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CN106128727B - A kind of automobile ignition coil static iron core - Google Patents

A kind of automobile ignition coil static iron core Download PDF

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CN106128727B
CN106128727B CN201610607892.0A CN201610607892A CN106128727B CN 106128727 B CN106128727 B CN 106128727B CN 201610607892 A CN201610607892 A CN 201610607892A CN 106128727 B CN106128727 B CN 106128727B
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iron core
static iron
ignition coil
automobile ignition
alloy
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CN106128727A (en
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沈荣存
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Ningbo Chenjiang Electromechanical Technology Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F38/00Adaptations of transformers or inductances for specific applications or functions
    • H01F38/12Ignition, e.g. for IC engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/102Metallic powder coated with organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02Compacting only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • H01F1/14708Fe-Ni based alloys
    • H01F1/14733Fe-Ni based alloys in the form of particles
    • H01F1/14741Fe-Ni based alloys in the form of particles pressed, sintered or bonded together
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F27/00Details of transformers or inductances, in general
    • H01F27/24Magnetic cores
    • H01F27/255Magnetic cores made from particles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0206Manufacturing of magnetic cores by mechanical means
    • H01F41/0246Manufacturing of magnetic circuits by moulding or by pressing powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • B22F2003/248Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • B22F2009/041Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by mechanical alloying, e.g. blending, milling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F38/00Adaptations of transformers or inductances for specific applications or functions
    • H01F38/12Ignition, e.g. for IC engines
    • H01F2038/122Ignition, e.g. for IC engines with rod-shaped core

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Ignition Installations For Internal Combustion Engines (AREA)

Abstract

本发明公开了一种汽车点火线圈用静铁芯,软磁铁芯的形状为圆柱体;软磁铁芯的组分及含量,按重量百分比计,包括Ni 4‑6%、Mo 2‑3%、Co 0.2‑0.5%、Cd 0.2‑0.4%、Mn 0.1‑0.2%、Ba 0.1‑0.3%、酚醛树脂1‑2%以及余量为铁。软磁铁芯按照如下工艺进行制备。制备工艺包括真空熔炼、初粉碎、酸洗、中粉碎、细粉碎、脱液、烘干、筛分、退火处理、绝缘包覆、压制成型、热处理等步骤。采用上述组分与制备工艺后,软磁铁芯为一体竖向成型压制,成型压力低,具有更高的成型密度、电阻率、初始磁导率、饱和磁感应强度和频谱特性,且高频损耗低。The invention discloses a static iron core for an automobile ignition coil. The shape of the soft magnetic core is a cylinder; the composition and content of the soft magnetic core include Ni 4-6%, Mo 2-3%, Co 0.2-0.5%, Cd 0.2-0.4%, Mn 0.1-0.2%, Ba 0.1-0.3%, phenolic resin 1-2%, and the balance is iron. The soft magnetic core is prepared according to the following process. The preparation process includes steps such as vacuum smelting, primary crushing, pickling, secondary crushing, fine crushing, dehydration, drying, screening, annealing treatment, insulation coating, compression molding, and heat treatment. After adopting the above components and preparation process, the soft magnetic core is vertically molded and pressed in one piece, with low molding pressure, higher molding density, resistivity, initial magnetic permeability, saturation magnetic induction and spectral characteristics, and low high-frequency loss .

Description

一种汽车点火线圈用静铁芯Static iron core for automobile ignition coil

技术领域technical field

本发明涉及汽车发动机点火系统,特别是一种汽车点火线圈用静铁芯。The invention relates to an ignition system of an automobile engine, in particular to a static iron core for an automobile ignition coil.

背景技术Background technique

在汽车发动机点火系统中,点火线圈是为点燃发动机汽缸内空气和燃油混合物提供点火能量的执行部件。它基于电磁感应的原理,通过关断和打开点火线圈的初级回路,初级回路中的电流增加然后又突然减小,这样在次级就会感 应产生点燃所需的高电压。点火线圈可以认为是一种特殊的脉冲变压器,它将 10-12V的低电压转换成25000V或更高的电压。目前,较典型的为开磁路笔式点火线圈,其包括构成点火线圈磁路的开放式铁芯、绕在铁芯上的次级铜线绕组和绕于次级绕组外侧的初级线圈绕组。主要是通过初级线圈绕组的电流作为磁场储存。当初级线圈绕组电流突然被切断(通过功率晶体管断开电路接地端)时,磁场衰减,使次级线圈绕组产生感应电动势,该感应电动势的电压足以使 笔式线圈放电,我们称其为电感放电式点火。另外也有电容放电式点火系统, 通常被称为CDI点火方式。In the ignition system of an automobile engine, the ignition coil is an executive component that provides ignition energy for igniting the air and fuel mixture in the engine cylinder. It is based on the principle of electromagnetic induction, by turning off and on the primary circuit of the ignition coil, the current in the primary circuit increases and then suddenly decreases, so that the high voltage required for ignition is induced in the secondary. The ignition coil can be thought of as a special pulse transformer that converts a low voltage of 10-12V into a voltage of 25000V or higher. At present, the more typical one is the open magnetic circuit pen type ignition coil, which includes an open iron core forming the magnetic circuit of the ignition coil, a secondary copper wire winding wound on the iron core, and a primary coil winding wound outside the secondary winding. Mainly the current through the primary coil winding is stored as a magnetic field. When the current of the primary coil winding is cut off suddenly (disconnecting the ground terminal of the circuit through the power transistor), the magnetic field decays, causing the secondary coil winding to generate an induced electromotive force, and the voltage of the induced electromotive force is sufficient to discharge the pencil coil, which we call inductive discharge type ignition. There is also a capacitive discharge ignition system, commonly referred to as CDI ignition.

