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CN106178892A - Exhaust gas treating method and system are reclaimed in a kind of enamel-covered wire pyrolysis - Google Patents

Exhaust gas treating method and system are reclaimed in a kind of enamel-covered wire pyrolysis Download PDF

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Publication number
CN106178892A
CN106178892A CN201610719609.3A CN201610719609A CN106178892A CN 106178892 A CN106178892 A CN 106178892A CN 201610719609 A CN201610719609 A CN 201610719609A CN 106178892 A CN106178892 A CN 106178892A
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China
Prior art keywords
gas
enamel
reclaimed
covered wire
pyrolysis
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Inventor
戴煜
姜纯
羊建高
冯建光
周强
刘先国
宋巧雨
蒋振宇
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Anhui Truchum Advanced Materials And Technology Co Ltd
Advanced Corp for Materials and Equipments Co Ltd
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Anhui Truchum Advanced Materials And Technology Co Ltd
Advanced Corp for Materials and Equipments Co Ltd
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Priority to CN201610719609.3A priority Critical patent/CN106178892A/en
Publication of CN106178892A publication Critical patent/CN106178892A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • B01D46/04Cleaning filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/112Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to exhaust emissions processing technology field, disclose a kind of enamel-covered wire pyrolysis and reclaim exhaust gas treating method and system, described method specifically, sequentially pass through burn processing, quenching, adsorption treatment, dust removal process, spray washing process by the tail gas that enamel-covered wire pyrolysis is reclaimed;Two English in tail gas are by the most fully burning, the processing procedure of chilling, decomposed up hill and dale, and inhibit its secondary to generate, will not be produced and in discharge process because process is the most thorough at continuous tail gas, cause two English constantly to accumulate during vent gas treatment, cause discharge to exceed standard;Flue gas after chilling is through adsorption treatment, further two English remained in flue gas and acidic materials are adsorbed, spray washing processing procedure again after flue gas elder generation dedusting after adsorption treatment, avoid the cleaning mixture that first spray washing dedusting again brings and may bring cleaner unit into flue gas, the problem easily blocking dust-filtering hole.

Description

Exhaust gas treating method and system are reclaimed in a kind of enamel-covered wire pyrolysis
Technical field
The present invention relates to exhaust emissions processing technology field, particularly relate to a kind of enamel-covered wire pyrolysis and reclaim vent gas treatment side Method.
Background technology
Enamel-covered wire remanufacture reclaimed copper accounts for the proportion of China's copper production to be increased, day by day to pollutant emission in removal process Process be the most increasingly subject to people's attention.The kind of wire enamel mainly has acetal, polyurethane, polyester, polyester-imide, gathers Amide imide, polyimides etc., one-level or two grades of toxic solvents such as cresols to be used, dimethylbenzene during production.State at present What the recovery of interior enamel-covered wire was widely used is direct burning method, carries out enamel-covered wire burning in pyrolysis removal process, will produce in a large number The soot dust granule things such as the white carbon black of incomplete combustion, tar and the harmful gas such as benzene,toluene,xylene, hydrogen chloride, and two English class violent in toxicity, causes severe contamination to environment.National standard " dangerous waste incineration Environmental capacity standard " (GB 18484- 2001) atmospheric emission standard specifying two English is≤0.5ng TEQ/m3;Within 2015, promulgated national standard " reclaimed copper, aluminum, Lead, Zn Cr coating pollutant emission standard " (GB 31574-2015) Press release, the discharge to harmful gas and two English proposes Higher requirement, the enamel-covered wire of development energy-conserving and environment-protective reclaims tail gas disposal technique has become trend of the times.
Enamel-covered wire can complete depainting by pyrolysis, then is reclaimed by cooling zone, and produced waste gas is typically selected directly Connect oxidative combustion, i.e. by directly discharging after lighting process.Oxidation operation in flue gas can be divided by such processing mode Solving is CO2, H2O, but processes excessively simple, and soot dust granule thing, tar, harmful gas and the volatile matter of wherein most have been difficult to Full burning, particulate matter processes without filtration, collection, is still discharged in air.It addition, two English class violents in toxicity also without Reactive absorption or prevent secondary generation from processing, impacts equally to environment.
In nearest scheme, disclose the tail gas disposal technique that the pyrolysis of a kind of copper scrap enamel-covered wire is reclaimed, fire including tail gas Burning, wash, neutralize and the step such as absorption, high treating effect, safety is high, solves a series of of direct oxidation combustion method and asks Topic.But for the pyrolysis recovery technology of continuous way enamel-covered wire, tail gas need to carry out long-time discharge continuously, and discharge capacity is big, discharge effect Fruit easily accumulates amplification, particularly discharge capacity is required two higher English class materials, needs to carry out in vent gas treatment flow process Clear up thoroughly continuously, it is therefore necessary to exploitation meets the technique of such technology and the exhaust gas treating method of device requirement, makes tail Gas discharge reaches the environmental protection standard of national regulation.
