CN106117937A - A kind of high-strength flexible waterproof material and preparation method thereof - Google Patents
A kind of high-strength flexible waterproof material and preparation method thereof Download PDFInfo
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- CN106117937A CN106117937A CN201610568788.5A CN201610568788A CN106117937A CN 106117937 A CN106117937 A CN 106117937A CN 201610568788 A CN201610568788 A CN 201610568788A CN 106117937 A CN106117937 A CN 106117937A
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- waterproof material
- flexible waterproof
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- strength flexible
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- 239000000463 material Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 19
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 18
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- 235000012241 calcium silicate Nutrition 0.000 claims abstract description 15
- 239000010445 mica Substances 0.000 claims abstract description 15
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 229940049964 oleate Drugs 0.000 claims abstract description 15
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 15
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 241000779819 Syncarpia glomulifera Species 0.000 claims abstract description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 14
- 230000003647 oxidation Effects 0.000 claims abstract description 14
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 14
- 239000001739 pinus spp. Substances 0.000 claims abstract description 14
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 14
- 229920001225 polyester resin Polymers 0.000 claims abstract description 14
- 239000004645 polyester resin Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 14
- 229920002545 silicone oil Polymers 0.000 claims abstract description 14
- 229940036248 turpentine Drugs 0.000 claims abstract description 14
- 239000006185 dispersion Substances 0.000 claims abstract description 13
- 238000013019 agitation Methods 0.000 claims abstract description 10
- 239000001341 hydroxy propyl starch Substances 0.000 claims abstract description 10
- 235000013828 hydroxypropyl starch Nutrition 0.000 claims abstract description 10
- 229940057950 sodium laureth sulfate Drugs 0.000 claims abstract description 7
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims abstract description 7
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 claims abstract description 6
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 230000006641 stabilisation Effects 0.000 claims description 10
- 238000011105 stabilization Methods 0.000 claims description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
- 230000003487 anti-permeability effect Effects 0.000 abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 7
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 description 7
- 239000013049 sediment Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a kind of high-strength flexible waterproof material and preparation method thereof, described preparation method includes: (1) adds polyacrylate dispersion 15 25 parts, amino modified hydroxy-silicone-oil emulsion 6 11 parts, Turpentine aqueous polyester resin 26 parts, polyvinyl alcohol 48 parts, oxidation hydroxypropyl starch 25 parts in reactor by weight, and composition in reactor is carried out mechanical agitation；(2) in reactor, calcium silicates 26 parts, mica powder 25 parts, stannous oleate 14 parts, phosphatase 11 3 parts, sodium laureth sulfate 25 parts, ring five polydimethylsiloxane 26 parts are added the most by weight, stirring seals and preserves, for high-strength flexible waterproof material.The waterproof material prepared has excellent anti-permeability, comprcssive strength and rupture strength.
Description
Technical field
The invention belongs to field of waterproof materials, relate to a kind of high-strength flexible waterproof material and preparation method thereof.
Background technology
Architectural waterproof material is mainly used for construction wall, roofing and tunnel, highway, refuse landfill etc., plays
Resist the flexible building material product of a kind of rollable one-tenth web-like of extraneous rainwater, subsoil water seepage, as engineering foundation and building
Between ne-leakage connect, be the first barrier of whole engineering waterproofing, whole engineering played vital effect.Product master
Modified asphalt waterproof material to be had and high polymer waterproof material.The antiseepage effect of waterproof material refer to prevent subsoil water, rainwater or
Salt in the ground Korrosionsmedium that grades penetrates into the inside of building element or foundation, prevents the performance caused therefrom bad
Change, even lost efficacy.Leakproof effect refers to prevent rainwater, snow water, subsoil water etc. from roof, metope, ground or concrete component
Seam crossing leaks into building and uses inside space, the outside seepage of water in water storage structure or channel structure or building, structures
Mutually sealing.So waterproof material is to protect building and structures and component thereof not by erosion and the destruction of water, it is ensured that build
Build thing and an indispensable functional material of class that structures normally use.For tunnel, the flexible water material of top board, metope
Material needs possess excellent anti-permeability and other intensity.
Summary of the invention
Solve the technical problem that: flexible waterproof material all has purposes widely in metope, top board and tunnel,
For above-mentioned waterproof middle time, flexible waterproof material needs possess the saturating performance of preferable waterproof, seepage control, in addition, in addition it is also necessary to tool
There are the intensity of good pressure-resistant folding-resistant, wet basis face adhesive strength, after having possessed higher intensity, go for different technology
Purposes.
