[go: up one dir, main page]

CN106189612A - A kind of solar selective heat-absorbing paint - Google Patents

A kind of solar selective heat-absorbing paint Download PDF

Info

Publication number
CN106189612A
CN106189612A CN201610558074.6A CN201610558074A CN106189612A CN 106189612 A CN106189612 A CN 106189612A CN 201610558074 A CN201610558074 A CN 201610558074A CN 106189612 A CN106189612 A CN 106189612A
Authority
CN
China
Prior art keywords
parts
modified
acrylate
emulsion
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610558074.6A
Other languages
Chinese (zh)
Inventor
蒙献芳
金建荣
陈会杰
黄可煜
莫小青
周帆
谢刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanning Keyu Energy Technology Co Ltd
Original Assignee
Nanning Keyu Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanning Keyu Energy Technology Co Ltd filed Critical Nanning Keyu Energy Technology Co Ltd
Priority to CN201610558074.6A priority Critical patent/CN106189612A/en
Publication of CN106189612A publication Critical patent/CN106189612A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of solar selective heat-absorbing paint, this solar energy heat absorbing coating is made up of each component of following weight: acrylate modified complex emulsions 25~35 parts, fluorocarbon surfactant 2~6 parts, nano titanium oxide and carbon nanotube mixture 2~8 parts, 7 12 parts of firming agent, nano-nickel powder/carbon mano-tube composite 35 55 parts, absorption enhancer 13 parts, solvent 10 20 parts, sodium lauryl sulphate and Polyethylene Glycol or polyvinylpyrrolidone mixture 5~10 parts, conditioning agent 0.1~0.3 part, dispersant 0.3~0.7 part, defoamer 0.2~0.4 part, thickening agent 0.5~0.7 part, antioxidant 0.2~0.6 part, glass fibre 0.4~0.8 part, emulsified wax 0.4~0.6 part.The present invention, by being modified acrylic acid, can make the coating made have good weatherability and water proofing property under outdoor conditions, and preparation technology is easily understood, it is ensured that the heat absorption efficiency of heat-absorbing paint.

