CN106189848A - A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint - Google Patents
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint Download PDFInfo
- Publication number
- CN106189848A CN106189848A CN201610566629.1A CN201610566629A CN106189848A CN 106189848 A CN106189848 A CN 106189848A CN 201610566629 A CN201610566629 A CN 201610566629A CN 106189848 A CN106189848 A CN 106189848A
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- China
- Prior art keywords
- parts
- raw material
- finish paint
- organic siliconresin
- temperature
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000003973 paint Substances 0.000 title claims abstract description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 12
- 239000010703 silicon Substances 0.000 title claims abstract description 12
- 229920005989 resin Polymers 0.000 title claims abstract description 10
- 239000011347 resin Substances 0.000 title claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 15
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 13
- 239000005011 phenolic resin Substances 0.000 claims abstract description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 10
- 239000000919 ceramic Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000000875 high-speed ball milling Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- -1 poly-ammonia Ester Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000003763 carbonization Methods 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint, relate to chemistry painting industry preparing technical field, be made up of following raw material: organic siliconresin 20 30 parts, modified acrylic acid emulsion 15 25 parts, 10 20 parts of phenolic resin, zinc stearate 15 25 parts, carborundum 8 10 parts, dimethylbenzene 68 parts, M-and P-cresols 24 parts, titanium dioxide 35 parts, Pulvis Talci 68 parts, nanometer calcium powder 57 parts, mica powder 68 parts, ceramics 68 parts, wax liquid 65 75 parts, deionized water 120 130 parts;The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use organic siliconresin and modified acrylic acid emulsion as main material, coordinate the use of remaining auxiliary agent, obtain finish paint, homogeneous, resistance to elevated temperatures is strong, can tolerate 600 DEG C of high temperature through checking, and hardness is high, paint film is the most crisp simultaneously, and adhesive force is strong.
Description
Technical field
The present invention relates to chemistry painting industry preparing technical field, be specifically related to a kind of high-temperature-resistant silicon resin modified acroleic acid face
Paint.
Background technology
Paint is that one can firmly cover at body surface, rises and protect, decorates, indicates and the chemistry of other specific uses is mixed
Compound coating.China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, this
Material can be coated in object surface by different construction technologies, formed adhere to firmly, to have some strength, continuous print solid-state thin
Film.The film common name film so formed, also known as paint film or coating.
Paint, due to the difference of its application, has different component proportioning different performance, is directed in some field, high
Temperature environment, paint must possess resistance to elevated temperatures accordingly, and tradition its cost of heat resistance paint is of a relatively high, and its high temperature holds
Stress is not the strongest, and therefore range is the most extensive.
Summary of the invention:
The technical problem to be solved is to provide a kind of formula reasonable, and production technology is simple, and performance consolidates
High-temperature-resistant silicon resin modified acroleic acid finish paint.
The technical problem to be solved realizes by the following technical solutions:
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint, it is characterised in that: it is made up of following raw material:
Organic siliconresin 20-30 part, modified acrylic acid emulsion 15-25 part, phenolic resin 10-20 part, zinc stearate 15-25
Part, carborundum 8-10 part, dimethylbenzene 6-8 part, M-and P-cresols 2-4 part, titanium dioxide 3-5 part, Pulvis Talci 6-8 part, nanometer calcium powder 5-7
Part, mica powder 6-8 part, ceramics 6-8 part, wax liquid 65-75 part, deionized water 120-130 part.
The preferred component of each raw material is: organic siliconresin 25 parts, modified acrylic acid emulsion 20 parts, 15 parts of phenolic resin, hard
20 parts of ester acid zinc, carborundum 9 parts, dimethylbenzene 7 parts, M-and P-cresols 3 parts, titanium dioxide 4 parts, Pulvis Talci 7 parts, nanometer calcium powder 6 parts, cloud
Female 7 parts of powder, ceramics 7 parts, wax liquid 70 parts, deionized water 125 parts.
Described modified acrylic acid emulsion comprises following raw material: acrylic acid 15kg, silane coupler 8kg, pure-acrylic emulsion
25kg, base polyurethane prepolymer for use as 8kg;
During preparation: after acrylic acid and pure-acrylic emulsion being merged, then heat to 60-65 DEG C, by silane coupler and
Base polyurethane prepolymer for use as is dispersed therein, the most available.
It is a further object to provide a kind of side preparing high-temperature-resistant silicon resin modified acroleic acid finish paint of the present invention
Method, it is characterised in that comprise the following steps:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, will change
Property acrylic emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are closed
After and, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, continuously stirred 10-12min
After, add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500-
3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use organic siliconresin and change
Property acrylic emulsion as main material, coordinate the use of remaining auxiliary agent, obtain finish paint, homogeneous, resistance to elevated temperatures is strong, passes through
Inspection can tolerate 600 DEG C of high temperature, and hardness is high, and paint film is the most crisp simultaneously, and adhesive force is strong.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Close specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh: organic siliconresin 20kg, modified acrylic acid emulsion 15kg, phenolic resin 10kg, zinc stearate 15kg, carbonization
Silicon 8kg, dimethylbenzene 6kg, M-and P-cresols 2kg, titanium dioxide 3kg, Pulvis Talci 6kg, nanometer calcium powder 5kg, mica powder 6kg, ceramics
6kg, wax liquid 65kg, deionized water 120kg.