Technical scheme: in order to solve the problems referred to above, the invention discloses a kind of high-strength flexible waterproof material, described height
Intensity flexible waterproof material includes the composition of following weight parts:
Polyacrylate dispersion 15-25 part,
Amino modified hydroxy-silicone-oil emulsion 6-11 part,
Turpentine aqueous polyester resin 2-6 part,
Polyvinyl alcohol 4-8 part,
Oxidation hydroxypropyl starch 2-5 part,
Calcium silicates 2-6 part,
Mica powder 2-5 part,
Stannous oleate 1-4 part,
Phosphatase 11-3 parts,
Sodium laureth sulfate 2-5 part,
Ring five polydimethylsiloxane 2-6 part.
Preferably, described a kind of high-strength flexible waterproof material, including the composition of following weight parts:
Polyacrylate dispersion 18-23 part,
Amino modified hydroxy-silicone-oil emulsion 7-10 part,
Turpentine aqueous polyester resin 3-5 part,
Polyvinyl alcohol 5-7 part,
Oxidation hydroxypropyl starch 3-4 part,
Calcium silicates 3-5 part,
Mica powder 3-4 part,
Stannous oleate 2-3 part,
Phosphoric acid 2-3 part,
Sodium laureth sulfate 3-4 part,
Ring five polydimethylsiloxane 3-5 part.
A kind of preparation method of high-strength flexible waterproof material, the step including following:
(1) temperature of reaction kettle is set as 160-180 DEG C, after temperature stabilization, in reactor, adds polyacrylate by weight
Emulsion 15-25 part, amino modified hydroxy-silicone-oil emulsion 6-11 part, Turpentine aqueous polyester resin 2-6 part, polyvinyl alcohol 4-8
Part, oxidation hydroxypropyl starch 2-5 part, carry out mechanical agitation by composition in reactor, and speed of agitator is 150-200r/min, stirring
10-30min；
(2) in reactor the most by weight add calcium silicates 2-6 part, mica powder 2-5 part, stannous oleate 1-4 part, phosphatase 11-3 parts,
Sodium laureth sulfate 2-5 part, ring five polydimethylsiloxane 2-6 part, then under rotating speed 200-400r/min, stir 20-
60min, seals and preserves, for high-strength flexible waterproof material.
Preferably, the preparation method of described a kind of high-strength flexible waterproof material, speed of agitator in described step (1)
For 180r/min, stir 20min.
Preferably, the preparation method of described a kind of high-strength flexible waterproof material, again at rotating speed in described step (2)
40min is stirred under 300r/min.
Beneficial effect: the waterproof material of the present invention, in addition to having possessed the saturating performance of the best waterproof, seepage control, is also equipped with
Excellent comprcssive strength, rupture strength and wet basis face adhesive strength, the waterproof material of the present invention is for top board, tunnel and wall
In the construction of body, sealing can be improved, improve the waterproof strength of above-mentioned material.
Detailed description of the invention
Embodiment 1
(1) temperature of reaction kettle is set as 180 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
25 parts, amino modified hydroxy-silicone-oil emulsion 11 parts, Turpentine aqueous polyester resin 2 parts, polyvinyl alcohol 8 parts, oxidation hydroxypropyl
Starch 2 parts, carries out mechanical agitation by composition in reactor, and speed of agitator is 200r/min, stirs 10min；
(2) in reactor, addition calcium silicates 2 parts, mica powder 5 parts, stannous oleate 4 parts, phosphatase 11 part, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 2 parts, ring five polydimethylsiloxane 6 parts, then under rotating speed 200r/min, stir 60min, seal and preserve, for height
Intensity flexible waterproof material.
Embodiment 2
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
15 parts, amino modified hydroxy-silicone-oil emulsion 6 parts, Turpentine aqueous polyester resin 6 parts, polyvinyl alcohol 4 parts, oxidation hydroxypropyl form sediment
5 parts of powder, carries out mechanical agitation by composition in reactor, and speed of agitator is 150r/min, stirs 30min；
(2) in reactor, addition calcium silicates 6 parts, mica powder 2 parts, stannous oleate 1 part, phosphoric acid 3 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 5 parts, ring five polydimethylsiloxane 2 parts, then under rotating speed 400r/min, stir 20min, seal and preserve, for height
Intensity flexible waterproof material.
