods.The functions such as lattice Racine paper has certain high temperature resistant, moistureproof, grease proofing, It is generally used for the packaging of the industry such as food, medicine.It is mainly used in: High-Speed Automatic labeling (particularly suitable high speed label stickup) is special Adhesive tape, two-sided tape base material trade mark, laser anti-counterfeit mark and other release application etc..Medical product is mainly used for as glue Band and the release paper of casting product.Conventional grammes per square metre is 58g-120g.The purposes of lattice Racine paper and top grade two-sided film release paper Similar, owing to this product is more environmentally-friendly, the market share from now on will be increasing.Domestic so that the people live in plenty in Zhejiang special paper, Zhejiang five It is main that the enterprises such as continent paper industry, justice south, Yiwu paper industry, Wuhan Chenming's paper industry produce Ge Laxin (former) paper, along with the change of market capacity Greatly, increasing enterprise by participation exploitation and produces Ge Laxin (former) paper.My company is not because having supercalender, therefore only Develop glassine paper.
Glassine paper is processed as Ge Laxin paper process: body paper rewetting--supercalendering---being coated with silicone oil---rewind slitting
Lattice Racine paper primary quality measure includes: smoothness, transparency, water absorption, tensile strength, homogeneity etc..
The glassine paper of my company's exploitation in 2016, main innovation point has: (i) from slurry selection, beating process and papermaking Technical study and innovation, the product quality at the glassine paper of PM9 exploitation fully meets the use requirement of client, mainly studies Including: 1. study grout structure;Selecting commodity sulfate bleached wood pulp (needle and broad-leaved) is primary raw material.2. research is optimal Wet end furnish;By laboratory handsheet and the research with slurry of paper machine, determine optimal wet end furnish scope----softwood pulp: leaf wood Slurry=(70-80): (30-20).3. optimal beating degree span of control is studied, in order to allow paper machine be dehydrated and manufacture paper with pulp normal, with Time meet and improve needle slurry ratio, it is ensured that end product Ge Laxin paper transparency is high;We start with research from beating process, pass through Use fast beating mode test of many times research, overturned general Ge Laxin paper beating process, finally determined optimal Beating degree span of control is (as broad-leaved slurry beating degree controls 22-260SR, needle slurry beating degree controls 22-300SR).4. use Film transitional surface sizing equipment carries out top sizing process, and glassine paper does not use Oxytarch glue-applying technique, but adopts With the glue-applying technique of full PVA, boil technique and insulation is operated after all being groped by many experiments and just determines, it is ensured that the PVA of ton paper Resin added reaches 15-20kg.(ii) product structure innovation transition, (call of response company, product is tied to promote company's profitability Structure is made the transition to industry paper by Cultural Paper, and glassine paper rate of gross profit is apparently higher than company's existing product);Simultaneously market share by Year increases, and is an industrial paper new product being worth exploitation.
Summary of the invention
It is an object of the invention to provide the manufacture method of a kind of glassine paper.
The technical scheme is that the manufacture method of a kind of glassine paper, including using softwood pulp, leaf wood Slurry, through making beating respectively, with slurry and adjuvant adds, l Water Paper page is manufactured paper with pulp, front be dried, coating applying glue, after the processing step such as be dried, it is special Levy and be:
(1) sulfate wood pulp slurry weight proportioning, softwood pulp: hardwood pulp=70-80: 30-20;
(2) freedom after slurry pulping: softwood pulp 22-30 SR;Hardwood pulp 22-26 SR;
(3) oven dry stock consumption is by adjuvant: (a) AKD weight ratio 1.5-2.0%;(b) retention agent weight ratio 0.02- 0.04%;(c) cationic starch weight ratio 0.8-1.0%;
(4) applying glue portion: with PVA, boil concentration 9%, upper gum concentration 4.0%, it is ensured that PVA coating weight is at 15-20kg/ ton paper.Metering Rod type number: 1#, gauge stick pressure 100kpa;Up/down roller applying glue flow is respectively 1050L/min/1050L/min;Surface, two sides Applying glue, one side controls at 0.5-0.8g/m2, page tension force 220N/m before applying glue portion2, page tension force 200N/m behind applying glue portion2