点火线圈中铁芯是核心部件,铁芯的电感量直接影响到线圈的点火能量。The iron core in the ignition coil is the core component, and the inductance of the iron core directly affects the ignition energy of the coil.

2014年1月1日公开的申请号为201310273684.8的中国发明专利申请,其发明创造的名称为“一种汽车火花塞点火器铁芯组”,其中第一铁芯是由多层电工钢带的冲片料带叠成并连在一起的分段铁芯折叠成封闭形状的环形铁芯;每层冲片料带由4个分段及连接区组成,第一分段和第二分段、第二分段和第三分段、第三分段和第四分段之间由连接区连接,而第一分段和第四分段的外侧相对的位置上分别设计成凸台及凹槽以便铰接锁紧;电工钢带的晶粒方向与四个分段的长度方向一致;第二铁芯安装在上面提到的连接成环的第一铁芯里面,它也是由多层电工钢冲片料带叠压而成,并且其长度方向与电工钢晶粒方向一致。从而具有节省材料以及降低成本的优点。The Chinese invention patent application with the application number 201310273684.8 published on January 1, 2014, the name of its invention is "A core set for automobile spark plug igniter", in which the first core is made of multi-layer electrical steel strips. The segmented iron core stacked and connected together is folded into a closed-shaped annular iron core; each layer of punched sheet material is composed of 4 segments and connecting areas, the first segment and the second segment, the second segment The first segment and the third segment, and the third segment and the fourth segment are connected by a connecting area, and the opposite positions on the outside of the first segment and the fourth segment are respectively designed as bosses and grooves for hinged lock Tight; the grain direction of the electrical steel strip is consistent with the length direction of the four segments; the second iron core is installed in the above-mentioned first iron core connected into a ring, and it is also made of multi-layer electrical steel strips It is laminated, and its length direction is consistent with the grain direction of electrical steel. Therefore, it has the advantages of material saving and cost reduction.

2013年2月27日公开的申请号为“201210485879.4”的中国发明专利申请,其发明创造的名称为“一种汽车点火线圈铁芯级进模自动冲压计数叠片铆压成型的方法”,其主要由冲床压铆机、单片机及电控柜、料带固定卷放装置、余料带收卷装置组成,在电控柜中设有单片机,在级进模上设有接近传感器开关、电磁阀利用接近传感器开关进行记忆计数,设定要求数值,由单片机数值设置输出信号,控制电磁阀,电磁阀输出控制气缸实现叠片计数,还在级进模内设置一个防错纠正传感器,即防错纠正按钮,控制冲床和级进模停止工作,对设备进行调整正确后,重新开始连续冲压工作。本发明提高生产效率10倍,只需1人操作,产品合格率从原来的85%—90%提高到99.7%,降低了生产成本。The Chinese invention patent application with the application number "201210485879.4" published on February 27, 2013 is titled "A Method for Automated Stamping and Counting Lamination Riveting Forming of Auto Ignition Coil Core Progressive Die", which It is mainly composed of a punch press riveting machine, a single-chip computer and an electric control cabinet, a fixed tape unwinding device, and a rewinding device for the remaining material tape. There is a single-chip computer in the electric control cabinet, and a proximity sensor switch and a solenoid valve are installed on the progressive die. Use the proximity sensor switch for memory counting, set the required value, set the output signal by the value of the single-chip microcomputer, control the solenoid valve, the output of the solenoid valve controls the cylinder to realize the lamination counting, and set an error-proof correction sensor in the progressive die, that is, error-proofing Correct the button, control the punch press and progressive die to stop working, and restart the continuous punching work after the equipment is adjusted correctly. The invention improves the production efficiency by 10 times, only needs one person to operate, and the qualified rate of the product is increased from 85%-90% to 99.7%, which reduces the production cost.

