CN106242145A - A kind of desulfurization wastewater reverse osmosis reconcentration device - Google Patents
A kind of desulfurization wastewater reverse osmosis reconcentration device Download PDFInfo
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- CN106242145A CN106242145A CN201610731649.XA CN201610731649A CN106242145A CN 106242145 A CN106242145 A CN 106242145A CN 201610731649 A CN201610731649 A CN 201610731649A CN 106242145 A CN106242145 A CN 106242145A
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- entrance
- reverse osmosis
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- oxidation pond
- osmosis unit
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- 238000001223 reverse osmosis Methods 0.000 title claims abstract description 41
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 26
- 239000002351 wastewater Substances 0.000 title claims abstract description 26
- 230000023556 desulfurization Effects 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 230000003647 oxidation Effects 0.000 claims abstract description 26
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 26
- 238000000909 electrodialysis Methods 0.000 claims abstract description 20
- 238000004062 sedimentation Methods 0.000 claims abstract description 19
- 238000002425 crystallisation Methods 0.000 claims abstract description 13
- 230000008025 crystallization Effects 0.000 claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 10
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 14
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000010842 industrial wastewater Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 9
- 238000001704 evaporation Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 238000001728 nano-filtration Methods 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 239000013505 freshwater Substances 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000010612 desalination reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/10—Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/04—Flow arrangements
- C02F2301/046—Recirculation with an external loop
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/14—Maintenance of water treatment installations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The present invention relates to a kind of technique for treating industrial wastewater and device, it is specifically related to a kind of desulfurization wastewater reverse osmosis reconcentration device, the entrance of sedimentation tank is connected with the entrance of the outlet of oxidation pond and more medium filter, the outlet of more medium filter is connected with the entrance of electrodialysis plant, the dense water out of electrodialysis plant is connected with the entrance of oxidation pond, the water outlet of electrodialysis plant is connected with the entrance of reverse osmosis unit, the water outlet of reverse osmosis unit is connected with the entrance of sedimentation tank and the entrance of oxidation pond respectively, the dense water out of reverse osmosis unit is connected with the entrance of evaporated crystallization device, the outlet of the first dosing tank is connected with the entrance of oxidation pond, the outlet of the second dosing tank is connected with the entrance of sedimentation tank.The present invention can effectively remove the salinity in heat-engine plant desulfurized waste water and other compositions, but also can reclaim these compositions with useful form.
Description
Technical field
The present invention relates to a kind of technique for treating industrial wastewater and device, be specifically related to a kind of desulfurization wastewater reverse osmosis reconcentration
Device.
Background technology
At present, the desulfuration waste water treatment process that domestic and international thermal power plant is common is predominantly: hydraulic(-ash) sluicing, be separately provided at chemistry
The methods such as reason system (predominantly three headers process), evaporation.Wherein evaporation process is to make desulfurization give up by evaporation and crystallization apparatus
Water is separated into steam and the solid waste of high-quality, in order to realize full factory waste water zero discharge.Use at evaporative crystallisation process
Reason desulfurization wastewater has the drawback that: investing the highest, because whole desulfurization wastewaters are all evaporated, operating cost is the highest.Therefore, need
Desulfurization wastewater is carried out decrement treatment, reduces the processing cost of evaporation and crystallization system.
Technique for desulfurization wastewater decrement treatment mainly includes reverse osmosis and nanofiltration etc..Due to desulfurization wastewater salinity
Higher, and rich in Organic substance and fouling tendency material, use reverse osmosis to carry out concentrating decrement, pretreating process requires strict, and
It is on the low side that the system response rate controls, and typically about 50%, and the salinity of strong brine increases to about 70000ppm, disposes such
Saline, for desalination industry, will face huge cost and challenge, causes longer startup time and higher water
Cost.Using nanofiltration to carry out desulfurization wastewater decrement treatment, nanofiltration is bigger than normal to the clearance of monovalent ion, produces water and cannot directly return
With, needing that the further desalination of water is produced in nanofiltration and can be only achieved reuse requirement, technological process is the longest, and processing cost is higher.Therefore, need
Explore suitable desulfurization wastewater deweighting treating technology.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides be applicable to heat-engine plant desulfurized waste water process a kind of desulfurization give up
Water reverse osmosis reconcentration device, thus effectively remove the salinity in heat-engine plant desulfurized waste water and other compositions, but also can have
These compositions are reclaimed by form.
