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CN106189848A - A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint - Google Patents

A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint Download PDF

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Publication number
CN106189848A
CN106189848A CN201610566629.1A CN201610566629A CN106189848A CN 106189848 A CN106189848 A CN 106189848A CN 201610566629 A CN201610566629 A CN 201610566629A CN 106189848 A CN106189848 A CN 106189848A
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CN
China
Prior art keywords
parts
raw material
finish paint
organic siliconresin
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610566629.1A
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Chinese (zh)
Inventor
董鸿梅
孙巨福
戴宇钧
汪鹏程
祝盆鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Julong Car and Ship Coating Co Ltd
Original Assignee
Tianchang Julong Car and Ship Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Julong Car and Ship Coating Co Ltd filed Critical Tianchang Julong Car and Ship Coating Co Ltd
Priority to CN201610566629.1A priority Critical patent/CN106189848A/en
Publication of CN106189848A publication Critical patent/CN106189848A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06Waxes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint, relate to chemistry painting industry preparing technical field, be made up of following raw material: organic siliconresin 20 30 parts, modified acrylic acid emulsion 15 25 parts, 10 20 parts of phenolic resin, zinc stearate 15 25 parts, carborundum 8 10 parts, dimethylbenzene 68 parts, M-and P-cresols 24 parts, titanium dioxide 35 parts, Pulvis Talci 68 parts, nanometer calcium powder 57 parts, mica powder 68 parts, ceramics 68 parts, wax liquid 65 75 parts, deionized water 120 130 parts;The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use organic siliconresin and modified acrylic acid emulsion as main material, coordinate the use of remaining auxiliary agent, obtain finish paint, homogeneous, resistance to elevated temperatures is strong, can tolerate 600 DEG C of high temperature through checking, and hardness is high, paint film is the most crisp simultaneously, and adhesive force is strong.

Description

A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint
Technical field
The present invention relates to chemistry painting industry preparing technical field, be specifically related to a kind of high-temperature-resistant silicon resin modified acroleic acid face Paint.
Background technology
Paint is that one can firmly cover at body surface, rises and protect, decorates, indicates and the chemistry of other specific uses is mixed Compound coating.China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, this Material can be coated in object surface by different construction technologies, formed adhere to firmly, to have some strength, continuous print solid-state thin Film.The film common name film so formed, also known as paint film or coating.
Paint, due to the difference of its application, has different component proportioning different performance, is directed in some field, high Temperature environment, paint must possess resistance to elevated temperatures accordingly, and tradition its cost of heat resistance paint is of a relatively high, and its high temperature holds Stress is not the strongest, and therefore range is the most extensive.
Summary of the invention:
The technical problem to be solved is to provide a kind of formula reasonable, and production technology is simple, and performance consolidates High-temperature-resistant silicon resin modified acroleic acid finish paint.
The technical problem to be solved realizes by the following technical solutions:
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint, it is characterised in that: it is made up of following raw material:
Organic siliconresin 20-30 part, modified acrylic acid emulsion 15-25 part, phenolic resin 10-20 part, zinc stearate 15-25 Part, carborundum 8-10 part, dimethylbenzene 6-8 part, M-and P-cresols 2-4 part, titanium dioxide 3-5 part, Pulvis Talci 6-8 part, nanometer calcium powder 5-7 Part, mica powder 6-8 part, ceramics 6-8 part, wax liquid 65-75 part, deionized water 120-130 part.
The preferred component of each raw material is: organic siliconresin 25 parts, modified acrylic acid emulsion 20 parts, 15 parts of phenolic resin, hard 20 parts of ester acid zinc, carborundum 9 parts, dimethylbenzene 7 parts, M-and P-cresols 3 parts, titanium dioxide 4 parts, Pulvis Talci 7 parts, nanometer calcium powder 6 parts, cloud Female 7 parts of powder, ceramics 7 parts, wax liquid 70 parts, deionized water 125 parts.
Described modified acrylic acid emulsion comprises following raw material: acrylic acid 15kg, silane coupler 8kg, pure-acrylic emulsion 25kg, base polyurethane prepolymer for use as 8kg;
During preparation: after acrylic acid and pure-acrylic emulsion being merged, then heat to 60-65 DEG C, by silane coupler and Base polyurethane prepolymer for use as is dispersed therein, the most available.
It is a further object to provide a kind of side preparing high-temperature-resistant silicon resin modified acroleic acid finish paint of the present invention Method, it is characterised in that comprise the following steps:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, will change Property acrylic emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are closed After and, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, continuously stirred 10-12min After, add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500- 3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use organic siliconresin and change Property acrylic emulsion as main material, coordinate the use of remaining auxiliary agent, obtain finish paint, homogeneous, resistance to elevated temperatures is strong, passes through Inspection can tolerate 600 DEG C of high temperature, and hardness is high, and paint film is the most crisp simultaneously, and adhesive force is strong.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh: organic siliconresin 20kg, modified acrylic acid emulsion 15kg, phenolic resin 10kg, zinc stearate 15kg, carbonization Silicon 8kg, dimethylbenzene 6kg, M-and P-cresols 2kg, titanium dioxide 3kg, Pulvis Talci 6kg, nanometer calcium powder 5kg, mica powder 6kg, ceramics 6kg, wax liquid 65kg, deionized water 120kg.
Embodiment 2
Weigh: organic siliconresin 25kg, modified acrylic acid emulsion 20kg, phenolic resin 15kg, zinc stearate 20kg, carbonization Silicon 9kg, dimethylbenzene 7kg, M-and P-cresols 3kg, titanium dioxide 4kg, Pulvis Talci 7kg, nanometer calcium powder 6kg, mica powder 7kg, ceramics 7kg, wax liquid 70kg, deionized water 125kg.
The preparation method of above-described embodiment 1 or 2 is as follows:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, will change Property acrylic emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are closed After and, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, continuously stirred 10-12min After, add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500- 3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (3)

