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CN106221469A - A kind of water-water reflective insulation anti-fog haze multicolor finish - Google Patents

A kind of water-water reflective insulation anti-fog haze multicolor finish Download PDF

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Publication number
CN106221469A
CN106221469A CN201610728560.8A CN201610728560A CN106221469A CN 106221469 A CN106221469 A CN 106221469A CN 201610728560 A CN201610728560 A CN 201610728560A CN 106221469 A CN106221469 A CN 106221469A
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Prior art keywords
parts
water
powder
reflective insulation
agent
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CN201610728560.8A
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Chinese (zh)
Inventor
王植飞
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SHANGHAI LVTEDAN THERMAL INSULATION ENGINEERING Co Ltd
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SHANGHAI LVTEDAN THERMAL INSULATION ENGINEERING Co Ltd
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Priority to CN201610728560.8A priority Critical patent/CN106221469A/en
Publication of CN106221469A publication Critical patent/CN106221469A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of water-water reflective insulation anti-fog haze multicolor finish, be mixed in proportion with continuous phase after the colour reflective phase pelletize being made up of anion powder, protection glue and photocatalyst and form;Or mixed with the continuous phase containing photocatalyst after the colour reflective phase pelletize protecting glue to form by anion powder.The photocatalyst of the present invention not only can be scattered in colour reflective phase but also can mix with continuous phase, improves the reflection to solar thermal energy.Coating prepared by the present invention can not only reflect the near infrared ray of 40 80%.The flue dust in air, oil dirt, industrial waste gas, abatement haze degree can be decomposed simultaneously, also there are clean air, sterilization, deodorization, antidusting ash disposal, numerous miscellaneous functions such as self-cleaning.

Description

A kind of water-water reflective insulation anti-fog haze multicolor finish
Technology neck city:
The present invention relates to chemical field, particularly relate to energy-saving material field, particularly a kind of water-water reflective insulation is anti-fog Haze multicolor finish.
Background technology:
The multicolor finish of oil-in-water or oil oil-in just can obtain multiple chromatic pattern by once spraying, and can copy Going out the effect of the lithotome such as artificial granite, marble, but this coating is with benzene-type products as auxiliary agent, toxic is big, with ring Border is unfriendly.Therefore, prior art also been proposed water type multicolor paint for water drum, such as Application No. 93115122.8 and application Number it is the patent of invention of 94111425.2, discloses two kinds of low costs, production technology is simple, particle is soft and solid water-water The production technology of type coating of multi-colour pattern, this coating one rifle when construction just can form the color being abundant without compare, can be the most square Just copy out the decorative effect surpassing stone material, obtain numerous building designers and the favorable comment of house exploitation industry, use face more Come the biggest.But, this coating only produces protection and beautification function to the surface of ornament, lacks sunlight and near-infrared The reflectance of line heat, its temperature of body of wall using this coating is very nearly the same with the body of wall not using this coating, due to wall Temperature is high, and the idle call electricity that room temperature lowering is consumed is the biggest, and the waste energy is the most.
The water-water reflective insulation multicolor finish of Application No. 201410429910.1, disclosing one can dispute painting by a rifle Just form artificial granite decorative pattern, and the reflective insulation function to solar heat can be produced, for promoting water-water artificial granite paint Can make contributions, but going from bad to worse due to air quality, and haze weather is increasing, carries from meteorological department of China in 2013 Haze one word gone out, becomes hot issue, China's overwhelming majority city, all suffers from haze invasion and attack, the safety to people's property Cause serious threat;But water-water reflective insulation multicolor finish disclosed in 201410429910.1, lacks haze air Comprehensive control function, still has much room for improvement and improves.
Summary of the invention:
It is an object of the invention to provide a kind of water-water reflective insulation anti-fog haze multicolor finish, described this water-water Reflective insulation anti-fog haze multicolor finish the deficiencies in the prior art to be solved, not only have reflective insulation function, also have decomposition sky concurrently Flue dust in gas, oil dirt, industry and automobile exhaust gas, abatement haze degree, also have clean air, sterilization, deodorization, antidusting remove Numerous miscellaneous functions such as grey, self-cleaning.
The present invention is to be realized by following technical scheme:
A kind of water-water reflective insulation anti-fog haze multicolor finish, is made up of anion powder, protection glue and photocatalyst Being mixed in proportion with continuous phase after colour reflective phase pelletize and form, by weight, described protection glue is by the protection of 4~20 parts Rubber powder, the sodium pyrophosphate of 0~2 part and the deionized water of 80~95 parts, 0.1~5 portion of preservative, the antibacterial of 0.1~1 part and suitable Amount PH regulator composition, described containing anion powder, photocatalyst composition colour reflective by 1~10 part of anion powder, 0.1 ~5 parts of photocatalysts, the synthetic resin emulsion of 10~50 parts, the deionized water of 5~30 parts, hydroxy ethyl fibers of 0.1~1 part Element, 0.1~the PH regulator of 3, the preservative of 0.1~0.5 part, 0.1~2 part of antibacterial, the dispersant of 0.1~2 part, 0.1~2 Part stabilizer, the coalescents of 0.1~2 part, the antifreezing agent of 0.1~2 part, the reflective insulation powder of 2~30 parts, 0.1~10 part 4000 mesh calcined kaolins, the cold pigment of 1~10 part, the fine sand 1 of 0~20 part~the wetting agent of 5 parts, the protection of 1~30 part The defoamer mixing of glue and 0.1~5 part forms through pelletize, described continuous phase by 10~70 parts deionized water, 0.1~2 part Anticorrosion and bactericidal agent, the synthetic resin emulsion of 30~90 parts, appropriate PH regulator and appropriate thickening agent be dispersed through mixing and Become.
