CN106221657A - The flame retardant polyurethane foamed glue that a kind of air-tightness is good - Google Patents
The flame retardant polyurethane foamed glue that a kind of air-tightness is good Download PDFInfo
- Publication number
- CN106221657A CN106221657A CN201610614324.3A CN201610614324A CN106221657A CN 106221657 A CN106221657 A CN 106221657A CN 201610614324 A CN201610614324 A CN 201610614324A CN 106221657 A CN106221657 A CN 106221657A
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- China
- Prior art keywords
- foamed glue
- tightness
- flame retardant
- good
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003292 glue Substances 0.000 title claims abstract description 25
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 18
- 239000004814 polyurethane Substances 0.000 title claims abstract description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000003063 flame retardant Substances 0.000 title claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 27
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000006260 foam Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims abstract description 9
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012153 distilled water Substances 0.000 claims abstract description 8
- 239000003365 glass fiber Substances 0.000 claims abstract description 8
- 239000012802 nanoclay Substances 0.000 claims abstract description 8
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229950009789 cetomacrogol 1000 Drugs 0.000 claims abstract description 7
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 7
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000008117 stearic acid Substances 0.000 claims abstract description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229940126062 Compound A Drugs 0.000 claims description 7
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 230000006837 decompression Effects 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 241000218195 Lauraceae Species 0.000 claims 1
- 235000017858 Laurus nobilis Nutrition 0.000 claims 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000007789 sealing Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 208000005156 Dehydration Diseases 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- -1 diphenylmethane diisocyanate Ester Chemical class 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
- C08G18/165—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22 covered by C08G18/18 and C08G18/24
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/6696—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/36 or hydroxylated esters of higher fatty acids of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/60—Compositions for foaming; Foamed or intumescent adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/10—Water or water-releasing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses the flame retardant polyurethane foamed glue that a kind of air-tightness is good, it is prepared by the raw materials in: methyl diphenylene diisocyanate 150 160, trihydroxy polypropylene oxide ether 100 105, Oleum Ricini 100 110, glycerol 56, diethyl phosphate 40 43, the sodium hydroxide solution of 1mol/L is appropriate, kieselguhr 13 15, distilled water 56, triethanolamine 23, dibutyl tin laurate 34, stearic acid 23, polyvinyl alcohol 34, cetomacrogol 1000 23, short glass fiber 45, nanoclay 23, silane coupler KH560 0.8 1, dehydrated alcohol is appropriate.The foamed glue that the present invention makes can foam at the scene, has backfilled enclosed effective, features such as simple, safe and reliable, low cost of constructing, and great is widely applied prospect.
Description
Technical field
The present invention relates to foamed glue technical field, particularly relate to the flame retardant polyurethane foamed glue that a kind of air-tightness is good.
Background technology
Dual-component polyurethane adhesive is a most important class in adhesive for polyurethane, generally by component A (host) and B group
Dividing (firming agent) composition, wherein component A is hydroxy component, and B component is containing free isocyanate groups component, and the two is separately packed,
Use can be prepared by a certain percentage.In China, the research of expansion type dual-component polyurethane adhesive starts from nineteen ninety-five, 20th century 90
Later stage in age gradually comes into operation.Expansion type dual-component polyurethane adhesive has that porous, relative density be relatively low, specific strength relatively
High, according to the difference of raw material and formula can be made into common soft bubble, hard bubble, high rebound foam and low resilience urethane foam resilient foam etc.,
Multiple application necks such as automobile, electronics, rack, filter, three-prevention lamp, explosion-proof casing, household electrical appliance are widely used in it
Territory.Therefore, the promotion prospect of expansion type dual-component polyurethane adhesive is the most optimistic.The present invention is directed to it at switch cubicle, rack
The application of the aspects such as sealing is studied.The effect of the shell such as switch cubicle or rack avoids internal unit by extraneous factor
Interference, but only shell is not enough to stop outside dust storm or electromagnetic radiation, therefore, it is desirable to and sealing strip increases product integral sealing
Performance.Conventional seals technique is to use physical bonds method that standard seal part is bonded in sealing station, and the method exists production
Efficiency is low, poor reliability, many defects such as unsightly.