Summary of the invention
(1) to solve the technical problem that
It is an object of the invention to provide a kind of enamel-covered wire pyrolysis and reclaim exhaust gas treating method and system, to solve continuous way paint The problem that in envelope curve pyrolytic process exhaust emissions amount is big, emission effect easily accumulates amplification.
(2) technical scheme
In order to solve above-mentioned technical problem, the present invention provides a kind of enamel-covered wire pyrolysis to reclaim exhaust gas treating method, by enamel-cover The tail gas that line pyrolysis is reclaimed sequentially passes through burn processing, quenching, adsorption treatment, dust removal process, spray washing process;
The tail gas reclaimed fully is burnt by described burn processing,
The flue gas formed after burn processing is cooled down by described quenching rapidly,
Remnants bis-English in flue gas after cooling rapidly is adsorbed by described adsorption treatment,
The fine solid particle being detained in tail gas will be filtered by described dust removal process,
Described spray washing processes for absorbing soluble gas remaining in flue gas after removing dust processes.
Further, described burn processing is specifically, suck the tail gas that enamel-covered wire pyrolysis is reclaimed continuously by wind collector In combustor, and in combustor, it is continually fed into imflammable gas and the oxygenating air for supplemental oxygen.
Further, described quenching is that the formation flue gas after burning is cooled down by alkali liquor rapidly that use atomization.
Further, described adsorption treatment specifically uses the mixture of activated carbon and slaked lime to the cigarette after cooling rapidly Remnants bis-English in gas adsorbs, and is neutralized acid ingredient remaining in flue gas simultaneously.
Further, temperature during described burn processing is 600~1200 DEG C, and described oxygenating air uses at burning in advance Cooling down smoke pre-heating before treatment after reason, the temperature after described oxygenating air preheat is not less than 100 DEG C;
The suction flow velocity of the tail gas that the pyrolysis of described enamel-covered wire is reclaimed is 50~500m3/ h, the blast of described wind collector is 500 ~5000Pa, the flow velocity that is passed through of described imflammable gas is 2~20m3/ h, described oxygenating air be passed through flow velocity be 40~ 400m3/ h, the tail gas that the pyrolysis of described enamel-covered wire the is reclaimed time of staying in described combustor is not less than 2s.
Further, the alkali liquor of described quenching is the aqueous solution of sodium hydroxide or potassium hydroxide, described alkali liquor dense Degree is 0.1~10wt.%;
After described quenching, the temperature of flue gas is not more than 200 DEG C.
Further, described adsorption treatment is specifically, pass through high pressure by the dry dust mixture of activated carbon and slaked lime Blower fan sprays in the venturi dry type reactor of belt cleaner unit, the flue gas after chilling through venturi dry type reactor, and with Activated carbon in venturi dry type reactor and slaked lime mixing;
The straying quatity of described activated carbon and slaked lime is 0.4~8kg/h, the air output of described high pressure positive blower be 5~ 100m3/h。
Further, described dust removal process specifically, flue gas after carrying out adsorption treatment enters pulsed sack cleaner, Through the dust particale of described pulsed sack cleaner arrested particles size >=1 μm, wherein, in described pulsed sack cleaner Being provided with the Rapping apparatus shaking cloth bag, the frequency that shakes of described Rapping apparatus is 5~60min/ time.
Further, the water loss that described spray washing processes is 20~240kg/h;
Flue-gas temperature after described spray washing processes is not more than 100 DEG C.
For solving above-mentioned technical problem, another aspect of the present invention provides a kind of enamel-covered wire pyrolysis to reclaim vent gas treatment system System, including the combustor arranged along exhaust gas flow direction successively, chilling tower, bag-type dust collector, spray scrubber, wherein, described combustion Burn room and include the inlet exhaust gas being connected with exhaust collection pipeline, for the air intlet of combustion air entrance, for providing combustion gas Fuel gas inlet and burning after exhanst gas outlet, described exhanst gas outlet is by the first exhaust gases passes and described chilling tower even Logical, spray into the spray assembly of alkali liquor in described chilling tower arranges oriented described chilling tower, described chilling tower removes with described cloth bag Dirt device is connected by the second exhaust gases passes, described second exhaust gases passes is provided with for spraying in described second exhaust gases passes Penetrate the charcoal Calx adsorbent equipment of activated carbon and slaked lime;
Described air intlet connects hot-air duct, is provided with air preheater in described first exhaust gases passes, described Hot-air duct is connected with the air outlet slit of described air preheater, and the air intake of described air preheater is provided with the external world The aerator of air into air pipeline;
Described charcoal Calx adsorbent equipment includes high pressure positive blower, charcoal pulverized limestone storage tank and venturi dry type reactor, described literary composition In mound, dry type reactor is arranged on described second exhaust gases passes, and described high pressure positive blower is for by the activity in charcoal pulverized limestone storage tank Charcoal and slaked lime introduce in described venturi dry type reactor, and described charcoal pulverized limestone storage tank is provided with the vibrations dress preventing material from crystallizing Putting, the interlude that shakes of described shaking device is 5~30min;
Being provided with thermocouple on the sidewall of described combustor, described combustor is connected with described thermocouple signal.
