CN106167612A - A kind of carbon fiber modifying nano green environment-friendly rubber and preparation method thereof - Google Patents
A kind of carbon fiber modifying nano green environment-friendly rubber and preparation method thereof Download PDFInfo
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- CN106167612A CN106167612A CN201610621216.9A CN201610621216A CN106167612A CN 106167612 A CN106167612 A CN 106167612A CN 201610621216 A CN201610621216 A CN 201610621216A CN 106167612 A CN106167612 A CN 106167612A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 64
- 239000005060 rubber Substances 0.000 title claims abstract description 64
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 25
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 25
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 18
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims abstract description 11
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims abstract description 10
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 10
- 239000010426 asphalt Substances 0.000 claims abstract description 9
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 42
- -1 polypropylene Polymers 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 16
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 16
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 239000004793 Polystyrene Substances 0.000 claims description 15
- 229920001155 polypropylene Polymers 0.000 claims description 15
- 229920002223 polystyrene Polymers 0.000 claims description 15
- 239000008187 granular material Substances 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 239000010445 mica Substances 0.000 claims description 9
- 229910052618 mica group Inorganic materials 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 229920002472 Starch Polymers 0.000 claims description 8
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 8
- 239000010881 fly ash Substances 0.000 claims description 8
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 8
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 8
- 229920000609 methyl cellulose Polymers 0.000 claims description 8
- 239000001923 methylcellulose Substances 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 8
- 229920001228 polyisocyanate Polymers 0.000 claims description 8
- 239000005056 polyisocyanate Substances 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 239000008107 starch Substances 0.000 claims description 8
- 235000019698 starch Nutrition 0.000 claims description 8
- 239000013638 trimer Substances 0.000 claims description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 4
- 239000011324 bead Substances 0.000 claims description 4
- 239000000306 component Substances 0.000 claims description 4
- 230000009970 fire resistant effect Effects 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
- OFGVPLJWXLEAEN-UHFFFAOYSA-N 2,2-dimethylpropoxy-diethoxy-pentylsilane Chemical compound CC(CO[Si](OCC)(OCC)CCCCC)(C)C OFGVPLJWXLEAEN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims 2
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- HTMIBDQKFHUPSX-UHFFFAOYSA-N methdilazine Chemical group C1N(C)CCC1CN1C2=CC=CC=C2SC2=CC=CC=C21 HTMIBDQKFHUPSX-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
- C08L71/03—Polyepihalohydrins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of carbon fiber modifying nano green environment-friendly rubber and preparation method thereof, the constitutive material that it includes is: chlorohydrin rubber, nitrile rubber, acrylonitrile butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber, reclaimed rubber, toner etc..Instant component preparation is reasonable, with chlorohydrin rubber, nitrile rubber etc..For major ingredient with the use of the toughness substantially increasing material, effectively solve the situation that conveyer belt is easily broken off, also will not produce harmful gas under higher temperature high temperature resistant, the performance such as tear-resistant perfectly merges so that the present invention can apply to work under various mal-condition simultaneously.Use asphalt base carbon fiber to enhance the mechanical property of material can adsorb greatly and the harmful gas of removing in tail gas and dust material, the simple science of preparation method, it is adaptable to promote on a large scale.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, particularly relate to a kind of carbon fiber modifying nano green environment-friendly rubber
And preparation method thereof.
Background technology
Decorative plate of outer wall is the building exposed wall decoration heat-insulating integral formed material researched and developed in recent years, also cries horizon, Shandong
Heat insulating decorative board;This material is by enamel polyester paint or F-C paint, carving alumin(i)um zinc alloy steel plate, polyurethane insulation coating, glass fabric
It is composited;It is mainly used in the decoration of exterior wall of the various buildings such as the office building of gymnasium, library, school and hospital, villa
And reducing energy consumption；Major function is building decoration, heat preservation energy-saving, heat-insulating sound-insulating, waterproof mildew-resistant.