Description

A kind of solar selective heat-absorbing paint
Technical field
The present invention relates to field of solar energy utilization, particularly relate to a kind of solar selective heat-absorbing paint.
Background technology
Solar energy optical-thermal application be human use's solar energy the most simply, the most directly, one of most efficient method, but due to too After sun can arrive the earth, energy density is less discontinuous again, therefore, brings difficulty for large-scale exploitation.For a long time with Come, how low-grade solar energy is converted into high-grade heat energy, and solar energy is enriched with, in order to land productivity to greatest extent With solar energy, become the hot issue of research.In the middle of existing Photo-thermal technology application technology, coating for selective absorption technology is recognized For being the technology of the most more core, it is to improving solar heat conversion efficiency, and the application of large-scale promotion solar energy optical-thermal plays Vital effect.
It is known that solar energy absorbing coating is broadly divided into spectral selective absorbing coating and high-absorbility absorber coatings, Spectral selection heat absorbing coating is that one has a visible near infrared light high-selenium corn, the special coating to the reflection of infrared light height, I.e. it can effectively absorb solar energy, and the heat loss that after being heated, self long wave causes is the least, is widely used in solar energy optical-thermal Conversion, such as solar water heater, solar electrical energy generation etc..Solar energy heat absorbing coating is responsible for reception and absorbs the important of solar energy Effect, affects stability and the height of efficiency of whole solar energy heat absorbing system.Solar energy heat absorbing coating is a kind of functional Coating, solar radiant energy is converted into heat energy by the film made with it, and film works under outdoor conditions, it is necessary to have good weather-proof Property and water proofing property.
Summary of the invention
The technical problem to be solved is to provide a kind of solar selective heat-absorbing paint, it is possible to solve heat absorption Coating weatherability and the problem of water proofing property difference, and can guarantee that heat absorption efficiency.
The present invention adopts the following technical scheme that
A kind of solar selective heat-absorbing paint, it is characterised in that: this coating includes each component system of following weight Become: acrylate modified complex emulsions 25~35 parts, fluorocarbon surfactant 2~6 parts, nano titanium oxide and CNT Mixture 2~8 parts, firming agent 7-12 part, nano-nickel powder/carbon mano-tube composite 35-55 part, absorption enhancer 1-3 part is molten Agent 10-20 part, sodium lauryl sulphate and Polyethylene Glycol or polyvinylpyrrolidone mixture 5~10 parts, conditioning agent 0.1~ 0.3 part, dispersant 0.3~0.7 part, defoamer 0.2~0.4 part, thickening agent 0.5~0.7 part, antioxidant 0.2~0.6 part, Glass fibre 0.4~0.8 part, emulsified wax 0.4~0.6 part;After the method that mentioned component utilizes ball milling is uniformly dispersed, then add Enter coalescents mix homogeneously, i.e. can get solar selective heat-absorbing paint.
Preferably technical scheme is: described acrylate modified complex emulsions is 7~8 parts of acrylic acid ester emulsions, 6~8 Part polyurethane-modified polyacrylate emulsion, 6~10 parts of epoxy resin modification acrylic acid ester emulsions, 6~9 parts of organic-silicon-modified propylene Acid esters emulsion is composited.
In the present invention, further, described solvent is ethanol, propylene glycol or ethylene glycol.
In the present invention, further, described polyurethane-modified polyacrylate emulsion, its preparation method is: at nitrogen atmosphere In, the acrylate of 5~6 mass fractions is heated, after stirring and dissolving, obtains the first reactant liquor;Described first reactant liquor adds Enter the polyurethane of 1~2 mass fractions, add water mixing, be uniformly mixing to obtain polyurethane-modified polyacrylate emulsion.
In the present invention, further, described epoxy resin modification acrylic acid ester emulsion, its preparation method is: in blanket of nitrogen In enclosing, the acrylate of 5~8 mass fractions is heated, after stirring and dissolving, obtains the first reactant liquor;In described first reactant liquor Add the epoxy resin of 1~2 mass fractions, add water mixing, be uniformly mixing to obtain epoxy resin modification acrylic acid ester emulsion.
In the present invention, further, described organosilicon-modified acrylate emulsion, its preparation method is: at nitrogen atmosphere In, the acrylate of 5~7 mass fractions is heated, after stirring and dissolving, obtains the first reactant liquor;Described first reactant liquor adds Enter the organosilicon of 1~2 mass fractions, add water mixing, be uniformly mixing to obtain organosilicon-modified acrylate emulsion.
