CN106221333A - A kind of sunlight reflective coating - Google Patents
A kind of sunlight reflective coating Download PDFInfo
- Publication number
- CN106221333A CN106221333A CN201610837291.9A CN201610837291A CN106221333A CN 106221333 A CN106221333 A CN 106221333A CN 201610837291 A CN201610837291 A CN 201610837291A CN 106221333 A CN106221333 A CN 106221333A
- Authority
- CN
- China
- Prior art keywords
- reflective coating
- prepares
- mixture
- sunlight reflective
- sunlight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011248 coating agent Substances 0.000 title claims abstract description 45
- 238000000576 coating method Methods 0.000 title claims abstract description 45
- 239000000835 fiber Substances 0.000 claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 28
- -1 polyoxyethylene Polymers 0.000 claims abstract description 28
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 24
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004952 Polyamide Substances 0.000 claims abstract description 16
- 229920002647 polyamide Polymers 0.000 claims abstract description 16
- FEPBITJSIHRMRT-UHFFFAOYSA-N 4-hydroxybenzenesulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C=C1 FEPBITJSIHRMRT-UHFFFAOYSA-N 0.000 claims abstract description 13
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004743 Polypropylene Substances 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960000892 attapulgite Drugs 0.000 claims abstract description 13
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 13
- 239000010941 cobalt Substances 0.000 claims abstract description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 13
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 13
- 229920001225 polyester resin Polymers 0.000 claims abstract description 13
- 239000004645 polyester resin Substances 0.000 claims abstract description 13
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 13
- 229920001155 polypropylene Polymers 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 13
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 13
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 13
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 13
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical class CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 13
- 239000010456 wollastonite Substances 0.000 claims abstract description 13
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 12
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 12
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 12
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 12
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 12
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940059574 pentaerithrityl Drugs 0.000 claims abstract description 11
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 45
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 24
- 238000005453 pelletization Methods 0.000 claims description 14
- 229910052697 platinum Inorganic materials 0.000 claims description 13
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 12
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 12
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 11
- 239000004611 light stabiliser Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 6
- JMUOXOJMXILBTE-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 JMUOXOJMXILBTE-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000009413 insulation Methods 0.000 abstract description 8
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000002469 indenes Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- DKXULEFCEORBJK-UHFFFAOYSA-N magnesium;octadecanoic acid Chemical compound [Mg].CCCCCCCCCCCCCCCCCC(O)=O DKXULEFCEORBJK-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of sunlight reflective coating, including following raw material: polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecylbenzene sodium sulfonate, 3 glycydoxy trimethoxy silanes, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite, zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, colourless cobalt, peroxidating trimethylacetic acid tertiary butyl ester, propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene tetramethylolmethane ether, indene resin, p-hydroxybenzenyl sulfonate, sodium benzoate, 2, 4 dihydroxy benaophenonels, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, additive.The coating of the present invention has excellent resistance to ag(e)ing, sunlight reflexive, heat insulation property, wearability and resistance to impact, and product nonhazardous, is the sunlight reflective coating of a kind of excellent combination property.
Description
Technical field
The invention belongs to coating technology of preparing neck, be specifically related to a kind of sunlight reflective coating.
Background technology
Metal is a kind of to have gloss, be rich in the material of the character such as ductility, easily conduction, heat conduction.The above-mentioned spy of metal
All with metallic crystal, to be contained within free electron relevant for matter.In nature, most metals exist with compound state, a few metals
Such as gold, platinum, silver, bismuth exist with free state.The range of metal is widely.A lot of outdoor facilities are all by metal system
Become.People are by protecting metal at metal surface coating coating.But, owing to being placed in outdoor for a long time, coating is easy to always
Change is faded, and is easy to be worn.
The solar reflecting properties of the most existing metal coating is poor, elastic low, it is impossible to impact resistance well,
And not there is good insulation and anti-wear performance.Such as Chinese invention patent (patent No. 201310734028.3, application
Day 2013-12-26) disclose metal surface aqueous, environmental protective reflecting heat insulation paint, this coating can effectively reflect every
Heat, high insulating effect, and heat-insulating property are stable, and corrosion-resistant, service life is long, environment friendly and pollution-free, but its wear-resisting and resistance to punching
Hit poor performance, receive shock and easily peel off；Chinese invention patent (patent No. 201110195842.3, applying date 2011-07-13)
Disclosing a kind of Ultrathin metal plate heat-insulation reflection coating and preparation method thereof, this coating has that coating layer thickness is thin, the scope of application
Extensively, the advantage such as easy construction, but go reflecting properties poor, elastic low, it is impossible to impact resistance well.