A kind of water-water reflective insulation anti-fog haze multicolor finish, the colour reflective phase being made up of anion powder and protection glue Mix with the continuous phase containing photocatalyst after pelletize, by weight, described protection glue by 4~20 parts protection rubber powders, 0 ~the sodium pyrophosphate of 2 parts and the deionized water of part of 80~95, appropriate antimildew disinfectant and pH adjusting agent composition, described containing negative Ion powder and the colour reflective phase containing protection glue, the synthetic resin emulsion of the anion powder of the part by 1~10,10~50,5~30 Part the hydroxyethyl cellulose of deionized water, 0.1~0.8, the pH adjusting agent of 0.1~1 part, the anticorrosion and bactericidal agent of 0.1~1 part, 0.1~2 dispersants, the stabilizer of 0.1~2 part, 0.5~3 part of coalescents, the antifreezing agent of 0.1~0.2 part, 2~30 parts anti- Penetrate heat-insulating powder, 1~10 part calcining kaolin, the cold pigment of 1~20 part, the fine sand of 0~20 part, the wetting agent of 0.1~3 part, 1 ~the protection glue of 30 and the defoamer of 0.1~4 part are dispersed through mixing, pelletize forms, the described continuous phase containing photocatalyst by The photocatalyst of 0.1~5 part, the deionized water of 10~50 parts, the anticorrosion and bactericidal agent of 0.1~2 part, the synthetic resin of 30~90 parts Emulsion, appropriate pH adjusting agent and appropriate thickening agent, blended form.
Described anion powder is by one or more groups in the tourmaline powder that can produce anion in atmosphere Become.
Described photocatalyst is by nano zine oxide, nano titanium oxide, nano silicon, nanometer titanium dioxide aluminum, nanometer Magnesium oxide and one or more in producing the powder body of catalytic action under light illumination thereof are formed.
Further, described reflective insulation powder is that rutile titanium dioxide powder body such as Britain Huntsman Corporation produces Altiys550 and Altiys800 type infrared reflecting paint and the inorganic particle that is coated with by nm-class rutile-type TiO 2 are as above One or more mixture in the TK501W type angstrom health powder that Hai Shizhan chemical industry is produced.
Further, one during described protection glue is commercially available KD powder, RT-1 powder, GTS powder and S-482 powder or one with On the mixing of any proportioning further, described synthetic resin emulsion is pure third 7016G that Shanghai BASF AG produces BLj-9385T, BLj-9388, BLj-that emulsion, the RS-9389 of Shanghai Ahmedabad richness company product, Shanghai Bao Lijia company produce 4369 and other silicon the third synthetic resin emulsion that KD96, Jiangsu sunrise company produce, pure third synthetic resin emulsion and other spread out One or more mixture in biology.
Further, described colour include white, redness, yellow, blue, green, orange, purple and black and on State the two or more mixing in the induced color of color.
Further, described antibacterial is the LXE that Rhom and Hass produces, and described preservative is that Shanghai grid is public The FI-31 of department, described defoamer is the G298 of Shanghai grid company, and described dispersant is the 120V of Shanghai grid company, Described wetting agent is G-396, G-399, G-535 of Shanghai grid company, and described PH regulator is Shanghai grid company AMP-95, described stabilizer is the S-PLUS of Shanghai Ke Naiou company, described thickening agent be Shanghai grid company G-535, Or 530 or the HISOL-700 of Shanghai Cai Yang company, described coalescents is the Lauryl Alcohol fat that Yi Si Man produces, Described antifreezing agent is the mixture of propylene glycol or ethylene glycol or propylene glycol and ethylene glycol, and the cold pigment of described white is Rutile type titanium dioxide R-706, R-902 of du pont company's product or domestic R-258 titanium dioxide.
Further, the cold pigment of described colour is, Shanghai generation exhibition chemical industry, upper sea God promise Company advanced in years by Britain's Hensel The cold pigment of colour in one or more mixture.
Further, described fine sand be particle diameter be the quartz sand of 120~250 mesh, 70 sand, colored stone sand, fluvial sand, sea sand, One or more mixture in river sand, hollow glass microbead, hollow haydite.
Further, 4000 described mesh calcined kaolins and sodium pyrophosphate, triple superphosphate, fine particle calcium carbonate, wollastonite in powder and fine sand, It is domestic known commercially available prod.
The protection rubber powder used in the present invention is a kind of silicate inorganic Binder Materials, expands and form water white transparency in water Liquid, the precipitation of heavy pigment and filler can be prevented.
The invention have the benefit that
The present invention compares with prior art, and its effect is positive and obvious.The present invention is by anion powder, photocatalyst Near infrared ray is had the material such as powder body and rubber powder, sodium pyrophosphate, filler, emulsion, auxiliary agent, cold pigment of strength reflective insulation ability Material, is remixed technique produced the decorative paint of multi colour effect by mixing, pelletize.The film of the 150 above thickness of μm is to the sun In near infrared reflectivity can reach 40-80%, make to be reduced temperature 12-27 DEG C by jewelry, air can also be produced simultaneously and bear Ion, kills noxious bacteria, eliminates the flue dust in air, oil dirt and industrial tail gas thus reduces or delay the heat of decorated thing Degraded and cracking catabiosis, clean air, cut down haze degree, increase the service life, more can take the saving of cool place for cooling Air conditioner energy source is contributed.
Specific implementation:
The present invention has following three kinds of implementations.
Implementation 1
As a example by making black, yellow, three kinds of colored water-water reflective insulation anti-fog haze multicolor finishes of white:
1st step: weigh commercially available KD rubber powder 5-10 part, sodium pyrophosphate 0.2-2 part, deionized water 70-90 part, antibacterial 0.05-0.2 part, preservative 0.05-0.2 part, in mixed cylinder after dispersion, adjust the liquid of PH=7-10, as the guarantor of the present invention Protect glue standby.
2nd step: make continuous phase: weigh deionized water 20-50 part, synthetic resin emulsion 50-70 part, Lauryl Alcohol fat 1- 4 parts, propylene glycol 1-3 part, antibacterial 0.1-0.5 part, preservative 0.1-0.5 part, stabilizer 0.2-1 part, photocatalyst 0-5 part mix After conjunction, by its PH furnishing 7-10, after adjusting viscosity KU=40-80 with thickening agent, the continuous phase as the present invention packages spare.
3rd step: make black reflection female slurry mutually: weigh deionized water 15-45 part, the hydroxy ethyl fiber of 2.5-10 ten thousand viscosity Element 0.1-0.6 part, Lauryl Alcohol fat 0.5-1.5 part, propylene glycol 0.1-0.5 part, the protection glue 0.4-20 that above-mentioned 1st step prepares Part, wetting agent 0.1-0.6 part, defoamer 0.05-0.5 part, stabilizer 0.1-1 part, anion powder 1-10 part photocatalyst 0.5-5 Part, reflective insulation powder 5-15 part, 4000 mesh calcined kaolin 1-8 parts, cold pigment black pigment powder 0.1-10 part, high speed dispersion is extremely Fineness reaches Hegman grind gage 50-70 μm, adds synthetic resin emulsion 20-50 part, after mix homogeneously, by the pH furnishing 7-of slurry 10, then with thickening agent be thickened to KU=70-140 be black reflection phase granule mother slurry, package spare.