(3) beneficial effect
Exhaust gas treating method is reclaimed in a kind of enamel-covered wire pyrolysis that the present invention provides, and tail gas enamel-covered wire pyrolysis reclaimed is successively Discharge again after burn processing, quenching, adsorption treatment, dust removal process, spray washing process;In tail gas two English, by the most fully burning, the processing procedure of chilling, is decomposed up hill and dale, and inhibits its secondary to generate, Bu Hui Tail gas produces and not thorough because processing in discharge process continuously, causes two English constantly to accumulate during vent gas treatment, causes Discharge exceeds standard;Two English remained in flue gas and acidic materials, through adsorption treatment, are carried out by flue gas after chilling further Absorption, spray washing processing procedure again after the flue gas elder generation dedusting after adsorption treatment, it is to avoid the dedusting again of first spray washing brings Cleaning mixture may bring cleaner unit into flue gas, the problem easily blocking dust-filtering hole.
It is rationally reliable that exhaust gas treating method is reclaimed in the enamel-covered wire pyrolysis that the present invention provides, and the Continuous Heat adapting to enamel-covered wire is freed Paint volume production process, the tail gas after process is fully able to reach the environmental protection standard of national regulation.
Accompanying drawing explanation
Fig. 1 is the flow chart that exhaust gas treating method is reclaimed in the pyrolysis of embodiment of the present invention enamel-covered wire;
Fig. 2 reclaims the schematic diagram of the processing system that exhaust gas treating method is used by the pyrolysis of embodiment of the present invention enamel-covered wire.
In figure, 1, exhaust collection pipeline;2, combustor;3, combustor;4, air-flue gas heat-exchange unit;5, extraneous blast pipe; 6, aerator;7, chilling tower;8, chilling pump;9, twin spray gun;10, charcoal pulverized limestone storage tank;11, high pressure positive blower;12, literary composition Dry type reactor in mound;13, bag-type dust collector;14, spray scrubber;15, auxiliary device;16, the first exhaust gases passes;17、 Second exhaust gases passes;18. hot-air ducts.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment, the detailed description of the invention of the present invention is described in further detail.Following instance For the present invention is described, but it is not limited to the scope of the present invention.
In describing the invention, it should be noted that unless otherwise clearly defined and limited, term " is installed ", " phase Even ", " connection " should be interpreted broadly, for example, it may be fixing connection, it is also possible to be to removably connect, or be integrally connected;Can To be mechanical connection, it is also possible to be electrical connection;Can be to be joined directly together, it is also possible to be indirectly connected to by intermediary, Ke Yishi The connection of two element internals.For the ordinary skill in the art, can understand that above-mentioned term is at this with concrete condition Concrete meaning in invention.
As in figure 2 it is shown, the pyrolysis of the present embodiment one enamel-covered wire reclaims exhaust treatment system, including the flow direction along flue gas The combustor 2 that sets gradually, chilling tower 7, bag-type dust collector 13, spray scrubber 14, wherein, described combustor 2 includes tail Gas import, for combustion air enter air intlet, for provide combustion gas fuel gas inlet and burning after exhanst gas outlet, Described inlet exhaust gas is connected with by exhaust collection pipeline 1, and air intlet is connected with hot-air duct 18, and fuel gas inlet is arranged Being provided with the combustor 3 of combustion gas, described exhanst gas outlet is connected with described chilling tower 7 by the first exhaust gases passes, described chilling tower 7 On oriented described chilling tower 7 is set in spray into the spray assembly of alkali liquor, described chilling tower 7 leads to described bag-type dust collector 13 Cross the second exhaust gases passes 17 to connect, described second exhaust gases passes 17 is provided with for spraying in described second exhaust gases passes 17 The charcoal Calx adsorbent equipment of activated carbon and slaked lime.It is provided with air preheater 4, described heat in described first exhaust gases passes 16 Air line 18 is connected with the air outlet slit of described air preheater 4, and the air intlet of described air preheater 4 connects the external world Blast pipe 5, and extraneous blast pipe pipe connects and has aerator 6, outside air is introduced in described air preheater 4 by aerator 6.