Summary of the invention
The present invention provides a kind of sunlight reflective coating, to solve existing sunlight reflective coating wearability, impact resistance
Property, sunlight reflexive, heat insulation property difference etc. problem.The coating of the present invention has excellent resistance to ag(e)ing, sunlight reflection
Property, heat insulation property, wearability and resistance to impact, and product nonhazardous, is that the sunlight reflection of a kind of excellent combination property is coated with
Material.
For solve above technical problem, the present invention by the following technical solutions:
A kind of sunlight reflective coating, in units of weight, including following raw material: polyester resin 150-180 part, polyamide
80-120 part, butyl acrylate 60-100 part, methyl pyrrolidone 30-45 part, alkylphenol polyoxyethylene 15-20 part, 12
Sodium alkyl benzene sulfonate 12-18 part, 3-glycydoxy trimethoxy silane 5-10 part, propanol 25-32 part, paraffin
12-18 part, silicone acrylic emulsion 35-55 part, wollastonite in powder 4-8 part, sodium bicarbonate 5-9 part, attapulgite 6-10 part, zinc stearate 5-
8 parts, polyvinyl chloride fibre 3-6 part, polypropylene fibre 6-9 part, Fypro 4-8 part, Benzoinum 0.7-1.2 part, stearic acid
Magnesium 0.6-0.9 part, wetting agent 407 0.4-0.7 part, colourless cobalt 0.4-0.8 part, platinum catalyst 0.3-0.6 part, peroxidating uncle penta
Acid tertiary butyl ester 0.3-0.5 part, polybutadiene rubber 0.5-0.7 part, polyoxyethylene polyoxypropylene tetramethylolmethane ether 0.4-0.8
Part, indene resin 0.6-0.9 part, p-hydroxybenzenyl sulfonate 1.2-1.8 part, sodium benzoate 0.7-1 part, antioxidant 2246 0.5-0.9
Part, light stabilizer 3853 0.4-0.6 part, 2,4-DihydroxyBenzophenone 0.4-0.6 part, carboxymethyl cellulose 0.5-0.7 part,
Propylene glycol methyl ether acetate 0.5-0.8 part, antimony oxide 1.6-2 part；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 180-230W at microwave power, and temperature is 90-94 DEG C, and rotating speed is
Stir 1-1.5h under 3000-3500r/min, prepare mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 150-175W at microwave power, and temperature is 108-112 DEG C, and rotating speed is to stir under 600-700r/min
Mix 2.5-4.5h, prepare mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
180-250W, temperature is 95-100 DEG C, and rotating speed is stirring 1.2-2h under 400-500r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 114-117 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 160-180 mesh sieve after pulverizing, and prepares sunlight reflective coating.
Preferably, microwave power described in step S1 is 230W, and temperature is 94 DEG C, and rotating speed is stirring 1h under 3500r/min.
Preferably, microwave power described in step S2 is 175W, and temperature is 112 DEG C, and rotating speed is to stir under 700r/min
2.5h。
Preferably, microwave power described in step S3 is 250W, and temperature is 100 DEG C, and rotating speed is to stir under 500r/min
1.2h。
Preferably, the temperature melt extruded described in step S4 is 117 DEG C.
Preferably, 180 mesh sieve are crossed after pelletizing described in step S6 is pulverized.
The method have the advantages that
(1) the sunlight reflective coating of the present invention had both had adhesive force and the mechanical property of excellence, have again excellent resistance to water,
Resistance to ag(e)ing, crack resistance, sunlight reflexive, heat insulation property, wearability and resistance to impact, and the nonhazardous of product own
Property, it is the sunlight reflective coating of a kind of excellent combination property；
(2) preparation method of the present invention is simple, is suitable to popularization and application on a large scale.
Detailed description of the invention
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the present invention's
Protection domain, but it is not intended to protection scope of the present invention.