4th step: black masterbatch slurry pelletize: weigh protection glue 4-50 part, deionized water 10-30 part, weigh after mix homogeneously The black masterbatch slurry 40-60 part stating step the 3 step prepared is added thereto, and with blade agitator, black masterbatch slurry is divided into 20-50MM3 Bean curd shape thing, then caused the granule of required size with screen filtration comminution granulation, be colour reflective mutually in black Particulate material.
5th step: make yellow by the method for present implementation the 3rd, the 4th step and white mother starches particulate material.
6th step: synthesis: weigh continuous phase 30-100 part that present implementation the 2nd step prepares, puts in mixed cylinder, then Take black masterbatch slurry particulate material 10-40 part that above-mentioned 4th, 5 steps prepare, yellow mother starches particulate material 10-50 part, white female slurry particulate material 10-30 part, also puts in the cylinder body of continuous phase, mixed on low speed, adjusts PH=7-10, and adjusting viscosity with thickening agent is KU=70- After 140, it is water-water reflective insulation anti-fog haze multicolor finish.
Implementation method 2:
As a example by making red, yellow, the most trichroism water-water reflective insulation anti-fog haze multicolor finish:
1st step, makes protection glue: weigh commercially available RT-1 rubber powder 5-10 part, sodium pyrophosphate 0.5-1 part, deionized water 70-90 Part, antibacterial, Preservative qs, after dispersion is melted in mixed cylinder, adjust PH=7-10, and the protection glue as the present invention is standby With.
2nd step, makes continuous phase: weigh deionized water 10-50 part, synthetic resin emulsion 50-70 part, coalescents 1- 3.5 parts, propylene glycol 1-3 part, antibacterial 0.5-1 part, preservative 0.05-1 part, at a slow speed after mixing, by its PH furnishing 7-10, use After thickening agent adjusts viscosity KU=40-100, the continuous phase as the present invention packages spare.
3rd step, makes red color reflection female slurry mutually: weigh deionized water 15-35 part, the hydroxy ethyl fiber of 50,000 viscosity Element 0.1-0.6 part, preservative 0.1-0.3 part, antibacterial 0.1-0.3 part, dispersant 0.1-2 part, Lauryl Alcohol fat 0.5-1.5 Part, propylene glycol 0.1-0.5 part, present implementation the 1st step prepare protection glue 1-10 part, wetting agent 0.1-0.6 part, defoamer 0.05-0.5 part, stabilizer 0.1-1 part, anion powder 1-10 part, photocatalyst 0.5-5 part, reflective insulation powder 3-15 part, 4000 Mesh calcined kaolin 1-15 part, white cold pigment (Rutile type titanium dioxide) 1-20 part, colored cold pigment iron oxide red 1-5 part, depend on In secondary input mixed cylinder, high speed dispersion to fineness reaches Hegman grind gage 50-70 μm, adds synthetic resin emulsion 20-50 part, mixed After closing uniformly, by PH furnishing PH=7-10, then it is anti-to be thickened to, with thickening agent, the red color that KU=70-140 is in reflection mutually Penetrate phase granule mother slurry, package spare.
4th step, makes yellow mother slurry: weigh the hydroxyethyl cellulose 0.2-0.8 of deionized water 15-28 part, 50,000 viscosity Part, coalescents 0.5-1.5 part, propylene glycol 0.1-1 part, put in mixed cylinder successively and disperse, then weigh present implementation the 2nd step Prepare protection glue 5-11 part, antibacterial 0.1-0.3 part, preservative 0.1-0.3 part, dispersant 0.1-0.5 part, wetting agent 0.1- 0.6 part, defoamer 0.05-0.5 part, stabilizer 0.1-1 part, anion powder 1-10 part, photocatalyst 0.5-5, reflective insulation powder 8-11 part, 4000 mesh calcined kaolin 1-15 parts, white cold pigment (Rutile type titanium dioxide) 6-15 part, colored cold pigment iron oxide yellow 3 parts of powder, high speed dispersion, to reaching Hegman grind gage 50-70 μm, adds synthetic resin elastic emulsion 20-50 part, particle diameter 250 mesh thin Sand 5-15 part of degree, pure acrylic acid synthetic resin emulsion 10-20 part, mix homogeneously, adjust PH=7-10, and adjustment viscosity is KU= 70-140, the yellow mother slurry being in reflection mutually, package spare.
5th step, makes white color reflection and starches mutually: weigh deionized water 15-28 part, the hydroxyethyl cellulose of 100,000 viscosity 0.3-0.8 part, antibacterial 0.1-1 part, preservative 0.1-0.3 part, dispersant 0.1-0.5 part, coalescents 0.1-2 part, the third two Alcohol 0.1-0.8 part, weighs protection glue 5-12 part that present implementation the 1st step prepares, and puts into after being uniformly dispersed in mixed cylinder successively, Weigh wetting agent 0.2-0.9 part, defoamer 0.05-0.5 part, stabilizer 0.1-1 part, anion powder 1-10 part, photocatalyst again 0.5-5 part, reflective insulation powder 5-10 part, 4000 mesh calcined kaolin 2-15 parts, domestic R-258 titanium dioxide 10-15 part, add successively Entering after being dispersed in same mixed cylinder reach Hegman grind gage 50-70 μm, addition synthetic resin emulsion 35 parts, particle diameter 200 mesh are thin Sand 1-10 part adjusts PH=7-10 after mixing well, and adjusts mother's slurry viscosity to Si Motuo viscosity KU=70-140 with thickening agent, is The female slurry of white in reflection mutually, packages spare.
6th step, pelletize: weigh present implementation the 1st step prepare protection glue 10-240 part, deionized water 70-200 part, Continuous phase 200-600 part, mixes in mixed cylinder, then weighs red female slurry 50-that present implementation the 3rd step prepares 100 parts, the yellow mother weighing present implementation the 4th step prepared starches 30-180 part, weighs the white that present implementation the 5th step prepares Female slurry 25-180 part, puts in the mixed cylinder equipped with protection glue, with blade agitator by each color masterbatch in cylinder the most respectively Slurry is cut into 10-30MM3Soft wet fritter, with screen mesh type comminutor disposably produce redness, yellow, white granule, be The granular materials of reflection phase.
