CN106222555A - By tensile strength >=1300MPa thin hot forming steel and the production method of sheet billet Direct Rolling - Google Patents
By tensile strength >=1300MPa thin hot forming steel and the production method of sheet billet Direct Rolling Download PDFInfo
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- CN106222555A CN106222555A CN201610713633.6A CN201610713633A CN106222555A CN 106222555 A CN106222555 A CN 106222555A CN 201610713633 A CN201610713633 A CN 201610713633A CN 106222555 A CN106222555 A CN 106222555A
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 65
- 239000010959 steel Substances 0.000 title claims abstract description 65
- 238000005096 rolling process Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000010791 quenching Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002791 soaking Methods 0.000 claims abstract description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 230000000171 quenching effect Effects 0.000 claims abstract description 12
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 9
- 238000003723 Smelting Methods 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 238000009749 continuous casting Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 6
- 238000004080 punching Methods 0.000 claims abstract description 5
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 238000005266 casting Methods 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000010079 rubber tapping Methods 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 229910000734 martensite Inorganic materials 0.000 description 6
- 239000010955 niobium Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229910052758 niobium Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910001566 austenite Inorganic materials 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005097 cold rolling Methods 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- -1 and meanwhile Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/04—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
- B21B45/08—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing hydraulically
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metal Rolling (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
With tensile strength >=1300MPa thin hot forming steel of sheet billet Direct Rolling, its component and wt%:C:0.17~0.20%, Si:0.21~0.25%, Mn:1.0~1.3%, P≤0.01%, S≤0.008%, Als:0.015~0.060%, Cr:0.19~0.24%, more than Ti:0.021~0.025% or Nb:0.021~0.025% or V:0.021~0.025% or two of which with the mixing of arbitrary proportion, B:0.002~0.003%, N≤0.005%.Production stage: desulfurizing iron;Electric furnace or converter smelting and refine;Continuous casting;Enter the de-scaling before soaking pit to process;Soaking;Heating;High-pressure water descaling before feed mill;Rolling;Cooling;Batch;Austenitizing;Mould punching shapes;Quenching.Flow process of the present invention is short, and product surface quality is good, and thickness and precision is high, it is possible to reach the prescription of cold-rolled products, high without resilience, the dimensional accuracy of part after smoothly completing complex deformation, and deformation.
Description
Technical field
The present invention relates to a kind of auto parts and components steel and production method thereof, specifically belong to one sheet billet and directly roll
Tensile strength >=1300MPa hot forming the steel of system and production method, and it is applicable to product thickness 0.8 to the 2mm produced.
Background technology
Along with Automobile Design and manufacture are gradually sent out by automobile industry development and automobile industry to energy-saving and environmental protection, safe direction
Exhibition, automotive light weight technology becomes the main flow direction of significant period of time Automobile Design at present and in the future.
Research finds, complete vehicle weight and the energy resource consumption of automobile are linear.According to statistics, vehicle weight often reduces by 10%
Then fuel efficiency can improve 6%~8%.One of most important approach of automotive light weight technology is to use high intensity and unimach, from
And can make while not reducing crashworthiness and comfortableness, adopt and automobile weight in working order can be greatly reduced.But along with intensity
Improving constantly, the forming property of steel plate can worse and worse, and the unimach of especially more than 1300MPa, in forming process
Cracking, resilience and accessory size can be there is and do not reach the problems such as permissible accuracy, and also pressing equipment be proposed higher simultaneously
Requirement, i.e. need large-tonnage stamping machine and high abrasion mould, and the mold use cycle also had large effect.Mesh
The front domestic cold forming pressing equipment also not having to shape more than 1300MPa and mould.
Currently, the hot forming steel that domestic and international prior art produces all uses cold rolled annealed state or cold rolled annealed rear precoated shet.
Its technological process of production is: desulphurised hot metal → converter smelting → external refining → continuous casting → heating of plate blank → hot continuous rolling → pickling+
Cold continuous rolling → continuous annealing → (precoated shet) → finishing packaging → blanking → heating → mould punching quenching.There is production technology stream
Journey is longer, relatively costly deficiency.All use multiple part combination component anti-to improve for some impact resistant or load bearing component
Collision and bearing capacity, and cause being greatly improved the cost of raw material and processing cost.