(5) other parameters of paper machine: network speed 680m/min, push up net dehydrating amount 27%, head box opening degree of slice lip 9.7mm, a line ball Pressure: 900 kN/m, two line ball pressure: 900 kN/m;Curl tension: 400kN/m;
(6) rolling condition: calender separately, is not pressurized;
(7) glassine paper is quantitative: 62-78g/m2, moisture (4.0-7.0%), form and aspect raw white, longitudinal fracture length (>= 7.0Km), water absorption (20-28g/m2), tightness (≤0.74g/m2), air permeability (≤120ml/min), transversal stretching rate (≤ 3.0%), thickness is stable, formation of sheet good, planarization is good.
The present invention is by grinding the functionalized chemical auxiliary agent etc. added in slurry selection, wet end furnish, beating process, slurry Study carefully, use film transitional surface applying glue to process, perform to produce qualified glassine paper, to company with reference to relevant paper machine parameter Optimize product structure and to promote company's profitability significant.
Detailed description of the invention
Embodiment 1:78 gram glassine paper
By softwood pulp, (beating degree controls at 22-260SR) and hardwood pulp (beating degree controls at 22-260SR) two kinds of slurries Material carries out with slurry in the ratio of 70%:30%, add 15-20kg/ ton paper AKD sizing agent, add in 8-10kg/ ton paper pulp sun from Sub-starch, addition 0.2-0.4kg/ ton paper retention agent, be configured to the approach flow that raw white has diluted, carry out two-sided by folded net Dehydration, it is ensured that fiber is uniformly dispersed, vertically and horizontally fiber alignment is orderly and is uniformly distributed, after l Water Paper page enters press section unipress; Being dried the page entrance applying glue portion to mass dryness fraction 95% before entering, (surface is executed to use film branch mode that paper is carried out top sizing process Glue sizing material is mainly composed of PVA);The control total resin added of PVA is at 15-20kg/ ton paper, and l Water Paper page after treatment is dry after entering Dry process;After dried later, the mass dryness fraction page in 94~95% passes through soft press-polishing machine (calender up-down rollers is separately), then Paper is batched, i.e. can get quantification of 78 g/m2Glassine paper, its leading indicator: moisture (4.0-7.0%), Form and aspect raw white, longitudinal fracture length (>=7.0Km), water absorption (20-28g/m2), tightness (≤0.74g/m2), air permeability (≤ 120ml/min), transversal stretching rate (≤3.0%), thickness is stable, formation of sheet good, planarization is good.Permissible according to process above Produce qualified glassine paper, the prescription of client can be met completely.
Embodiment 2:62 gram glassine paper
By softwood pulp, (beating degree controls at 26-300SR) and hardwood pulp (beating degree controls at 22-260SR) two kinds of slurries Material carries out with slurry in the ratio of 80%:20%, add 15-20kg/ ton paper AKD sizing agent, add in 8-10kg/ ton paper pulp sun from Sub-starch, addition 0.2-0.4kg/ ton paper retention agent, be configured to the approach flow that raw white has diluted, carry out two-sided by folded net Dehydration, it is ensured that fiber is uniformly dispersed, vertically and horizontally fiber alignment is orderly and is uniformly distributed, after l Water Paper page enters press section unipress; Being dried the page entrance applying glue portion to mass dryness fraction 95% before entering, (surface is executed to use film branch mode that paper is carried out top sizing process Glue sizing material is mainly composed of PVA);The control total resin added of PVA is at 15-20kg/ ton paper, and l Water Paper page after treatment is dry after entering Dry process;After dried later, the mass dryness fraction page in 94~95% passes through soft press-polishing machine (calender up-down rollers is separately), then Paper is batched, i.e. can get quantification of 62 g/m2Glassine paper, its leading indicator: moisture (4.0-7.0%), Form and aspect raw white, longitudinal fracture length (>=7.0Km), water absorption (20-28g/m2), tightness (≤0.74g/m2), air permeability (≤ 120ml/min), transversal stretching rate (≤3.0%), thickness is stable, formation of sheet good, planarization is good.Permissible according to process above Produce qualified glassine paper, the prescription of client can be met completely.