7th step, synthesis: weigh continuous phase 30-100 part that present implementation the 2nd step prepares, put in mixed cylinder, then Take reflective insulation phase particulate material 40-130 part that present implementation the 6th step prepares, carry out the mixed on low speed of less than 20 turns, it is ensured that Granule is broken, do not stick with paste, and then adjusts PH=7-10, adjusts viscosity KU=70-140 with thickening agent, i.e. possesses redness, yellow, white The water-water reflective insulation anti-fog haze multicolor finish of three kinds of colors of color, checks and packs warehouse-in.
Implementation method 3:
As a example by making the three color patterned colorful reflective insulation of water-water anti-fog haze coating red, yellow, white:
1st step, makes colour reflective phase base slurry: weigh GTS and protect rubber powder 8 parts, deionized water 180-150, antibacterial 0.1-0.6 part, preservative 0-0.5 part, Lauryl Alcohol fat 1-3 part, propylene glycol 0.1-4 part, defoamer 0.1-0.5 part, wetting agent 0.1-2 part, dispersant 0.2-1 part, 150-250 mesh sand 1-30 part, stabilizer 1-10 part, anion powder 2 parts, reflective insulation powder 5-20 part, calcined kaolin 1-10 part, put into synthetic resin emulsion 20-80 part again after the sand of 200-250 mesh fineness 10 parts, mixed Close uniformly, adjust PH=7-10, white cold pigment (Rutile type titanium dioxide) 1-20 part, adjust viscosity KU=70-with thickening agent The white female slurry packed for standby use being after 140 in reflection mutually.
2nd step, makes protection glue and continuous phase mixed liquor: weigh protection rubber powder 1-3 part, sodium pyrophosphate 0-0.3 part, go from Sub-water 30-60 part, synthetic resin elastic emulsion 30-100 part, preservative 0.1-0.4 part, photocatalyst 0.1-2 part, antibacterial 0.05-0.2 part, Lauryl Alcohol fat 1-6 part, ethylene glycol 0-4 part, defoamer 0.05-0.15 part, mixed on low speed adjusts PH the most afterwards Package spare after=7-10.
3rd step, make colour reflective mutually in red female slurry: take the colour reflective phase base that present implementation the 1st step prepares Material 70-130 part, adding cold pigment black mill base 2-8 part, mix homogeneously adjusts the PH=7-10 of body series, and viscosity is Si Motuo KU Package spare after=100-140.Be colour reflective of the present invention mutually in female slurry of black particle.
4th step, make colour reflective mutually in yellow mother slurry: take present implementation the 1st step prepare colour reflective phase base Expect 50 parts, add cold pigment yellow mill base 1-3 part, mix homogeneously, adjust PH=7-10, with thickening agent, denseness is adjusted to KU= 70-140 packages spare.Be present implementation colour reflective mutually in yellow mother slurry.
5th step, makes the female slurry of the white in reflection mutually: weigh the colored phase base material 40 parts that present implementation the 1st step prepares, Add white cold pigment (Rutile type titanium dioxide slurry) 5-10 part, stirring at low speed uniformly after with AMP-95 the PH that mother starches adjusted to 7-10, adjusts denseness with thickening agent and packages spare to Si Motuo KU=70-140.
6th step, pelletize also synthesizes: weigh the mixed liquor 50 of dispersion phase and the continuous phase prepared by present implementation the 2nd step Part, deionized water 10-20 part, first put in pelletize cylinder, weigh black masterbatch slurry 1-40 part the most again, yellow cold pigment mother starches 1-20 Part, in white female slurry 1-100 part, respectively input pelletize cylinder, with blade agitator, female for colour slurry is cut into design required (size), then with suitable screen filtration once, and PH=7-10, Si Motuo viscosity KU=of synthetic is adjusted with AMP-95 After 70-140, i.e. having trichroism alternate water-water reflective insulation anti-fog haze multicolor finish black, yellow, white, test package is put in storage.
Now the technology of the present invention is expanded on further with above-mentioned three kinds of implementations;All features disclosed in this specification, or Disclosed all methods or during step, in addition to mutually exclusive feature and/or step, all can be by any way Combination, not to retrain the present invention.
Any feature disclosed in this specification (including any accessory claim), unless specifically stated otherwise, all can be by it His equivalence or there is the alternative features of similar purpose replaced.I.e., unless specifically stated otherwise, each feature is a series of equivalences Or an example in similar characteristics.
Embodiment 1
As a example by the water-water reflective insulation anti-fog haze multicolor finish making two color point yellow, white:
1st step, the making of protection glue: by commercially available GTS protection rubber powder 8 parts, deionized water 92 parts, preservative 0.1 part, sterilization Agent 0.2 part, after the adjustment PH=7-10 that is uniformly dispersed, as the protection glue of the present embodiment, standby after packaging.
2nd step, the making of continuous phase: with deionized water 30 parts, coalescents 6 parts, propylene glycol 3 parts, antibacterial 0.1 part, Adding siliceous acrylate elastic emulsion 80 parts after preservative 0.2 part dispersion mixing, pure acrylic acid synthetic resin emulsion 40 parts disperses at a slow speed, With PH regulator, slurry is adjusted to PH=7-10, then with thickening agent, viscosity is adjusted to KU=40-120 as continuous phase bag Equipment is used.
3rd step, makes yellow reflection female slurry mutually: with deionized water 18 parts, the hydroxyethyl cellulose 0.2 part point of 30,000 viscosity It is sequentially added into preservative 0.2 part, antibacterial 0.1 part, dispersant 0.5 part, stabilizer 0.3 part, coalescents 1.7 after dissipating uniformly Part, propylene glycol 0.5 part, the present embodiment first step prepare protection 6 parts of glue, wetting agent 0.5 part, defoamer 0.1 part, anion powder 3 Part, photocatalyst 0.2 part, 9 parts of Altiys550 reflective insulation powder, 4000 mesh calcined kaolin 3 parts, cold pigment yellow toner 1 part, The cold pigment of white is Du Pont's R902 titanium dioxide 5 parts, and high speed dispersion to Hegman fineness grind adds flexible silicon acrylic emulsion 25 after reaching 70 μm Part, pure acrylic acid synthetic emulsion 10 parts mix homogeneously again, during with PH regulator by the PH=7-10 of slurry, regulate with thickening agent The viscosity of slurry to KU=100-140, be colour reflective mutually in yellow mother slurry, package spare.