Embodiment 3
(1) temperature of reaction kettle is set as 180 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
18 parts, amino modified hydroxy-silicone-oil emulsion 10 parts, Turpentine aqueous polyester resin 5 parts, polyvinyl alcohol 7 parts, oxidation hydroxypropyl
Starch 3 parts, carries out mechanical agitation by composition in reactor, and speed of agitator is 200r/min, stirs 10min；
(2) in reactor, addition calcium silicates 3 parts, mica powder 3 parts, stannous oleate 3 parts, phosphoric acid 2 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 3 parts, ring five polydimethylsiloxane 5 parts, then under rotating speed 200r/min, stir 60min, seal and preserve, for height
Intensity flexible waterproof material.
Embodiment 4
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
23 parts, amino modified hydroxy-silicone-oil emulsion 7 parts, Turpentine aqueous polyester resin 3 parts, polyvinyl alcohol 5 parts, oxidation hydroxypropyl form sediment
4 parts of powder, carries out mechanical agitation by composition in reactor, and speed of agitator is 150r/min, stirs 30min；
(2) in reactor, addition calcium silicates 5 parts, mica powder 4 parts, stannous oleate 2 parts, phosphoric acid 3 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 4 parts, ring five polydimethylsiloxane 3 parts, then under rotating speed 400r/min, stir 20min, seal and preserve, for height
Intensity flexible waterproof material.
Embodiment 5
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
20 parts, amino modified hydroxy-silicone-oil emulsion 8 parts, Turpentine aqueous polyester resin 4 parts, polyvinyl alcohol 6 parts, oxidation hydroxypropyl form sediment
3 parts of powder, carries out mechanical agitation by composition in reactor, and speed of agitator is 180r/min, stirs 20min；
(2) in reactor, addition calcium silicates 4 parts, mica powder 3 parts, stannous oleate 2 parts, phosphoric acid 2 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 3 parts, ring five polydimethylsiloxane 4 parts, then under rotating speed 300r/min, stir 40min, seal and preserve, for height
Intensity flexible waterproof material.
Comparative example 1
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
15 parts, polyvinyl alcohol 4 parts, oxidation hydroxypropyl starch 5 parts, composition in reactor is carried out mechanical agitation, speed of agitator is 150r/
Min, stirs 30min；
(2) in reactor, addition calcium silicates 6 parts, mica powder 2 parts, stannous oleate 1 part, phosphoric acid 3 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 5 parts, ring five polydimethylsiloxane 2 parts, then under rotating speed 400r/min, stir 20min, seal and preserve, for height
Intensity flexible waterproof material.
Comparative example 2
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
15 parts, amino modified hydroxy-silicone-oil emulsion 6 parts, Turpentine aqueous polyester resin 6 parts, composition in reactor is carried out machinery and stirs
Mixing, speed of agitator is 150r/min, stirs 30min；
(2) in reactor, addition calcium silicates 6 parts, mica powder 2 parts, stannous oleate 1 part, phosphoric acid 3 parts, lauryl alcohol gather the most by weight
Ether sodium sulfovinate 5 parts, ring five polydimethylsiloxane 2 parts, then under rotating speed 400r/min, stir 20min, seal and preserve, for height
Intensity flexible waterproof material.
Comparative example 3
(1) temperature of reaction kettle is set as 160 DEG C, after temperature stabilization, in reactor, adds polyacrylate dispersion by weight
15 parts, amino modified hydroxy-silicone-oil emulsion 6 parts, Turpentine aqueous polyester resin 6 parts, polyvinyl alcohol 4 parts, oxidation hydroxypropyl form sediment
5 parts of powder, carries out mechanical agitation by composition in reactor, and speed of agitator is 150r/min, stirs 30min；
(2) in reactor, calcium silicates 6 parts, mica powder 2 parts, stannous oleate 1 part, phosphoric acid 3 parts are added the most by weight, then at rotating speed
Stir 20min under 400r/min, seal and preserve, for high-strength flexible waterproof material.
Test the performance of embodiment 1 to 5 and comparative example 1 to 3, its anti-permeability performance, comprcssive strength, rupture strength and wet basis
Face bonding strength data is as follows:
| Impermeability pressure (28d, MPa) | Comprcssive strength (MPa) | Rupture strength (MPa) | Wet basis face adhesive strength (MPa) | |
| Embodiment 1 | 2.2 | 37 | 7.4 | 1.4 |
| Embodiment 2 | 2.1 | 36 | 7.7 | 1.3 |
| Embodiment 3 | 2.4 | 41 | 8.3 | 1.6 |
| Embodiment 4 | 2.3 | 40 | 8.1 | 1.6 |
| Embodiment 5 | 2.7 | 46 | 9.2 | 1.9 |
| Comparative example 1 | 1.5 | 30 | 4.2 | 1.0 |
| Comparative example 2 | 1.7 | 31 | 4.6 | 1.1 |
| Comparative example 3 | 1.9 | 32 | 4.9 | 1.1 |
Claims (5)
1. a high-strength flexible waterproof material, it is characterised in that described high-strength flexible waterproof material includes following weight
The composition of part:
Polyacrylate dispersion 15-25 part,
Amino modified hydroxy-silicone-oil emulsion 6-11 part,
Turpentine aqueous polyester resin 2-6 part,
Polyvinyl alcohol 4-8 part,
Oxidation hydroxypropyl starch 2-5 part,
Calcium silicates 2-6 part,
Mica powder 2-5 part,
Stannous oleate 1-4 part,
Phosphatase 11-3 parts,
Sodium laureth sulfate 2-5 part,
Ring five polydimethylsiloxane 2-6 part.