Along with the attention in terms of building energy conservation, building outer wall material are increasingly received publicity by country.Adhesive polystyrene
Grain thermal insulation mortar be a kind of conventional thermal insulation mortar, good with its application property, easy to operate, good heat insulating and very popular.
But adhesive polystyrene granule heat-insulating mortar there is also some shortcomings, show: surface strength is low, easy-weathering, the most low temperature resistant, it is dried
Speed is slow, poor with metope cohesive force.These shortcomings have impact on the use of adhesive polystyrene granule heat-insulating mortar.Glue powder polyphenyl particle by
Rubber powder material, granular polystyrene puddle composition, and adding water to stir i.e. obtains glue powder polyphenyl particle.If the property of glue powder polyphenyl particle to be improved
Matter, can only set about in terms of changing rubber powder material etc..
Summary of the invention
For overcoming above-mentioned deficiency, the present invention provides a kind of carbon fiber modifying nano green environment-friendly rubber and preparation method thereof.
The present invention takes techniques below scheme to realize: a kind of carbon fiber modifying nano green environment-friendly rubber, its bag
The constitutive material included is: chlorohydrin rubber 80-100 part, nitrile rubber 30-40 part, acrylonitrile-butadiene copolymer rubber 50-60
Part, diene rubber 50-60 part, butadiene-styrene rubber 20-30 part, reclaimed rubber 25-30 part, asphalt base carbon fiber powder 30-35 part, non-
Halogenation organophosphinate 5-7 part, hexamethylenetetramine 8-10 part, tri-methyl-amyl triethoxysilane 2-4 part, rubber powder slurry
10-20 weight portion, granules of polystyrene 6-10 weight portion, methylcellulose 12-18 weight portion, toner 5-15 weight portion, poly-
Tacryl 4-10 weight portion, starch ether 1-5 weight portion, flyash 2-6 weight portion, polypropylene chopped strand 10-16 weight portion,
Metakaolin 12-18 weight portion, silicon carbide micro-powder 2-6 weight portion, nano silicon 10-16 weight portion, Alumen 2-10 weight
Part, organic siliconresin 1-5 weight portion, nano-cerium oxide 1-5 weight portion, glass bead 5-9 weight portion, gangue 30-35 weight
Part, conductive mica powder 0.3-0.5 weight portion, conductive nano graphite powder 0.2-0.4 weight portion, the trimer 0.8-of polyisocyanates
1 weight portion, polytetrafluoroethylene fibre 1-2 weight portion.
The present invention also provides for the preparation method of a kind of carbon fiber modifying nano green environment-friendly rubber, comprises the steps of:
(1) asphalt base carbon fiber powder is joined non-halogenated organophosphinate, hexamethylenetetramine, tri-methyl-amyl three
In Ethoxysilane, and after adding the water of gross weight 5-6 times, magnetic agitation 2-4h to uniformly, then stirs at 200-300 DEG C and forges
Burn 3-4h, standby as component A；
(2) granules of polystyrene, methylcellulose, polypropylene fibre, starch ether, flyash, polypropylene chopped strand are placed in
Pulverizer is pulverized, crosses 100-200 mesh sieve, prepare component B standby；
(3) by micro-to metakaolin, silicon carbide micro-powder, nano silicon, Alumen, organic siliconresin, nano-cerium oxide, vitreous
Pearl, gangue, conductive mica powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre are placed in pulverizing
Machine is pulverized, crosses 100-200 mesh sieve, prepare component C standby；
(4) the rubber powder slurry mix and blend of half amount will be added after component A, the mixing of component B, mixing speed 450-550r/min,
Whipping temp is 55-65 DEG C, mixing time 30-45min.
