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CN106196009A - Fly ash and recycling method thereof - Google Patents

Fly ash and recycling method thereof Download PDF

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Publication number
CN106196009A
CN106196009A CN201610560338.1A CN201610560338A CN106196009A CN 106196009 A CN106196009 A CN 106196009A CN 201610560338 A CN201610560338 A CN 201610560338A CN 106196009 A CN106196009 A CN 106196009A
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Prior art keywords
fly ash
ash
boiler
coal
combustion
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王宇
王鹏
杨春红
周永彬
闵超
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Hongyunhonghe Tobacco Group Co Ltd
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Hongyunhonghe Tobacco Group Co Ltd
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Priority to CN201610560338.1A priority Critical patent/CN106196009A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B70/00Combustion apparatus characterised by means returning solid combustion residues to the combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B9/00Machines or apparatus for drying solid materials or objects at rest or with only local agitation; Domestic airing cupboards
    • F26B9/10Machines or apparatus for drying solid materials or objects at rest or with only local agitation; Domestic airing cupboards in the open air; in pans or tables in rooms; Drying stacks of loose material on floors which may be covered, e.g. by a roof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/60Intercepting solids using settling/precipitation chambers

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

本发明公开一种燃煤锅炉飞灰回收再利用的处理方法,燃煤锅炉飞灰对于机械式风力播煤来说,是锅炉热损失的主要原因之一,取不同时期的飞灰进行化验可知飞灰收到基的平均低位发热量在2500大卡左右,飞灰可燃物含量还有38%,为把这部分可燃物加以再利用,将飞灰收集晾晒之后掺入到煤中进行混烧以提高锅炉悬浮燃烧的强度,试验不同比例的飞灰找出最佳的飞灰搀兑比例。该方法可以有效的改善锅炉燃烧,减少污染,在节能降耗上有显著效果,实施也较容易,具有非常好的适用价值。

The invention discloses a treatment method for recovering and reusing the fly ash of a coal-fired boiler. The fly ash of a coal-fired boiler is one of the main reasons for the heat loss of the boiler for mechanical wind power sowing coal. The fly ash of different periods is tested for testing. The average low calorific value of the fly ash as received is about 2500 kcal, and the fly ash has a combustible content of 38%. In order to reuse this part of the combustibles, the fly ash is collected and dried and mixed into coal for co-firing In order to improve the intensity of boiler suspension combustion, test different proportions of fly ash to find out the best proportion of fly ash blending. The method can effectively improve boiler combustion, reduce pollution, have significant effects on energy saving and consumption reduction, and is easy to implement and has very good applicable value.

Description

一种飞灰及其回收再利用方法A kind of fly ash and its recycling method

技术领域technical field

本发明属于工业锅炉的技术领域,具体涉及一种飞灰及其回收再利用方法。The invention belongs to the technical field of industrial boilers, and in particular relates to a fly ash and a recovery and reuse method thereof.

背景技术Background technique

基于目前的锅炉燃烧模式,由于经过给煤系统的改造,锅炉的燃烧方式已经不是简单的闸板式给煤燃烧,而是半悬浮燃烧,这就要求煤中的颗粒度应该分布均匀,粉煤和颗粒度煤的比例较为适中。而目前的煤难以做到完全适宜锅炉燃烧所需,这就需要用粉煤来进行调节。除此之外,由于锅炉飞灰对于机械式风力抛煤来说,是锅炉固体不完全燃烧热损失的主要原因。取不同时期的飞灰进行化验,化验结果显示,其飞灰收到基的平均低位发热量在2500大卡左右,同飞灰含碳量38%吻合。飞灰含碳量高增加了锅炉热损失,影响了燃烧旺盛区的火焰高度及火床长度,是炉膛中心温度不高的直接原因。Based on the current boiler combustion mode, due to the transformation of the coal feeding system, the combustion method of the boiler is no longer a simple ram type coal feeding combustion, but a semi-suspension combustion, which requires that the particle size in the coal should be evenly distributed, and the pulverized coal and The proportion of particle size coal is relatively moderate. However, the current coal is difficult to be fully suitable for boiler combustion, which requires adjustment with pulverized coal. In addition, because the boiler fly ash is the main cause of the heat loss of the incomplete combustion of the boiler solid for the mechanical wind coal throwing. The fly ash of different periods was tested for testing. The test results showed that the average low calorific value of the fly ash as received was around 2500 kcal, which was consistent with the carbon content of the fly ash being 38%. The high carbon content of the fly ash increases the heat loss of the boiler, affects the flame height and the length of the fire bed in the vigorous combustion area, and is the direct cause of the low temperature in the furnace center.