Air preheater 4 is set in the first exhaust gases passes 16, both can preheat the oxygenating air entering combustor 2, and subtract The consumption of few combustor 2 fuel, air preheater 4 also corresponds to a heat exchanger simultaneously, can play the flue gas after burning The effect of cooling.The most in actual applications, the heat exchange area of air preheater 4 is 50~50m2, shell material is that Q235+ is resistance to Fire castable, the material of the first exhaust gases passes is 2520 heat resisting steel.
The inner side of combustor 2 is refractory masses, and according to the ignition temperature of general tail gas, the thickness of refractory material can be 100~500mm, for being typically pyrolyzed tail gas recycle, the combustor dischargeable capacity of employing can be 0.3~5m3, hot-air uses ring The tangential form of shape mends wind in combustor, it is ensured that has the oxygen of abundance during exhaust combustion, makes the organic principles such as two English obtain To complete combustive destruction.Currently preferred thermocouple can be set on the sidewall of combustor 2, and by thermocouple and combustor 3 is chain by temperature signal, is automatically adjusted natural gas size, temperature in long-time maintenance combustor 2, it is ensured that high-volume continuously Exhaust combustion processes.
Described spray assembly is twin spray gun 9, and described twin spray gun 9 includes double-deck clamp and is arranged on The nozzle head of double-deck clamp end, the inlet of described spray assembly is connected by the pressurization chilling pump 8 of pipeline with conveying alkali liquor. Chilling tower 7 uses the spray mode that directly cools down of alkali liquor, flow through the flue gas in chilling tower 7 directly be atomized after the liquid that sprays into connect Touching, mass transfer and heat transfer rate are fast, and the alkali liquor rapid vaporization sprayed into takes away substantial amounts of heat, makes cloth bag inlet exhaust gas temperature drop rapidly To about 200 DEG C, and ensure tail gas quenching time≤1s, thus avoid two English class materials 250~500 DEG C of temperature ranges Again generate.Exhaust temperature can be regulated by the alkali liquor emitted dose of chilling tower, and range of accommodation is 20~200kg/h.Chilling tower Overall dimensions is Φ 300~1500 × 1000~5000, can realize the most large-scale tail gas quenching.Twin spray gun 9 Having compressed alkali liquor atomization by air, its structure is Double-layer clamp sleeve pipe, and alkali liquor walks inner tube, and compressed air walks outer tube, serosity and pressure Contracting air sprays from nozzle after strongly mixing at nozzle head, so that slurry spraying is fine particle, contacts with tail gas Cooling;Compressed air consumption is 10~100m3/ h, alkali liquor described in chilling tower is the aqueous solution of sodium hydroxide or potassium hydroxide, The concentration of described alkali liquor is 0.1~10wt.%.
Simultaneously for ensureing that spraying into the alkali liquor in chilling tower 7 evaporates completely, prevents alkali liquor from gluing wall and wall erosion, cooling tower is excellent Selection of land use double-decker, be corrosion-resistant high-temperature refractory material with the internal layer of tail gas contact surface namely cooling tower, thickness be 100~ 500mm。
As in figure 2 it is shown, embodiment charcoal Calx adsorbent equipment includes high pressure positive blower 11, charcoal pulverized limestone storage tank 10 and venturi Dry type reactor 12, described venturi dry type reactor 12 is arranged on described second exhaust gases passes 17, described high pressure positive blower 11 For the activated carbon in charcoal pulverized limestone storage tank 10 and slaked lime are introduced in described venturi dry type reactor 12.
The pressure-air that activated carbon in charcoal pulverized limestone and slaked lime are introduced by high pressure positive blower 11 respectively carries constantly In venturi dry type reactor 12 before bag-type dust collector 13, through reactor throat, gas velocity increases, and produces Raw high turbulence, makes tail gas be fully contacted with charcoal pulverized limestone.At low temperatures (≤200 DEG C), two English class materials are the most active Charcoal adsorbs.After contact, two English of the most incompletely processed a small amount of residual are fully absorbed, it is achieved the of two English Double removal;Slaked lime is then neutralized absorption and processes the acidic materials in tail gas.
In order to prevent the material of charcoal pulverized limestone storage tank 10 from crystallizing, the present embodiment charcoal pulverized limestone storage tank 10 is provided with shaking device, Shaking frequency is 5~30min to shake once.
The sack cleaner reclaiming exhaust treatment system as the pyrolysis of a kind of preferred version the present embodiment enamel-covered wire can select In the pulsed sack cleaner using PTFE material to make, and pulsed sack cleaner, Rapping apparatus is installed, preferably Total filter area of pulsed sack cleaner is 4~40m2, and pulse valve quantity is 2~10, arrested particles size >=1 μm (namely space < 1 μm of cloth bag), dust remover resistance≤1.5kPa, cloth bag total number is 10~100, and cloth bag is by shaking dress Put every 5~60min and shake once, prevent the crystallization of dust stomach wall and reunite.
