CN106165879A - A kind of safe and efficient edible defoaming agent and preparation method thereof - Google Patents
A kind of safe and efficient edible defoaming agent and preparation method thereof Download PDFInfo
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- CN106165879A CN106165879A CN201610511245.XA CN201610511245A CN106165879A CN 106165879 A CN106165879 A CN 106165879A CN 201610511245 A CN201610511245 A CN 201610511245A CN 106165879 A CN106165879 A CN 106165879A
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- Prior art keywords
- silicone oil
- parts
- containing hydrogen
- water
- tween
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Links
- 239000002518 antifoaming agent Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920002545 silicone oil Polymers 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 15
- -1 polypropylene glycerol Polymers 0.000 claims abstract description 15
- 229920000136 polysorbate Polymers 0.000 claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 11
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 10
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 10
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 239000013530 defoamer Substances 0.000 abstract description 15
- 235000013305 food Nutrition 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000003254 anti-foaming effect Effects 0.000 abstract description 7
- 229910052785 arsenic Inorganic materials 0.000 abstract description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 229910002015 Aerosil® 150 Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000006260 foam Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 3
- 239000002778 food additive Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- AQLLBJAXUCIJSR-UHFFFAOYSA-N OC(=O)C[Na] Chemical compound OC(=O)C[Na] AQLLBJAXUCIJSR-UHFFFAOYSA-N 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Edible Oils And Fats (AREA)
Abstract
The present invention relates to safe and efficient edible defoaming agent of use and preparation method thereof in a kind of food manufacturing process；The invention aims to provide safe and efficient practical defoamer that a kind of antifoaming speed is fast, insoluble substance is few, usage amount is little and preparation method thereof.Defoamer includes containing hydrogen silicone oil, aerosil, polypropylene glycerol aether, sodium carboxymethyl cellulose, tween, span, water；Containing hydrogen silicone oil and aerosil 150 250 DEG C, being cooled to 40 50 DEG C after reacting 68 hours, addition polypropylene glycerol aether continues addition water, sodium carboxymethyl cellulose, span, tween after stirring is reacted 34 hours and carries out 24 hours i.e. obtaining product after emulsion reaction.The present invention improves 30 50% than the antifoaming speed of commercially available general defoamer, and usage amount reduces by 50%, reduces the water-insoluble after using defoamer, and product heavy metal, arsenic content are far below existing product.
Description
Technical field
The invention belongs to edible additive field, be specifically related in a kind of food manufacturing process the safe and efficient edible of use
Defoamer and preparation method thereof.
Background technology
When processing the raw-food material of high starch, high sugar, material can produce a large amount of foam, and now material can be with foam overflow
Causing waste and pollute environment, during fried food, oil bubbles to overflow then to there will be and hurts sb.'s feelings or fire incident；Bean product, canned food,
Flavoring agent, medicated beer, monosodium glutamate, milk powder, coffee, beverage, concentrated fruit juice, refine sugar, the production process such as fermentation also can produce foam.This
A little foams can affect working (machining) efficiency and effect, constrains food-processing industry, thus defoamer as food additive by extensively
General it is used in food-processing industry.In food processing, China allows the defoamer used to have propylene glycol, higher alcohols fatty acid ester multiple
Compound, aqueous emulsion of dimethyl polysiloxane fluid and solids.But either which kind of defoamer, has when using in food processing operation
Strict usage amount to limit.
In existing production technology, commercially available aqueous emulsion of dimethyl polysiloxane fluid and solid edible defoamer exist antifoaming speed slow,
Suds effect is poor, insoluble substance is many and the consumption of defoamer big, harmful substance increases the shortcomings such as risk, and serious restriction food is raw
Product, working (machining) efficiency and the popularization and application of follow-up product and development.
Summary of the invention
The invention aims to provide that a kind of antifoaming speed is fast, insoluble substance is few, that usage amount is little is safe and efficient
Practical defoamer and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is: a kind of safe and efficient edible defoaming agent includes as follows
Weight portion: containing hydrogen silicone oil 10-18 part, aerosil 4-10 part, polypropylene glycerol aether 2-6 part, sodium carboxymethyl cellulose
1-5 part, tween 1-2 part, span 1-2 part, water 50-80 part.Tween i.e. Polysorbate, span i.e. sorbitan fatty acid ester.
It is further preferred that containing hydrogen silicone oil 12-15 part, aerosil 5-8 part, polypropylene glycerol aether 3-5 part, carboxylic
Sodium carboxymethylcellulose pyce 2-4 part, tween 1-2 part, span 1-2 part, water 60-70 part.
