CN106118546B - A kind of high temperature engineering footwear bonding adhesive and its preparation method and application - Google Patents
A kind of high temperature engineering footwear bonding adhesive and its preparation method and application Download PDFInfo
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- CN106118546B CN106118546B CN201610595312.0A CN201610595312A CN106118546B CN 106118546 B CN106118546 B CN 106118546B CN 201610595312 A CN201610595312 A CN 201610595312A CN 106118546 B CN106118546 B CN 106118546B
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- 239000000853 adhesive Substances 0.000 title claims abstract description 31
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000004073 vulcanization Methods 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 9
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 238000011049 filling Methods 0.000 claims abstract description 8
- 239000002048 multi walled nanotube Substances 0.000 claims description 15
- -1 ammonia Ester Chemical class 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 7
- QHGFEUAAQKJXDI-UHFFFAOYSA-N 1,2,4-trithiolane Chemical class C1SCSS1 QHGFEUAAQKJXDI-UHFFFAOYSA-N 0.000 claims description 5
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 claims description 5
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 5
- 102100026735 Coagulation factor VIII Human genes 0.000 claims description 4
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000459 Nitrile rubber Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 238000013329 compounding Methods 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 229920000800 acrylic rubber Polymers 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- WZFUKMDQBLFYLC-UHFFFAOYSA-N P(=O)(O)(O)O.C(C=C)(=O)OCCC Chemical compound P(=O)(O)(O)O.C(C=C)(=O)OCCC WZFUKMDQBLFYLC-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J113/00—Adhesives based on rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2313/00—Characterised by the use of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of high temperature engineering adhesive for shoe use with excellent high temperature resistance, high bonding force, and provide a kind of its preparation method and application.Adhesive includes vulcanization XNBR 100 parts by weight, the parts by weight of vulcanized acrylate rubber 50 80, the parts by weight of heat filling 30 50, the parts by weight of coupling agent 38, the parts by weight of antioxidant 2 10, the parts by weight of tackifier 18 30.There is high hot excellent XNBR and ACM by selection, the compounding of graphene, CNT and ball-type alundum (Al2O3), and the selection of tackifier, high temperature resistant and bonding force are balanced, obtains the high temperature engineering adhesive for shoe use with excellent high temperature resistance, high bonding force.
Description
Technical field：
The present invention relates to adhesive for shoe use field, and in particular to high temperature engineering bonding adhesive field.
Background technology：
Nitrile rubber and acrylic rubber are two kinds of rubber commonly used in the prior art, and it has high temperature resistant, oil resistant, antifriction
The characteristics of wiping and bonding force are excellent, is widely used in major industrial circle.Graphene and CNT are used as to be developed in recent years
New carbon, it has high specific surface area, high thermal conductivity, resistance to elevated temperatures, turns into a kind of heat-resisting, heat conduction field
" new lover ", but itself and matrix resin poor compatibility, it is difficult to realize that high filler loading capacity limits its use.
In shoes production process, many places such as sole and upper of a shoe need to use adhesive to be bonded, but shoes are easiest to
Broken parts are exactly abutting edge, and under the high temperature conditions, due to adhesive poor heat resistance, bonding force declines to a great extent, and common footwear are used viscous
Mixture is difficult to the needs for meeting that high temperature engineer operation footwear are long-term use of.The present invention is produced to solve the above problems, and its is comprehensive
The universality energy such as new carbon and matrix resin has been closed, has obtained the high temperature engineering footwear with excellent high temperature resistance, high bonding force
Use adhesive.
The content of the invention：
Goal of the invention：The invention provides it is a kind of with excellent high temperature resistance, high bonding force high temperature engineering adhesive for shoe use,
And provide a kind of its preparation method and application.
Technical scheme provided by the invention：
A kind of high temperature engineering footwear bonding adhesive, including vulcanization XNBR 100 parts by weight, vulcanized acrylate
Rubber 50-80 parts by weight, heat filling 30-50 parts by weight, coupling agent 3-8 parts by weight, antioxidant 2-10 parts by weight, tackifier
18-30 parts by weight.
Using vulcanization XNBR and vulcanized acrylate rubber, two kinds of rubber are respectively provided with good resistance to the present invention
Heat, oil resistant and bonding force, in order to avoid vulcanization of the Elastomers with Different Curing Systems on non-targeted crosslinking rubber influences, therefore the present invention is right respectively
XNBR and ACM are vulcanized, after through granulation mixed again.Both two kinds of rubber difference had been remained
Property, form an interpenetrating networks again, improve the pliability of matrix.