It is to use the pyrolysis of above-mentioned enamel-covered wire to reclaim tail that exhaust gas treating method is reclaimed in the pyrolysis of embodiment of the present invention one enamel-covered wire Gas processing system realizes, as it is shown in figure 1, described method is particularly as follows: sequentially pass through burning by the tail gas that enamel-covered wire pyrolysis is reclaimed Process, quenching, adsorption treatment, dust removal process, spray washing process;Wherein, the tail gas reclaimed is filled by burn processing Divided combustion, described quenching is that the flue gas after burning is cooled down by alkali liquor rapidly that use atomization, and described adsorption treatment is adopted With the mixture of activated carbon and slaked lime, remnants bis-English in the flue gas after cooling rapidly and acid ingredient are adsorbed Processing, the fine solid particle being detained in tail gas, slaked lime and activated carbon are filtered by described dust removal process, at described spray washing Reason is for absorbing the soluble gas in flue gas after adsorption treatment.
Exhaust gas treating method is reclaimed in the pyrolysis of the present embodiment enamel-covered wire, and two English in the tail gas in enamel-covered wire pyrolytic process lead to Cross the most fully burning, the processing procedure of chilling, decomposed up hill and dale, and inhibit its secondary to generate, will not be continuously Tail gas produces and not thorough because processing in discharge process, causes two English constantly to accumulate during vent gas treatment, causes discharge Exceed standard;Two English remained in flue gas and acidic materials, through adsorption treatment, are adsorbed by flue gas after chilling further, Spray washing processing procedure again after flue gas elder generation dedusting after adsorption treatment, it is to avoid the washing that the dedusting again of first spray washing brings Liquid may bring cleaner unit into flue gas, the problem easily blocking dust-filtering hole.
Exhaust gas treating method is reclaimed in the pyrolysis of the present embodiment enamel-covered wire can use exhaust treatment system as shown in Figure 1, and excellent That selects is provided with wind collector on exhaust collection pipeline, and the basic procedure of described exhaust collection is: start wind collector, by air vent The tail gas discharged continuously sucks wind-collecting cover, then enter combustor by connecting the ventilation duct of wind-collecting cover, it is to avoid tail gas is to air Middle discharge.Wherein, the exhaust temperature produced during collected continuous way enamel-covered wire pyrolysis depainting is 50-400 DEG C, wind collector Exhaust collection amount be 50-500m3/ h, blast is 500-5000Pa.
Being passed through imflammable gas by combustor 3 in combustor, the flow of imflammable gas is 2-20m3/ h, passes through simultaneously Air duct is passed through the oxygenating air of oxygen needed for aftercombustion in combustor, and oxygenating wind flow is 40-400m3/ h, makes tail Combustible in gas fully burns under oxygen abundance environment, completes the burn processing of tail gas, wherein, in burning process, Keep chamber temperature to be 600-1200 DEG C, the combustion-supporting gas flow that is passed through ensure tail gas combustor the time of staying >= 2s, makes two English sufficiently decompose.
The oxygenating air of wherein said aftercombustion oxygen is passed through burning after being preheated by the flue gas after burning again Indoor, concrete process be outside air pass through aerator introduce air preheater, in air preheater with burning after cigarette Gas enters in combustor after carrying out heat exchange.
The process that cooling processes can be by the spray assembly jet atomization in described cooling tower being arranged on cooling tower Alkali liquor realize, concrete as in figure 2 it is shown, tail gas in cooling tower directly be atomized after the alkali liquor that sprays into contact, the alkali sprayed into Liquid rapid vaporization takes away heat, reaches the purpose quickly cooled down.The alkali liquor used is the water-soluble of sodium hydroxide or potassium hydroxide Liquid, concentration is 0.1~10wt.%.Alkali liquor sprays after carrying out supercharging by anticorrosive wear-resistant pump, and emitted dose is 30~300kg/h, Exhaust temperature is made to be rapidly reduced to≤200 DEG C, it is to avoid the regeneration of two English.
As in figure 2 it is shown, the present embodiment enamel-covered wire pyrolysis reclaim exhaust gas treating method, the charcoal Calx used be activated carbon and The dry dust mixture of slaked lime (calcium hydroxide), activated carbon and slaked lime spray into belt cleaner unit by high pressure positive blower respectively Venturi dry type reactor in, acidic materials in removing flue gas also adsorb the two English class harmful substances that major part is remaining. The emitted dose of activated carbon and slaked lime is 0.4~8kg/h, and high pressure positive blower air output is 5~100m3/h.