In an embodiment, described sunlight reflective coating, in units of weight, including following raw material: polyester resin 150-
180 parts, polyamide 80-120 part, butyl acrylate 60-100 part, methyl pyrrolidone 30-45 part, alkyl phenol polyoxy second
Alkene ether 15-20 part, dodecylbenzene sodium sulfonate 12-18 part, 3-glycydoxy trimethoxy silane 5-10 part, third
Alcohol 25-32 part, paraffin 12-18 part, silicone acrylic emulsion 35-55 part, wollastonite in powder 4-8 part, sodium bicarbonate 5-9 part, attapulgite 6-
10 parts, zinc stearate 5-8 part, polyvinyl chloride fibre 3-6 part, polypropylene fibre 6-9 part, Fypro 4-8 part, Benzoinum
0.7-1.2 part, magnesium stearate 0.6-0.9 part, wetting agent 407 0.4-0.7 part, colourless cobalt 0.4-0.8 part, platinum catalyst 0.3-
0.6 part, peroxidating trimethylacetic acid tertiary butyl ester 0.3-0.5 part, polybutadiene rubber 0.5-0.7 part, polyoxyethylene polyoxypropylene season
Penta 4 alcohol ether 0.4-0.8 parts, indene resin 0.6-0.9 part, p-hydroxybenzenyl sulfonate 1.2-1.8 part, sodium benzoate 0.7-1 part, antioxygen
Agent 2246 0.5-0.9 part, light stabilizer 3853 0.4-0.6 part, 2,4-DihydroxyBenzophenone 0.4-0.6 part, carboxymethyl fibre
Dimension element 0.5-0.7 part, propylene glycol methyl ether acetate 0.5-0.8 part, antimony oxide 1.6-2 part；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 180-230W at microwave power, and temperature is 90-94 DEG C, and rotating speed is
Stir 1-1.5h under 3000-3500r/min, prepare mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 150-175W at microwave power, and temperature is 108-112 DEG C, and rotating speed is to stir under 600-700r/min
Mix 2.5-4.5h, prepare mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
180-250W, temperature is 95-100 DEG C, and rotating speed is stirring 1.2-2h under 400-500r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 114-117 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 160-180 mesh sieve after pulverizing, and prepares sunlight reflective coating.
Embodiment 1
A kind of sunlight reflective coating, in units of weight, including following raw material: 165 parts of polyester resin, polyamide 100
Part, butyl acrylate 80 parts, methyl pyrrolidone 38 parts, alkylphenol polyoxyethylene 18 parts, dodecylbenzene sodium sulfonate 15 parts,
3-glycydoxy trimethoxy silane 8 parts, propanol 28 parts, 15 parts of paraffin, silicone acrylic emulsion 45 parts, wollastonite in powder 6
Part, sodium bicarbonate 7 parts, attapulgite 8 parts, zinc stearate 6 parts, polyvinyl chloride fibre 5 parts, polypropylene fibre 8 parts, polyamide fibre
Tie up 6 parts, Benzoinum 1 part, magnesium stearate 0.8 part, wetting agent 407 0.6 parts, colourless cobalt 0.6 part, platinum catalyst 0.5 part, peroxide
Change trimethylacetic acid tertiary butyl ester 0.4 part, polybutadiene rubber 0.6 part, 0.6 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, indenes tree
0.8 part of fat, p-hydroxybenzenyl sulfonate 1.5 parts, sodium benzoate 0.8 part, antioxidant 2246 0.8 part, light stabilizer 3,853 0.5 parts,
2,4-DihydroxyBenzophenone 0.5 part, carboxymethyl cellulose 0.6 part, propylene glycol methyl ether acetate 0.7 part, antimony oxide 1.8
Part；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 200W at microwave power, and temperature is 92 DEG C, and rotating speed is 3300r/min
Lower stirring 1.2h, prepares mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 165W at microwave power, and temperature is 110 DEG C, and rotating speed is stirring 3.5h under 650r/min, prepares
Mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
220W, temperature is 98 DEG C, and rotating speed is stirring 1.8h under 450r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 116 DEG C by extruder, and by crusher film-making,
Lamellar body is prepared after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 170 mesh sieve after pulverizing, and prepares sunlight reflective coating.
Embodiment 2
A kind of sunlight reflective coating, in units of weight, including following raw material: 150 parts of polyester resin, polyamide 80
Part, butyl acrylate 60 parts, methyl pyrrolidone 30 parts, alkylphenol polyoxyethylene 15 parts, dodecylbenzene sodium sulfonate 12 parts,
3-glycydoxy trimethoxy silane 5 parts, propanol 25 parts, 12 parts of paraffin, silicone acrylic emulsion 35 parts, wollastonite in powder 4
Part, sodium bicarbonate 5 parts, attapulgite 6 parts, zinc stearate 5 parts, polyvinyl chloride fibre 3 parts, polypropylene fibre 6 parts, polyamide fibre
Tie up 4 parts, Benzoinum 0.7 part, magnesium stearate 0.6 part, wetting agent 407 0.4 parts, colourless cobalt 0.4 part, platinum catalyst 0.3 part, mistake
Oxidation trimethylacetic acid tertiary butyl ester 0.3 part, polybutadiene rubber 0.5 part, 0.4 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, indenes
Resin 0.6 part, p-hydroxybenzenyl sulfonate 1.2 parts, sodium benzoate 0.7 part, antioxidant 2246 0.5 part, light stabilizer 3,853 0.4
Part, 2,4-DihydroxyBenzophenone 0.4 part, carboxymethyl cellulose 0.5 part, propylene glycol methyl ether acetate 0.5 part, antimony oxide
1.6 part；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 180W at microwave power, and temperature is 90 DEG C, and rotating speed is 3000r/min
Lower stirring 1.5h, prepares mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 150W at microwave power, and temperature is 108 DEG C, and rotating speed is stirring 4.5h under 600r/min, prepares
Mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
180W, temperature is 95 DEG C, and rotating speed is stirring 2h under 400r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 114 DEG C by extruder, and by crusher film-making,
Lamellar body is prepared after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 160 mesh sieve after pulverizing, and prepares sunlight reflective coating.