4th step, make colour reflective mutually in the female slurry of white: weigh deionized water 43 parts, the hydroxy ethyl fiber of 50,000 viscosity Element 0.7 part, is sequentially added into preservative 0.2 part, antibacterial 0.1 part, dispersant 0.5 part, wetting agent 0.2 part, steady after being uniformly dispersed Determine agent 0.5 part, defoamer 0.1 part, anion powder 4 parts, photocatalyst 1.5 parts, white cold pigment are Du Pont's R-706 titanium dioxide 10 Part, 5 parts of Altiys550 reflective insulation powder, 5 parts of Altiys800 reflective insulation powder, 4000 mesh Kaolin 0.5 part, coalescents 2 Part, propylene glycol 0.5,12 parts of the protection glue prepared by the present embodiment the 1st step, after high speed dispersion fineness reaches Hegman fineness grind 60 μm Add silicon acrylate elastic emulsion 40 parts, with PH regulator, the PH of slurry is adjusted to 7-10 after stirring, then with thickening agent by slurry Viscosity adjusts to Si Motuo KU=100-140, be the present embodiment colour reflective mutually in the female slurry of white.
5th step, colour reflective mutually in the making of yellow particle: weigh 200 parts of protection glue that the present embodiment the 1st step prepares, Join in the cylinder of 300 parts of yellow mother slurries after deionized water 85 parts mixing, with blade agitator, mother's slurry is divided into 10-30MM3 Bulk, and the making of the 6th step colour reflective middle white particle material mutually of required size it is made into screen filtration comminutor: Weigh deionized water 40 parts, with the mixed liquor 140 parts of 100 parts of the glue of protection that the present embodiment first step prepares, add after mixing Cross among the female slurry of 150 parts of whites claimed, after static 5-15 minute, slurry blade is divided into 10-30MM3After size, use screen mesh type 7th step colored synthesis: the continuous phase 300 parts weighing the present embodiment the 2nd step prepared joins in mixed cylinder, then by the present embodiment The white particle 150 parts of the reflection phase that the yellow that the 5th step prepares reflects phase particulate material 300 parts, the present embodiment the 5th step prepares is (yellow Color can regulate on demand with the ratio of white) add in same cylinder, 20 turns of speed below mixing, adjust PH=7-10 and viscosity For packing after KU=70-140, it is the heat insulation anti-fog haze multicolor finish of water-water colour reflective of the present invention.
Embodiment 2:
As a example by making the colorful reflective insulation of water-water red, yellow, black, Bai Sise anti-fog haze coating:
1st step, the making of dispersion phase: weigh commercially available KD rubber powder 6 parts, sodium pyrophosphate 0.6 part, deionized water 93 parts, prevent Rotten agent 0.2 part, antibacterial 0.1 part.
2nd step, makes continuous phase 100 parts according to the method for the second step in embodiment 1.
3rd step, the colored red female slurry made in reflection mutually: weigh deionized water 30 parts, the hydroxy ethyl fiber of 50,000 viscosity Element 0.4 part, add after being uniformly dispersed preservative 0.2 part, antibacterial 0.1 part, dispersant 0.4 part, coalescents 0.8 part, third Glycol 1 part, wetting agent 0.3 part, defoamer 0.2 part, stabilizer 0.5 part, anion powder 2 parts, photocatalyst 2 parts, Du Pont R-706 5 parts of the protection glue that titanium dioxide 5 parts, 4000 mesh calcined kaolin 1 part, use the present embodiment first step prepare, cold paratonere toner 1 Part, 10 parts of Altiys800 reflective insulation powder, reach 60 μm by Hegman fineness grind measurement fineness after high speed dispersion, add synthesis tree After fat elastic emulsion 15 parts, 7016G pure acrylic latex 15 parts are mixed well, and regulated pH adjustment 7-10, will slurry with thickening agent Material is when being thickened to stormer viscosity pusher side KU=70-140, as the present invention colour reflective mutually in red female slurry pack Close stand-by.Produced yellow color reflection phase masterbatch by the above-mentioned cold pigment of method yellow, produced with the cold pigment of black The female mutually female slurry of white starching, producing with white cold pigment (R-706 titanium dioxide) white colour reflective phase of black reflection also divides Do not package spare.
4th step, pelletize: weigh 30 parts of the protection glue that the present embodiment the 1st step prepares, put into mixed after deionized water 10 parts mixing Closing in cylinder, then put into wherein by 47 parts of red female slurry of the colour reflective phase prepared in the present embodiment the 3rd step, static 10-15 divides Bulk slurry blender is cut into 20-50MM by Zhong Houyong blade agitator3Block, then use multicolor finish screen mesh type Comminutor produce the granule of required size be colour reflective mutually in red granules material.
5th step, synthesis: according to coating coloured silk point distribution number (ratio), calculate color grains demand and by than Example (such as red reflex 20 parts mutually, yellow, black, white, each 10 parts of colored material etc., can arrange in pairs or groups on demand) is by colour reflective The ratio of phase particulate material totally 50 parts of continuous phases 42 parts prepared with the present embodiment the 2nd step mixes, and is and has red, yellow, black, Bai Si The water-water reflective insulation anti-fog haze multicolor finish of color point.Adjust PH=7-10 with AMP-95, adjust viscosity KU with thickening agent =70-140 gets final product packed for standby use.
Embodiment 3:
As a example by the water-water reflective insulation anti-fog haze multicolor finish making blue color point, ash color point, purplish red color point:
1st step, the making of protection glue: weigh KD rubber powder 7 parts, sodium pyrophosphate 0.7 part, deionized water 92 parts, preservative 0.2 Part, antibacterial 0.1 part, as the protection glue of the present invention after the use that is uniformly dispersed PH regulator regulation PH=7-10, standby after packaging.
2nd step, the making of continuous phase: weigh deionized water 50 parts, preservative 0.2 part, antibacterial 0.1 part, coalescents 7 Part, propylene glycol 3 parts, synthetic resin emulsion 140 parts, after photocatalyst 0.5 part, dispersion mixing are uniform, adjust PH=7-10 and KU Package spare during=40-140.