(5), while component C being added in step (4), add the rubber powder slurry of residue half amount, add after stirring 30min
Entering toner, mixing speed 450-550r/min, whipping temp is 55-65 DEG C, mixing time 40-60min, prepares adhesive polystyrene
Granule exterior wall fire-resistant nanometer substrate component D；
Plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber, regeneration
Rubber puts into mix and blend 30min in the plasticator that internal temperature is 120 DEG C, obtains component E,
(6) mixing, component D, E are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
(7) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
The method have the advantages that the present invention is common with chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene in sum
Copolymer rubber, diene rubber, butadiene-styrene rubber, reclaimed rubber are major ingredient with the use of substantially increasing the toughness of material, effectively
Solve the situation that conveyer belt is easily broken off, also will not produce harmful gas under higher temperature high temperature resistant simultaneously, resistance to
The performances such as tear perfectly merge so that the present invention can apply to work under various mal-condition.A kind of carbon fiber is provided to change
Property nano green environment-friendly rubber and preparation method thereof, component preparation rationally, is specifically designed for external wall, and the present invention selects, and uses
Asphalt base carbon fiber enhances the mechanical property of material and can adsorb greatly and the harmful gas of removing in tail gas and dust
Material, is equipped with the composition such as hard-foam polyurethane, mortar, and cohesive force is strong, and good heat insulating is low temperature resistant, and comprcssive strength is high, curing rate
Hurry up, improve the various aspects of performance of decorative panel, such as: high temperature resistant, fire prevention, anti-skidding, waterproof, the moisture absorption, wear-resisting, antioxidation and anti-corruption
The performances such as erosion, compared with existing decorative plate of outer wall material, the most rational in infrastructure, own wt is light, construction technology is simple, and have
There are the features such as ornamental strong, attractive in appearance, durable, length in service life, shorten the engineering construction duration and reduce resource consumption, making building
Thing more energy-saving, safe and environment-friendly, it is adaptable to promote on a large scale.The rock gangue of interpolation, conductive mica powder, conductive nano graphite powder
Resistant to thermal aging cracking performance can be improved Deng reinforcing agent, thus improve casting efficiency, reduce casting cost.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with
Detailed description of the invention, is expanded on further the present invention.
1 one kinds of carbon fiber modifying nano green environment-friendly rubbers of embodiment and preparation method thereof
A kind of carbon fiber modifying nano green environment-friendly rubber, the constitutive material that it includes is: chlorohydrin rubber 80-100 part, Ding Qing
Rubber 30 parts, acrylonitrile-butadiene copolymer rubber 50 parts, diene rubber 50 parts, 20 parts of butadiene-styrene rubber, reclaimed rubber 25 parts,
30 parts of asphalt base carbon fiber powder, non-halogenated organophosphinate 5 parts, hexamethylenetetramine 8 parts, tri-methyl-amyl triethoxy
2 parts of silane, rubber powder slurry 10 weight portion, granules of polystyrene 6 weight portion, methylcellulose 12 weight portion, toner 5 weight
Part, polypropylene fibre 4 weight portion, starch ether 1 weight portion, flyash 2 weight portion, polypropylene chopped strand 10 weight portion, higher
Ridge soil 12 weight portions, silicon carbide micro-powder 2 weight portion, nano silicon 10 weight portion, Alumen 2 weight portion, organic siliconresin 1 weight
Measure part, nano-cerium oxide 1 weight portion, glass bead 5 weight portion, gangue 30 weight portion, conductive mica powder 0.3 weight portion, receive
Rice electrically conductive graphite powder 0.2 weight portion, trimer 0.8 weight portion of polyisocyanates, polytetrafluoroethylene fibre 1 weight portion.
The present invention also provides for the preparation method of a kind of carbon fiber modifying nano green environment-friendly rubber, comprises the steps of:
(1) asphalt base carbon fiber powder is joined non-halogenated organophosphinate, hexamethylenetetramine, tri-methyl-amyl three second
In TMOS, and after adding the water of gross weight 5-6 times, magnetic agitation 2-4h to uniformly, then stirring calcining at 200-300 DEG C
3-4h, standby as component A；
(2) granules of polystyrene, methylcellulose, polypropylene fibre, starch ether, flyash, polypropylene chopped strand are placed in
Pulverizer is pulverized, crosses 100-200 mesh sieve, prepare component B standby；
(3) by micro-to metakaolin, silicon carbide micro-powder, nano silicon, Alumen, organic siliconresin, nano-cerium oxide, vitreous
Pearl, gangue, conductive mica powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre are placed in pulverizing
Machine is pulverized, crosses 100-200 mesh sieve, prepare component C standby；
(4) the rubber powder slurry mix and blend of half amount will be added after component A, the mixing of component B, mixing speed 450-550r/min,
Whipping temp is 55-65 DEG C, mixing time 30-45min.