With trihydroxy polypropylene oxide ether, Oleum Ricini and two in " preparation of expansion type dual-component polyurethane adhesive " literary composition
Methylenebis phenyl isocyanate is primary raw material, and glycerol is chain extender, and water is foaming agent, by suitable proportioning, uses pre-
Poly-method has synthesized a kind of expansion type dual-component polyurethane adhesive, the foaming adhesive foam uniform and smooth made, tensile shear
Intensity is higher, and combination property is more excellent, but its heat resistance is poor, easily burns, when being used as the sealing of switch cubicle or rack, no
Can meet the safety used, this is accomplished by carrying out its heat stability strengthening modification, improves fire resistance.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the flame retardant polyurethane foaming that a kind of air-tightness is good
Glue.
The present invention is achieved by the following technical solutions:
The flame retardant polyurethane foamed glue that a kind of air-tightness is good, is prepared by the raw materials in: diphenylmethane diisocyanate
Ester 150-160, trihydroxy polypropylene oxide ether 100-105, Oleum Ricini 100-110, glycerol 5-6, diethyl phosphate 40-43,
The sodium hydroxide solution of 1mol/L is appropriate, kieselguhr 13-15, distilled water 5-6, triethanolamine 2-3, dibutyl tin laurate 3-
4, stearic acid 2-3, polyvinyl alcohol 3-4, cetomacrogol 1000 2-3, short glass fiber 4-5, nanoclay 2-3, silane coupled
Agent KH560 0.8-1, dehydrated alcohol are appropriate.
The flame retardant polyurethane foamed glue that described a kind of air-tightness is good, is made up of step in detail below:
(1) pouring in reactor by trihydroxy polypropylene oxide ether, Oleum Ricini and glycerol, water bath with thermostatic control is heated to 85-90 DEG C,
Stir reaction 60-90 minute with the speed of 150-200 rev/min, be then cooled to 40-50 DEG C, be slowly added dropwise diethyl phosphate,
Add in 30 minutes, drip complete, be warming up to 70-75 DEG C, react 2-3 hour, the sodium hydroxide of the complete 1mol/L of question response
It is 7 that solution is neutralized to pH, at 55-60 DEG C of decompression dehydration；
(2) short glass fiber is pulverized, mix with nanoclay after crossing 300 mesh sieves and put into mixing and ball milling 30-40 in ball mill
Minute, it is subsequently adding and is dissolved in the silane coupler KH560 of 2-3 times amount dehydrated alcohol, cetomacrogol 1000, be heated to 50-60 DEG C,
Continue ball milling discharging after 40-60 minute, obtain mixed material；
(3) kieselguhr being dried pulverizing, cross 300 mesh sieves, it is mixed that the product then obtained with step (1), step (2) obtain
Compound material mixes, and is sequentially added into triethanolamine, dibutyl tin laurate, distilled water and removes methyl diphenylene diisocyanate
Outside remaining residual components, stir 2-3 minute with the speed of 800-1000 rev/min, obtain compound A；
(4) use scene that compound A is heated to constant temperature 30 DEG C at foamed glue, be subsequently adding methyl diphenylene diisocyanate,
Quickly mixing, after being stirred the 15-20 second with motor stirrer with the speed of 300-400 rev/min, is coated onto workpiece table by compound
Face, is heated to 25-30 DEG C so that it is foam voluntarily, then dry tack free, it is achieved foam-in-place molding, obtains foamed glue.
The invention have the advantage that the present invention passes through trihydroxy polypropylene oxide ether, Oleum Ricini compounds with glycerol, by stirring
Mix the NCO that mixing can be free with B component and crosslink reaction, generate stable three-dimensional-structure；In reaction system
Middle interpolation diethyl phosphate, can improve the oxygen index (OI) of system, coordinates diatomaceous interpolation, improves the anti-flammability of system further
Can, and along with diatomaceous interpolation, the abscess of foamed glue becomes more tight, reduces its heat conductivity so that it is have good
Good effect of heat insulation；The present invention also adds a certain amount of triethanolamine and dibutyl tin laurate in course of reaction so that it is
Form composite catalyst system, each reaction in system is carried out catalytic action thus reaches the foamed state of balance；Present invention profit
With distilled water as foaming agent, do not use organic solvent, safety and environmental protection, good appearance, foam uniform and smooth, viscosity can be formed
Moderate, flame retardant effect is excellent, is prone to the foamed glue that the tensile shear strength after coating, and solidification is higher during use.