上述两件专利申请中, 汽车点火线圈铁芯均采用硅钢片叠放后,铆压成型的方法进行制备。硅钢片在叠片及铆压成型时,叠片容易错位,片与片之间有铆压间隙及铆压损伤等,故导致汽车点火线圈铁芯的电阻率低下,初始导磁率及磁感应强度低,损耗高,高频响应较差,铁芯的电感量较小,从而导致线圈的 点火能量小。In the above two patent applications, the iron cores of the automobile ignition coils are all prepared by stacking silicon steel sheets and then riveting and forming. When the silicon steel sheets are laminated and riveted, the laminations are easily dislocated, and there are riveting gaps and riveting damage between the sheets, which leads to low resistivity, initial magnetic permeability and low magnetic induction of the automobile ignition coil core. , high loss, poor high-frequency response, and small inductance of the iron core, resulting in low ignition energy of the coil.

另外,目前,静铁芯的制作工艺都是采用水平固定压制法,具体过程为:将凹模固定在 模架上,凹模内装上铁粉,采用上冲和下冲一起压制,其中,下冲为一半圆柱形,固定不动,凹模也固定不动,上冲也为一半圆柱形,通过上冲的上下移动 完成压制过程。因为整根铁芯由两个半圆柱形拼合而成,两半圆之间总是存在一定的接口,不能形成一个完整的圆,使铁芯的电感量较小,从而导致线圈的点火能量小。同时,铁芯地横截面为类似椭圆形,并且中间有较宽的接缝,表面光洁度差。铁芯采用纯铁粉制作,具有较低的电阻率,低的饱和磁感应强度, 较大的损耗,且高频响应较差。In addition, at present, the manufacturing process of the static iron core adopts the horizontal fixed pressing method. The specific process is: the die is fixed on the formwork, iron powder is installed in the die, and the upper punch and the lower punch are used to press together. The punch is half-cylindrical and fixed, the die is also fixed, and the upper punch is also half-cylindrical, and the pressing process is completed by moving the upper punch up and down. Because the whole iron core is composed of two semi-cylindrical shapes, there is always a certain interface between the two semi-circles, which cannot form a complete circle, so that the inductance of the iron core is small, resulting in a small ignition energy of the coil. At the same time, the cross section of the iron core is similar to an ellipse, and there is a wide seam in the middle, and the surface finish is poor. The iron core is made of pure iron powder, which has low resistivity, low saturation magnetic induction, large loss, and poor high-frequency response.

发明内容Contents of the invention

本发明要解决的技术问题是针对上述现有技术的不足,而提供一种汽车点火线圈用静铁芯,该汽车点火线圈用静铁芯为一体竖向成型压制,成型压力低,具有更高的成型密度、电阻率、初始磁导率、饱和磁感应强度和频谱特性,且高频损耗低。另外,静铁芯的表面光洁度好,横截面为正圆形,使一定尺寸的铁芯具有更大的电感量,为线圈提供更高的点火能量。The technical problem to be solved by the present invention is to provide a static iron core for an automobile ignition coil, which is integrally formed and pressed vertically, with low molding pressure and higher Excellent molding density, resistivity, initial permeability, saturation magnetic induction and spectral characteristics, and low high-frequency loss. In addition, the surface finish of the static iron core is good, and the cross section is a perfect circle, so that the iron core of a certain size has greater inductance and provides higher ignition energy for the coil.

为解决上述技术问题,本发明采用的技术方案是:In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:

一种汽车点火线圈用静铁芯,静铁芯的形状为圆柱体;静铁芯的组分及含量,按重量百分比计,包括Ni 4-6%、Mo 2-3%、Co 0.2-0.5%、Cd 0.2-0.4%、Mn 0.1-0.2%、Ba 0.1-0.3%、酚醛树脂1-2%以及余量主要为铁。静铁芯按照如下工艺进行制备。A static iron core for an automobile ignition coil, the shape of the static iron core is a cylinder; the composition and content of the static iron core, by weight percentage, include Ni 4-6%, Mo 2-3%, Co 0.2-0.5 %, Cd 0.2-0.4%, Mn 0.1-0.2%, Ba 0.1-0.3%, phenolic resin 1-2%, and the balance is mainly iron. The static iron core is prepared according to the following process.

第一步,真空熔炼:将铁块、镍块和钼块按照配比,投入真空感应炉中进行熔炼浇铸。The first step is vacuum smelting: the iron block, nickel block and molybdenum block are put into the vacuum induction furnace according to the ratio for smelting and casting.