1. a high-temperature-resistant silicon resin modified acroleic acid finish paint, it is characterised in that: it is made up of following raw material:
Organic siliconresin 20-30 part, modified acrylic acid emulsion 15-25 part, phenolic resin 10-20 part, zinc stearate 15-25 part, Carborundum 8-10 part, dimethylbenzene 6-8 part, M-and P-cresols 2-4 part, titanium dioxide 3-5 part, Pulvis Talci 6-8 part, nanometer calcium powder 5-7 part, Mica powder 6-8 part, ceramics 6-8 part, wax liquid 65-75 part, deionized water 120-130 part;
Preparation method is:
(1) select Scattered Kettle, above-mentioned organic siliconresin and phenolic resin are added thereto, after being uniformly mixed, by modification third Olefin(e) acid emulsion is added thereto, and high-speed stirred is until after organic siliconresin and phenolic resin is all dispersed therein, standby;
(2) zinc stearate, carborundum, M-and P-cresols, titanium dioxide, Pulvis Talci, nanometer calcium powder, mica powder and ceramics are merged After, carrying out being milled to fineness of the particles is 25-35um;
(3) dimethylbenzene in raw material is added in stirred tank, then add deionized water, after continuously stirred 10-12min, then Add wax liquid, after being again stirring for 35min, standby;
(4) raw material obtained in above-mentioned steps 1,2 and 3 is thrown to ball mill, the rotating speed of ball mill is controlled at 2500- 3500r/min, high speed ball milling is until fineness of the particles is less than after 20um, and discharging, packaging is the most available.
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint the most according to claim 1, it is characterised in that each raw material excellent The component is selected to be: organic siliconresin 25 parts, modified acrylic acid emulsion 20 parts, 15 parts of phenolic resin, zinc stearate 20 parts, carborundum 9 Part, dimethylbenzene 7 parts, M-and P-cresols 3 parts, titanium dioxide 4 parts, Pulvis Talci 7 parts, nanometer calcium powder 6 parts, mica powder 7 parts, ceramics 7 parts, Wax liquid 70 parts, deionized water 125 parts.
A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint the most according to claim 1, it is characterised in that: described modification Acrylic emulsion comprises following raw material: acrylic acid 15kg, silane coupler 8kg, pure-acrylic emulsion 25kg, base polyurethane prepolymer for use as 8kg;
During preparation: after acrylic acid and pure-acrylic emulsion being merged, then heat to 60-65 DEG C, by silane coupler and poly-ammonia Ester performed polymer is dispersed therein, the most available.
CN201610566629.1A 2016-07-18 2016-07-18 A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint Pending CN106189848A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610566629.1A CN106189848A (en) 2016-07-18 2016-07-18 A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610566629.1A CN106189848A (en) 2016-07-18 2016-07-18 A kind of high-temperature-resistant silicon resin modified acroleic acid finish paint