(5), while component C being added in step (4), add the rubber powder slurry of residue half amount, add after stirring 30min
Entering toner, mixing speed 450-550r/min, whipping temp is 55-65 DEG C, mixing time 40-60min, prepares adhesive polystyrene
Granule exterior wall fire-resistant nanometer substrate component D；
Plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber, regeneration
Rubber puts into mix and blend 30min in the plasticator that internal temperature is 120 DEG C, obtains component E,
(6) mixing, component D, E are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
(7) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
2 one kinds of carbon fiber modifying nano green environment-friendly rubbers of embodiment and preparation method thereof
A kind of carbon fiber modifying nano green environment-friendly rubber, the constitutive material that it includes is: chlorohydrin rubber 100 parts, nitrile rubber
40 parts, acrylonitrile-butadiene copolymer rubber 60 parts, diene rubber 60 parts, 30 parts of butadiene-styrene rubber, reclaimed rubber 30 parts, Colophonium
35 parts of base carbon fibre powder, non-halogenated organophosphinate 7 parts, hexamethylenetetramine 10 parts, tri-methyl-amyl triethoxysilicane
4 parts of alkane, rubber powder slurry 20 weight portion, granules of polystyrene 10 weight portion, methylcellulose 18 weight portion, toner 15 weight
Part, polypropylene fibre 10 weight portion, starch ether 5 weight portion, flyash 6 weight portion, polypropylene chopped strand 16 weight portion, higher
Ridge soil 18 weight portions, silicon carbide micro-powder 6 weight portion, nano silicon 16 weight portion, Alumen 10 weight portion, organic siliconresin 5
Weight portion, nano-cerium oxide 5 weight portion, glass bead 9 weight portion, gangue 35 weight portion, conductive mica powder 0.5 weight portion,
Conductive nano graphite powder 0.4 weight portion, trimer 1 weight portion of polyisocyanates, polytetrafluoroethylene fibre 2 weight portion.
The present invention also provides for the preparation method of a kind of carbon fiber modifying nano green environment-friendly rubber, comprises the steps of:
(1) asphalt base carbon fiber powder is joined non-halogenated organophosphinate, hexamethylenetetramine, tri-methyl-amyl three second
In TMOS, and after adding the water of gross weight 5-6 times, magnetic agitation 2-4h to uniformly, then stirring calcining at 200-300 DEG C
3-4h, standby as component A；
(2) granules of polystyrene, methylcellulose, polypropylene fibre, starch ether, flyash, polypropylene chopped strand are placed in
Pulverizer is pulverized, crosses 100-200 mesh sieve, prepare component B standby；
(3) by micro-to metakaolin, silicon carbide micro-powder, nano silicon, Alumen, organic siliconresin, nano-cerium oxide, vitreous
Pearl, gangue, conductive mica powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre are placed in pulverizing
Machine is pulverized, crosses 100-200 mesh sieve, prepare component C standby；
(4) the rubber powder slurry mix and blend of half amount will be added after component A, the mixing of component B, mixing speed 450-550r/min,
Whipping temp is 55-65 DEG C, mixing time 30-45min.
(5), while component C being added in step (4), add the rubber powder slurry of residue half amount, add after stirring 30min
Entering toner, mixing speed 450-550r/min, whipping temp is 55-65 DEG C, mixing time 40-60min, prepares adhesive polystyrene
Granule exterior wall fire-resistant nanometer substrate component D；
Plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber, regeneration
Rubber puts into mix and blend 30min in the plasticator that internal temperature is 120 DEG C, obtains component E,
(6) mixing, component D, E are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
(7) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute
The equivalence change done or modification, in the range of being all included in present patent application.