第二步,初粉碎:将第一步熔炼浇铸完成的合金,使用粉碎机进行初步粉碎。The second step, primary crushing: the alloy that has been smelted and casted in the first step is initially crushed using a pulverizer.

第三步,酸洗:将第二步初粉碎的合金使用金属表面酸洗液进行酸洗。The third step, pickling: the alloy pulverized in the second step is pickled with a metal surface pickling solution.

第四步,中粉碎:在氮气保护氛围下,先将第二步初粉碎的合金放入风选砂磨机内,再按照配比,依次加入Co、Cd、Mn和Ba,开启风选砂磨机,进行中粉碎。The fourth step, medium crushing: under the nitrogen protection atmosphere, first put the alloy that was crushed in the second step into the winnowing sand mill, and then add Co, Cd, Mn and Ba in sequence according to the proportion, and start the winnowing sand Mill, crushing in progress.

第五步,细粉碎:在酒精保护氛围下,将粉碎的合金使用风选砂磨机再次进行细粉碎。The fifth step, fine crushing: under the protective atmosphere of alcohol, the crushed alloy is finely crushed again with a winnowing sand mill.

第六步,脱液、烘干:使用离心机对细粉碎的合金粉,进行脱液;再利用烘箱将脱液后的合金粉进行烘干。The sixth step, deliquoring and drying: use a centrifuge to deliquify the finely pulverized alloy powder; then use an oven to dry the deliquored alloy powder.

第七步,筛分:对脱液烘干完成的合金粉使用振动筛进行筛分。The seventh step, sieving: use a vibrating sieve to sieve the alloy powder that has been deliquored and dried.

第八步,退火处理:在氢氮混合气氛下,将筛分完成的合金粉使用推舟炉进行退火处理。The eighth step, annealing treatment: under the mixed atmosphere of hydrogen and nitrogen, the sieved alloy powder is annealed in a push boat furnace.

第九步,绝缘包覆:将退火处理完成的合金粉加入绝缘包覆搅拌桶内,再按照配比加入酚醛树脂、云母粉和润滑剂,绝缘包覆搅拌桶进行加热搅拌与包覆。The ninth step, insulation coating: add the annealed alloy powder into the insulation coating mixing tank, then add phenolic resin, mica powder and lubricant according to the ratio, heat, stir and coat the insulation coating mixing tank.

第十步,压制成型:使用成型压机,采用垂直竖向压制的方式,使圆柱形的静铁芯一体成型压制。The tenth step, pressing and forming: using a forming press, adopting a vertical and vertical pressing method, so that the cylindrical static iron core is integrally formed and pressed.

第十一步,热处理:将第十步压制成型的静铁芯进行热处理。The eleventh step, heat treatment: the static iron core pressed and formed in the tenth step is subjected to heat treatment.

所述第八步中,退火处理的温度为800-1200℃,保温2-4小时。In the eighth step, the temperature of the annealing treatment is 800-1200° C., and the temperature is kept for 2-4 hours.

所述第十一步中,热处理的温度为120-200℃,保温4-6小时。In the eleventh step, the heat treatment temperature is 120-200° C., and the temperature is kept for 4-6 hours.

所述绝缘包覆搅拌桶的加热温度为55-65℃,绝缘包覆搅拌桶包括内桶、外桶和包覆在外桶四周的加热装置,内桶既能自转,又能随着外桶进行公转。The heating temperature of the insulating and coating mixing barrel is 55-65°C. The insulating and covering mixing barrel includes an inner barrel, an outer barrel and a heating device wrapped around the outer barrel.

圆柱形的静铁芯一体成型压制时的成型压力为6-12T/cm2,成型温度为60-200℃。When the cylindrical static iron core is integrally molded and pressed, the molding pressure is 6-12T/cm 2 , and the molding temperature is 60-200°C.

本发明采用上述组分与制备工艺后,静铁芯为一体竖向成型压制,成型压力低,具有更高的成型密度、电阻率、初始磁导率、饱和磁感应强度和频谱特性,且损耗低。另外,静铁芯的表面光洁度好,横截面为正圆形,使一定尺寸的铁芯具有更大的电感量,为线圈提供更高的点火能量。After the above components and preparation process are adopted in the present invention, the static iron core is integrally formed and pressed vertically, with low forming pressure, higher forming density, resistivity, initial magnetic permeability, saturation magnetic induction and spectral characteristics, and low loss . In addition, the surface finish of the static iron core is good, and the cross section is a perfect circle, so that the iron core of a certain size has greater inductance and provides higher ignition energy for the coil.

具体实施方式detailed description

下面就具体较佳实施方式对本发明作进一步详细的说明。The present invention will be further described in detail with respect to specific preferred embodiments.