It is preferred that the preparation of the vulcanization XNBR：First by multi-walled carbon nanotube 5-10 parts by weight and D2EHDTPA
Disulphide 3-8 parts by weight, N- oxydiethylenes -2-[4-morpholinodithio sulfenamide 1-3 parts by weight are sufficiently mixed, and are further added
Enter into XNBR 75-100 parts by weight, heating vulcanization, be granulated.
In order to improve the dispersiveness of multi-walled carbon nanotube and loading, CNT has cavernous structure, multi-wall carbon nano-tube
Pipe has more pore structures, and vulcanizing agent and vulcanization accelerator are pre-mixed, and it is entered in multi-wall carbon nano-tube tubular construction.When opening
When beginning to vulcanize, vulcanization point allows CNT to be effectively dispersed in matrix since multi-wall carbon nano-tube tubular construction, meanwhile,
It uniformly disperses to improve system thermal conductivity and heat resistance.
The present invention further employs a kind of new vulcanizing system, and the vulcanization of XNBR is to use D2EHDTPA
Disulphide and N- oxydiethylenes -2-[4-morpholinodithio sulfenamide, its rate of cure improve 1-3 times, final state of cure (vulcanization)
Improve, improve heat-resisting ability.
It is preferred that the preparation of the vulcanized acrylate rubber：First by multi-walled carbon nanotube 3-9 parts by weight and 1,3,5- tri-
Sulfydryl -2,4,6- s-triazine 2-11 parts by weight are sufficiently mixed, are further added in ACM 90-100 parts by weight, add
Heat cure, it is granulated.
The pretreatment of multi-walled carbon nanotube is similar with previous step effect, 1,3,5- tri-thiol -2,4,6- s-triazine conducts
Vulcanize a little more, and there is aromatic structure, the heat resistance of its final products is substantially improved.
The heat filling is made up of graphene and ball-type alundum (Al2O3), and graphene is the heat-resisting carbon for having laminated structure
Material, alundum (Al2O3) are heat conduction, the inorganic material of excellent heat resistance, and ball-type is preferred, forms " point-face " structure, such
Structure can effectively improve thermal conductivity and heat resistance.Speculate its mechanism：Point-face structure forms contact point, effective to improve
The export speed of heat；It can also be explained further, linear carbon nanotube, flake graphite alkene and ball-type three are contained in system
Al 2 O, CNT forms " piece-line " structure with graphene, due to content problem, it is understood that there may be can not effectively contact, greatly
The ball-type alundum (Al2O3) of amount addition serves supplementary function, has filled up the breaking part of piece-line, ultimately forms " point-line-piece " knot
Structure.It is preferred that the weight of graphene and ball-type alundum (Al2O3) ratio is 1：5, ball-type alundum (Al2O3) is played effective tie point.
The filler preferably uses coupling agent treatment, improves the dispersiveness and connectivity of filler and matrix resin, the coupling agent is most
Preferably KH-550, KH-560.
The tackifier are aromatic urethane, due to shoe body much use for polyurethane, in order to improve polyurethane shoe
The adhesion property of body and adhesive, polyurethane is added in adhesive as tackifier, had both added the adhesiveness of adhesive
Can, and its adhesion to PU materials is specifically improved, while aromatic urethane is used, the heat-resisting of adhesive entirety is not reduced
Performance.
The antioxidant is antioxidant 1010, antioxidant 1076 or irgasfos 168, avoids oxygen and heat to adhesive
Oxidation, extends service life.
The ACM is by methyl methacrylate, n-octyl, hydroxypropyl acrylate, acrylic acid benzyl
Base ester, 2- HEMA phosphates are prepared by radical polymerization.The introducing of hydroxypropyl acrylate carries
High ACM later stage crosslinking degree, benzyl methacrylate introduce aromatic group, improve resistance to elevated temperatures,
2- HEMA phosphates not only introduce hydroxyl, have also been further introduced into bound phosphate groups, improve resistance
Combustion type, temperature tolerance.It is preferred that methyl methacrylate, n-octyl, hydroxypropyl acrylate, benzyl acrylate, 2- hydroxyls
Ethylmethyl acrylate phosphate ratio is 5:3:1:1:1, by selecting the suitable amounts of monomer, balance crosslinking degree
With ACM as the pliability of elastomer and the resistance to elevated temperatures of ACM.
