CN106115502A - The hoisting tool special of chopper - Google Patents
The hoisting tool special of chopper Download PDFInfo
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- CN106115502A CN106115502A CN201610467771.0A CN201610467771A CN106115502A CN 106115502 A CN106115502 A CN 106115502A CN 201610467771 A CN201610467771 A CN 201610467771A CN 106115502 A CN106115502 A CN 106115502A
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- steel pipe
- muffle furnace
- crown
- fluorescent material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B66—HOISTING; LIFTING; HAULING
- B66C—CRANES; LOAD-ENGAGING ELEMENTS OR DEVICES FOR CRANES, CAPSTANS, WINCHES, OR TACKLES
- B66C23/00—Cranes comprising essentially a beam, boom, or triangular structure acting as a cantilever and mounted for translatory of swinging movements in vertical or horizontal planes or a combination of such movements, e.g. jib-cranes, derricks, tower cranes
- B66C23/16—Cranes comprising essentially a beam, boom, or triangular structure acting as a cantilever and mounted for translatory of swinging movements in vertical or horizontal planes or a combination of such movements, e.g. jib-cranes, derricks, tower cranes with jibs supported by columns, e.g. towers having their lower end mounted for slewing movements
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7743—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing terbium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
- C09K2211/1033—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom with oxygen
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
- Luminescent Compositions (AREA)
Abstract
本发明公开了一种断路器的专用吊装工具,钢管与之间均匀设置数块。底部设有底座,底座上安装卷扬机,卷扬机的连接绳的一端与钢管的上部连接;上设有铰链座,通过铰链座与钢管铰接,铰链座朝向卷扬机的一侧设有,与钢管配合。它是针对35kV设备区环境与西门子3AP1FG系列开关的安装特点设计的专用吊装工具,可在狭小空间中将西门子3AP1FG型断路器的单相开关吊起。所述钢管上设有,上安装,底部设有,内开设,与配合,的输出轴上安装,固定杆上安装,与啮合,的一侧设在,与钢管固定。本发明的制备方法避免了合成复杂的有机小分子时产率低的缺陷,采用溶剂热法合成,操作简单,易于实现,产率高。本发明还具有结构简洁紧凑、制造成本低廉和使用简便的优点。
The invention discloses a special hoisting tool for a circuit breaker. Several pieces are evenly arranged between steel pipes. There is a base at the bottom, and a hoist is installed on the base, and one end of the connecting rope of the hoist is connected to the upper part of the steel pipe; a hinge seat is provided on the top, which is hinged to the steel pipe through the hinge seat, and the hinge seat is provided on the side facing the hoist to cooperate with the steel pipe. It is a special lifting tool designed for the 35kV equipment area environment and the installation characteristics of Siemens 3AP1FG series switches. It can lift the single-phase switch of Siemens 3AP1FG circuit breaker in a small space. The steel pipe is provided on the top, installed on the bottom, set on the inside, matched with, installed on the output shaft, installed on the fixed rod, engaged with, located on one side, and fixed with the steel pipe. The preparation method of the invention avoids the defect of low yield when synthesizing complex organic small molecules, adopts solvothermal synthesis, has simple operation, is easy to realize, and has high yield. The invention also has the advantages of simple and compact structure, low manufacturing cost and easy use.
Description
技术领域technical field
本发明涉及一种专用吊装工具,具体地说是一种断路器的专用吊装工具。The invention relates to a special hoisting tool, in particular to a special hoisting tool for a circuit breaker.
背景技术Background technique
目前500kV变电站普遍采用紧凑式设计,其中35kV设备区由于临近主变且采用敞开式设计造成检修作业空间狭小、大型吊装设备无法顺利进入或展开。并且,西门子3AP1FG型断路器的单相开关的安装紧密的特点决定了在这种作业环境下一旦35kV设备区内的断路器的单相开关损坏需要拆卸、更换时没有适用的吊装工具,因此,为检修工作带来极大的困难。At present, the 500kV substation generally adopts a compact design, and the 35kV equipment area is close to the main transformer and adopts an open design, resulting in a narrow maintenance work space, and large hoisting equipment cannot be smoothly entered or deployed. Moreover, the tight installation of the single-phase switch of the Siemens 3AP1FG circuit breaker determines that once the single-phase switch of the circuit breaker in the 35kV equipment area is damaged in this working environment, there is no suitable lifting tool for disassembly and replacement. Therefore, Bring great difficulty for maintenance work.
发明内容Contents of the invention
本发明的目的是提供一种断路器的专用吊装工具,它为按照35kV设备区环境与西门子3AP1FG型断路器的单相开关的安装特点制作的专用开关吊塔,可以解决上述技术的不足,采用组装式吊塔,实现单相开关的吊装功能,从而能够解决上述问题。The purpose of the present invention is to provide a special hoisting tool for a circuit breaker, which is a special switch pendant made according to the installation characteristics of the 35kV equipment area environment and the single-phase switch of Siemens 3AP1FG type circuit breaker, which can solve the above-mentioned deficiencies in the technology. The assembled pendant can realize the hoisting function of the single-phase switch, so as to solve the above problems.