实施例1Example 1

一种汽车点火线圈用静铁芯,静铁芯的形状为圆柱体;静铁芯的组分及含量,按重量百分比计,包括Ni 4%、Mo 2%、Co 0.2%、Cd 0.2%、Mn 0.1%、Ba 0.1%、酚醛树脂1%以及余量主要为铁。静铁芯按照如下工艺进行制备。A static iron core for an automobile ignition coil, the shape of the static iron core is a cylinder; the composition and content of the static iron core, by weight percentage, include Ni 4%, Mo 2%, Co 0.2%, Cd 0.2%, 0.1% of Mn, 0.1% of Ba, 1% of phenolic resin, and the balance are mainly iron. The static iron core is prepared according to the following process.

第一步,真空熔炼:将铁块、镍块和钼块按照配比,投入真空感应炉中进行熔炼浇铸。The first step is vacuum smelting: the iron block, nickel block and molybdenum block are put into the vacuum induction furnace according to the ratio for smelting and casting.

第二步,初粉碎:将第一步熔炼浇铸完成的合金,使用粉碎机进行初步粉碎。The second step, primary crushing: the alloy that has been smelted and casted in the first step is initially crushed using a pulverizer.

第三步,酸洗:将第二步初粉碎的合金使用金属表面酸洗液进行酸洗。The third step, pickling: the alloy pulverized in the second step is pickled with a metal surface pickling solution.

第四步,中粉碎:在氮气保护氛围下,先将第二步初粉碎的合金放入风选砂磨机内,再按照配比,依次加入Co、Cd、Mn和Ba,开启风选砂磨机,进行中粉碎。The fourth step, medium crushing: under the nitrogen protection atmosphere, first put the alloy that was crushed in the second step into the winnowing sand mill, and then add Co, Cd, Mn and Ba in sequence according to the proportion, and start the winnowing sand Mill, crushing in progress.

第五步,细粉碎:在酒精保护氛围下,将粉碎的合金使用风选砂磨机再次进行细粉碎。The fifth step, fine crushing: under the protective atmosphere of alcohol, the crushed alloy is finely crushed again with a winnowing sand mill.

第六步,脱液、烘干:使用离心机对细粉碎的合金粉,进行脱液;再利用烘箱将脱液后的合金粉进行烘干。The sixth step, deliquoring and drying: use a centrifuge to deliquify the finely pulverized alloy powder; then use an oven to dry the deliquored alloy powder.

第七步,筛分:对脱液烘干完成的合金粉使用振动筛进行筛分。The seventh step, sieving: use a vibrating sieve to sieve the alloy powder that has been deliquored and dried.

第八步,退火处理:在氢氮混合气氛下,将筛分完成的合金粉使用推舟炉进行退火处理退火处理的温度为800-1200℃,保温2-4小时。The eighth step, annealing treatment: in a hydrogen-nitrogen mixed atmosphere, anneal the sieved alloy powder in a boat furnace. The temperature of the annealing treatment is 800-1200° C., and the temperature is kept for 2-4 hours.

第九步,绝缘包覆:将退火处理完成的合金粉加入绝缘包覆搅拌桶内,再按照配比加入酚醛树脂、云母粉和润滑剂,绝缘包覆搅拌桶进行加热搅拌与包覆。绝缘包覆搅拌桶的加热温度为55-65℃,绝缘包覆搅拌桶包括内桶、外桶和包覆在外桶四周的加热装置,内桶既能自转,又能随着外桶进行公转。The ninth step, insulation coating: add the annealed alloy powder into the insulation coating mixing tank, then add phenolic resin, mica powder and lubricant according to the ratio, heat, stir and coat the insulation coating mixing tank. The heating temperature of the insulation-coated mixing barrel is 55-65°C. The insulation-coated mixing barrel includes an inner barrel, an outer barrel and a heating device wrapped around the outer barrel. The inner barrel can not only rotate by itself, but also revolve with the outer barrel.

第十步,压制成型:使用成型压机,采用垂直竖向压制的方式,使圆柱形的静铁芯一体成型压制。 圆柱形的静铁芯一体成型压制时的成型压力为6-12T/cm2,成型温度为60-200°。The tenth step, pressing and forming: using a forming press, adopting a vertical and vertical pressing method, so that the cylindrical static iron core is integrally formed and pressed. When the cylindrical static iron core is integrally molded and pressed, the molding pressure is 6-12T/cm 2 , and the molding temperature is 60-200°.

第十一步,热处理:将第十步压制成型的静铁芯进行热处理。热处理的温度为120-200℃,保温4-6小时。The eleventh step, heat treatment: the static iron core pressed and formed in the tenth step is subjected to heat treatment. The temperature of the heat treatment is 120-200° C., and the temperature is kept for 4-6 hours.