Publications (1)

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CN106189848A true CN106189848A (en) 2016-12-07

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883701A (en) * 2017-03-07 2017-06-23 沈阳宣伯新材料科技有限公司 The heavy antisepsis of resistance to dust storm wind power equipment waterborne metallic paint
CN107227099A (en) * 2017-07-25 2017-10-03 合肥欧仕嘉机电设备有限公司 A kind of air compressor wear resistant fire-retardant coating and preparation method thereof
CN107236388A (en) * 2017-07-25 2017-10-10 合肥欧仕嘉机电设备有限公司 A kind of thermostable heat-isolating coating and preparation method thereof
CN107997888A (en) * 2017-11-30 2018-05-08 张磊 A kind of Medical patient transfer car(buggy) clamping device
CN108078689A (en) * 2017-11-30 2018-05-29 张磊 A kind of Medical patient transfer car(buggy) elevator mechanism

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101724330A (en) * 2009-12-02 2010-06-09 天津大学 Heat and humidity resistant acrylic acid/phenolic resin/nano-SiO2 coating for metal film resistor and preparation method thereof
CN102020897A (en) * 2009-09-16 2011-04-20 北京有色金属研究总院 Corrosion resistant paint for the inner surface of radiator and preparation method thereof
WO2012064081A2 (en) * 2010-11-08 2012-05-18 Son Sang Dal Underwater antifouling coating sheet and coating method
CN103694840A (en) * 2013-12-04 2014-04-02 铜陵三佳变压器有限责任公司 High-temperature-resistant wire coating enamel for electric reactor and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020897A (en) * 2009-09-16 2011-04-20 北京有色金属研究总院 Corrosion resistant paint for the inner surface of radiator and preparation method thereof
CN101724330A (en) * 2009-12-02 2010-06-09 天津大学 Heat and humidity resistant acrylic acid/phenolic resin/nano-SiO2 coating for metal film resistor and preparation method thereof
WO2012064081A2 (en) * 2010-11-08 2012-05-18 Son Sang Dal Underwater antifouling coating sheet and coating method
CN103694840A (en) * 2013-12-04 2014-04-02 铜陵三佳变压器有限责任公司 High-temperature-resistant wire coating enamel for electric reactor and preparation method thereof

Non-Patent Citations (1)

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Title
金勇等: "聚氨酯改性丙烯酸树脂涂饰剂概述", 《皮革化工》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883701A (en) * 2017-03-07 2017-06-23 沈阳宣伯新材料科技有限公司 The heavy antisepsis of resistance to dust storm wind power equipment waterborne metallic paint
CN107227099A (en) * 2017-07-25 2017-10-03 合肥欧仕嘉机电设备有限公司 A kind of air compressor wear resistant fire-retardant coating and preparation method thereof
CN107236388A (en) * 2017-07-25 2017-10-10 合肥欧仕嘉机电设备有限公司 A kind of thermostable heat-isolating coating and preparation method thereof
CN107997888A (en) * 2017-11-30 2018-05-08 张磊 A kind of Medical patient transfer car(buggy) clamping device
CN108078689A (en) * 2017-11-30 2018-05-29 张磊 A kind of Medical patient transfer car(buggy) elevator mechanism

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Application publication date: 20161207

RJ01 Rejection of invention patent application after publication