In order to achieve the above object, the technical solution adopted in the present invention is, a kind of desulfurization wastewater reverse osmosis reconcentration dress
Put, including oxidation pond, sedimentation tank, more medium filter, electrodialysis plant, reverse osmosis unit, regulating reservoir, evaporated crystallization device,
First dosing tank and the second dosing tank;
The entrance of described sedimentation tank is connected with the entrance of the outlet of oxidation pond and more medium filter, described more medium filter
Outlet be connected with the entrance of electrodialysis plant, the dense water out of described electrodialysis plant is connected with the entrance of oxidation pond,
The water outlet of described electrodialysis plant is connected with the entrance of reverse osmosis unit, and the water outlet of described reverse osmosis unit is respectively
It is connected with the entrance of sedimentation tank and the entrance of oxidation pond, the dense water out of reverse osmosis unit and the entrance phase of evaporated crystallization device
Connection, the described outlet of the first dosing tank is connected with the entrance of oxidation pond, the outlet of described second dosing tank and sedimentation tank
Entrance is connected.
Further, also including regulating reservoir, the dense water out of described reverse osmosis unit is also connected with regulating reservoir, described regulation
Pond is back to the water inlet of reverse osmosis unit.
Further, the first described dosing tank is built with sodium hypochlorite.
Further, the second described dosing tank is built with sodium hydroxide.
The present invention, by using technique scheme, compared with prior art, has the advantage that
The present invention is by one brand-new desulfurization wastewater reverse osmosis reconcentration device of design, by one brand-new reverse osmosis of design
Reconcentration device, the oxidation pond in the pretreatment unit having plays protective action, prevents the inferior sulfate radical in desulfurization wastewater not
Oxidation is completely.A large amount of calcium ions and magnesium ions are removed by sedimentation tank with precipitation form, alleviate follow-up individual event ion and hand over while reducing SS
Change EDBM device workload and reduce the probability of electrodialyzer fouling.Electrodialysis cycles of concentration is high, alleviates subsequent evaporation
The load of crystallization, reduces investment and operating cost.
Accompanying drawing explanation
Fig. 1 is the structural representation of embodiments of the invention.
Detailed description of the invention
In conjunction with the drawings and specific embodiments, the present invention is further described.
As a specific embodiment, as it is shown in figure 1, a kind of desulfurization wastewater reverse osmosis reconcentration device, including oxidation
Pond 1, sedimentation tank 2, more medium filter 3, electrodialysis plant 4, reverse osmosis unit 7, regulating reservoir 8, evaporated crystallization device 9, first
Dosing tank 5 and the second dosing tank 6;
The entrance of described sedimentation tank 2 is connected with the entrance of the outlet of oxidation pond 1 and more medium filter 3, described multimedium mistake
The outlet of filter 3 is connected with the entrance of electrodialysis plant 4, the dense water out of described electrodialysis plant 4 and the entrance of oxidation pond 1
Being connected, the water outlet of described electrodialysis plant 4 is connected with the entrance of reverse osmosis unit 7, described reverse osmosis unit 7 light
Water out is connected with the entrance of sedimentation tank 2 and the entrance of oxidation pond 1 respectively, the dense water out of reverse osmosis unit 7 and evaporation knot
The entrance of brilliant device 9 is connected, and the described outlet of the first dosing tank 5 is connected with the entrance of oxidation pond 1, described second dosing tank
The outlet of 6 is connected with the entrance of sedimentation tank 2.
