CN106191678A - By the tensile strength of medium thin slab Direct Rolling >=1700MPa hot forming steel and production method - Google Patents
By the tensile strength of medium thin slab Direct Rolling >=1700MPa hot forming steel and production method Download PDFInfo
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- CN106191678A CN106191678A CN201610713646.3A CN201610713646A CN106191678A CN 106191678 A CN106191678 A CN 106191678A CN 201610713646 A CN201610713646 A CN 201610713646A CN 106191678 A CN106191678 A CN 106191678A
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 71
- 239000010959 steel Substances 0.000 title claims abstract description 71
- 238000005096 rolling process Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000010791 quenching Methods 0.000 claims abstract description 17
- 230000000171 quenching effect Effects 0.000 claims abstract description 14
- 238000002791 soaking Methods 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 9
- 238000003723 Smelting Methods 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 6
- 238000009749 continuous casting Methods 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 238000004080 punching Methods 0.000 claims abstract description 5
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 238000005266 casting Methods 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 229910000734 martensite Inorganic materials 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000010079 rubber tapping Methods 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 239000010955 niobium Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 229910052758 niobium Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910001566 austenite Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- -1 and meanwhile Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
With the tensile strength of medium thin slab Direct Rolling >=1700MPa hot forming steel, its component and wt%:C:0.26~0.30%, Si:0.31~0.35%, Mn:1.3~1.5%, P≤0.008%, S≤0.005%, Als:0.015~0.060%, Cr:0.31~0.35%, more than Ti:0.031~0.035% or Nb:0.031~0.035% or V:0.031~0.035% or two of which with the mixing of arbitrary proportion, B:0.003~0.004%, Mo:0.20~0.25%, Ni:0.06~0.10%, N≤0.005%.Production stage: desulfurizing iron;Electric furnace or converter smelting and refine;Continuous casting;Enter the de-scaling before soaking pit to process;Soaking;Heating;High-pressure water descaling before feed mill;Rolling;Cooling;Batch;Austenitizing;Mould punching shapes;Quenching.Flow process of the present invention is short, and product surface quality is good, and thickness and precision is high, it is possible to reach the prescription of cold-rolled products, high without resilience, the dimensional accuracy of part after smoothly completing complex deformation, and deformation, is significant for automobile lightweight.
Description
Technical field
The present invention relates to a kind of auto parts and components steel and production method thereof, specifically belong to one medium thin slab direct
Tensile strength >=1700MPa hot forming the steel of rolling and production method, and the product thickness being applicable to produce is more than 2 to 10mm.
Background technology
Along with Automobile Design and manufacture are gradually sent out by automobile industry development and automobile industry to energy-saving and environmental protection, safe direction
Exhibition, automotive light weight technology becomes the main flow direction of significant period of time Automobile Design at present and in the future.
Research finds, complete vehicle weight and the energy resource consumption of automobile are linear.According to statistics, vehicle weight often reduces by 10%
Then fuel efficiency can improve 6%~8%.One of most important approach of automotive light weight technology is to use high intensity and unimach, from
And can make while not reducing crashworthiness and comfortableness, adopt and automobile weight in working order can be greatly reduced.But along with intensity
Improving constantly, the forming property of steel plate can worse and worse, and the unimach of especially more than 1700MPa, in forming process
Cracking, resilience and accessory size can be there is and do not reach the problems such as permissible accuracy, and also pressing equipment be proposed higher simultaneously
Requirement, i.e. need large-tonnage stamping machine and high abrasion mould, and the mold use cycle also had large effect.Mesh
The front domestic cold forming pressing equipment also not having to shape more than 1700MPa and mould.
Currently, the tensile strength of domestic and international existing hot forming steel all can not arrive 1700MPa and more than, and all use cold
Roll annealed state or cold rolled annealed rear precoated shet.Its technological process of production is: desulphurised hot metal → converter smelting → external refining → company
Casting → heating of plate blank → hot continuous rolling → pickling+cold continuous rolling → continuous annealing → (precoated shet) → finishing packaging → blanking → heating →
Mould punching quenches.There is the technological process of production longer, relatively costly deficiency.Some impact resistant or load bearing component are all adopted
Improve impact resistant and bearing capacity with multiple part combination components, and cause being greatly improved the cost of raw material and being processed into
This.