3rd step, makes colour reflective blue masterbatch slurry mutually: weigh the ethoxy fibre of deionized water 41 parts, 100,000 viscosity Dimension element 0.6 part, be uniformly dispersed after be sequentially added into preservative 0.2 part, antibacterial 0.25 part, dispersant 0.21 part, wetting agent 0.5 Part, defoamer 0.3 part, stabilizer 0.1-1 part, anion powder 2.5 parts, 4000 mesh calcined kaolin 3 parts, Altiys800 reflection Heat-insulating powder 12 parts, cold pigment R-706 titanium dioxide 4 parts, 0.8 part of cold pigment titanium ultramarine powder, 180 mesh sand 10 parts, bentonite 1 part, Coalescents 1 part, propylene glycol 1 part, 15 parts of protection glue preparing by embodiment the 1st step, through high speed dispersion uniformly after add and close Resin elastic emulsion 20 parts, 7016G pure acrylic latex 10 parts, then carry out after low speed is mixed well, using PH regulator by the PH of slurry Regulation adjusts viscosity again to Stormer KU=70-140 to 7-10, and the blue mother as colour reflective phase starches, and packages spare.
4th step, make colour reflective mutually in grey color masterbatch slurry: weigh deionized water 39 parts, 100,000 viscosity ethoxy fine Dimension element 0.5 part, be sequentially added into after being uniformly dispersed dispersant 0.1 part, antibacterial 0.2 part, preservative 0.1 part, wetting agent 0.4 part, Defoamer 0.2 part, stabilizer 0.6 part, by the present embodiment the 1st step prepare 10 parts of protection glue, coalescents 1 part, propylene glycol 0.5 Part, anion powder 3 parts, photocatalyst 3 parts, 4 parts of Altiys550 reflective insulation powder, 5 parts of Altiys800 reflective insulation powder, 4000 Mesh calcined kaolin 8 parts, white cold pigment (R-902 titanium dioxide) 2 parts, 1 part of cold pigment black powder, be dispersed to Hegman fineness grind and reach 60 Add after μm silicone acrylic emulsion 34 parts, stirring at low speed uniformly after adjust PH to 7-10, then viscosity mother starched with thickening agent with AMP-95 Adjust and package spare to KU=70-140.
5th step, make colour reflective mutually in purplish red color masterbatch slurry: with deionized water 43 parts, the hydroxy ethyl fiber of 50,000 viscosity It is sequentially added into dispersant 0.3 part, antibacterial 0.15 part, preservative 0.1 part, wetting agent 0.1 part, defoamer after element 0.7 part dispersion 0.15 part, stabilizer 1 part, coalescents 1.2 parts, propylene glycol 0.5 part, by the present embodiment the 1st step prepare 10 parts of protection glue, third Glycol 0.6 part, anion powder 2 parts, photocatalyst 3 parts, 4 parts of cold Pigment white (R-902) powder, Hensel step Altiys550 reflection every 3 parts of 5 parts of Altiys800 reflective insulation powder of hot powder, 4000 mesh calcined kaolin 2 parts, 1 part of cold pigment Hydrargyri Oxydum Rubrum, cold pigment titanium ultramarine Powder is appropriate, after high speed dispersion to Hegman fineness grind reaches 50 μm, in the case of stirring at low speed, adds synthetic resin elastic emulsion 20 Part, 7016G pure acrylic latex 15 parts, adjust PH=7-10 with AMP-95 after stirring evenly, then be KU=by thickening agent regulation viscosity 70-140, makes aubergine colour reflective female slurry mutually, packages spare.
6th step, pelletize: weigh in 90 parts prepared of protection glue of the present embodiment the 1st step, 40 parts of input cylinders of deionized water mixed Close, weigh the present embodiment the 3rd step prepare colour reflective phase blue mother starch 70 parts, Lycoperdon polymorphum Vitt colour mother starch 40 parts, purplish red color masterbatch slurry 20 parts (ratio of each color masterbatch slurry can adjust on demand), puts in same mixed cylinder the most successively, uses cutter after static 10-20 minute Female for colour slurry is divided into 20-50MM by blade agitator3Irregular fritter after, select the screen cloth of mesh being suitable for, use screen mesh type After comminutor is fabricated to required particulate material, packed for standby use.
7th step, synthesis: 70 parts of the reflection phase color grains material prepared by the present embodiment the 6th step and the present embodiment the 2nd step system Continuous phase 55 parts mixing, be have blue, Lycoperdon polymorphum Vitt, purplish red color point the water-water anti-fog haze of colorful reflective insulation colorful Coating, adjusts PH=8-10 with AMP-95, when adjusting viscosity KU=70-140 with thickening agent, and packed for standby use.
Embodiment 4:
As a example by the colorful reflective insulation of the water-water anti-fog haze coating making red, yellow, and green, white four color point:
1st step, weighs commercially available RT-1 rubber powder 7 parts, sodium pyrophosphate 0.6 part, deionized water 95 parts, antibacterial 0.15 part, prevents Rotten agent 0.1 part, mix homogeneously, after reaching 7-10 with the pH value of AMP-95 regulation slurry, the protection glue as the present invention is packed standby With.
2nd step, the making of continuous phase: weigh deionized water 100 parts, ethylene glycol 3 parts, 12 parts of Lauryl Alcohol fat, propylene glycol 4 Part, preservative 0.1 part, antibacterial 0.2 part, defoamer 0.2 part, 250 parts of mix homogeneously of BLj-KD96 emulsion, adjust PH=7- 10, viscosity is that KU=40-100 can package spare.
3rd step, the colored female slurry making reflection phase red color point: weigh deionized water 50 parts, the ethoxy of 100,000 viscosity Cellulose 0.6 part, adds antibacterial 0.1 part, preservative 0.2 part, dispersant 0.4 part, Lauryl Alcohol fat 1.5 after being uniformly dispersed It is steady that part, propylene glycol 2 parts, the present embodiment the 1st step prepare 10 parts of glue of protection, wetting agent 0.5 part, defoamer 0.2 part, S-PLUS moistening Determine agent 0.3 part, anion powder 2.5 parts, photocatalyst 1 part, 4000 mesh Kaolin 2 parts, 10 parts of Altiys800 reflective insulation powder, Cold pigment iron oxide red 1 part, adds 7016G emulsion 28 when reaching more than 60 μm by Hegman fineness grind measurement fineness after high speed dispersion Part, and it is adjusted to PH=7-10, can be used as this when adjusting Si Motuo viscosity KU=70-140 of slurry with thickening agent Red female slurry packed for standby use of bright colour reflective phase.
4th step, continues to produce yellow, green by the method described in the present embodiment the 3rd step, the colour of two kinds of colors Reflection female slurry packed for standby use respectively mutually.