Further preferred, containing hydrogen silicone oil 13 parts, aerosil 6 parts, polypropylene glycerol aether 4 parts, carboxymethyl
Sodium cellulosate 3 parts, tween 1.5 parts, span 1.5 parts, 65 parts of water.
Further, described containing hydrogen silicone oil is methyl-silicone oil.
The preparation method of above-mentioned edible defoaming agent includes step:
A. containing hydrogen silicone oil and aerosil add in reactor, after stirring mixing, are heated to 150-250 DEG C,
React 6-8 hour；
B. material cooling down is to 40-50 DEG C, under agitation adds polypropylene glycerol aether and continues stirring reaction 3-4 hour
After, proceed to emulsion reactor after being cooled to room temperature；
C., under higher mixing speed stirs, in emulsifying kettle, addition water, sodium carboxymethyl cellulose, span, tween are carried out
Product is i.e. obtained after 2-4 hour emulsion reaction.
The defoamer using the inventive method to prepare has the advantage that
The most all raw materials meet state food Additive Production requirement, and application effect of products is faster than existing product antifoaming speed,
Improve 30-50% than the antifoaming speed of commercially available general defoamer, and suds effect is stable.It is particularly suited for cauldron (bore
More than 1m) equipment use, its antifoaming speed can promote several times, and same defoaming effect need to use the amount of this product to disappear than tradition
Infusion decreases 50%, and the industrialized production of food service industry is greatly facilitated.
2. the water-insoluble produced after using defoamer decreases 90% compared with common defoamer, saves energy resource consumption,
Maintaining original quality and the mouthfeel of application food, dispersive property good quality is stable.
3. product heavy metal, the arsenic content that prepared by employing this method are less than existing product, than standard SN/T 2360.4-2009
The arsenic content of defined is low, and intermediate polyethers silicone grease can be additionally used in cosmetics manufacture and pharmaceuticals industry.
4. inventive formulation eliminates the raw material ground calcium carbonate containing heavy metal and arsenic, all raw materials in invention formula
Meet food additive production requirement.Preparation process will not introduce heavy metal, arsenic poisonous and harmful substance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.The described embodiment only present invention is preferable to carry out
Example, is not limited to the present invention, and for a person skilled in the art, the present invention can have various change and change
Change.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention
Protection domain within.
Embodiment one
18kg containing hydrogen silicone oil and 5kg aerosil add in reactor, after stirring mixing, are heated to 250 DEG C,
After reacting 6 hours, material cooling down to 40 DEG C, under agitation add 3kg polypropylene glycerol aether and continue stirring reaction 4 hours
After, proceed to emulsion reactor after being cooled to room temperature.Under higher mixing speed stirs, in emulsifying kettle, add 69kg water, 2kg carboxylic first
Base sodium cellulosate, 1kg span, 1.5kg tween prepare product after carrying out 4 hours emulsion reactions.
Embodiment two
12kg containing hydrogen silicone oil and 7kg aerosil add in reactor, after stirring mixing, are heated to 150 DEG C,
After reacting 8 hours, material cooling down to 50 DEG C, under agitation add 4kg polypropylene glycerol aether and continue stirring reaction 3 hours
After, proceed to emulsion reactor after being cooled to room temperature.Under higher mixing speed stirs, in emulsifying kettle, add 60kg water, 4kg carboxylic first
Base sodium cellulosate, 2kg span, 1kg tween prepare product after carrying out 2 hours emulsion reactions.
Embodiment three
13kg containing hydrogen silicone oil and 6kg aerosil add in reactor, after stirring mixing, are heated to 200 DEG C,
After reacting 7 hours, material cooling down to 45 DEG C, under agitation add the continuation stirring reaction 3.5 of 4kg polypropylene glycerol aether little
Shi Hou, proceeds to emulsion reactor after being cooled to room temperature.Under higher mixing speed stirs, in emulsifying kettle, add 65kg water, 3kg carboxylic
Sodium carboxymethylcellulose pyce, 1.5kg span, 1.5kg tween prepare product after carrying out 3 hours emulsion reactions.
Claims (5)
1. a safe and efficient edible defoaming agent, it is characterised in that: include following weight portion: containing hydrogen silicone oil 10-18 part, gas phase two
Silicon oxide 4-10 part, polypropylene glycerol aether 2-6 part, sodium carboxymethyl cellulose 1-5 part, tween 1-2 part, span 1-2 part, water
50-80 part.