Embodiment 2
Weigh: organic siliconresin 25kg, modified acrylic acid emulsion 20kg, phenolic resin 15kg, zinc stearate 20kg, carbonization
Silicon 9kg, dimethylbenzene 7kg, M-and P-cresols 3kg, titanium dioxide 4kg, Pulvis Talci 7kg, nanometer calcium powder 6kg, mica powder 7kg, ceramics
7kg, wax liquid 70kg, deionized water 125kg.
The preparation method of above-described embodiment 1 or 2 is as follows:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, will change
Property acrylic emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are closed
After and, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, continuously stirred 10-12min
After, add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500-
3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (3)
1. a high-temperature-resistant silicon resin modified acroleic acid finish paint, it is characterised in that: it is made up of following raw material:
Organic siliconresin 20-30 part, modified acrylic acid emulsion 15-25 part, phenolic resin 10-20 part, zinc stearate 15-25 part,
Carborundum 8-10 part, dimethylbenzene 6-8 part, M-and P-cresols 2-4 part, titanium dioxide 3-5 part, Pulvis Talci 6-8 part, nanometer calcium powder 5-7 part,
Mica powder 6-8 part, ceramics 6-8 part, wax liquid 65-75 part, deionized water 120-130 part;
Preparation method is:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, by modification third
Olefin(e) acid emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are merged
After, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, after continuously stirred 10-12min, then
Add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500-
3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint the most according to claim 1, it is characterised in that each raw material excellent
The component is selected to be: organic siliconresin 25 parts, modified acrylic acid emulsion 20 parts, 15 parts of phenolic resin, zinc stearate 20 parts, carborundum 9
Part, dimethylbenzene 7 parts, M-and P-cresols 3 parts, titanium dioxide 4 parts, Pulvis Talci 7 parts, nanometer calcium powder 6 parts, mica powder 7 parts, ceramics 7 parts,
Wax liquid 70 parts, deionized water 125 parts.
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint the most according to claim 1, it is characterised in that: described modification
Acrylic emulsion comprises following raw material: acrylic acid 15kg, silane coupler 8kg, pure-acrylic emulsion 25kg, base polyurethane prepolymer for use as 8kg;
During preparation: after acrylic acid and pure-acrylic emulsion being merged, then heat to 60-65 DEG C, by silane coupler and poly-ammonia
Ester performed polymer is dispersed therein, the most available.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610566629.1A CN106189848A (en) | 2016-07-18 | 2016-07-18 | A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610566629.1A CN106189848A (en) | 2016-07-18 | 2016-07-18 | A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint |
Publications (1)
Publication Number | Publication Date |
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CN106189848A true CN106189848A (en) | 2016-12-07 |
Family
ID=57494080
Family Applications (1)
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CN201610566629.1A Pending CN106189848A (en) | 2016-07-18 | 2016-07-18 | A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint |
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CN (1) | CN106189848A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106883701A (en) * | 2017-03-07 | 2017-06-23 | 沈阳宣伯新材料科技有限公司 | The heavy antisepsis of resistance to dust storm wind power equipment waterborne metallic paint |
CN107227099A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of air compressor wear resistant fire-retardant coating and preparation method thereof |
CN107236388A (en) * | 2017-07-25 | 2017-10-10 | 合肥欧仕嘉机电设备有限公司 | A kind of thermostable heat-isolating coating and preparation method thereof |
CN107997888A (en) * | 2017-11-30 | 2018-05-08 | 张磊 | A kind of Medical patient transfer car(buggy) clamping device |
CN108078689A (en) * | 2017-11-30 | 2018-05-29 | 张磊 | A kind of Medical patient transfer car(buggy) elevator mechanism |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106883701A (en) * | 2017-03-07 | 2017-06-23 | 沈阳宣伯新材料科技有限公司 | The heavy antisepsis of resistance to dust storm wind power equipment waterborne metallic paint |
CN107227099A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of air compressor wear resistant fire-retardant coating and preparation method thereof |
CN107236388A (en) * | 2017-07-25 | 2017-10-10 | 合肥欧仕嘉机电设备有限公司 | A kind of thermostable heat-isolating coating and preparation method thereof |
CN107997888A (en) * | 2017-11-30 | 2018-05-08 | 张磊 | A kind of Medical patient transfer car(buggy) clamping device |
CN108078689A (en) * | 2017-11-30 | 2018-05-29 | 张磊 | A kind of Medical patient transfer car(buggy) elevator mechanism |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
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RJ01 | Rejection of invention patent application after publication |