5th step, makes the reflection female slurry of white mutually: weigh deionized water 50 parts, 100,000 hydroxyethyl cellulose 0.7 part, sterilization The protection that agent 0.1 part, preservative 0.2 part, dispersant 0.4 part, 1.5 parts of Lauryl Alcohol fat, propylene glycol 3 parts, the present embodiment prepare 13 parts of glue, wetting agent 0.5 part, defoamer 0.3 part, stabilizer 0.4 part, anion powder 2 parts, photocatalyst 1 part, Altiys550 10 parts of reflective insulation powder, white cold pigment R-706 titanium dioxide 15 parts, 4000 mesh calcined kaolin 5 parts, through high-speed stirred, make slurry The fineness of material system weighs synthetic resin elastic emulsion 15 parts, BLj-KD96 pure-acrylic emulsion 15 again after reaching scraper plate thermometer 60 μm Part, mix homogeneously, adjust the PH=7-10 of slurry system, viscosity KU=70-140, be the white in the present embodiment reflection mutually Color some mother's slurry, packages spare.
6th step, weighs 30 parts of protection glue, deionized water 8 parts that the present embodiment the 1st step prepares, adds in pelletize cylinder, then Weigh colour reflective 10 parts of red female slurry mutually that the present embodiment 3-5 step prepares, yellow mother starch 5 parts, 5 parts of green female slurry, white 13 parts of female slurry, joins the most at a slow speed in the mixed cylinder filling 30 parts of protection glue, after static 5-15 minute, produces required with screen cloth The color grains material of size, packed for standby use.
7th step, synthesis: weigh continuous phase 60 parts, deionized water 18 parts that the present embodiment the 2nd step prepares, put into mixed cylinder After middle mixing, then weigh four kinds of colored particulate material 80 parts in the reflection mutually that the present embodiment the 6th step prepares, mix homogeneously, adjust Whole PH=7-10, be during viscosity KU=70-140 have red, yellow, and green, white 4 color point the anti-fog haze of water-water reflective insulation many Color coating material, examination spray, and after inspection, packaging warehouse-in is standby.
Embodiment 5:
Make light gray with the first and second double-component methods, the colorful reflective insulation of water-water of three kinds of color decorative patterns pale yellow, white resists As a example by haze multicolor finish:
1st step, weigh S-482 protect 7 parts of glue, resistance to 0.7 part of pyrophosphoric acid, deionized water 93 parts, anticorrosion and bactericidal agent 0.2 part, PH adjusting agent is appropriate, makees protection glue standby after being uniformly dispersed.
2nd step, makes reflection female slurry white basic material (first component) mutually: weigh S-482 rubber powder 2 parts, sodium pyrophosphate 0.2 part, Deionized water 93 parts, the hydroxyethyl cellulose 1.2 parts of 100,000 viscosity, antibacterial 0.3 part, preservative 0.4 part, dispersant 0.8 part, Wetting agent 0.8 part, defoamer 0.4 part, stabilizer 1 part, 2 parts of Lauryl Alcohol fat, propylene glycol 3 parts, anion powder 4 parts, 4000 mesh Calcined kaolin 6 parts, 8 parts of reflective insulation Altiys800 powder, 5 parts of 200-250 whitish eye sand, 250 mesh hollow glass microbead 5 parts warps Mix homogeneously, weighs BLj-9386 emulsion 40 parts, continues mix homogeneously, adjusts PH=7-10, viscosity KU=70-140, can wrap Pretend the base material for reflection phase first component stand-by.
3rd step, makes the mixed liquor (component B) of protection glue and continuous phase: weigh deionized water 60 parts, S-482 rubber powder 4 Part, sodium pyrophosphate 0.4 part, antibacterial 0.3 part, preservative 0.3 part, defoamer 0.3 part, stabilizer 2 parts, photocatalyst 0.5 part It is uniformly dispersed and adds synthetic resin emulsion 40 parts, 0.5 part of Lauryl Alcohol fat, propylene glycol 0.5 part, continue mix homogeneously, adjust PH=7-10, gets final product packed for standby use.
4th step, the preparation of reflection phase light gray color masterbatch slurry: weigh the reflection phase base material 50 parts that the present embodiment the 2nd step prepares, throw Enter in mixed cylinder, weigh cold pigment black mill base 0.5 part, cold pigment rutile titanium white slurry 5 parts, weigh the implementation case first step Prepare protection glue to mix well in right amount, be the grey color masterbatch in the reflection mutually of water-water reflective insulation of the present invention anti-fog haze multicolor finish Slurry, packed for standby use.
5th step, make reflection mutually in yellow mother slurry: weigh the present embodiment the 1st step prepare reflection phase base material 100 parts, Cold pigment yellow mill base 1 part, 180 mesh fine sand 15 parts, white cold pigment (R-902 titanium dioxide slurry) 6 parts, dispersion mixing is uniform, is The present embodiment colour reflective mutually in yellow mother slurry.6th step, make colour reflective mutually in the female slurry of white: weigh the present embodiment The colour reflective that 1st step prepares 100 parts of female slurry, 180 mesh hollow haydites 10 parts, R-706 titanium dioxide slurry 8 parts mutually, dispersion mixing is equal The female slurry of white that is even, that be in the present embodiment reflection mutually, packed for standby use.
7th step, synthesis: the mixed liquor 100 parts of the dispersion phase and the continuous phase that prepare by the present embodiment the 3rd step, weigh this reality Execute example the 3rd step prepare colour reflective mutually in light gray color masterbatch starch 20 parts, weigh the present embodiment the 5th step prepare reflection mutually in Pale yellow color masterbatch is starched 50 parts, is weighed 50 parts of the female slurry of white that the present embodiment the 5th step prepares, and slowly puts into successively and fills dispersion phase and company In the mixing fluid cylinder of continuous phase, after static 10-20 minute, with blade type pelletize blender pelletize, pelletize adjusts PH=7-after completing 10, viscosity KU=70-140, check, pack warehouse-in standby.
The invention feature of the present invention be to have introduced in water-in-water multicolor coating have produce anion ability bear from Sub-powder and the photocatalyst with sterilization, dedusting, smoke eliminating function, not only ensure that the finished product coating made can reach the China people altogether With state's GB/T31389-2015 national standard, also have the function purifying haze, the material of each component during actual fabrication concurrently And manufacture method all can change, but as long as anion powder and photocatalyst are raw at water-in-water multicolor coating formula and reality Product exists, within broadly falling into the scope of the present invention.
The execution standard of the present invention is GB/T31389-2015 " external wall and face, house heat-reflecting material technical conditions And evaluation methodology ".