Edible defoaming agent the most according to claim 1, it is characterised in that: include following weight portion: containing hydrogen silicone oil 12-15
Part, aerosil 5-8 part, polypropylene glycerol aether 3-5 part, sodium carboxymethyl cellulose 2-4 part, tween 1-2 part, span 1-
2 parts, water 60-70 part.
Edible defoaming agent the most according to claim 1, it is characterised in that: include following weight portion: containing hydrogen silicone oil 13 parts, gas
Aerosil 6 parts, polypropylene glycerol aether 4 parts, sodium carboxymethyl cellulose 3 parts, tween 1.5 parts, span 1.5 parts, 65 parts of water.
Edible defoaming agent the most as claimed in any of claims 1 to 3, it is characterised in that: described containing hydrogen silicone oil is first
Base silicone oil.
The preparation method of edible defoaming agent the most as claimed in any of claims 1 to 4, it is characterised in that: include step
Rapid:
A. containing hydrogen silicone oil and aerosil add in reactor, after stirring mixing, are heated to 150-250 DEG C, reaction
6-8 hour；
B. material cooling down is to 40-50 DEG C, after under agitation adding polypropylene glycerol aether continuation stirring reaction 3-4 hour,
Emulsion reactor is proceeded to after being cooled to room temperature；
C., under higher mixing speed stirs, in emulsifying kettle, water, sodium carboxymethyl cellulose, span are added, that tween carries out 2-4 is little
Time emulsion reaction after obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610511245.XA CN106165879A (en) | 2016-06-30 | 2016-06-30 | A kind of safe and efficient edible defoaming agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610511245.XA CN106165879A (en) | 2016-06-30 | 2016-06-30 | A kind of safe and efficient edible defoaming agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106165879A true CN106165879A (en) | 2016-11-30 |
Family
ID=58065971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610511245.XA Pending CN106165879A (en) | 2016-06-30 | 2016-06-30 | A kind of safe and efficient edible defoaming agent and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106165879A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108998497A (en) * | 2018-05-28 | 2018-12-14 | 广州富诺营养科技有限公司 | A kind of number of viable detection method of embedding type probiotic products |
| CN111171321A (en) * | 2020-02-24 | 2020-05-19 | 华南理工大学 | Long-chain alkyl silicone oil type silicon paste and preparation method and application thereof |
| CN112293725A (en) * | 2020-10-21 | 2021-02-02 | 扬州宏远新材料股份有限公司 | Preparation process of food-grade additive polydimethylsiloxane emulsion |
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| CN1657147A (en) * | 2005-01-05 | 2005-08-24 | 长春理工大学 | Silicone ether defoamer for food processing |
| CN101053802A (en) * | 2007-02-28 | 2007-10-17 | 王旭东 | Water soluble compound organosilicon emulsion highly effective defoaming agent and its synthetic method |
| CN101357309A (en) * | 2008-09-26 | 2009-02-04 | 贺明波 | Silicon oil foam killer |
| CN104452346A (en) * | 2014-12-04 | 2015-03-25 | 宿州市华润化工有限责任公司 | Organic silicon defoaming agent for textile printing and dyeing |
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2016
- 2016-06-30 CN CN201610511245.XA patent/CN106165879A/en active Pending
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| CN1657147A (en) * | 2005-01-05 | 2005-08-24 | 长春理工大学 | Silicone ether defoamer for food processing |
| CN101053802A (en) * | 2007-02-28 | 2007-10-17 | 王旭东 | Water soluble compound organosilicon emulsion highly effective defoaming agent and its synthetic method |
| CN101357309A (en) * | 2008-09-26 | 2009-02-04 | 贺明波 | Silicon oil foam killer |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108998497A (en) * | 2018-05-28 | 2018-12-14 | 广州富诺营养科技有限公司 | A kind of number of viable detection method of embedding type probiotic products |
| CN108998497B (en) * | 2018-05-28 | 2021-09-14 | 广州富诺营养科技有限公司 | Method for detecting viable bacteria quantity of embedded probiotic product |
| CN111171321A (en) * | 2020-02-24 | 2020-05-19 | 华南理工大学 | Long-chain alkyl silicone oil type silicon paste and preparation method and application thereof |
| CN111171321B (en) * | 2020-02-24 | 2021-05-14 | 华南理工大学 | Long-chain alkyl silicone oil type silicon paste and preparation method and application thereof |
| CN112293725A (en) * | 2020-10-21 | 2021-02-02 | 扬州宏远新材料股份有限公司 | Preparation process of food-grade additive polydimethylsiloxane emulsion |
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Application publication date: 20161130 |