实施例2Example 2

一种汽车点火线圈用静铁芯,静铁芯的形状为圆柱体;静铁芯的组分及含量,按重量百分比计,包括Ni 4-6%、Mo 2.5%、Co 0.3%、Cd 0.3%、Mn 0.15%、Ba 0.2%、酚醛树脂1.5%以及余量主要为铁。静铁芯按照如下工艺进行制备。A static iron core for an automobile ignition coil, the shape of the static iron core is a cylinder; the composition and content of the static iron core, by weight percentage, include Ni 4-6%, Mo 2.5%, Co 0.3%, Cd 0.3 %, Mn 0.15%, Ba 0.2%, phenolic resin 1.5%, and the balance is mainly iron. The static iron core is prepared according to the following process.

第一步,真空熔炼:将铁块、镍块和钼块按照配比,投入真空感应炉中进行熔炼浇铸。The first step is vacuum smelting: the iron block, nickel block and molybdenum block are put into the vacuum induction furnace according to the ratio for smelting and casting.

第二步,初粉碎:将第一步熔炼浇铸完成的合金,使用粉碎机进行初步粉碎。The second step, primary crushing: the alloy that has been smelted and casted in the first step is initially crushed using a pulverizer.

第三步,酸洗:将第二步初粉碎的合金使用金属表面酸洗液进行酸洗。The third step, pickling: the alloy pulverized in the second step is pickled with a metal surface pickling solution.

第四步,中粉碎:在氮气保护氛围下,先将第二步初粉碎的合金放入风选砂磨机内,再按照配比,依次加入Co、Cd、Mn和Ba,开启风选砂磨机,进行中粉碎。The fourth step, medium crushing: under the nitrogen protection atmosphere, first put the alloy that was crushed in the second step into the winnowing sand mill, and then add Co, Cd, Mn and Ba in sequence according to the proportion, and start the winnowing sand Mill, crushing in progress.

第五步,细粉碎:在酒精保护氛围下,将粉碎的合金使用风选砂磨机再次进行细粉碎。The fifth step, fine crushing: under the protective atmosphere of alcohol, the crushed alloy is finely crushed again with a winnowing sand mill.

第六步,脱液、烘干:使用离心机对细粉碎的合金粉,进行脱液;再利用烘箱将脱液后的合金粉进行烘干。The sixth step, deliquoring and drying: use a centrifuge to deliquify the finely pulverized alloy powder; then use an oven to dry the deliquored alloy powder.

第七步,筛分:对脱液烘干完成的合金粉使用振动筛进行筛分。The seventh step, sieving: use a vibrating sieve to sieve the alloy powder that has been deliquored and dried.

第八步,退火处理:在氢氮混合气氛下,将筛分完成的合金粉使用推舟炉进行退火处理退火处理的温度为800-1200℃,保温2-4小时。The eighth step, annealing treatment: in a hydrogen-nitrogen mixed atmosphere, anneal the sieved alloy powder in a boat furnace. The temperature of the annealing treatment is 800-1200° C., and the temperature is kept for 2-4 hours.

第九步,绝缘包覆:将退火处理完成的合金粉加入绝缘包覆搅拌桶内,再按照配比加入酚醛树脂、云母粉和润滑剂,绝缘包覆搅拌桶进行加热搅拌与包覆。绝缘包覆搅拌桶的加热温度为55-65℃,绝缘包覆搅拌桶包括内桶、外桶和包覆在外桶四周的加热装置,内桶既能自转,又能随着外桶进行公转。The ninth step, insulation coating: add the annealed alloy powder into the insulation coating mixing tank, then add phenolic resin, mica powder and lubricant according to the ratio, heat, stir and coat the insulation coating mixing tank. The heating temperature of the insulation-coated mixing barrel is 55-65°C. The insulation-coated mixing barrel includes an inner barrel, an outer barrel and a heating device wrapped around the outer barrel. The inner barrel can not only rotate by itself, but also revolve with the outer barrel.

第十步,压制成型:使用成型压机,采用垂直竖向压制的方式,使圆柱形的静铁芯一体成型压制。 圆柱形的静铁芯一体成型压制时的成型压力为6-12T/cm2,成型温度为60-200℃。The tenth step, pressing and forming: using a forming press, adopting a vertical and vertical pressing method, so that the cylindrical static iron core is integrally formed and pressed. When the cylindrical static iron core is integrally molded and pressed, the molding pressure is 6-12T/cm 2 , and the molding temperature is 60-200°C.

第十一步,热处理:将第十步压制成型的静铁芯进行热处理。热处理的温度为120-200℃,保温4-6小时。The eleventh step, heat treatment: the static iron core pressed and formed in the tenth step is subjected to heat treatment. The temperature of the heat treatment is 120-200° C., and the temperature is kept for 4-6 hours.