The method of high temperature engineering footwear bonding adhesive, including：(1) heat filling is pre-mixed with coupling agent；(2) add
Enter to vulcanize XNBR and vulcanized acrylate rubber mix；(3) antioxidant, tackifier are added, are sufficiently mixed each component.
The application that high temperature engineering footwear bonding adhesive is bonded in shoes, relate generally to bonding, shoe body of the shoe body with upper of a shoe
Attachment is bonding with shoe body.
Technique effect：
The present invention has high hot excellent XNBR and ACM by selection, and graphene and carbon are received
For mitron as new carbon, it can improve the thermal conductivity of system and heat resistance.Vulcanizing system and CNT are mixed first
Close, form vulcanization starting point, improve the dispersiveness of CNT, improve heat resistance.Heat filling system uses graphene
With soccer star's alundum (Al2O3), thus it is speculated which form the conductive structure of " point-line-piece " shape, significantly improve heat conductivility and resistance to
Hot property, improve the overall heat resistance of adhesive.The processing such as further tackifier, coupling agent, improve the viscous of adhesive
The balance of conjunction performance, heat resistance and bond properties meets the demand to high temperature engineering footwear bonding.
Embodiment：
The principles and features of the present invention are described below, and example is only intended to explain the present invention, is not intended to
Limit the scope of the present invention.
Vulcanize XNBR 1：First by the parts by weight of multi-walled carbon nanotube 10 and the weight of D2EHDTPA disulphide 5
Part, N- oxydiethylenes-parts by weight of 2-[4-morpholinodithio sulfenamide 2 are sufficiently mixed, and are further added to sulfurized nitrile rubber
In 83 parts by weight, heating vulcanization, it is granulated.
Vulcanize XNBR 2：The parts by weight of D2EHDTPA disulphide 5, N- oxydiethylene -2- benzo thiophenes first
The parts by weight of azoles sulfenamide 2 are sufficiently mixed, and are further added in the parts by weight of XNBR 83, heating vulcanization, further
The parts by weight of multi-walled carbon nanotube 10 are added, are granulated after well mixed.
Acrylic rubber 1：Methyl methacrylate, n-octyl, hydroxypropyl acrylate, benzyl acrylate, 2-
HEMA phosphate is 5 according to mol ratio:3:1:1:1 copolymerization obtains；
Acrylic rubber 2：Methyl methacrylate, n-octyl, hydroxypropyl acrylate, benzyl acrylate according to
5：3：1：2 copolymerization obtain.
Acrylic rubber：Methyl methacrylate, n-octyl, hydroxypropyl acrylate, 2- hydroxy ethyl methyls third
Olefin(e) acid ester phosphate is 5 according to mol ratio:3:1:2 copolymerization obtain
Vulcanized acrylate rubber 1：It is first that multi-walled carbon nanotube 3-9 parts by weight and 1,3,5- tri-thiols -2,4,6- is equal
Triazine 2-11 parts by weight are sufficiently mixed, and are further added in ACM 190-100 parts by weight, heating vulcanization, are granulated.
Vulcanized acrylate rubber 2：1,3,5- tri-thiol -2,4,6- s-triazine 2-11 parts by weight are sufficiently mixed first,
It is added in ACM 190-100 parts by weight, heating vulcanization, and further adds multi-walled carbon nanotube 3-9 parts by weight,
It is well mixed, it is granulated.
Vulcanized acrylate rubber 3：It is first that multi-walled carbon nanotube 3-9 parts by weight and 1,3,5- tri-thiols -2,4,6- is equal
Triazine 2-11 parts by weight are sufficiently mixed, and are further added in ACM 290-100 parts by weight, heating vulcanization, are granulated.
Vulcanized acrylate rubber 4：It is first that multi-walled carbon nanotube 3-9 parts by weight and 1,3,5- tri-thiols -2,4,6- is equal
Triazine 2-11 parts by weight are sufficiently mixed, and are further added in ACM 390-100 parts by weight, heating vulcanization, are granulated.
The preparation method all same of adhesive：The method of high temperature engineering footwear bonding adhesive, including：(1) heat filling
It is pre-mixed with coupling agent；(2) vulcanization XNBR and vulcanized acrylate rubber mix are added；(3) antioxygen is added
Agent, tackifier, are sufficiently mixed each component.