考虑到上述种种问题的存在,现需要研究一种方式来进行优化完善。Considering the existence of the above problems, it is necessary to study a way to optimize and perfect.

发明内容Contents of the invention

本发明针对现有技术的不足,提供了一种切后烟块的飞灰回收再利用的处理方法,通过合适的飞灰加入比例,从而提高炉膛中悬浮燃烧的强度,使飞灰中的未燃尽碳得到再利用。Aiming at the deficiencies of the prior art, the present invention provides a treatment method for reclaiming and reusing the fly ash of the cut cigarette block. By adding a suitable proportion of fly ash, the intensity of suspension combustion in the furnace is improved, and the unused fly ash in the fly ash is The burnt carbon is reused.

为了解决上述的问题本发明的采用的技术以及方法如下:In order to solve the problems referred to above, the technology and method adopted in the present invention are as follows:

一种飞灰,按照6%的比例添加于燃煤中。A fly ash that is added to coal combustion at a rate of 6%.

进一步的,所述飞灰为未经过燃烧或者燃烧不完全的飞灰。Further, the fly ash is unburned or incompletely burned fly ash.

本发明要解决的另一技术问题为提供一种飞灰的回收再利用方法,包括以下步骤:Another technical problem to be solved by the present invention is to provide a method for recycling fly ash, comprising the following steps:

1)将锅炉中燃烧后的烟气进行脱硫除尘处理,得到灰水混合物、备用;1) Desulfurization and dust removal treatment is carried out on the flue gas after combustion in the boiler to obtain the ash-water mixture for subsequent use;

2)将锅炉中燃烧后的灰渣进行除渣处理,得到灰水混合物和悬浮于水面的飞灰、备用;2) Carry out slag removal treatment on the ash after combustion in the boiler to obtain the ash-water mixture and fly ash suspended on the water surface, for subsequent use;

3)将步骤1)与步骤2)中的灰水混合物一并放入高位沉淀池,得到灰水混合物和悬浮于水面的飞灰、备用;3) Put the gray-water mixture in step 1) and step 2) into a high-level sedimentation tank together to obtain the gray-water mixture and fly ash suspended on the water surface for subsequent use;

4)将步骤3)中得到的灰水混合物放入渣场,待灰水自然分离,得到飞灰,备用;4) Put the ash-water mixture obtained in step 3) into the slag yard, and wait for the ash-water to separate naturally to obtain fly ash for subsequent use;

5)将步骤2)、步骤3)和步骤4)中的飞灰进行晾晒处理,直至飞灰中的水分≤8%;5) Airing the fly ash in step 2), step 3) and step 4) until the moisture content in the fly ash is ≤8%;

6)将步骤5中的飞灰按照6%的比例加入锅炉中,进行混合燃烧,即可。6) Add the fly ash in step 5 into the boiler according to the ratio of 6%, and carry out mixed combustion.

进一步的,在步骤5)中,对晾晒处理后的飞灰进行含水量检测,并将含水量>8%的飞灰再次进行晾晒处理。Further, in step 5), the water content of the air-dried fly ash is tested, and the fly ash with a water content > 8% is air-dried again.

进一步的,所述飞灰为未经过燃烧或者燃烧不完全的飞灰。Further, the fly ash is unburned or incompletely burned fly ash.