Further, also including regulating reservoir 8, the dense water out of described reverse osmosis unit 7 is also connected with regulating reservoir 8, described
Regulating reservoir 8 is back to the water inlet of reverse osmosis unit 7.
Further, the first described dosing tank 5 is built with sodium hypochlorite.
Further, the second described dosing tank 6 is built with sodium hydroxide.
Desulfurization wastewater situation produced by certain thermal power plant employing Limestone-gypsum Wet Flue Gas Desulfurization Process: treating capacity 9t/d, sulfate radical
12000mg/L, inferior sulfate radical 6500mg/L, calcium ion content 1300mg/L, magnesium ion content 2500mg/L, chloride ion content
24000mg/L, sodium ions content 23000mg/L, pH are 5.9.
Desulfurization wastewater is through peroxidating and precipitation process: desulfurization is given up by the sodium hypochlorite adding 65mmol/L in oxidation pond 1
Sulfite oxidation in water becomes sulfate, the waste water after oxidation completely to enter sedimentation tank 2;Add in sedimentation tank 2 again
Calcium ions and magnesium ions is precipitated by the sodium hydroxide of 162mmol/L, isolated supernatant.
Clear liquid carries out multi-medium filtering successively, and particulate matter is filtered out and obtains SS passing through less than 5 by more medium filter 3
Liquid, entering back into electrodialysis plant 4 and being adjusted deep or light water flow velocity is 4cm/s, and pole water flow velocity is 6cm/s, and voltage is by tune film
0.5V, is circulated concentration.Circulation 90min after obtain about 15% the dense water of electrodialysis, the electrodialysis fresh water of about 3%, pH value
It is the negative electrode pole water of 9.5 and anode pole water that pH value is 2.3.Anode pole water is recycled to oxidation pond 1, and negative electrode pole water is recycled to precipitation
Pond 2, the dense water of electrodialysis enters vaporizer and is evaporated crystallization, and it is light that electrodialyzer fresh water entrance reverse osmosis unit 7 obtains reverse osmosis
Water and reverse osmosis concentrated water, reverse osmosis freshwater is back to oxidation pond 1 and sedimentation tank 2 respectively, and reverse osmosis concentrated water enters evaporative crystallization dress
Put and be evaporated crystallization.
Although specifically showing and describe the present invention in conjunction with preferred embodiment, but those skilled in the art should be bright
In vain, in the spirit and scope of the present invention limited without departing from appended claims, in the form and details can be right
The present invention makes a variety of changes, and is protection scope of the present invention.
Claims (4)
1. a desulfurization wastewater reverse osmosis reconcentration device, it is characterised in that: include oxidation pond, sedimentation tank, more medium filter,
Electrodialysis plant, reverse osmosis unit, regulating reservoir, evaporated crystallization device, the first dosing tank and the second dosing tank;
The entrance of described sedimentation tank is connected with the entrance of the outlet of oxidation pond and more medium filter, described more medium filter
Outlet be connected with the entrance of electrodialysis plant, the dense water out of described electrodialysis plant is connected with the entrance of oxidation pond,
The water outlet of described electrodialysis plant is connected with the entrance of reverse osmosis unit, and the water outlet of described reverse osmosis unit is respectively
It is connected with the entrance of sedimentation tank and the entrance of oxidation pond, the dense water out of reverse osmosis unit and the entrance phase of evaporated crystallization device
Connection, the described outlet of the first dosing tank is connected with the entrance of oxidation pond, the outlet of described second dosing tank and sedimentation tank
Entrance is connected.
A kind of desulfurization wastewater reverse osmosis reconcentration device the most according to claim 1, it is characterised in that: also include regulation
Pond, the dense water out of described reverse osmosis unit is also connected with regulating reservoir, and described regulating reservoir is back to the water inlet of reverse osmosis unit.