Along with the development of steel and iron industry, medium thin slab continuous casting and rolling technique has obtained tremendous development, uses medium thin slab even
Casting continuous rolling process can produce > 2.0~10 mm specification steel plate and steel band with Direct Rolling, and some can only use cold rolling high-strength originally
The Thin Specs part of steel or the structure for increase intensity employing multiple parts composition the most progressively use casting and rolling process directly to roll
Ultrahigh-strength steel plates processed is replaced.Yield strength (the R such as Patent exploitation that China Patent Publication No. is CN 102965573AeL)
>=700MPa, tensile strength (RmThe engineering structure high strength steel of) >=750MPa, its component percentages is: C:0.15~
0.25%, Si :≤0.10%, Mn:1.00~1.80%, P :≤0.020%, S≤0.010%, Ti:0.09~0.20%, Als:
0.02~0.08%, N≤0.008%, remaining for Fe and is inevitably mingled with;Its production stage, for smelting and being casting continuously to form base, enters
Row soaking, control soaking temperature is at 1200~1300 DEG C, and soaking time is 20~60min;Roll, and control start rolling temperature
Being not less than 1200 DEG C, finishing temperature is at 870~930 DEG C;Carry out section cooling, in rate of cooling for being not less than under 20 DEG C/s cooling
To coiling temperature;Batch, and control coiling temperature at 580~650 DEG C.China Patent Publication No. is CN 103658178A
A kind of short route of patented invention method of producing high-strength thin strip steel, the strip steel yield strength (R that inventedeL) >=
550MPa, tensile strength (Rm) >=600MPa, its chemical composition mass percent is: C:0.02~0.15%, Si:0.20~
0.6%, Mn:0.2~1.50%, P:0.02~0.3%, S≤0.006%, Cr:0.40~0.8%, Ni:0.08~0.40%, Cu:
0.3~0.80%, Nb:0.010~0.025%, Ti:0.01~0.03%, Al:0.01~0.06%, Re:0.02~0.25%;Remaining
For Fe and inevitable impurity, it is cast into 1.0~2.0mm thick Cast Strips, casting rate 60~150m/min after smelting, rolls
System, control finishing temperature 850~1000 DEG C;Use atomization cooling, rate of cooling 50~100 DEG C/s, batch, control to batch
Temperature is 520~660 DEG C.The tensile strength of above-mentioned two documents is the lowest, it is impossible to meet high-end body of a motor car to more than 1700MPa
The demand of superhigh intensity.
Summary of the invention
The invention reside in the intensity rank overcoming prior art to exist low, it is impossible to meet user to superhigh intensity part demand
Deficiency, it is provided that a kind of both can meet the Automobile Design requirement to superhigh intensity mechanical property, complicated change can have been smoothly completed again
Without resilience after shape, and deformation, tensile strength >=1700MPa hot forming steel that the dimensional accuracy of part is high and production method.
Realize the measure of above-mentioned purpose:
With the tensile strength of medium thin slab Direct Rolling >=1700MPa hot forming steel, its component and weight percent content be: C:
0.26~0.30%, Si:0.31~0.35%, Mn:1.3~1.5%, P≤0.008%, S≤0.005%, Als:0.015~
0.060%, Cr:0.31~0.35%, Ti:0.031~0.035% or Nb:0.031~0.035% or V:0.031~0.035% or its
In the two or more mixing with arbitrary proportion, B:0.003~0.004%, Mo:0.20~0.25%, Ni:0.06~0.10%, N≤
0.005%, remaining for Fe and inevitable impurity;Metallographic structure after quenching is full lath martensite;Mechanical property: surrender is strong
Degree >=1150 MPa, tensile strength >=1700MPa, percentage elongation A80mm≥5%。
Produce the method with the tensile strength >=1700MPa hot forming steel of medium thin slab Direct Rolling, it is characterised in that: its
Step:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 61~150mm, and casting speed is 2.8
~5.5 m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) entering to heat to strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1150~1180
℃;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 40~50%, the second percentage pass reduction is: 40~50%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is at 3~8 m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 615 ~ 645 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 930~980 DEG C, and is incubated 6~15 min;
12) mould punching shapes, and pressurize 6~9 s in mould;
13) quench, control quenching rate of cooling at 50~100 DEG C/s;After naturally cool to room temperature.
It is: the operation of rolling of described medium thin slab is that 6F produces line or 1R+6F produces line or 2R+ at rolling mill layout
6F produces line or 7F produces line or 3R+4F produces line or 2R+5F produces line or 1R+5F produces line and carries out.
Each element and the effect of main technique and mechanism in the present invention
C: carbon is strong solution strengthening element, and the acquisition to superhigh intensity plays a decisive role, the carbon content tissue shape to final products
State and performance have considerable influence, but content is the highest, are easily formed substantial amounts of pearlite or bayesian in the cooling procedure after finish rolling
Body, martensite, its content is the highest, and intensity is the highest, thus causes plasticity to reduce, the blanking difficulty before forming.So protecting
On the premise of card heat treatment reinforcement, carbon content is difficult to too high.Therefore its content is limited to 0.26~0.30% scope.