实验步骤:Experimental steps:

1、晾干高位沉淀池漂浮于水面上和沉积的飞灰以及除渣槽中漂浮的飞灰;1. Dry the fly ash floating on the water surface and deposited in the high-level sedimentation tank and the fly ash floating in the slag removal tank;

2、取样化验飞灰的低位发热量,以选取适宜燃烧的飞灰;2. Sampling and testing the low calorific value of fly ash to select fly ash suitable for combustion;

3、根据化验结果,针对使用煤炭特性,计算出可行的理论比例;3. According to the test results, according to the characteristics of the coal used, calculate the feasible theoretical ratio;

4、根据理论比例投入试验;4. Put into the test according to the theoretical ratio;

5、跟踪燃烧工况及采集相应煤渣样,进行化验分析;5. Track the combustion conditions and collect corresponding cinder samples for laboratory analysis;

6、统计相同产汽量的耗煤量进行对比分析,得出最佳的飞灰添加比例。6. Statistically compare and analyze the coal consumption of the same steam production, and get the best fly ash addition ratio.

本发明的有益效果为:飞灰回收再利用在改善锅炉燃烧,减少污染,节能降耗上有显著效果,实施也较容易,具有非常好的适用价值。The beneficial effect of the invention is that the recovery and reuse of fly ash has remarkable effects in improving boiler combustion, reducing pollution, saving energy and reducing consumption, and is easy to implement and has very good application value.

附图说明Description of drawings

图1为本发明一种飞灰及其回收再利用方法的流程图;Fig. 1 is the flow chart of a kind of fly ash of the present invention and its recycling method;

图2为锅炉炉膛温度变化曲线图。Figure 2 is a curve diagram of boiler furnace temperature change.

具体实施方式detailed description

下面结合实施例和附图对本发明做进一步的详细说明,但它们并不是对本发明技术方案的限定。基于本发明教导所做出的任何变换,均落在本发明的保护范围。The present invention will be further described in detail below in conjunction with the embodiments and accompanying drawings, but they are not intended to limit the technical solution of the present invention. Any transformation made based on the teaching of the present invention falls within the protection scope of the present invention.

参阅图1所示,一种飞灰的回收再利用方法,包括以下步骤:Referring to shown in Fig. 1, a kind of fly ash recycling method comprises the following steps:

1)将锅炉中燃烧后的烟气进行脱硫除尘处理,得到灰水混合物、备用;1) Desulfurization and dust removal treatment is carried out on the flue gas after combustion in the boiler to obtain the ash-water mixture for subsequent use;

2)将锅炉中燃烧后的灰渣进行除渣处理,得到灰水混合物和悬浮于水面的飞灰、备用;2) Carry out slag removal treatment on the ash after combustion in the boiler to obtain the ash-water mixture and fly ash suspended on the water surface, for subsequent use;

3)将步骤1)与步骤2)中的灰水混合物一并放入高位沉淀池,得到灰水混合物和悬浮于水面的飞灰、备用;3) Put the gray-water mixture in step 1) and step 2) into a high-level sedimentation tank together to obtain the gray-water mixture and fly ash suspended on the water surface for subsequent use;

4)将步骤3)中得到的灰水混合物放入渣场,待灰水自然分离,得到飞灰,备用;4) Put the ash-water mixture obtained in step 3) into the slag yard, and wait for the ash-water to separate naturally to obtain fly ash for subsequent use;

5)将步骤2)、步骤3)和步骤4)中的飞灰进行晾晒处理,直至飞灰中的水分≤8%;5) Airing the fly ash in step 2), step 3) and step 4) until the moisture content in the fly ash is ≤8%;

6)将步骤5中的飞灰按照6%的比例加入锅炉中,进行混合燃烧,即可。6) Add the fly ash in step 5 into the boiler according to the ratio of 6%, and carry out mixed combustion.

在步骤5)中,对晾晒处理后的飞灰进行含水量检测,并将含水量>8%的飞灰再次进行晾晒处理。In step 5), the water content of the air-dried fly ash is tested, and the fly ash with a water content > 8% is air-dried again.

所述飞灰为未经过燃烧或者燃烧不完全的飞灰。The fly ash is unburned or incompletely burned fly ash.