Claims (1)

1. a manufacture method for glassine paper, including use softwood pulp, hardwood pulp, through respectively making beating, with slurry and auxiliary Material adds, l Water Paper page is manufactured paper with pulp, front dry, coating applying glue, rear drying process step, it is characterised in that:
(1) sulfate wood pulp slurry weight proportioning, softwood pulp: hardwood pulp=70-80: 30-20;
(2) freedom after slurry pulping: softwood pulp 22-30 SR;Hardwood pulp 22-26 SR;
(3) oven dry stock consumption is by adjuvant: (a) AKD weight ratio 1.5-2.0%;(b) retention agent weight ratio 0.02- 0.04%;(c) cationic starch weight ratio 0.8-1.0%;
(4) applying glue portion: with PVA, boil concentration 9%, upper gum concentration 4.0%, it is ensured that PVA coating weight is at 15-20kg/ ton paper.Metering Rod type number: 1#, gauge stick pressure 100kpa;Up/down roller applying glue flow is respectively 1050L/min/1050L/min;Surface, two sides Applying glue, one side controls at 0.5-0.8g/m2, page tension force 220N/m before applying glue portion2, page tension force 200N/m behind applying glue portion2
(5) other parameters of paper machine: network speed 680m/min, push up net dehydrating amount 27%, head box opening degree of slice lip 9.7mm, a line ball Pressure: 900 kN/m, two line ball pressure: 900 kN/m;Curl tension: 400kN/m;
(6) rolling condition: calender separately, is not pressurized;
(7) glassine paper is quantitative: 62-78g/m2, moisture 4.0-7.0%, form and aspect raw white, longitudinal fracture length >=7.0Km, Water absorption 20-28g/m2, tightness≤0.75g/m2, air permeability≤120ml/min, transversal stretching rate≤3.0%, thickness is stable, paper Evenness is good, planarization is good.
CN201610725022.3A 2016-08-26 2016-08-26 A kind of manufacture method of glassine paper Active CN106245415B (en)

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CN106245415B CN106245415B (en) 2018-01-23

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107345380A (en) * 2017-07-20 2017-11-14 岳阳林纸股份有限公司 A kind of manufacture method of literature and art book paper
CN109235140A (en) * 2018-09-21 2019-01-18 岳阳林纸股份有限公司 A kind of manufacturing method of High-strength adhesive tape body paper
CN111663362A (en) * 2020-05-20 2020-09-15 湖南得凯纸业有限公司 Production equipment and process of plastic-free tableware packaging paper
CN112921706A (en) * 2021-01-04 2021-06-08 义乌市义南纸业有限公司 Method for manufacturing glassine paper based on-line monitoring of paper sizing surface properties

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09170200A (en) * 1995-12-20 1997-06-30 Ehime Pref Gov Sheet having continuous gradient function in flow direction and its production
CN102277786A (en) * 2010-06-09 2011-12-14 中国制浆造纸研究院 Preparation method for double-sided gummed paper or electrostatic copy paper
CN102454136A (en) * 2011-10-29 2012-05-16 常熟市华海电子有限公司 Production process of paper for printer
CN102493284A (en) * 2011-11-29 2012-06-13 岳阳林纸股份有限公司 Method for producing glassine paper
CN105586802A (en) * 2016-02-19 2016-05-18 岳阳林纸股份有限公司 Manufacturing method of Pinfeng base paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09170200A (en) * 1995-12-20 1997-06-30 Ehime Pref Gov Sheet having continuous gradient function in flow direction and its production
CN102277786A (en) * 2010-06-09 2011-12-14 中国制浆造纸研究院 Preparation method for double-sided gummed paper or electrostatic copy paper
CN102454136A (en) * 2011-10-29 2012-05-16 常熟市华海电子有限公司 Production process of paper for printer
CN102493284A (en) * 2011-11-29 2012-06-13 岳阳林纸股份有限公司 Method for producing glassine paper
CN105586802A (en) * 2016-02-19 2016-05-18 岳阳林纸股份有限公司 Manufacturing method of Pinfeng base paper

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107345380A (en) * 2017-07-20 2017-11-14 岳阳林纸股份有限公司 A kind of manufacture method of literature and art book paper
CN109235140A (en) * 2018-09-21 2019-01-18 岳阳林纸股份有限公司 A kind of manufacturing method of High-strength adhesive tape body paper
CN111663362A (en) * 2020-05-20 2020-09-15 湖南得凯纸业有限公司 Production equipment and process of plastic-free tableware packaging paper
CN111663362B (en) * 2020-05-20 2022-03-08 湖南得凯纸业有限公司 Production equipment and process of plastic-free tableware packaging paper
CN112921706A (en) * 2021-01-04 2021-06-08 义乌市义南纸业有限公司 Method for manufacturing glassine paper based on-line monitoring of paper sizing surface properties

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