Embodiment 3
A kind of sunlight reflective coating, in units of weight, including following raw material: 180 parts of polyester resin, polyamide 120
Part, butyl acrylate 100 parts, methyl pyrrolidone 45 parts, alkylphenol polyoxyethylene 20 parts, dodecylbenzene sodium sulfonate 18
Part, 3-glycydoxy trimethoxy silane 10 parts, propanol 32 parts, 18 parts of paraffin, silicone acrylic emulsion 55 parts, wollastonite
8 parts of powder, sodium bicarbonate 9 parts, attapulgite 10 parts, zinc stearate 8 parts, polyvinyl chloride fibre 6 parts, polypropylene fibre 9 parts, polyamides
Amine fiber 8 parts, Benzoinum 1.2 parts, magnesium stearate 0.9 part, wetting agent 407 0.7 parts, colourless cobalt 0.8 part, platinum catalyst 0.6
Part, peroxidating trimethylacetic acid tertiary butyl ester 0.5 part, polybutadiene rubber 0.7 part, polyoxyethylene polyoxypropylene tetramethylolmethane ether 0.8
Part, indene resin 0.9 part, p-hydroxybenzenyl sulfonate 1.8 parts, sodium benzoate 1 part, antioxidant 2246 0.9 part, light stabilizer 3853
0.6 part, 2,4-DihydroxyBenzophenone 0.6 part, carboxymethyl cellulose 0.7 part, propylene glycol methyl ether acetate 0.8 part, three oxidation
Two 2 parts of antimony；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 230W at microwave power, and temperature is 94 DEG C, and rotating speed is 3500r/min
Lower stirring 1h, prepares mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 175W at microwave power, and temperature is 112 DEG C, and rotating speed is stirring 4.5h under 700r/min, prepares
Mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
250W, temperature is 100 DEG C, and rotating speed is stirring 1.2h under 500r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 117 DEG C by extruder, and by crusher film-making,
Lamellar body is prepared after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 180 mesh sieve after pulverizing, and prepares sunlight reflective coating.
The performance indications of the sunlight reflective coating that detection embodiment 1-3 prepares, result is as shown in the table.
As seen from the above table: the sunlight reflective coating of the present invention had both had adhesive force and the mechanical property of excellence, had again
Excellent resistance to water, resistance to ag(e)ing, crack resistance, sunlight reflexive, heat insulation property, wearability and resistance to impact, and produce
The nonhazardous of product own, is the sunlight reflective coating of a kind of excellent combination property.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (6)
1. a sunlight reflective coating, it is characterised in that in units of weight, including following raw material: polyester resin 150-180
Part, polyamide 80-120 part, butyl acrylate 60-100 part, methyl pyrrolidone 30-45 part, alkylphenol polyoxyethylene
15-20 part, dodecylbenzene sodium sulfonate 12-18 part, 3-glycydoxy trimethoxy silane 5-10 part, propanol
25-32 part, paraffin 12-18 part, silicone acrylic emulsion 35-55 part, wollastonite in powder 4-8 part, sodium bicarbonate 5-9 part, attapulgite 6-10
Part, zinc stearate 5-8 part, polyvinyl chloride fibre 3-6 part, polypropylene fibre 6-9 part, Fypro 4-8 part, Benzoinum 0.7-
1.2 parts, magnesium stearate 0.6-0.9 part, wetting agent 407 0.4-0.7 part, colourless cobalt 0.4-0.8 part, platinum catalyst 0.3-0.6
Part, peroxidating trimethylacetic acid tertiary butyl ester 0.3-0.5 part, polybutadiene rubber 0.5-0.7 part, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether 0.4-0.8 part, indene resin 0.6-0.9 part, p-hydroxybenzenyl sulfonate 1.2-1.8 part, sodium benzoate 0.7-1 part, antioxidant
2246 0.5-0.9 parts, light stabilizer 3853 0.4-0.6 part, 2,4-DihydroxyBenzophenone 0.4-0.6 part, carboxymethyl cellulose
Element 0.5-0.7 part, propylene glycol methyl ether acetate 0.5-0.8 part, antimony oxide 1.6-2 part；
The preparation method of described sunlight reflective coating, comprises the following steps:
S1: by polyester resin, polyamide, butyl acrylate, methyl pyrrolidone, alkylphenol polyoxyethylene, dodecane
Base benzene sulfonic acid sodium salt, 3-glycydoxy trimethoxy silane, paraffin, wollastonite in powder, sodium bicarbonate, attapulgite,
Zinc stearate, polyvinyl chloride fibre, polypropylene fibre, Fypro, Benzoinum, magnesium stearate, wetting agent 407, colourless cobalt,
Platinum catalyst, peroxidating trimethylacetic acid tertiary butyl ester mix, and are 180-230W at microwave power, and temperature is 90-94 DEG C, and rotating speed is
Stir 1-1.5h under 3000-3500r/min, prepare mixture a；
S2: add propanol, silicone acrylic emulsion, polybutadiene rubber, polyoxyethylene polyoxypropylene in the mixture a that step S1 prepares
Tetramethylolmethane ether, indene resin, be 150-175W at microwave power, and temperature is 108-112 DEG C, and rotating speed is to stir under 600-700r/min
Mix 2.5-4.5h, prepare mixture b；
S3: add p-hydroxybenzenyl sulfonate, sodium benzoate, antioxidant 2246, light stabilizer in the mixture b that step S2 prepares
3853,2,4-DihydroxyBenzophenone, carboxymethyl cellulose, propylene glycol methyl ether acetate, antimony oxide, at microwave power be
180-250W, temperature is 95-100 DEG C, and rotating speed is stirring 1.2-2h under 400-500r/min, prepares mixture c；
S4: mixture c step S3 prepared is melt extruded at 114-117 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 160-180 mesh sieve after pulverizing, and prepares sunlight reflective coating.
Sunlight reflective coating the most according to claim 1, it is characterised in that microwave power described in step S1 is 230W,
Temperature is 94 DEG C, and rotating speed is stirring 1h under 3500r/min.
Sunlight reflective coating the most according to claim 1, it is characterised in that microwave power described in step S2 is 175W,
Temperature is 112 DEG C, and rotating speed is stirring 2.5h under 700r/min.
Sunlight reflective coating the most according to claim 1, it is characterised in that microwave power described in step S3 is 250W,
Temperature is 100 DEG C, and rotating speed is stirring 1.2h under 500r/min.
Sunlight reflective coating the most according to claim 1, it is characterised in that the temperature melt extruded described in step S4 is
117℃。
Sunlight reflective coating the most according to claim 1, it is characterised in that pelletizing described in step S6 crosses 180 after pulverizing
Mesh sieve.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610837291.9A CN106221333A (en) | 2016-09-21 | 2016-09-21 | A kind of sunlight reflective coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610837291.9A CN106221333A (en) | 2016-09-21 | 2016-09-21 | A kind of sunlight reflective coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117024973A (en) * | 2023-08-11 | 2023-11-10 | 广东恩客线缆有限公司 | Anti-aging polyvinyl chloride net wire and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093764A (en) * | 2010-12-31 | 2011-06-15 | 长安大学 | Colorful selective solar heat reflective coating for asphalt pavement |
| CN102164997A (en) * | 2008-09-29 | 2011-08-24 | 纳幕尔杜邦公司 | Polymer-based products having improved solar reflectivity and uv protection |
-
2016
- 2016-09-21 CN CN201610837291.9A patent/CN106221333A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102164997A (en) * | 2008-09-29 | 2011-08-24 | 纳幕尔杜邦公司 | Polymer-based products having improved solar reflectivity and uv protection |
| CN102093764A (en) * | 2010-12-31 | 2011-06-15 | 长安大学 | Colorful selective solar heat reflective coating for asphalt pavement |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117024973A (en) * | 2023-08-11 | 2023-11-10 | 广东恩客线缆有限公司 | Anti-aging polyvinyl chloride net wire and preparation method thereof |
| CN117024973B (en) * | 2023-08-11 | 2024-02-09 | 广东恩客线缆有限公司 | Anti-aging polyvinyl chloride net wire and preparation method thereof |
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