Si: silicon has stronger solid solution strengthening effect, can improve the intensity of steel, and meanwhile, silicon can improve the quenching degree of steel, has and subtracts
Few austenite effect of change in volume when martensite transfor mation, thus effectively control the generation of hardening flaw;When lonneal
Carbon diffusion can be hindered, delay martensite to decompose and the speed of carbide agglomeration, make steel hardness when tempering decline relatively slow,
Significantly improve steel belt roof bolt stability and intensity.So, its content is limited to 0.31~0.35% scope.
Mn: manganese plays solution strengthening effect, can remove the FeO in steel simultaneously, significantly improve the quality of steel.Can also be with sulfide
Generating dystectic MnS, when hot-working, MnS has enough plasticity, makes steel not produce hot-short phenomenon, alleviates harmful work of sulfur
With, improve the hot-working character of steel.Manganese can reduce phase driving force, makes " C " curve move to right, and improves the quenching degree of steel, expands γ
Phase region, separately it can reduce the Ms point of steel, therefore can ensure to obtain martensite under suitable rate of cooling.So, its content is limited
It is scheduled on 1.3~1.5% scope.
Cr: chromium can reduce phase driving force, and when also reducing phase transformation, the forming core of carbide is grown up, so improving the through hardening of steel
Property.It addition, chromium can improve steel belt roof bolt stability.So, its content is limited to 0.31~0.35% scope.
B: boron is strongly to improve quenching degree element, and the boron element adding trace in steel can significantly improve the quenching degree of steel.But
It is that its content is less than 0.003%, or higher than 0.004%, the effect to improving quenching degree is inconspicuous.So, for considering to produce
Actual and quenching degree effect, is limited to 0.003~0.004% scope by its content.
Als, it plays deoxidation in steel, should ensure that there is a certain amount of dissolved aluminum in steel, otherwise can not play its effect,
But too much aluminum also can make to produce aluminum system in steel to be mingled with, and is unfavorable for smelting and the casting of steel.Steel adds appropriate aluminum simultaneously
Nitrogen in steel, the oxygen atom adverse effect to performance can be eliminated.Therefore its content is limited to 0.015~0.060% scope.
P: phosphorus is the harmful element in steel, easily causes center segregation of casting blank.In hot continuous rolling heating process subsequently the most partially
Gather crystal boundary, make the fragility of steel significantly increase.It is simultaneously based on cost consideration and does not affect the performance of steel, its content is controlled
Less than 0.008%.
S: sulfur is very harmful element.Sulfur in steel often exists with the oxide morphology of manganese, this sulphide inculsion meeting
The toughness of deterioration steel, and cause the anisotropy of performance, therefore, need to sulfur content in steel be controlled the lowest more good.Based on to system
Cause this consideration, sulfur content in steel is controlled below 0.005%.
N: nitrogen can be combined formation titanium nitride in the steel add titanium with titanium, and this second phase at high temperature separated out is conducive to strong
Change matrix, and improve the welding performance of steel plate.But nitrogen content is higher than 0.005%, and nitrogen is higher with the solubility product of titanium, when high temperature
Steel will form the titanium nitride that granule is thick, the plasticity of serious infringement steel and toughness;It addition, higher nitrogen content can make stable
Micro alloying element content needed for nitrogen element increases, thus increases cost.Therefore its content is controlled below 0.005%.
Ti: titanium is that strong C, N compound forms element, and the purpose adding Ti in steel is the N element in fixing steel, but excess
Ti can be combined with C thus reduce hardness and the intensity of martensite after test steel quenches.It addition, the quenching degree to steel that adds of titanium has
Certain contribution.So, its content is limited to 0.031~0.035% scope.
Nb, V: niobium and vanadium are also that strong C, N compound forms element, can play the effect of fining austenite grains, add in steel
A small amount of niobium or vanadium just can form the carbon of a certain amount of niobium, nitride, thus hinder Austenite Grain Growth, and therefore, it is quenched
Martensite lath size after fire is less, is greatly improved the intensity of steel.Therefore its content is all controlled 0.031~0.035% it
Between.
Mo: molybdenum can significantly improve the quenching degree of steel, and the stacking fault energy of molybdenum is higher, and the low temperature that can improve steel in addition steel is moulded
Property and toughness.Therefore its content is controlled between 0.20~0.25%.
Ni: nickel addition steel can improve the intensity of steel and do not significantly reduce its toughness.Can improve simultaneously steel processability and
Solderability.It addition, nickel can improve the resistance to corrosion of steel, can not only be acidproof, and can alkali resistant and the corrosion of air.So will
Its content is limited to 0.06~0.10%.
Why the present invention takes three de-scalings in whole production process, is due to by controlling de-scaling passage with suitable
De-scaling water pressure, the iron scale of belt steel surface can be removed as far as possible, thus ensure that strip steel has good surface matter
Amount.Control additionally by one, two roads and end percentage pass reduction, even tissue and the stable performance of strip steel can be realized.