Spray washing process completed by spray scrubber, the tower overall dimensions of spray scrubber be Φ 0.1~1m × 1~ 6m, the water yield of consumption is 20~240kg/h, by spray washing, flue gas exit temperature is reduced to≤100 DEG C after again flue gas is led to Cross smoke stack emission.
It is given below and uses the pyrolysis of the present embodiment enamel-covered wire to reclaim the right of exhaust gas treating method and prior art processing method Compare practical application example.
The practical solution one of the present embodiment enamel-covered wire pyrolysis recovery exhaust gas treating method:
The pyrolysis of continuous way enamel-covered wire is reclaimed the tail gas produced uses wind collector to be collected, and exhaust temperature is 105 DEG C, tail Gas collecting amount is 200m3/h.By tail gas, by combustor, (dischargeable capacity is 1m3), heating-up temperature is 800 DEG C, is passed through natural gas flow Amount is 4m3/ h, oxygenating air quantity is 80m3/ h, temperature is 100 DEG C.Through burning after tail gas enter cooling tower (size Φ 0.85m × 3m), the alkali liquor emitted dose of cooling tower is 100kg/h, and exhaust temperature reduces rapidly, and the venturi subsequently entering sack cleaner is done Formula reactor, during sprayed into the dry dust mixture of activated carbon and calcium hydroxide, activated carbon and hydroxide by high pressure positive blower The emitted dose of calcium is 2kg/h, and blower fan air output is 20m3/h.Tail gas passes through pulsed cloth bag subsequently, and cloth bag number is 30, The gross area is 15m2, pulse valve quantity is 6, and cloth bag shakes once by the every 20min of Rapping apparatus, prevents dust stomach wall from crystallizing And reunion.Tail gas after bag-type dust enters spray scrubber (a size of Φ 0.6m × 3m), and the water yield of consumption is 100kg/ h.By spray washing, tail gas is by high 25m, the smoke stack emission of diameter 0.16m.Tail gas is transferred to environmental protection relevant departments detect, In tail gas, smoke content is 35.12mg/m3, benzene content is 0.14mg/m3, toluene level is 0.04mg/m3, xylene content is 0.05mg/m3, hydrogen chloride content is 2.52mg/m3.Detecting department's detection through specialty, in tail gas, two English content are 0.017ng TEQ/m3
The practical solution two of the present embodiment enamel-covered wire pyrolysis recovery exhaust gas treating method:
The pyrolysis of continuous way enamel-covered wire is reclaimed the tail gas produced uses wind collector to be collected, and exhaust temperature is 141 DEG C, tail Gas collecting amount is 300m3/h.By tail gas, by combustor, (dischargeable capacity is 1m3), heating-up temperature is 1100 DEG C, is passed through natural gas Flow is 5m3/ h, oxygenating air quantity is 100m3/ h, temperature is 100 DEG C.Through burning after tail gas enter cooling tower (size Φ 0.85m × 3m), the alkali liquor emitted dose of cooling tower is 120kg/h, and exhaust temperature reduces rapidly, and the venturi subsequently entering sack cleaner is done Formula reactor, during sprayed into the dry dust mixture of activated carbon and calcium hydroxide, activated carbon and hydroxide by high pressure positive blower The emitted dose of calcium is 2.5kg/h, and blower fan air output is 20m3/h.Tail gas passes through pulsed cloth bag subsequently, and cloth bag number is 30 Bar, the gross area is 15m2, pulse valve quantity is 6, and cloth bag shakes once by the every 10min of Rapping apparatus, prevents dust stomach wall Crystallization and reunion.Tail gas after bag-type dust enters spray scrubber (a size of Φ 0.6m × 3m), and the water yield of consumption is 120kg/h.By spray washing, tail gas is by high 25m, the smoke stack emission of diameter 0.16m.Tail gas is carried out by environmental protection relevant departments Detection, in tail gas, smoke content is 11.24mg/m3, benzene content is 0.06mg/m3, toluene level is 0.06mg/m3, hydrogen chloride contains Amount is 0.35mg/m3, do not detect dimethylbenzene.Detecting department's detection through specialty, in tail gas, two English content are 0.005ng TEQ/m3
Contrast use prior art carry out enamel-covered wire pyrolysis reclaim vent gas treatment:
The pyrolysis of continuous way enamel-covered wire is reclaimed the tail gas produced directly light at offgas outlet, two produced after directly lighting Secondary tail gas is detected by environmental protection relevant departments, and in tail gas, smoke content is 31966mg/m3, benzene content is 5462mg/m3, toluene Content is 636.6mg/m3, xylene content is 20.98mg/m3, hydrogen chloride content is 3.78mg/m3.Department's inspection is detected through specialty Surveying, in tail gas, two English content are 10.1ng TEQ/m3
Through comparing, use the pyrolysis of the present embodiment enamel-covered wire to reclaim exhaust gas treating method and effectively control the row of exhaust pollutant Putting, every discharge standard has reached People's Republic of China's environmental protection standard " dangerous waste incineration Environmental capacity standard " (GB 18484-2001) and, and use in the tail gas that direct oxidation combustion method processes and walk owing to lacking smoke catching, abundant burning etc. Suddenly so that the pollutant severe overweights such as the flue dust in secondary tail gas.Step is processed owing to lacking two English of high temperature pyrolysis chilling Suddenly, two English discharges there is also situation about exceeding standard.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (10)

1. exhaust gas treating method is reclaimed in an enamel-covered wire pyrolysis, it is characterised in that the tail gas warp successively enamel-covered wire pyrolysis reclaimed Cross burn processing, quenching, adsorption treatment, dust removal process, spray washing process;
The tail gas reclaimed fully is burnt by described burn processing,
The flue gas formed after burn processing is cooled down by described quenching rapidly,
Remnants bis-English in flue gas after cooling rapidly is adsorbed by described adsorption treatment,
The fine solid particle being detained in tail gas will be filtered by described dust removal process,
Described spray washing processes for absorbing soluble gas remaining in flue gas after removing dust processes.
2. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 1, it is characterised in that described burn processing is concrete For, the tail gas that enamel-covered wire pyrolysis is reclaimed is sucked in combustor continuously by wind collector, and is continually fed into flammable in combustor Property gas and for the oxygenating air of supplemental oxygen.
3. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 1, it is characterised in that described quenching is to adopt With the alkali liquor of atomization, the formation flue gas after burning is cooled down rapidly.
4. exhaust gas treating method is reclaimed in enamel-covered wire as claimed in claim 1 pyrolysis described in, it is characterised in that described adsorption treatment Remnants bis-English in flue gas after cooling rapidly is adsorbed by the mixture specifically using activated carbon and slaked lime, and with Time acid ingredient remaining in flue gas is neutralized.
5. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 2, it is characterised in that during described burn processing Temperature is 600~1200 DEG C, and described oxygenating air cools down smoke pre-heating before treatment, described oxygenating after using burn processing in advance Temperature after air preheat is not less than 100 DEG C;
The suction flow velocity of the tail gas that the pyrolysis of described enamel-covered wire is reclaimed is 50~500m3/ h, the blast of described wind collector be 500~ 5000Pa, the flow velocity that is passed through of described imflammable gas is 2~20m3/ h, the flow velocity that is passed through of described oxygenating air is 40~400m3/ H, the tail gas that the pyrolysis of described enamel-covered wire the is reclaimed time of staying in described combustor is not less than 2s.
6. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 3, it is characterised in that the alkali of described quenching Liquid is the aqueous solution of sodium hydroxide or potassium hydroxide, and the concentration of described alkali liquor is 0.1~10wt.%;
After described quenching, the temperature of flue gas is not more than 200 DEG C.
7. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 4, it is characterised in that described adsorption treatment is concrete For, the venturi dry type that the dry dust mixture of activated carbon and slaked lime sprays into belt cleaner unit by high pressure positive blower is reacted In device, the flue gas after chilling through venturi dry type reactor, and with the activated carbon in venturi dry type reactor and slaked lime Mixing;
The straying quatity of described activated carbon and slaked lime is 0.4~8kg/h, and the air output of described high pressure positive blower is 5~100m3/h。
8. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 1, it is characterised in that described dust removal process is concrete For, carry out the flue gas after adsorption treatment and enter pulsed sack cleaner, through described pulsed sack cleaner arrested particles chi The dust particale of very little >=1 μm, wherein, is provided with the Rapping apparatus shaking cloth bag, described shake in described pulsed sack cleaner The frequency that shakes beating device is 5~60min/ time.
9. exhaust gas treating method is reclaimed in enamel-covered wire pyrolysis as claimed in claim 1, it is characterised in that described spray washing processes Water loss be 20~240kg/h;
Flue-gas temperature after described spray washing processes is not more than 100 DEG C.