Along with the development of steel and iron industry, medium thin slab continuous casting and rolling technique has obtained tremendous development, uses medium thin slab even
Casting continuous rolling process can produce 0.8~2 mm specification steel plate and steel bands with Direct Rolling, and some can only use cold rolling high-strength steel originally
Thin Specs part or for increase intensity use multiple parts composition component the most progressively use casting and rolling process Direct Rolling
Ultrahigh-strength steel plates is replaced.Patent exploitation yield strength (R such as Application No. CN 102965573AeL) >=700MPa, anti-
Tensile strength (RmThe engineering structure high strength steel of) >=750MPa, its component percentages is: C:0.15~0.25%, Si :≤
0.10%, Mn:1.00~1.80%, P :≤0.020%, S≤0.010%, Ti:0.09~0.20%, Als:0.02~0.08%, N
≤ 0.008%, remaining for Fe and is inevitably mingled with;Its production stage, for smelting and being casting continuously to form base, carries out soaking, controls all
Hot temperature is at 1200~1300 DEG C, and soaking time is 20~60min;Roll, and control start rolling temperature and be not less than 1200 DEG C,
Finishing temperature is at 870~930 DEG C;Carry out section cooling, be cooled to coiling temperature in rate of cooling for being not less than under 20 DEG C/s;Enter
Row batches, and controls coiling temperature at 580~650 DEG C.A kind of short route of the patented invention of Patent No. CN 103658178A
The method producing high-strength thin strip steel, the strip steel yield strength (R inventedeL) >=550MPa, tensile strength (Rm) >=600MPa,
Its chemical composition mass percent is: C:0.02~0.15%, Si:0.20~0.6%, Mn:0.2~1.50%, P:0.02~
0.3%, S≤0.006%, Cr:0.40~0.8%, Ni:0.08~0.40%, Cu:0.3~0.80%, Nb:0.010~0.025%,
Ti:0.01~0.03%, Al:0.01~0.06%, Re:0.02~0.25%;Remaining is Fe and inevitable impurity, waters after smelting
Cast 1.0~2.0mm thick Cast Strips, casting rate 60~150m/min, roll, control finishing temperature 850~1000 DEG C;
Using atomization cooling, rate of cooling 50~100 DEG C/s, batch, controlling coiling temperature is 520~660 DEG C.Above-mentioned two documents
The tensile strength of invention steel is the lowest, it is impossible to meet the high-end body of a motor car demand to more than 1300MPa superhigh intensity.
Summary of the invention
The invention reside in the intensity rank overcoming prior art to exist low, it is impossible to meet user to superhigh intensity part demand
Deficiency, it is provided that a kind of flow process is short, and product surface quality is good, and thickness and precision is high, it is possible to reach the prescription of cold-rolled products, energy
Smoothly complete complex deformation, and without resilience after deformation, tensile strength >=1300MPa hot forming steel that the dimensional accuracy of part is high and
Production method.
Realize the measure of above-mentioned purpose:
With tensile strength >=1300MPa thin hot forming steel of sheet billet Direct Rolling, its component and weight percent content be: C:
0.17~0.20%, Si:0.21~0.25%, Mn:1.0~1.3%, P≤0.01%, S≤0.008%, Als:0.015~0.060%,
Cr:0.19~0.24%, Ti:0.021~0.025% or Nb:0.021~0.025% or V:0.021~0.025% or two of which
Above with the mixing of arbitrary proportion, B:0.002~0.003%, N≤0.005%, remaining for Fe and inevitable impurity.
The method of tensile strength >=1300MPa thin hot forming steel of production sheet billet Direct Rolling, it is: its step
Rapid:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 55~60mm, and casting speed is 3.5
~7.0m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) entering to heat to strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1180~1200
℃;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 52~63%, the second percentage pass reduction is: 50~60%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is 8~12m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 665 ~ 695 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 850~920 DEG C, and is incubated 3~5 min;
12) mould punching shapes, and pressurize 10~20s in mould;
13) quench, control quenching rate of cooling at 20~40 DEG C/s;After naturally cool to room temperature.
It is: the operation of rolling of described medium thin slab is that 6F produces line or 1R+6F produces line or 2R+ at rolling mill layout
6F produces the short route product line of line or 7F product line or 3R+4F product line or 2R+5F product line or 1R+5F to be carried out.