在燃煤中添加6%的飞灰是基于一系列试验所得出,试验的过程和结论如下:The addition of 6% fly ash in coal combustion is based on a series of tests. The process and conclusions of the tests are as follows:

试验前对飞灰进行摊开暴晒,取样分析飞灰水分在8%以下后再进行试验,试验前数据以技术监督科分析得出数据为准,试验后数据以输煤电子称及蒸汽流量计计量为准,为减少误差,分别拉煤和飞灰去磅称房过磅的精准计量方式进行飞灰和煤的配制。Before the test, the fly ash was spread out and exposed to the sun, and the test was carried out after sampling and analysis of the moisture content of the fly ash below 8%. The data before the test were based on the data analyzed by the technical supervision department, and the data after the test were based on the coal transportation electronic scale and steam flow meter The measurement shall prevail. In order to reduce the error, the fly ash and coal are prepared by the precise measurement method of pulling coal and fly ash to the weighing room for weighing.

在数据采集时,为表征掺入飞灰对锅炉运行的影响,采集炉膛温度进行跟踪对比,因为这个参数是锅炉正常运行的一个体现,也是表征锅炉热效率的主要参数,炉膛温度的高低直接决定了锅炉相关运行参数汽煤比、汽电比及产汽量的高低;另外在进行试验时,煤炭是同一批次,以排除煤炭不同对试验产生的影响,且生产负荷基本一致、数据取样间隔时间较短,有可比性。During data collection, in order to characterize the impact of fly ash on boiler operation, the furnace temperature was collected for tracking and comparison, because this parameter is a reflection of the normal operation of the boiler and is also the main parameter to characterize the thermal efficiency of the boiler. The furnace temperature directly determines the The steam-to-coal ratio, steam-to-electricity ratio, and steam production of boiler-related operating parameters are high and low; in addition, during the test, the coal is the same batch to eliminate the influence of different coal on the test, and the production load is basically the same, and the data sampling interval Shorter and comparable.

为了从理论上对加入飞灰后的煤灰混煤样进行测算分析,将煤样、飞灰样、以及不同比例的煤灰混合样随机取样进行化验分析,得到下表:In order to theoretically calculate and analyze the coal ash-mixed samples after adding fly ash, the coal samples, fly ash samples, and coal ash mixed samples of different proportions were randomly sampled for laboratory analysis, and the following table was obtained:

从表中可以看出,搀兑不同比例的飞灰后煤灰样的检测指标变化不大,适宜锅炉燃烧用,而为了找出最佳的飞灰搀兑比例,在锅炉负荷相对稳定、锅炉运行操作模式一致的基础上,从3%的比例开始进行添加试验,随后分别加入4%、5%、6%、7%比例的飞灰,进行燃烧试验,从整个宏观状况上来看,加入不同比例的飞灰后,对燃烧产生了有利的影响,既保证了生产,又节约了能源。加入不同比例飞灰后,相同情况下炉膛温度均比未加飞灰时提高,前后拱温差变小,朝着有利于燃烧的方向进行。前拱温度的降低及后拱温度的提高证明了所加飞灰提高了锅炉的悬浮燃烧,增长了火焰长度,其燃烧效果是显著的。对不同飞灰掺入比例时不同负荷下的锅炉炉膛温度进行跟踪观测,最后绘制出炉膛温度的变化曲线,如图2所示,根据炉膛温度的高低最终确定飞灰的最佳配比为6%。It can be seen from the table that after mixing different proportions of fly ash, the detection index of the coal ash sample does not change much, which is suitable for boiler combustion. On the basis of the same operating mode, the addition test was carried out from the proportion of 3%, and then 4%, 5%, 6% and 7% of fly ash were added to carry out the combustion test. From the perspective of the overall macroscopic situation, the addition of different The proportion of fly ash has a favorable effect on combustion, which not only ensures production, but also saves energy. After adding different proportions of fly ash, the temperature of the furnace is higher than that without adding fly ash under the same conditions, and the temperature difference between the front and back arches becomes smaller, and it moves in a direction that is conducive to combustion. The reduction of the front arch temperature and the increase of the rear arch temperature prove that the added fly ash improves the suspension combustion of the boiler, increases the flame length, and its combustion effect is remarkable. Track and observe the boiler furnace temperature under different loads with different fly ash mixing ratios, and finally draw the furnace temperature change curve, as shown in Figure 2. According to the furnace temperature, the optimal ratio of fly ash is finally determined to be 6 %.