10. exhaust treatment system is reclaimed in an enamel-covered wire pyrolysis, it is characterised in that include the burning arranged successively along exhaust gas flow direction Room, chilling tower, bag-type dust collector, spray scrubber, wherein, described combustor includes the tail gas being connected with exhaust collection pipeline Import, for combustion air enter air intlet, for provide combustion gas fuel gas inlet and burning after exhanst gas outlet, Described exhanst gas outlet is connected with described chilling tower by the first exhaust gases passes, described chilling tower is arranged in oriented described chilling tower Spraying into the spray assembly of alkali liquor, described chilling tower is connected by the second exhaust gases passes with described bag-type dust collector, and described second It is provided with on exhaust gases passes for spraying activated carbon and the charcoal Calx adsorbent equipment of slaked lime in described second exhaust gases passes;
Described air intlet connects hot-air duct, is provided with air preheater in described first exhaust gases passes, and described heat is empty Feed channel is connected with the air outlet slit of described air preheater, and the air intake of described air preheater is provided with outside air Introduce the aerator of air line;
Described charcoal Calx adsorbent equipment includes high pressure positive blower, charcoal pulverized limestone storage tank and venturi dry type reactor, described venturi Dry type reactor is arranged on described second exhaust gases passes, described high pressure positive blower for by the activated carbon in charcoal pulverized limestone storage tank and Slaked lime introduces in described venturi dry type reactor, and described charcoal pulverized limestone storage tank is provided with the shaking device preventing material from crystallizing, The interlude that shakes of described shaking device is 5~30min;
Being provided with thermocouple on the sidewall of described combustor, described combustor is connected with described thermocouple signal.
CN201610719609.3A 2016-08-24 2016-08-24 Exhaust gas treating method and system are reclaimed in a kind of enamel-covered wire pyrolysis Pending CN106178892A (en)

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CN107551793A (en) * 2017-10-26 2018-01-09 长沙双合盛企业管理有限公司 Industrial waste gas purifying processing unit
CN108295602A (en) * 2018-03-08 2018-07-20 广西博世科环保科技股份有限公司 Thermal desorption tail gas multi-stage filtration systems and method
CN108714344A (en) * 2018-06-28 2018-10-30 镇江市富昌塑胶有限公司 Exhaust gas recovery system for artificial leather production
CN109340769A (en) * 2018-09-21 2019-02-15 湖南顶立科技有限公司 The exhaust gas treating method and system of discarded circuit board pyrolysis
CN110585847A (en) * 2019-08-16 2019-12-20 无锡雷顿电器有限公司 Treatment method for controlling wet method to reduce concentration of dioxin and dust in industrial flue gas
CN110652825A (en) * 2019-11-08 2020-01-07 广东佳德环保科技有限公司 Removal system of dioxin in flue gas
CN111578304A (en) * 2020-06-16 2020-08-25 李楠 Garbage incineration pollution-free treatment system
CN112076601A (en) * 2020-09-25 2020-12-15 中国恩菲工程技术有限公司 Cremation tail gas purification system and purification method
CN112076625A (en) * 2020-09-25 2020-12-15 中国恩菲工程技术有限公司 Cremation tail gas purification system and purification method
CN112815336A (en) * 2020-12-31 2021-05-18 重庆长江造型材料(集团)股份有限公司 Low-emission method for powder combustion
CN113091075A (en) * 2021-04-08 2021-07-09 马帅 A kind of control method of dioxin in waste salt pyrolysis
CN113932231A (en) * 2021-09-23 2022-01-14 中铁市政环境建设有限公司 Device for treating carbonization pyrolysis tail gas through combustion

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CN107441915A (en) * 2017-07-31 2017-12-08 合肥国轩高科动力能源有限公司 Treatment method of waste gas generated by cracking waste power batteries
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CN108295602A (en) * 2018-03-08 2018-07-20 广西博世科环保科技股份有限公司 Thermal desorption tail gas multi-stage filtration systems and method
CN108714344A (en) * 2018-06-28 2018-10-30 镇江市富昌塑胶有限公司 Exhaust gas recovery system for artificial leather production
CN109340769A (en) * 2018-09-21 2019-02-15 湖南顶立科技有限公司 The exhaust gas treating method and system of discarded circuit board pyrolysis
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CN111578304A (en) * 2020-06-16 2020-08-25 李楠 Garbage incineration pollution-free treatment system
CN112076601A (en) * 2020-09-25 2020-12-15 中国恩菲工程技术有限公司 Cremation tail gas purification system and purification method
CN112076625A (en) * 2020-09-25 2020-12-15 中国恩菲工程技术有限公司 Cremation tail gas purification system and purification method
CN112815336A (en) * 2020-12-31 2021-05-18 重庆长江造型材料(集团)股份有限公司 Low-emission method for powder combustion
CN112815336B (en) * 2020-12-31 2023-07-07 重庆长江造型材料(集团)股份有限公司 Low-emission method for powder combustion
CN113091075A (en) * 2021-04-08 2021-07-09 马帅 A kind of control method of dioxin in waste salt pyrolysis
CN113932231A (en) * 2021-09-23 2022-01-14 中铁市政环境建设有限公司 Device for treating carbonization pyrolysis tail gas through combustion

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