Glass fibre, nanoclay, Polyethylene Glycol are added by the present invention by the compounding mixed material of making of certain technique
In foamed glue system, import long flexible ether linkage, thus improve the toughness of foams, by synergism, can be notable
Improve the compressive strength of foamed glue, heat stability and anti-flammability, reduce pulverization rate and shrinkage factor, and improve foam structure,
Improve the sealing property of foamed glue；The foamed glue that the present invention makes can foam at the scene, has backfilled enclosed effective, construction
Simply, the feature such as safe and reliable, low cost, great be widely applied prospect.
Detailed description of the invention
The flame retardant polyurethane foamed glue that a kind of air-tightness is good, is made up of the raw material of following weight portion (kilogram): diphenylmethyl
Alkane diisocyanate 150, trihydroxy polypropylene oxide ether 100, Oleum Ricini 100, glycerol 5, diethyl phosphate 40,1mol/L
Sodium hydroxide solution is appropriate, kieselguhr 13, distilled water 5, triethanolamine 2, dibutyl tin laurate 3, stearic acid 2, polyethylene
Alcohol 3, cetomacrogol 1000 2, short glass fiber 4, nanoclay 2, silane coupler KH560 0.8, dehydrated alcohol are appropriate.
The flame retardant polyurethane foamed glue that described a kind of air-tightness is good, is made up of step in detail below:
(1) pouring in reactor by trihydroxy polypropylene oxide ether, Oleum Ricini and glycerol, water bath with thermostatic control is heated to 85 DEG C, with
The speed stirring reaction of 150 revs/min 60 minutes, is then cooled to 40 DEG C, is slowly added dropwise diethyl phosphate, added in 30 minutes
Complete, drip complete, be warming up to 70 DEG C, react 2 hours, it is 7 that the sodium hydroxide solution of the complete 1mol/L of question response is neutralized to pH,
At 55 DEG C of decompression dehydrations；
(2) short glass fiber is pulverized, mix with nanoclay after crossing 300 mesh sieves and put into mixing and ball milling 30 points in ball mill
Clock, is subsequently adding and is dissolved in the silane coupler KH560 of 2 times amount dehydrated alcohol, cetomacrogol 1000, is heated to 50 DEG C, continues ball
Discharging after grinding 40 minutes, obtains mixed material；
(3) kieselguhr being dried pulverizing, cross 300 mesh sieves, it is mixed that the product then obtained with step (1), step (2) obtain
Compound material mixes, and is sequentially added into triethanolamine, dibutyl tin laurate, distilled water and removes methyl diphenylene diisocyanate
Outside remaining residual components, stir 2 minutes with the speed of 800 revs/min, obtain compound A；
(4) use scene that compound A is heated to constant temperature 30 DEG C at foamed glue, be subsequently adding methyl diphenylene diisocyanate,
Quickly mixing, after being stirred 15 seconds with motor stirrer with the speed of 300 revs/min, is coated onto surface of the work by compound, heating
To 25 DEG C so that it is foam voluntarily, then dry tack free, it is achieved foam-in-place molding, obtain foamed glue.
Compound A is passed through mix and blend with methyl diphenylene diisocyanate by suitable proportioning by the present invention, repastes
In the groove of switch cubicle or rack, through chemical reaction foaming, surface skining, it is achieved foam-in-place molding；By test, obtain
Surface drying time 18 clock, the time that is fully cured was less than 12 hours；Carrying out the compression test of special project, test rebound loss rate meets product
Requirement.
Claims (2)
1. the flame retardant polyurethane foamed glue that an air-tightness is good, it is characterised in that be prepared by the raw materials in: diphenyl
Methane diisocyanate 150-160, trihydroxy polypropylene oxide ether 100-105, Oleum Ricini 100-110, glycerol 5-6, phosphoric acid
The sodium hydroxide solution of diethylester 40-43,1mol/L is appropriate, kieselguhr 13-15, distilled water 5-6, triethanolamine 2-3, two Laurels
Acid dibutyl tin 3-4, stearic acid 2-3, polyvinyl alcohol 3-4, cetomacrogol 1000 2-3, short glass fiber 4-5, nanoclay
2-3, silane coupler KH560 0.8-1, dehydrated alcohol are appropriate.