Each key component dosage and its performance are prepared referring to following table：
Claims (7)
- A kind of 1. high temperature engineering footwear bonding adhesive, it is characterised in that：Adhesive includes the vulcanization weight of XNBR 100 Part, vulcanized acrylate rubber 50-80 parts by weight, heat filling 30-50 parts by weight, coupling agent 3-8 parts by weight, antioxidant 2-10 Parts by weight, tackifier 18-30 parts by weight；The preparation of the vulcanization XNBR：First by multi-walled carbon nanotube 5-10 parts by weight and D2EHDTPA disulphide 3-8 parts by weight, N- oxydiethylenes -2-[4-morpholinodithio sulfenamide 1-3 parts by weight are sufficiently mixed, and are further added to carboxyl In nitrile rubber 75-100 parts by weight, heating vulcanization, it is granulated；The preparation of the vulcanized acrylate rubber：First by multi-walled carbon nanotube 3-9 parts by weight and 1,3,5- tri-thiols -2,4, 6- s-triazine 2-11 parts by weight are sufficiently mixed, and are further added in ACM 90-100 parts by weight, heating vulcanization, are made Grain；The heat filling is made up of graphene and ball-type alundum (Al2O3), and its weight ratio is 1：5.
- 2. high temperature engineering footwear bonding adhesive as claimed in claim 1, it is characterised in that：The tackifier are fragrant adoption ammonia Ester.
- 3. high temperature engineering footwear bonding adhesive as claimed in claim 1, it is characterised in that：The coupling agent is KH-550, KH- 560。
- 4. high temperature engineering footwear bonding adhesive as claimed in claim 1, it is characterised in that：The antioxidant is antioxidant 1010th, antioxidant 1076 or irgasfos 168.
- 5. high temperature engineering footwear bonding adhesive as claimed in claim 1, it is characterised in that：The ACM is by first Base methyl acrylate, n-octyl, hydroxypropyl acrylate, benzyl acrylate, 2- HEMA phosphorus Acid esters is prepared by radical polymerization.
- 6. prepare the method for high temperature engineering footwear bonding adhesive as claimed in claim 1, it is characterised in that：Including：（1）Heat conduction Filler is pre-mixed with coupling agent；（2）Add vulcanization XNBR and vulcanized acrylate rubber mix；（3）Add Antioxidant, tackifier, are sufficiently mixed each component, produce.
- 7. the application that any one of claim 1-5 high temperature engineering footwear bonding adhesives are bonded in shoes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595312.0A CN106118546B (en) | 2016-07-27 | 2016-07-27 | A kind of high temperature engineering footwear bonding adhesive and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595312.0A CN106118546B (en) | 2016-07-27 | 2016-07-27 | A kind of high temperature engineering footwear bonding adhesive and its preparation method and application |
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| CN106634654A (en) * | 2016-12-16 | 2017-05-10 | 东莞市翔龙能源科技有限公司 | Adhesive film with radiant heat dissipation function for LED (Light Emitting Diode) and preparation method of adhesive film |
| CN107236506A (en) * | 2017-06-28 | 2017-10-10 | 常州水精灵环保设备有限公司 | A kind of double-component epoxy resin embedding adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533158A (en) * | 2011-12-31 | 2012-07-04 | 南京占一科技有限公司 | Pressure-sensitive adhesive and pressure-sensitive adhesive tape, and preparation method thereof |
| CN103666328A (en) * | 2013-11-29 | 2014-03-26 | 山东永泰化工有限公司 | Rubber adhesive |
| CN104059567A (en) * | 2014-06-26 | 2014-09-24 | 青岛博洋生物技术有限公司 | Rubber adhesive |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE102006016577A1 (en) * | 2006-04-06 | 2007-10-11 | Henkel Kgaa | Adhesives / sealants based on liquid rubbers |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533158A (en) * | 2011-12-31 | 2012-07-04 | 南京占一科技有限公司 | Pressure-sensitive adhesive and pressure-sensitive adhesive tape, and preparation method thereof |
| CN103666328A (en) * | 2013-11-29 | 2014-03-26 | 山东永泰化工有限公司 | Rubber adhesive |
| CN104059567A (en) * | 2014-06-26 | 2014-09-24 | 青岛博洋生物技术有限公司 | Rubber adhesive |
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