Compared with prior art, its intensity is high, and manufacturing process is short, and product surface quality is good for the present invention, and thickness and precision is high, energy
Enough reach the prescription of cold-rolled products, significantly save energy resource consumption;It addition, with existing medium thin slab Direct Rolling product phase
Ratio, its intensity is significantly larger than existing product, is significant for automobile lightweight.
Accompanying drawing explanation
Fig. 1 is product metallographic structure figure of the present invention.
Detailed description of the invention
Below the present invention is described in detail:
Table 1 is the chemical composition value list of various embodiments of the present invention and comparative example;
Table 2 is the main technologic parameters value list of various embodiments of the present invention and comparative example;
Table 3 is the performance detection case list of various embodiments of the present invention and comparative example.
Various embodiments of the present invention are all produced by following technique:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 61~150mm, and casting speed is 2.8
~5.5 m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) entering to heat to strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1150~1180
℃;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 40~50%, the second percentage pass reduction is: 40~50%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is at 3~8 m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 615 ~ 645 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 930~980 DEG C, and is incubated 6~15 min;
12) mould punching shapes, and pressurize 6~9 s in mould;
13) quench, control quenching rate of cooling at 50~100 DEG C/s;After naturally cool to room temperature.
The chemical composition (wt.%) of table 1 various embodiments of the present invention and comparative example
The main technologic parameters value list of table 2 various embodiments of the present invention and comparative example
Table 3 various embodiments of the present invention and comparative example mechanical property situation list
From table 3 it can be seen that the application by shorter technological process be successfully realized the intensity of invention steel reach 1700MPa with
On, for advancing the development of automotive light weight technology to be significant.
This detailed description of the invention is only and most preferably enumerates, the not restricted enforcement to technical solution of the present invention.
Claims (3)
1., with the tensile strength >=1700MPa hot forming steel of medium thin slab Direct Rolling, its component and weight percent content be:
C:0.26~0.30%, Si:0.31~0.35%, Mn:1.3~1.5%, P≤0.008%, S≤0.005%, Als:0.015~
0.060%, Cr:0.31~0.35%, Ti:0.031~0.035% or Nb:0.031~0.035% or V:0.031~0.035% or its
In the two or more mixing with arbitrary proportion, B:0.003~0.004%, Mo:0.20~0.25%, Ni:0.06~0.10%, N≤
0.005%, remaining for Fe and inevitable impurity;Metallographic structure after quenching is full lath martensite;Mechanical property: surrender is strong
Degree >=1150 MPa, tensile strength >=1700MPa, percentage elongation A80mm≥5%。
2. produce the method with the tensile strength >=1700MPa hot forming steel of medium thin slab Direct Rolling described in claim 1,
It is characterized in that: its step:
1) desulfurizing iron, and control S≤0.002%, after skimming, molten iron exposed surface is not less than 96%;
2) conventional electric furnace or converter smelting, and conventional refinery;
3) carrying out continuous casting, in control, bag molten steel overheat is at 15~30 DEG C, and slab thickness is 61~150mm, and casting speed is 2.8
~5.5 m/min;
4) carry out the de-scaling before strand enters soaking pit to process, and control the pressure of de-scaling water at 300~400 bar;
5) strand is carried out conventional soaking, control soaking pit interior in weak oxide atmosphere, even if remaining oxygen is 0.5~5.0% in stove;
6) heating strand, and control strand charging temperature at 780~1000 DEG C, tapping temperature is 1150~1180 DEG C;
7) carry out the high-pressure water descaling before feed mill, and control de-scaling water pressure 280~420bar;
8) rolling, and control the first percentage pass reduction and be: 40~50%, the second percentage pass reduction is: 40~50%, extreme trace time pressure
Rate is: 10~16%;Controlled rolling speed is at 3~8 m/s;And setting-out de-scaling in carrying out between the first passage and second time,
De-scaling water pressure is 200~280bar;Control finishing temperature at 840~880 DEG C;
9) cooling down, the type of cooling is that the mode of section cooling or Water-Curta in Cooling or encryption cooling is cooled to coiling temperature;
10) batch, and to control coiling temperature be 615~645 DEG C;
11) carrying out the austenitizing after uncoiling blanking, control austenitizing temperature is at 930~980 DEG C, and is incubated 6~15 min;
12) mould punching shapes, and pressurize 6~9 s in mould;
13) quench, control quenching rate of cooling at 50~100 DEG C/s;After naturally cool to room temperature.
3. the side produced with the tensile strength >=1700MPa hot forming steel of medium thin slab Direct Rolling as claimed in claim 2
Method, it is characterised in that: the operation of rolling of described medium thin slab is that 6F produces line or 1R+6F produces line or 2R+6F at rolling mill layout
Produce line or 7F produces line or 3R+4F produces line or 2R+5F produces line or 1R+5F produces line and carries out.
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