Each element and the effect of main technique and mechanism in the present invention
C: carbon is strong solution strengthening element, and the acquisition to superhigh intensity plays a decisive role, the carbon content tissue shape to final products
State and performance have considerable influence, but content is the highest, are easily formed substantial amounts of pearlite or bayesian in the cooling procedure after finish rolling
Body, martensite, its content is the highest, and intensity is the highest, thus causes plasticity to reduce, the blanking difficulty before forming.So protecting
On the premise of card heat treatment reinforcement, carbon content is difficult to too high.Therefore its content is limited to 0.17~0.20% scope.
Si: silicon has stronger solid solution strengthening effect, can improve the intensity of steel, and meanwhile, silicon can improve the quenching degree of steel, has and subtracts
Few austenite effect of change in volume when martensite transfor mation, thus effectively control the generation of hardening flaw;When lonneal
Carbon diffusion can be hindered, delay martensite to decompose and the speed of carbide agglomeration, make steel hardness when tempering decline relatively slow,
Significantly improve steel belt roof bolt stability and intensity.So, its content is limited to 0.21~0.25% scope.
Mn: manganese plays solution strengthening effect, can remove the FeO in steel simultaneously, significantly improve the quality of steel.Can also be with sulfide
Generating dystectic MnS, when hot-working, MnS has enough plasticity, makes steel not produce hot-short phenomenon, alleviates harmful work of sulfur
With, improve the hot-working character of steel.Manganese can reduce phase driving force, makes " C " curve move to right, and improves the quenching degree of steel, expands γ
Phase region, separately it can reduce the Ms point of steel, therefore can ensure to obtain martensite under suitable rate of cooling.So, its content is limited
It is scheduled on 1.0~1.3% scope.
Cr: chromium can reduce phase driving force, and when also reducing phase transformation, the forming core of carbide is grown up, so improving the through hardening of steel
Property.It addition, chromium can improve steel belt roof bolt stability.So, its content is limited to 0.19~0.24% scope.
B: boron is strongly to improve quenching degree element, and the boron element adding trace in steel can significantly improve the quenching degree of steel.But
It is that its content is less than 0.002%, or higher than 0.003%, the effect to improving quenching degree is inconspicuous.So, for considering to produce
Actual and quenching degree effect, is limited to 0.002~0.003% scope by its content.
Als, it plays deoxidation in steel, should ensure that there is a certain amount of dissolved aluminum in steel, otherwise can not play its effect,
But too much aluminum also can make to produce aluminum system in steel to be mingled with, and is unfavorable for smelting and the casting of steel.Steel adds appropriate aluminum simultaneously
Nitrogen in steel, the oxygen atom adverse effect to performance can be eliminated.Therefore its content is limited to 0.015~0.060% scope.
P: phosphorus is the harmful element in steel, easily causes center segregation of casting blank.In hot continuous rolling heating process subsequently the most partially
Gather crystal boundary, make the fragility of steel significantly increase.It is simultaneously based on cost consideration and does not affect the performance of steel, its content is controlled
Less than 0.01%.
S: sulfur is very harmful element.Sulfur in steel often exists with the oxide morphology of manganese, this sulphide inculsion meeting
The toughness of deterioration steel, and cause the anisotropy of performance, therefore, need to sulfur content in steel be controlled the lowest more good.Based on to system
Cause this consideration, sulfur content in steel is controlled below 0.008%.
N: nitrogen can be combined formation titanium nitride in the steel add titanium with titanium, and this second phase at high temperature separated out is conducive to strong
Change matrix, and improve the welding performance of steel plate.But nitrogen content is higher than 0.005%, and nitrogen is higher with the solubility product of titanium, when high temperature
Steel will form the titanium nitride that granule is thick, the plasticity of serious infringement steel and toughness;It addition, higher nitrogen content can make stable
Micro alloying element content needed for nitrogen element increases, thus increases cost.Therefore its content is controlled below 0.005%.
Ti: titanium is that strong C, N compound forms element, and the purpose adding Ti in steel is the N element in fixing steel, but excess
Ti can be combined with C thus reduce hardness and the intensity of martensite after test steel quenches.It addition, the quenching degree to steel that adds of titanium has
Certain contribution.So, its content is limited to 0.021~0.025% scope.
Nb, V: niobium and vanadium are also that strong C, N compound forms element, can play the effect of fining austenite grains, add in steel
A small amount of niobium or vanadium just can form the carbon of a certain amount of niobium, nitride, thus hinder Austenite Grain Growth, and therefore, it is quenched
Martensite lath size after fire is less, is greatly improved the intensity of steel.Therefore its content is all controlled 0.021~0.025% it
Between.