In the present invention, further, in described polyurethane-modified polyacrylate emulsion preparation method, described heating-up temperature is 70 DEG C~80 DEG C;The speed of described stirring is 100~150r/min;The time of described stirring is 6~10 min.
In the present invention, further, in described epoxy resin modification acrylic acid ester emulsion preparation method, described heating-up temperature It it is 70 DEG C~80 DEG C;The speed of described stirring is 100~150r/min;The time of described stirring is 6~10 min.
In the present invention, further, in described organosilicon-modified acrylate emulsion preparation method, described heating-up temperature is 70 DEG C~80 DEG C;The speed of described stirring is 100~150r/min;The time of described stirring is 6~10 min.
In the present invention, further, in described polyurethane-modified polyacrylate emulsion preparation method, the weight of described addition water Amount is polyurethane and the 0.2~0.6 of acrylate gross weight.
In the present invention, further, in described epoxy resin modification acrylic acid ester emulsion preparation method, described addition water Weight is the 0.2~0.6 of epoxy resin and acrylate gross weight.
In the present invention, further, in described organosilicon-modified acrylate emulsion preparation method, the weight of described addition water Amount is organosilicon and the 0.2~0.6 of acrylate gross weight.
This most compared with prior art, the device have the advantages that into:
1, due to fluorine compounds, there is the performances such as good stability, weatherability, corrosion resistance, non-oxidizability, therefore fluorine carbon table Face activating agent can modified acrylate emulsion so that it is have good weather resistance, chemical stability, water resistance.It addition, Fluorocarbon surfactant is not only a kind of superpower water-repelling agent, and film coated surface can be made to have ultra-low surface energy, and dust is difficult to stick, Strengthen the anti-contamination capability of coating;Itself or the levelling agent of a kind of coating, it is possible to accelerate levelling speed and the wetting speed of coating, Coating is promoted to form a film smooth, smooth, uniform during drying and forming-film.
2, in the present invention, adding acrylate modified complex emulsions, wherein polyurethane-modified polyacrylate emulsion has good The features such as pliability well, lower temperature resistance, resistance to water, resistance to ag(e)ing, bin stability, make the combination property of film carry significantly High;Epoxy resin has good to steam and the shielding of oxygen, and adhesive force is good, shrinkage factor is low, the most modified breast Liquid had both had good film-forming property, adhesive force by force, improved again weather-proof ability;Organosilicon has heat-resisting, antioxidation, stain resistant, radiation hardness Etc. performance, the most modified emulsion had both had good film property, improve again the adhesive force of film, resistance to ag(e)ing, anti-contamination Property, resistance to water, mechanical strength.
3, the preparation technology of the present invention is simple, understandable, and feasibility is high, and test proves that coating absorbs after being coated Visible ray is high with infrared light performance, and heat conductivity is high, and water proofing property is strong, high temperature resistant, corrosion-resistant, and stability is high, and emissivity is low, transmission Rate is high, and coating adhesion is strong, and density is high, is preferable panel solar heat-absorbing paint, has great promotional value.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close concrete example, the present invention is expanded on further.
Embodiment 1.
A kind of solar selective heat-absorbing paint, raw materials quality number is:
Acrylate modified complex emulsions: 7kg acrylic acid ester emulsion, 6kg polyurethane-modified polyacrylate emulsion, 6kg asphalt mixtures modified by epoxy resin Fat modified acrylate emulsion, 6kg organosilicon-modified acrylate emulsion
Fluorocarbon surfactant 2kg
Nano modified material: nano titanium oxide 1kg, carbon nanotube mixture 1kg
Firming agent 7kg
Absorbent: nano-nickel powder 20kg, CNT 15kg
Absorption enhancer 1kg
Solvent: ethanol 10kg
Coalescents 5kg, conditioning agent 0.1kg
Dispersant: sodium lauryl sulphate 0.1kg, Polyethylene Glycol or polyvinylpyrrolidone 0.2kg
Defoamer 0.2kg, thickening agent 0.5kg, antioxidant 0.2kg, glass fibre 0.4kg, emulsified wax 0.4kg;
The step preparing modified acrylate emulsion according to above-mentioned raw material is as follows:
(1) preparation method of polyurethane-modified polyacrylate emulsion is: in nitrogen atmosphere, and the acrylate of 5kg is heated 70 DEG C, mixing speed is 100r/min, and the time of stirring is 6min, obtains the first reactant liquor after dissolving;At described first reactant liquor The polyurethane of middle addition 1 mass fraction, adds the mixing of 1.2kg water, is uniformly mixing to obtain polyurethane-modified polyacrylate emulsion;
The preparation method of epoxy resin modification acrylic acid ester emulsion is: in nitrogen atmosphere, and the acrylate of 5kg is heated 70 DEG C, mixing speed is 100r/min, and the time of stirring is 6 min, obtains the first reactant liquor after dissolving;At described first reactant liquor The epoxy resin of middle addition 1 mass fraction, adds the mixing of 1.2kg water, is uniformly mixing to obtain epoxy resin modification acrylate breast Liquid;
The preparation method of organosilicon-modified acrylate emulsion is: in nitrogen atmosphere, and the acrylate of 5kg is heated 70 DEG C, Mixing speed is 100r/min, and the time of stirring is 6 min, obtains the first reactant liquor after dissolving;In described first reactant liquor Add the organosilicon of 1 mass fraction, add the mixing of 1.2kg water, be uniformly mixing to obtain organosilicon-modified acrylate emulsion;
(2) according to ratio of weight and number, by acrylate modified complex emulsions, fluorocarbon surfactant, nano modified material, solidification Agent, absorbent, absorption enhancer, solvent, conditioning agent, dispersant, defoamer, thickening agent, antioxidant, glass fibre, emulsifying Paraffin puts in ball mill, starts ball mill and carries out after each raw material ball milling is uniformly dispersed by ball milling operation 5min, adding into After film auxiliary agent mix homogeneously, i.e. can get solar selective heat-absorbing paint.
Embodiment 2.
A kind of solar selective heat-absorbing paint, raw materials quality mark is:
Acrylate modified complex emulsions: 8kg acrylic acid ester emulsion, 8kg polyurethane-modified polyacrylate emulsion, 10kg asphalt mixtures modified by epoxy resin Fat modified acrylate emulsion, 9kg organosilicon-modified acrylate emulsion
Fluorocarbon surfactant 6kg
Nano modified material: nano titanium oxide 4kg, carbon nanotube mixture 4kg
Firming agent 12kg
Absorbent: nano-nickel powder 30kg, CNT 25kg
Absorption enhancer 3kg
Solvent: propylene glycol 20kg
Coalescents 10kg, conditioning agent 0.3kg
Dispersant: sodium lauryl sulphate 0.4kg, Polyethylene Glycol or polyvinylpyrrolidone 0.3kg
Defoamer 0.4kg, thickening agent 0.7kg, antioxidant 0.6kg, glass fibre 0.8kg, emulsified wax 0.6kg;
The step preparing modified acrylate emulsion according to above-mentioned raw material is as follows:
(1) preparation method of polyurethane-modified polyacrylate emulsion is: in nitrogen atmosphere, and the acrylate of 6kg is heated 80 DEG C, mixing speed is 150r/min, and the time of stirring is 10 min, obtains the first reactant liquor after dissolving;React described first Liquid adds the polyurethane of 2 mass fractions, adds the mixing of 4.8kg water, be uniformly mixing to obtain polyurethane-modified polyacrylate emulsion;
The preparation method of epoxy resin modification acrylic acid ester emulsion is: in nitrogen atmosphere, and the acrylate of 8kg is heated 80 DEG C, mixing speed is 150r/min, and the time of stirring is 10 min, obtains the first reactant liquor after dissolving;React described first Liquid adds the epoxy resin of 2 mass fractions, adds the mixing of 6.0kg water, be uniformly mixing to obtain epoxy resin modification acrylate Emulsion;
The preparation method of organosilicon-modified acrylate emulsion is: in nitrogen atmosphere, and the acrylate of 7kg is heated 80 DEG C, Mixing speed is 150r/min, and the time of stirring is 10 min, obtains the first reactant liquor after dissolving;In described first reactant liquor Add the organosilicon of 2 mass fractions, add the mixing of 5.4g water, be uniformly mixing to obtain organosilicon-modified acrylate emulsion;
(3) according to ratio of weight and number, by acrylate modified complex emulsions, fluorocarbon surfactant, nano modified material, solidification Agent, absorbent, absorption enhancer, solvent, conditioning agent, dispersant, defoamer, thickening agent, antioxidant, glass fibre, emulsifying Paraffin puts in ball mill, starts ball mill and carries out after each raw material ball milling is uniformly dispersed by ball milling operation 15min, adding into After film auxiliary agent mix homogeneously, i.e. can get solar selective heat-absorbing paint.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any Those familiar with the art, in the technical scope that the invention discloses, can readily occur in change or replace, should contain Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with described scope of the claims.