实施例3Example 3

一种汽车点火线圈用静铁芯,静铁芯的形状为圆柱体;静铁芯的组分及含量,按重量百分比计,包括Ni 6%、Mo 3%、Co 0.5%、Cd 0.4%、Mn 0.2%、Ba 0.3%、酚醛树脂2%以及余量主要为铁。静铁芯按照如下工艺进行制备。A static iron core for an automobile ignition coil, the shape of the static iron core is a cylinder; the composition and content of the static iron core, by weight percentage, include Ni 6%, Mo 3%, Co 0.5%, Cd 0.4%, 0.2% of Mn, 0.3% of Ba, 2% of phenolic resin and the balance are mainly iron. The static iron core is prepared according to the following process.

第一步,真空熔炼:将铁块、镍块和钼块按照配比,投入真空感应炉中进行熔炼浇铸。The first step is vacuum smelting: the iron block, nickel block and molybdenum block are put into the vacuum induction furnace according to the ratio for smelting and casting.

第二步,初粉碎:将第一步熔炼浇铸完成的合金,使用粉碎机进行初步粉碎。The second step, primary crushing: the alloy that has been smelted and casted in the first step is initially crushed using a pulverizer.

第三步,酸洗:将第二步初粉碎的合金使用金属表面酸洗液进行酸洗。The third step, pickling: the alloy pulverized in the second step is pickled with a metal surface pickling solution.

第四步,中粉碎:在氮气保护氛围下,先将第二步初粉碎的合金放入风选砂磨机内,再按照配比,依次加入Co、Cd、Mn和Ba,开启风选砂磨机,进行中粉碎。The fourth step, medium crushing: under the nitrogen protection atmosphere, first put the alloy that was crushed in the second step into the winnowing sand mill, and then add Co, Cd, Mn and Ba in sequence according to the proportion, and start the winnowing sand Mill, crushing in progress.

第五步,细粉碎:在酒精保护氛围下,将粉碎的合金使用风选砂磨机再次进行细粉碎。The fifth step, fine crushing: under the protective atmosphere of alcohol, the crushed alloy is finely crushed again with a winnowing sand mill.

第六步,脱液、烘干:使用离心机对细粉碎的合金粉,进行脱液;再利用烘箱将脱液后的合金粉进行烘干。The sixth step, deliquoring and drying: use a centrifuge to deliquify the finely pulverized alloy powder; then use an oven to dry the deliquored alloy powder.

第七步,筛分:对脱液烘干完成的合金粉使用振动筛进行筛分。The seventh step, sieving: use a vibrating sieve to sieve the alloy powder that has been deliquored and dried.

第八步,退火处理:在氢氮混合气氛下,将筛分完成的合金粉使用推舟炉进行退火处理的温度为800-1200℃,保温2-4小时。The eighth step, annealing treatment: in a hydrogen-nitrogen mixed atmosphere, the sieved alloy powder is annealed in a boat furnace at a temperature of 800-1200° C. and kept for 2-4 hours.

第九步,绝缘包覆:将退火处理完成的合金粉加入绝缘包覆搅拌桶内,再按照配比加入酚醛树脂、云母粉和润滑剂,绝缘包覆搅拌桶进行加热搅拌与包覆。绝缘包覆搅拌桶的加热温度为55-65℃,绝缘包覆搅拌桶包括内桶、外桶和包覆在外桶四周的加热装置,内桶既能自转,又能随着外桶进行公转。The ninth step, insulation coating: add the annealed alloy powder into the insulation coating mixing tank, then add phenolic resin, mica powder and lubricant according to the ratio, heat, stir and coat the insulation coating mixing tank. The heating temperature of the insulation-coated mixing barrel is 55-65°C. The insulation-coated mixing barrel includes an inner barrel, an outer barrel and a heating device wrapped around the outer barrel. The inner barrel can not only rotate by itself, but also revolve with the outer barrel.

第十步,压制成型:使用成型压机,采用垂直竖向压制的方式,使圆柱形的静铁芯一体成型压制。 圆柱形的静铁芯一体成型压制时的成型压力为6-12T/cm2,成型温度为60-200℃。The tenth step, pressing and forming: using a forming press, adopting a vertical and vertical pressing method, so that the cylindrical static iron core is integrally formed and pressed. When the cylindrical static iron core is integrally molded and pressed, the molding pressure is 6-12T/cm 2 , and the molding temperature is 60-200°C.