Claims (2)
1. a carbon fiber modifying nano green environment-friendly rubber, it is characterised in that the constitutive material that it includes is: chlorohydrin rubber
80-100 part, nitrile rubber 30-40 part, acrylonitrile-butadiene copolymer rubber 50-60 part, diene rubber 50-60 part, butylbenzene
Rubber 20-30 part, reclaimed rubber 25-30 part, asphalt base carbon fiber powder 30-35 part, non-halogenated organophosphinate 5-7 part,
Hexamethylenetetramine 8-10 part, tri-methyl-amyl triethoxysilane 2-4 part, rubber powder slurry 10-20 weight portion, polystyrene
Grain 6-10 weight portion, methylcellulose 12-18 weight portion, toner 5-15 weight portion, polypropylene fibre 4-10 weight portion, starch
Ether 1-5 weight portion, flyash 2-6 weight portion, polypropylene chopped strand 10-16 weight portion, metakaolin 12-18 weight portion, carbon
SiClx micropowder 2-6 weight portion, nano silicon 10-16 weight portion, Alumen 2-10 weight portion, organic siliconresin 1-5 weight portion,
Nano-cerium oxide 1-5 weight portion, glass bead 5-9 weight portion, gangue 30-35 weight portion, conductive mica powder 0.3-0.5 weight
Part, conductive nano graphite powder 0.2-0.4 weight portion, the trimer 0.8-1 weight portion of polyisocyanates, polytetrafluoroethylene fibre 1-
2 weight portions.
The preparation method of a kind of carbon fiber modifying nano green environment-friendly rubber the most according to claim 1, it is characterised in that:
Comprise the steps of:
(1) asphalt base carbon fiber powder is joined non-halogenated organophosphinate, hexamethylenetetramine, tri-methyl-amyl three second
In TMOS, and after adding the water of gross weight 5-6 times, magnetic agitation 2-4h to uniformly, then stirring calcining at 200-300 DEG C
3-4h, standby as component A；
(2) granules of polystyrene, methylcellulose, polypropylene fibre, starch ether, flyash, polypropylene chopped strand are placed in
Pulverizer is pulverized, crosses 100-200 mesh sieve, prepare component B standby；
(3) by micro-to metakaolin, silicon carbide micro-powder, nano silicon, Alumen, organic siliconresin, nano-cerium oxide, vitreous
Pearl, gangue, conductive mica powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre are placed in pulverizing
Machine is pulverized, crosses 100-200 mesh sieve, prepare component C standby；
(4) the rubber powder slurry mix and blend of half amount will be added after component A, the mixing of component B, mixing speed 450-550r/min,
Whipping temp is 55-65 DEG C, mixing time 30-45min.
(5) while component C being added in step (4), add the rubber powder slurry of residue half amount, add after stirring 30min and adjust
Toner, mixing speed 450-550r/min, whipping temp is 55-65 DEG C, mixing time 40-60min, prepares glue powder polyphenyl particle
Exterior wall fire-resistant nanometer substrate component D；
Plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber, regeneration
Rubber puts into mix and blend 30min in the plasticator that internal temperature is 120 DEG C, obtains component E,
(6) mixing, component D, E are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
(7) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110615992A (en) * | 2019-10-15 | 2019-12-27 | 中国工程物理研究院化工材料研究所 | Chopped fiber reinforced organic silicon resin composition and preparation method thereof |
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| CN105462177A (en) * | 2016-01-07 | 2016-04-06 | 苏州法斯特信息科技有限公司 | High-temperature resistance inflaming retarding bamboo-plastic composite material and preparation method thereof |
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| CN101778903A (en) * | 2007-07-06 | 2010-07-14 | 独立行政法人产业技术综合研究所 | Structural body comprising filler and incompatible resin or elastomer, and production process or use thereof |
| CN102378834A (en) * | 2009-01-30 | 2012-03-14 | 帝人株式会社 | Graphitized short fibers and composition thereof |
| CN105164193A (en) * | 2013-05-03 | 2015-12-16 | 埃克森美孚化学专利公司 | Filled elastomeric composite and process to control composite crumb size |
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