Claims (7)

1. a solar selective heat-absorbing paint, it is characterised in that: this coating includes that each component of following parts by weight is made: Acrylate modified complex emulsions 25~35 parts, fluorocarbon surfactant 2~6 parts, nano titanium oxide and CNT mixing Thing 2~8 parts, firming agent 7-12 part, nano-nickel powder and carbon mano-tube composite 35-55 part, absorption enhancer 1-3 part, solvent 10- 20 parts, sodium lauryl sulphate and Polyethylene Glycol or polyvinylpyrrolidone mixture 5~10 parts, conditioning agent 0.1~0.3 part, Dispersant 0.3~0.7 part, defoamer 0.2~0.4 part, thickening agent 0.5~0.7 part, antioxidant 0.2~0.6 part, glass fibers Tie up 0.4~0.8 part, emulsified wax 0.4~0.6 part;After the method that mentioned component utilizes ball milling is uniformly dispersed, add film forming Auxiliary agent mix homogeneously, i.e. can get solar selective heat-absorbing paint.
Solar selective heat-absorbing paint the most according to claim 1, it is characterised in that: by weight, described propylene Acid esters modification complex emulsions is by 7~8 parts of acrylic acid ester emulsions, 6~8 parts of polyurethane-modified polyacrylate emulsions, 6~10 parts of epoxies Resin modified acrylic acid ester emulsion, 6~9 parts of organosilicon-modified acrylate emulsions are composited.
Solar selective heat-absorbing paint the most according to claim 1, it is characterised in that: described solvent is ethanol, propylene glycol Or ethylene glycol.
Solar selective heat-absorbing paint the most according to claim 1, it is characterised in that: described polyurethane-modified polyacrylate Emulsion, its preparation method is: in nitrogen atmosphere, is heated the acrylate of 5~6 mass fractions, obtains the after stirring and dissolving One reactant liquor;In described first reactant liquor, add the polyurethane of 1~2 mass fractions, add water mixing, be uniformly mixing to obtain poly- Urethane modified acrylate ester emulsion;Described epoxy resin modification acrylic acid ester emulsion, its preparation method is: in nitrogen atmosphere, The acrylate of 5~8 mass fractions is heated, after stirring and dissolving, obtains the first reactant liquor;1 is added in described first reactant liquor ~2 epoxy resin of mass fraction, add water mixing, be uniformly mixing to obtain epoxy resin modification acrylic acid ester emulsion;Described have Machine acrylate emulsion modified with organosiloxane, its preparation method is: in nitrogen atmosphere, is heated by the acrylate of 5~7 mass fractions, The first reactant liquor is obtained after stirring and dissolving;In described first reactant liquor, add the organosilicon of 1~2 mass fractions, add water and mix Close, be uniformly mixing to obtain organosilicon-modified acrylate emulsion.
Solar selective heat-absorbing paint the most according to claim 4, it is characterised in that: described polyurethane-modified polyacrylate In emulsion preparation method, heating-up temperature is 70 DEG C~80 DEG C;In described epoxy resin modification acrylic acid ester emulsion preparation method, add Hot temperature is 70 DEG C~80 DEG C;In described organosilicon-modified acrylate emulsion preparation method, heating-up temperature is 70 DEG C~80 DEG C.
Solar selective heat-absorbing paint the most according to claim 4, it is characterised in that: described acrylate modified Composite Milk In liquid and preparation method thereof, the speed of described stirring is 100~150r/min, and the time of described stirring is 6~10 min;Described epoxy In resin modified acrylic acid ester emulsion preparation method, the speed of described stirring is 100~150r/min, and the time of described stirring is 6~10 min;In described organosilicon-modified acrylate emulsion preparation method, the speed of described stirring is 100~150r/min, The time of described stirring is 6~10 min.
Solar selective heat-absorbing paint the most according to claim 4, it is characterised in that: described polyurethane-modified polyacrylate In emulsion preparation method, the weight of described addition water is the 0.2~0.6 of polyurethane and acrylate gross weight;Described asphalt mixtures modified by epoxy resin In fat modified acrylate emulsion preparation method, weight is epoxy resin and acrylate gross weight the 0.2 of described addition water ~0.6;In described organosilicon-modified acrylate emulsion preparation method, the weight of described addition water is organosilicon and acrylate The 0.2~0.6 of gross weight.
CN201610558074.6A 2016-07-15 2016-07-15 A kind of solar selective heat-absorbing paint Pending CN106189612A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610558074.6A CN106189612A (en) 2016-07-15 2016-07-15 A kind of solar selective heat-absorbing paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610558074.6A CN106189612A (en) 2016-07-15 2016-07-15 A kind of solar selective heat-absorbing paint

Publications (1)

Publication Number Publication Date
CN106189612A true CN106189612A (en) 2016-12-07

Family

ID=57474999

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610558074.6A Pending CN106189612A (en) 2016-07-15 2016-07-15 A kind of solar selective heat-absorbing paint

Country Status (1)