Why the present invention takes three de-scalings in whole production process, is due to by controlling de-scaling passage with suitable
De-scaling water pressure, the iron scale of belt steel surface can be removed as far as possible, thus ensure that strip steel has good surface matter
Amount.Control additionally by one, two roads and end percentage pass reduction, even tissue and the stable performance of strip steel can be realized.
Compared with prior art, flow process is short for the present invention, and product surface quality is good, and thickness and precision is high, it is possible to reach cold rolling product
The prescription of product is high without resilience, the dimensional accuracy of part after smoothly completing complex deformation, and deformation.
Accompanying drawing explanation
Fig. 1 is product metallographic structure figure of the present invention.
Detailed description of the invention
Below the present invention is described in detail:
Table 1 is the chemical composition value list of various embodiments of the present invention and comparative example;
Table 2 is the main technologic parameters value list of various embodiments of the present invention and comparative example;
Table 3 is the performance detection case list of various embodiments of the present invention and comparative example.
Various embodiments of the present invention are all produced by following technique:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 55~60mm, and casting speed is 3.5
~7.0m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) entering to heat to strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1180~1200
℃;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 52~63%, the second percentage pass reduction is: 50~60%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is 8~12m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 665 ~ 695 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 850~920 DEG C, and is incubated 3~5 min;
12) mould punching shapes, and pressurize 10~20s in mould;
13) quench, control quenching rate of cooling at 20~40 DEG C/s;After naturally cool to room temperature.
The chemical composition (wt.%) of table 1 various embodiments of the present invention and comparative example
The main technologic parameters value list of table 2 various embodiments of the present invention and comparative example
Table 3 various embodiments of the present invention and comparative example mechanical property situation list
From table 3 it can be seen that by the abbreviated system of sheet billet Direct Rolling, it is achieved that the intensity of invention steel reaches
More than 1300MPa, it is possible to reach with the purpose of hot Dai Leng, its intensity is significantly larger than existing short route and produces line product strength simultaneously,
For advancing automotive light weight technology development significant.
This detailed description of the invention is only and most preferably enumerates, the not restricted enforcement to technical solution of the present invention.
Claims (3)
1., with tensile strength >=1300MPa thin hot forming steel of sheet billet Direct Rolling, its component and weight percent content be:
C:0.17~0.20%, Si:0.21~0.25%, Mn:1.0~1.3%, P≤0.01%, S≤0.008%, Als:0.015~
0.060%, Cr:0.19~0.24%, Ti:0.021~0.025% or Nb:0.021~0.025% or V:0.021~0.025% or its
In the two or more mixing with arbitrary proportion, B:0.002~0.003%, N≤0.005%, remaining for Fe and inevitable impurity.
2. produce the method with tensile strength >=1300MPa thin hot forming steel of sheet billet Direct Rolling described in claim 1,
It is characterized in that: its step:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 55~60mm, and casting speed is 3.5
~7.0m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) heating strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1180~1200 DEG C;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 52~63%, the second percentage pass reduction is: 50~60%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is 8~12m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 665 ~ 695 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 850~920 DEG C, and is incubated 3~5 min;
12) mould punching shapes, and pressurize 10~20s in mould;
13) quench, control quenching rate of cooling at 20~40 DEG C/s;After naturally cool to room temperature.
3. the side of tensile strength >=1300MPa thin hot forming steel of production sheet billet Direct Rolling as claimed in claim 2
Method, it is characterised in that: the operation of rolling of described medium thin slab is that 6F produces line or 1R+6F produces line or 2R+6F at rolling mill layout
The short route product line producing line or 7F product line or 3R+4F product line or 2R+5F product line or 1R+5F is carried out.
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CN112760554A (en) * | 2019-10-21 | 2021-05-07 | 宝山钢铁股份有限公司 | High-strength steel with excellent ductility and manufacturing method thereof |
CN112962026A (en) * | 2021-01-31 | 2021-06-15 | 邯郸钢铁集团有限责任公司 | Wide-width high-wear-resistance automobile compartment body steel and manufacturing method thereof |
CN112962026B (en) * | 2021-01-31 | 2022-06-10 | 邯郸钢铁集团有限责任公司 | Wide-width high-wear-resistance automobile compartment body steel and manufacturing method thereof |
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CN113755746A (en) * | 2021-07-23 | 2021-12-07 | 唐山钢铁集团有限责任公司 | Method for improving band-shaped structure of hot-forming steel plate |
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