Claims (10)

1. a water-water reflective insulation anti-fog haze multicolor finish, it is characterised in that: by anion powder, protection glue and photocatalyst Being mixed in proportion with continuous phase after the colour reflective phase pelletize of composition and form, by weight, described protection glue is by 4~20 parts Protection rubber powder, the sodium pyrophosphate of 0~2 part and the deionized water of 80~95 parts, 0.1~5 part of preservative, sterilization of 0.1~1 part Agent and appropriate PH regulator composition, described containing anion powder, photocatalyst composition colour reflective by 1~10 part of anion Powder, 0.1~5 part of photocatalyst, the synthetic resin emulsion of 10~50 parts, the deionized water of 5~30 parts, ethoxy of 0.1~1 part The PH regulator of cellulose, 0.1~3, the preservative of 0.1~0.5 part, 0.1~2 part of antibacterial, the dispersant of 0.1~2 part, The stabilizer of 0.1~2 part, the coalescents of 0.1~2 part, the antifreezing agent of 0.1~2 part, the reflective insulation powder of 5~30 parts, 1~ The 4000 mesh calcined kaolins of 10 parts, the cold pigment of 1~10 part, the fine sand 1 of 0~20 part~the wetting agent of 5 parts, 1~30 part Protection glue and 0.1~5 part defoamer mixing and form through pelletize, described continuous phase by 10~50 parts deionized water, 0.1 ~the preservative of 2 parts, the antibacterial of 0.1~2 part, the synthetic resin emulsion of 30~90 parts, appropriate PH regulator and appropriate Thickening agent is dispersed through mixing.
2. a water-water reflective insulation anti-fog haze multicolor finish, is further characterized in that: be made up of anion powder and protection glue Mixing with the continuous phase containing photocatalyst after colour reflective phase pelletize, by weight, described protection glue is by 4~20 parts Protection rubber powder, the sodium pyrophosphate of 0~2 part and 80~the deionized water of part of 95, appropriate antimildew disinfectant and pH adjusting agent group Become, described containing anion powder and containing protection glue colour reflective phase, the synthesis tree of the anion powder of the part by 1~10,10~50 Fat liquor, the deionized water of 5~30 parts, 0.1~the hydroxyethyl cellulose of 0.8, the pH adjusting agent of 0.1~1 part, 0.1~1 part Anticorrosion and bactericidal agent, 0.1~2 dispersants, the stabilizer of 0.1~2 part, 0.5~3 part of coalescents, the antifreezing agent of 0.1~0.2 part, The reflective insulation powder of 2~30 parts, the calcining kaolin of 1~10 part, the cold pigment of 1~20 part, the fine sand of 0~20 part, 0.1~3 Part wetting agent, 1~30 protection glue and the defoamer of 0.1~4 part is dispersed through mixing, pelletize forms, described containing photocatalysis The continuous phase of agent by the photocatalyst of 0.1~5 part, the deionized water of 10~50 parts, the anticorrosion and bactericidal agent of 0.1~2 part, 30~90 Part synthetic resin emulsion, appropriate pH adjusting agent and appropriate thickening agent, blended form.
3. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described anion Powder is made up of one or more in the tourmaline powder that can produce anion in atmosphere.
4. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described photocatalysis Agent is by nano zine oxide, nano titanium oxide, nano silicon, nanometer titanium dioxide aluminum, nano magnesia and can be in illumination Under in air nuisance produce catalysis killing action powder body in one or more formed.
5. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described reflection every Hot powder is Altiys550 or the Altiys800 infrared external reflection that rutile titanium dioxide powder body such as Huntsman Corporation of Britain produces Pigment and the inorganic particle such as Shanghai generation being coated with by nm-class rutile-type TiO 2 open up angstrom health powder TK501W and the tool thereof of chemical industry It is made up of one or more in the powder body of identical reflective insulation function.
6. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described protection glue Powder is the commercially available KD powder of upper sea blue face company, the RT-1 powder of Shanghai Yu Zhu Industrial Co., Ltd., the GTS powder of Shanghai grid company Mixture with one or more any proportioning in the S-482 powder of Shanghai Ke Naiou trade Co., Ltd.
7. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described synthesis RS-9389 that pure third 7016G emulsion that resin emulsion is produced by Shanghai BASF AG, Shanghai Ahmedabad richness company produce, Shanghai 4369 and other spread out that BLj-9385T that Bao Lijia company produces, BLj-9388, BLj-KD96, Jiangsu sunrise company produce One or more mixture in biology.
8. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described colored bag Include the one in white, redness, yellow, blue, green, orange, purple and black and trichromatic induced color or one with Upper formed.
9. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: described antibacterial First-selection is ROHM AND HAAS (Tao Shi) LXE, and described preservative first-selection is Shanghai grid company FI-31, described defoamer first-selection is upper Sea grid company G298, described dispersant first-selection are the 120V of Shanghai grid company, and described wetting agent first-selection is Shanghai grid G-396, G-399, G-535, described PH regulator first-selection are the AMP-95 of Shanghai grid company, described stabilizer first-selection is Shanghai Ke Naiou company S-PIUS, described thickening agent first-selection is G-535 and 530 and the Shanghai Cai Yang company of Shanghai grid company HISOL-700, described coalescents are to be produced Lauryl Alcohol fat by known Yi Siman, and described antifreezing agent is by propylene glycol, second two One or one in alcohol are formed;4000 mesh calcined kaolins, sodium pyrophosphate, triple superphosphate, fine particle calcium carbonate, wollastonite in powder, silicon powder, thin Sand, is domestic known commercially available prod;Described titanium dioxide first-selection is rutile-type R-706, R-that du pont company produces 902 and domestic R-258 rutile titanium white lead in one or more formed.
10. water-water reflective insulation anti-fog haze multicolor finish as claimed in claim 1 or 2, it is characterised in that: by white cold face Material and the cold pigment of colour are formed, and the cold pigment of described white is Rutile type titanium dioxide, and described cold pigment is by iron oxide yellow, oxidation Iron oxide red, chromium oxide, titanium ultramarine, titanium viridescents etc. do not have in the pigment of ill effect to the reflective insulation function of reflective insulation powder Plant or more than one are formed.
CN201610728560.8A 2016-08-26 2016-08-26 A kind of water-water reflective insulation anti-fog haze multicolor finish Pending CN106221469A (en)

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Application publication date: 20161214