The flame retardant polyurethane foamed glue that a kind of air-tightness is good, it is characterised in that by walking in detail below
Suddenly make:
(1) pouring in reactor by trihydroxy polypropylene oxide ether, Oleum Ricini and glycerol, water bath with thermostatic control is heated to 85-90 DEG C,
Stir reaction 60-90 minute with the speed of 150-200 rev/min, be then cooled to 40-50 DEG C, be slowly added dropwise diethyl phosphate,
Add in 30 minutes, drip complete, be warming up to 70-75 DEG C, react 2-3 hour, the sodium hydroxide of the complete 1mol/L of question response
It is 7 that solution is neutralized to pH, at 55-60 DEG C of decompression dehydration；
(2) short glass fiber is pulverized, mix with nanoclay after crossing 300 mesh sieves and put into mixing and ball milling 30-40 in ball mill
Minute, it is subsequently adding and is dissolved in the silane coupler KH560 of 2-3 times amount dehydrated alcohol, cetomacrogol 1000, be heated to 50-60 DEG C,
Continue ball milling discharging after 40-60 minute, obtain mixed material；
(3) kieselguhr being dried pulverizing, cross 300 mesh sieves, it is mixed that the product then obtained with step (1), step (2) obtain
Compound material mixes, and is sequentially added into triethanolamine, dibutyl tin laurate, distilled water and removes methyl diphenylene diisocyanate
Outside remaining residual components, stir 2-3 minute with the speed of 800-1000 rev/min, obtain compound A；
(4) use scene that compound A is heated to constant temperature 30 DEG C at foamed glue, be subsequently adding methyl diphenylene diisocyanate,
Quickly mixing, after being stirred the 15-20 second with motor stirrer with the speed of 300-400 rev/min, is coated onto workpiece table by compound
Face, is heated to 25-30 DEG C so that it is foam voluntarily, then dry tack free, it is achieved foam-in-place molding, obtains foamed glue.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614324.3A CN106221657A (en) | 2016-07-29 | 2016-07-29 | The flame retardant polyurethane foamed glue that a kind of air-tightness is good |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614324.3A CN106221657A (en) | 2016-07-29 | 2016-07-29 | The flame retardant polyurethane foamed glue that a kind of air-tightness is good |
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| CN106221657A true CN106221657A (en) | 2016-12-14 |
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| CN107298960A (en) * | 2017-06-08 | 2017-10-27 | 倪巧玲 | Polyurethane foam glue that a kind of azido of fire resistant doorsets is modified and preparation method thereof |
| CN108219735A (en) * | 2017-12-18 | 2018-06-29 | 常州市好利莱光电科技有限公司 | A kind of preparation method of flame retardant type nail-free glue |
| CN109337639A (en) * | 2018-10-09 | 2019-02-15 | 合肥凯大新型材料科技有限公司 | A kind of moisture-proof adhesive and preparation method thereof |
| CN112029469A (en) * | 2020-08-13 | 2020-12-04 | 安徽南大星新材料科技有限公司 | Preparation method of single-component polyurethane foam adhesive for wall building |
| CN112920759A (en) * | 2021-01-22 | 2021-06-08 | 恩平市盈嘉丰胶粘制品有限公司 | High-comprehensive-performance polyurethane foam rubber and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298960A (en) * | 2017-06-08 | 2017-10-27 | 倪巧玲 | Polyurethane foam glue that a kind of azido of fire resistant doorsets is modified and preparation method thereof |
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| CN109337639A (en) * | 2018-10-09 | 2019-02-15 | 合肥凯大新型材料科技有限公司 | A kind of moisture-proof adhesive and preparation method thereof |
| CN112029469A (en) * | 2020-08-13 | 2020-12-04 | 安徽南大星新材料科技有限公司 | Preparation method of single-component polyurethane foam adhesive for wall building |
| CN112920759A (en) * | 2021-01-22 | 2021-06-08 | 恩平市盈嘉丰胶粘制品有限公司 | High-comprehensive-performance polyurethane foam rubber and preparation method thereof |
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Application publication date: 20161214 |