第十一步,热处理:将第十步压制成型的静铁芯进行热处理。热处理的温度为120-200℃,保温4-6小时。The eleventh step, heat treatment: the static iron core pressed and formed in the tenth step is subjected to heat treatment. The temperature of the heat treatment is 120-200° C., and the temperature is kept for 4-6 hours.

试验验证Test verification

将本申请的汽车点火线圈用静铁芯,以µe60为例,使用同一台LCR数字电感表、密度测试仪及功耗仪,进行初始磁导率、成型密度、磁感应强度的测试。Take the static iron core for the automobile ignition coil of this application, taking µe60 as an example, use the same LCR digital inductance meter, density tester and power consumption meter to test the initial magnetic permeability, molding density and magnetic induction.

同时,采用现有技术,如背景技术中硅钢片,作为对照例。At the same time, the existing technology, such as the silicon steel sheet in the background technology, is used as a comparative example.

试验结果如下:The test results are as follows:

初始磁导率initial permeability 成型密度g/cm3 Molding density g/cm 3 400KHz比总功耗Ps(W/kg)400KHz specific total power consumption Ps (W/kg) 实施例1Example 1 75007500 7.67.6 30.530.5 实施例2Example 2 78007800 7.87.8 28.228.2 实施例3Example 3 67006700 7.37.3 3131 对照例Comparative example 56005600 ———— 3838

通过以上试验,可见本发明的优势明显,便于广泛推广应用。Through the above tests, it can be seen that the present invention has obvious advantages and is convenient for wide popularization and application.

以上详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种等同变换,这些等同变换均属于本发明的保护范围。The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details in the above embodiments. Within the scope of the technical concept of the present invention, various equivalent transformations can be carried out to the technical solutions of the present invention. These equivalent transformations All belong to the protection scope of the present invention.

Claims (5)

1. a kind of automobile ignition coil static iron core, static iron core are shaped as cylinder;It is characterized in that:The component of static iron core and Content, by weight percentage, including:
Ni 4-6%;
Mo 2-3%;
Co 0.2-0.5%;
Cd 0.2-0.4%;
Mn 0.1-0.2%;
Ba 0.1-0.3%;
Phenolic resin 1-2%;
Surplus is mainly iron;
Static iron core is prepared according to following technique:
The first step, vacuum melting:By iron block, nickel block and molybdenum block according to proportioning, put into and melting casting is carried out in vaccum sensitive stove;
Second step, just crush:The alloy that first step melting casting is completed, preliminary crushing is carried out using pulverizer;
3rd step, pickling:The alloy crushed at the beginning of second step is subjected to pickling using metal surface pickle;
4th step, middle crushing:In the case where nitrogen protective atmosphere encloses, first the alloy crushed at the beginning of second step is put into selection by winnowing sand mill, then According to proportioning, Co, Cd, Mn and Ba are sequentially added, selection by winnowing sand mill is opened, is crushed in progress;
5th step, it is finely divided:Under protected alcohol atmosphere, the alloy of crushing is carried out using selection by winnowing sand mill again finely divided;
6th step, take off liquid, drying:Using centrifuge to finely divided alloyed powder, de- liquid is carried out;Baking oven is recycled by after de- liquid Alloyed powder is dried;
7th step, screening:The alloyed powder completed to taking off liquid drying is sieved using vibratory sieve;
8th step, annealing:Under hydrogen nitrogen mixed gas atmosphere, the alloyed powder use for sieving completion is pushed away into boat stove and carried out at annealing Reason;
9th step, insulating wrapped:It will make annealing treatment in the alloyed powder addition insulating wrapped agitator completed, added according still further to proportioning Phenolic resin, mica powder and lubricant, insulating wrapped agitator carry out heating stirring and cladding;
Tenth step, it is compressing:Using moulding press, by the way of vertically vertically suppressing, make the static iron core one of cylinder Shaping compacting;
11st step, heat treatment:The compressing static iron core of tenth step is heat-treated.
2. automobile ignition coil static iron core according to claim 1, it is characterised in that:In 8th step, at annealing The temperature of reason is 800-1200 DEG C, is incubated 2-4 hours.
3. automobile ignition coil static iron core according to claim 1, it is characterised in that:In 11st step, at heat The temperature of reason is 120-200 DEG C, is incubated 4-6 hours.
4. automobile ignition coil static iron core according to claim 1, it is characterised in that:The insulating wrapped agitator Heating-up temperature is 55-65 DEG C, and insulating wrapped agitator includes interior bucket, outer barrel and the heater for being coated on outer barrel surrounding, interior bucket Can rotation, and can revolved round the sun with outer barrel.
5. automobile ignition coil static iron core according to claim 1, it is characterised in that:Cylinder static iron core one into Briquetting pressure when type is suppressed is 6-12T/cm2, forming temperature is 60-200 DEG C.
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