Country Link
CN (1) CN106189612A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107090220A (en) * 2017-06-21 2017-08-25 合肥嘉仕诚能源科技有限公司 A kind of solar energy heat absorbing coating and preparation method thereof
CN107177262A (en) * 2017-07-25 2017-09-19 合肥嘉仕诚能源科技有限公司 A kind of nanometer matrix solar energy heat absorbing coating and preparation method thereof
CN113249010A (en) * 2021-05-18 2021-08-13 深圳优易材料科技有限公司 Coating for reducing adhesion of fly ash and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60156771A (en) * 1984-01-25 1985-08-16 Matsushita Electric Works Ltd Coating composition for solar heat energy selective absorption
CN101705037A (en) * 2009-11-19 2010-05-12 上海第二工业大学 Method for preparing solar selective heat-absorbing paint
CN104151880A (en) * 2014-08-18 2014-11-19 太仓派欧技术咨询服务有限公司 Nanometer carbon powder modified solar heat absorption coating
CN105199529A (en) * 2015-10-30 2015-12-30 桂林市和鑫防水装饰材料有限公司 Modified acrylic ester waterproof coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60156771A (en) * 1984-01-25 1985-08-16 Matsushita Electric Works Ltd Coating composition for solar heat energy selective absorption
CN101705037A (en) * 2009-11-19 2010-05-12 上海第二工业大学 Method for preparing solar selective heat-absorbing paint
CN104151880A (en) * 2014-08-18 2014-11-19 太仓派欧技术咨询服务有限公司 Nanometer carbon powder modified solar heat absorption coating
CN105199529A (en) * 2015-10-30 2015-12-30 桂林市和鑫防水装饰材料有限公司 Modified acrylic ester waterproof coating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107090220A (en) * 2017-06-21 2017-08-25 合肥嘉仕诚能源科技有限公司 A kind of solar energy heat absorbing coating and preparation method thereof
CN107177262A (en) * 2017-07-25 2017-09-19 合肥嘉仕诚能源科技有限公司 A kind of nanometer matrix solar energy heat absorbing coating and preparation method thereof
CN113249010A (en) * 2021-05-18 2021-08-13 深圳优易材料科技有限公司 Coating for reducing adhesion of fly ash and preparation method and application thereof
CN113249010B (en) * 2021-05-18 2022-02-08 深圳优易材料科技有限公司 Coating for reducing adhesion of fly ash and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN106010241A (en) Solar heat-absorbing paint
CN106010034A (en) Solar heat-absorbing paint with high weatherability
CN105331220B (en) A kind of composite metal roof insulation water-repellent paint and preparation method thereof
CN102585697B (en) Nuclear radiation-resistant coating and preparation method thereof
CN106433537A (en) Modified epoxy adhesive and preparing method thereof
CN102533011B (en) Thermosetting reflection thermal insulation coating and preparation method thereof
CN106700789A (en) Waterborne energy-saving building coating and preparation method thereof
CN103483963B (en) A kind of multi-functional batch of scratch-type single, double component heat insulating coatings and preparation method thereof
CN106189612A (en) A kind of solar selective heat-absorbing paint
CN105860777A (en) Nano modified solar heat-absorbing paint
CN106010032A (en) Colorful modified acrylate solar heat-absorbing coating
CN105419531A (en) Preparing method of superhigh-sunshine reflectance ratio coating
CN107177262A (en) A kind of nanometer matrix solar energy heat absorbing coating and preparation method thereof
CN103146290B (en) Preparation method for aqueous composite thermal insulation coating
CN106010033A (en) Solar endothermic paint
CN106047002A (en) Method for preparing solar-energy heat-absorbing coating by utilizing spinel type pigment as heat absorbent
CN106010031A (en) Modified acrylate solar heat absorbing coating
CN106189611A (en) A kind of environment protection solar heat-absorbing paint
CN110180769B (en) Weather resistance strengthening treatment method for reinforced concrete plastic-stone rockery in classical garden
CN107286799A (en) Water-based heat insulation coating and preparation method thereof
CN104356940A (en) Solar heat-absorbing paint and preparation method thereof
CN102260442A (en) Water-based solar heat radiation reflective paint and preparation process thereof
CN103897577A (en) Glass paint and preparation method thereof
CN105366987A (en) Water repellent agent for foam concrete
CN105569200A (en) Glass cotton and silica-alumina aerogel composite sandwich thermal-insulating and fireproof board

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161207

RJ01 Rejection of invention patent application after publication