A kind of high-strength flexible waterproof material the most according to claim 1, it is characterised in that described high-strength flexible
Waterproof material includes the composition of following weight parts:
Polyacrylate dispersion 18-23 part,
Amino modified hydroxy-silicone-oil emulsion 7-10 part,
Turpentine aqueous polyester resin 3-5 part,
Polyvinyl alcohol 5-7 part,
Oxidation hydroxypropyl starch 3-4 part,
Calcium silicates 3-5 part,
Mica powder 3-4 part,
Stannous oleate 2-3 part,
Phosphoric acid 2-3 part,
Sodium laureth sulfate 3-4 part,
Ring five polydimethylsiloxane 3-5 part.
3. the preparation method of a high-strength flexible waterproof material, it is characterised in that described preparation method includes following step
Rapid:
(1) temperature of reaction kettle is set as 160-180 DEG C, after temperature stabilization, in reactor, adds polyacrylate by weight
Emulsion 15-25 part, amino modified hydroxy-silicone-oil emulsion 6-11 part, Turpentine aqueous polyester resin 2-6 part, polyvinyl alcohol 4-8
Part, oxidation hydroxypropyl starch 2-5 part, carry out mechanical agitation by composition in reactor, and speed of agitator is 150-200r/min, stirring
10-30min；
(2) in reactor the most by weight add calcium silicates 2-6 part, mica powder 2-5 part, stannous oleate 1-4 part, phosphatase 11-3 parts,
Sodium laureth sulfate 2-5 part, ring five polydimethylsiloxane 2-6 part, then under rotating speed 200-400r/min, stir 20-
60min, seals and preserves, for high-strength flexible waterproof material.
The preparation method of a kind of high-strength flexible waterproof material the most according to claim 3, it is characterised in that described step
Suddenly in (1), speed of agitator is 180r/min, stirs 20min.
The preparation method of a kind of high-strength flexible waterproof material the most according to claim 3, it is characterised in that described step
(2) stir under rotating speed 300r/min 40min suddenly again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610568788.5A CN106117937A (en) | 2016-07-19 | 2016-07-19 | A kind of high-strength flexible waterproof material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610568788.5A CN106117937A (en) | 2016-07-19 | 2016-07-19 | A kind of high-strength flexible waterproof material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106117937A true CN106117937A (en) | 2016-11-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610568788.5A Pending CN106117937A (en) | 2016-07-19 | 2016-07-19 | A kind of high-strength flexible waterproof material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112297575A (en) * | 2020-10-31 | 2021-02-02 | 宁波丹盈服饰有限公司 | Waterproof breathable fabric and preparation method thereof |
| CN115093247A (en) * | 2022-07-25 | 2022-09-23 | 迈嘉尔(武汉)高新技术发展有限公司 | Osmopolymerization flexible waterproof material and preparation method thereof |
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| CN103553483A (en) * | 2013-10-11 | 2014-02-05 | 王福刚 | Cement-based capillary crystalline waterproof coating and preparation method thereof |
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| CN103553483A (en) * | 2013-10-11 | 2014-02-05 | 王福刚 | Cement-based capillary crystalline waterproof coating and preparation method thereof |
| CN104925355A (en) * | 2015-05-29 | 2015-09-23 | 铜陵方正塑业科技有限公司 | Waterproof paper-plastic compound bag and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112297575A (en) * | 2020-10-31 | 2021-02-02 | 宁波丹盈服饰有限公司 | Waterproof breathable fabric and preparation method thereof |
| CN112297575B (en) * | 2020-10-31 | 2022-05-27 | 宁波丹盈服饰有限公司 | Waterproof breathable fabric and preparation method thereof |
| CN115093247A (en) * | 2022-07-25 | 2022-09-23 | 迈嘉尔(武汉)高新技术发展有限公司 | Osmopolymerization flexible waterproof material and preparation method thereof |
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Application publication date: 20161116 |