本发明的有益效果为:飞灰回收再利用在改善锅炉燃烧,减少污染,节能降耗上有显著效果,实施也较容易,具有非常好的适用价值。The beneficial effect of the invention is that the recovery and reuse of fly ash has remarkable effects in improving boiler combustion, reducing pollution, saving energy and reducing consumption, and is easy to implement and has very good application value.

以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何不经过创造性劳动想到的变化或替换,都应涵盖在本发明的保护范围之内,因此,本发明的保护范围应该以权利要求书所限定的保护范围为准。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, and any change or replacement that is not thought of through creative work should be covered within the scope of protection of the present invention. Therefore, The protection scope of the present invention should be determined by the protection scope defined in the claims.

Claims (5)

1.一种飞灰,其特征在于:按照6%的比例添加于燃煤中。1. A kind of fly ash, it is characterized in that: add in the burning coal according to the ratio of 6%. 2.如权利要求1所述的飞灰,其特征在于:所述飞灰为未经过燃烧或者燃烧不完全的飞灰。2. The fly ash according to claim 1, characterized in that: the fly ash is unburned or incompletely burned fly ash. 3.一种飞灰的回收再利用方法,其特征在于,包括以下步骤:3. A method for recovering and reusing fly ash, comprising the following steps: 1)将锅炉中燃烧后的烟气进行脱硫除尘处理,得到灰水混合物、备用;1) Desulfurization and dust removal treatment is carried out on the flue gas after combustion in the boiler to obtain the ash-water mixture for subsequent use; 2)将锅炉中燃烧后的灰渣进行除渣处理,得到灰水混合物和悬浮于水面的飞灰、备用;2) Carry out slag removal treatment on the ash after combustion in the boiler to obtain the ash-water mixture and fly ash suspended on the water surface, for subsequent use; 3)将步骤1)与步骤2)中的灰水混合物一并放入高位沉淀池,得到灰水混合物和悬浮于水面的飞灰、备用;3) Put the gray-water mixture in step 1) and step 2) into a high-level sedimentation tank together to obtain the gray-water mixture and fly ash suspended on the water surface for subsequent use; 4)将步骤3)中得到的灰水混合物放入渣场,待灰水自然分离,得到飞灰,备用;4) Put the ash-water mixture obtained in step 3) into the slag yard, and wait for the ash-water to separate naturally to obtain fly ash for subsequent use; 5)将步骤2)、步骤3)和步骤4)中的飞灰进行晾晒处理,直至飞灰中的水分≤8%;5) Airing the fly ash in step 2), step 3) and step 4) until the moisture content in the fly ash is ≤8%; 6)将步骤5中的飞灰按照6%的比例加入锅炉中,进行混合燃烧,即可。6) Add the fly ash in step 5 into the boiler according to the ratio of 6%, and carry out mixed combustion. 4.如权利要求3所述的飞灰回收再利用的处理方法,其特征在于:在步骤5)中,对晾晒处理后的飞灰进行含水量检测,并将含水量>8%的飞灰再次进行晾晒处理。4. The processing method of fly ash recovery and reuse as claimed in claim 3, characterized in that: in step 5), the moisture content of the fly ash after drying treatment is detected, and the fly ash with a water content > 8% is Carry out drying treatment again. 5.如权利要求3或4所述的飞灰的回收再利用方法,其特征在于:所述飞灰为未经过燃烧或者燃烧不完全的飞灰。5. The method for recovering and reusing fly ash according to claim 3 or 4, characterized in that: the fly ash is unburned or incompletely burned fly ash.
CN201610560338.1A 2016-07-15 2016-07-15 Fly ash and recycling method thereof Pending CN106196009A (en)

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