A kind of desulfurization wastewater reverse osmosis reconcentration device the most according to claim 1, it is characterised in that: described first adds
Medicine-chest is built with sodium hypochlorite.
A kind of desulfurization wastewater reverse osmosis reconcentration device the most according to claim 1, it is characterised in that: described second adds
Medicine-chest is built with sodium hydroxide.
Priority Applications (1)
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CN201610731649.XA CN106242145A (en) | 2016-08-26 | 2016-08-26 | A kind of desulfurization wastewater reverse osmosis reconcentration device |
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CN201610731649.XA CN106242145A (en) | 2016-08-26 | 2016-08-26 | A kind of desulfurization wastewater reverse osmosis reconcentration device |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106865865A (en) * | 2017-04-12 | 2017-06-20 | 上海龙净环保科技工程有限公司 | Membrane separation process concentrates the processing unit and method of brackish water |
CN107473486A (en) * | 2017-09-26 | 2017-12-15 | 江苏中圣高科技产业有限公司 | A kind of combination treatment method of desulfurization wastewater |
CN108383295A (en) * | 2018-05-11 | 2018-08-10 | 上海晶宇环境工程股份有限公司 | The separating technology and its special equipment of organic matter and salt in strong brine |
US11502322B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell with heat pump |
US11502323B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell and methods of use thereof |
US11855324B1 (en) | 2022-11-15 | 2023-12-26 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell with heat pump |
US12040517B2 (en) | 2022-11-15 | 2024-07-16 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof |
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CN103288236A (en) * | 2013-05-27 | 2013-09-11 | 山东三维石化工程股份有限公司青岛分公司 | Treatment method for salt-containing wastewater |
CN105859006A (en) * | 2016-05-23 | 2016-08-17 | 海博伦(苏州)环境科技股份有限公司 | Desulfurization waste water reuse and zero discharge system and technology |
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CA2244109A1 (en) * | 1996-02-05 | 1997-08-14 | Veikko Jolkin | Method to treat whey |
CN201424394Y (en) * | 2009-06-17 | 2010-03-17 | 浙江玉泉环境工程有限公司 | Reverse osmosis water quality automatic control system |
CN201785261U (en) * | 2009-12-31 | 2011-04-06 | 上海轻工业研究所有限公司 | Treatment and recovery device for aluminum oxidation rinsing wastewater |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106865865A (en) * | 2017-04-12 | 2017-06-20 | 上海龙净环保科技工程有限公司 | Membrane separation process concentrates the processing unit and method of brackish water |
CN107473486A (en) * | 2017-09-26 | 2017-12-15 | 江苏中圣高科技产业有限公司 | A kind of combination treatment method of desulfurization wastewater |
CN107473486B (en) * | 2017-09-26 | 2020-12-29 | 江苏中圣高科技产业有限公司 | Combined treatment method of desulfurization wastewater |
CN108383295A (en) * | 2018-05-11 | 2018-08-10 | 上海晶宇环境工程股份有限公司 | The separating technology and its special equipment of organic matter and salt in strong brine |
US11502322B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell with heat pump |
US11502323B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell and methods of use thereof |
US11563229B1 (en) | 2022-05-09 | 2023-01-24 | Rahul S Nana | Reverse electrodialysis cell with heat pump |
US11611099B1 (en) | 2022-05-09 | 2023-03-21 | Rahul S Nana | Reverse electrodialysis cell and methods of use thereof |
US11699803B1 (en) | 2022-05-09 | 2023-07-11 | Rahul S Nana | Reverse electrodialysis cell with heat pump |
US12107308B2 (en) | 2022-05-09 | 2024-10-01 | Rahul S Nana | Reverse electrodialysis cell and methods of use thereof |
US11855324B1 (en) | 2022-11-15 | 2023-12-26 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell with heat pump |
US12040517B2 (en) | 2022-11-15 | 2024-07-16 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof |
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Application publication date: 20161221 |