本发明为实现上述目的,通过以下技术方案实现:断路器的专用吊装工具,包括固定装置包括夹板和,夹板和通过螺母和螺栓连接,上竖向安装钢管,钢管的上端内安装固定杆,固定杆的上段位于钢管外,固定杆上设有,与钢管配合限位,固定杆能相对钢管转动,固定杆的一侧水平安装吊臂,吊臂的上安装斜拉杆,斜拉杆的一端与固定杆连接,斜拉杆的另一端与吊臂的一端连接,吊臂、斜拉杆和固定杆构成三角形吊臂架,吊臂的外端安装旋转环,旋转环上安装吊环,吊环上安装手动葫芦,所述三角形吊臂架的外周设有荧光材料。In order to achieve the above object, the present invention is achieved through the following technical solutions: the special hoisting tool for the circuit breaker includes a fixing device including a splint and a splint connected by nuts and bolts, a steel pipe is vertically installed on the upper end of the steel pipe, and a fixing rod is installed inside the upper end of the steel pipe to fix the The upper part of the rod is located outside the steel pipe, and there is a set on the fixed rod, which cooperates with the steel pipe to limit the position. The fixed rod can rotate relative to the steel pipe. Rod connection, the other end of the diagonal tie rod is connected with one end of the boom, the boom, the diagonal tie rod and the fixed rod form a triangular boom frame, the outer end of the boom is equipped with a rotating ring, the rotating ring is equipped with a lifting ring, and a manual hoist is installed on the lifting ring. The outer periphery of the triangular boom frame is provided with fluorescent material.
为了进一步实现本发明的目的,还可以采用以下技术方案:所述钢管与之间均匀设置数块。所述底部设有底座,底座上安装卷扬机,卷扬机的连接绳的一端与钢管的上部连接;上设有铰链座,通过铰链座与钢管铰接,铰链座朝向卷扬机的一侧设有,与钢管配合。所述钢管上设有,上安装,底部设有,内开设,与配合,的输出轴上安装,固定杆上安装,与啮合,的一侧设在,与钢管固定。In order to further realize the object of the present invention, the following technical solution can also be adopted: several pieces are uniformly arranged between the steel pipe and the steel pipe. The bottom is provided with a base on which a hoist is installed, and one end of the connecting rope of the hoist is connected to the upper part of the steel pipe; a hinge seat is provided on the top, which is hinged with the steel pipe through the hinge seat, and the hinge seat is provided on the side facing the hoist to cooperate with the steel pipe . The steel pipe is provided on the top, installed on the bottom, set on the inside, matched with, installed on the output shaft, installed on the fixed rod, engaged with, located on one side, and fixed with the steel pipe.
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为ML,其中M为Eu或Tb,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, whose general formula is ML, wherein M is Eu or Tb, L is aza-containing 15-crown-5 cyclic crown ether, and its structural formula is:
,其中R为H,-NO2或-CHO。 , wherein R is H, -NO 2 or -CHO.
优选的含氮杂15-冠-5环状冠醚的荧光材料,M为Eu,R为-NO2。In the preferred fluorescent material containing aza-15-crown-5 cyclic crown ether, M is Eu, and R is -NO 2 .
本发明还包括含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The present invention also includes a method for preparing a fluorescent material containing aza-15-crown-5 cyclic crown ether, comprising the following steps:
将铕或铽的可溶性盐、L和有机溶剂加入溶剂热罐子中,加10~15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述铕或铽的可溶性盐、L和有机溶剂的添加比例为1~1.5mol:1mol:20~30ml;所述的有机溶剂为二甲苯、环己醇或DMF;所述铕或铽的可溶性盐为硝酸盐或氯化盐;所述L的结构式为 Add the soluble salt of europium or terbium, L and organic solvent into the solvent heating jar, add 10~15ml of distilled water to seal, then put the sealed solvent heating jar into the muffle furnace; the soluble salt of europium or terbium, L The addition ratio of the organic solvent is 1 ~ 1.5mol: 1mol: 20 ~ 30ml; the organic solvent is xylene, cyclohexanol or DMF; the soluble salt of europium or terbium is nitrate or chloride; The structural formula of L is
,其中R为H,-NO2,-CHO; , wherein R is H, -NO 2 , -CHO;
先将马弗炉的温度升至190~195℃恒温48~72小时,然后将马弗炉的温度降至50~55℃保温12~15小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 190~195°C for 48~72 hours, then lower the temperature of the muffle furnace to 50~55°C for 12~15 hours, turn off the power, and wait until the temperature of the muffle furnace drops to room temperature , the solvothermal jar was removed from the muffle furnace to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,铕或铽的可溶性盐、L和有机溶剂的添加比例为1.2mol:1mol:25ml。In the preferred preparation method of fluorescent material containing aza-15-crown-5 cyclic crown ether, the addition ratio of soluble salt of europium or terbium, L and organic solvent is 1.2mol:1mol:25ml.
优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,先将马弗炉的温度升至192℃恒温60小时,然后将马弗炉的温度降至52℃保温14小时。The preferred preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether, the temperature of the muffle furnace is raised to 192°C for 60 hours, and then the temperature of the muffle furnace is lowered to 52°C for 14 hours. .
进一步优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:A further preferred method for preparing a fluorescent material containing aza-15-crown-5 cyclic crown ether comprises the following steps:
将硝酸铕、L和DMF加入溶剂热罐子中,加15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述硝酸铕、L和DMF的添加比例为1.2mol:1mol:25ml;所述L的结构式为 Add europium nitrate, L and DMF in the solvent heating jar, add 15ml of distilled water to seal, then put the sealed solvent heating jar into the muffle furnace; the addition ratio of the europium nitrate, L and DMF is 1.2mol: 1mol: 25ml; the structural formula of the L is
; ;
先将马弗炉的温度升至192℃恒温60小时,然后将马弗炉的温度降至52℃保温14小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 192°C and keep it constant for 60 hours, then lower the temperature of the muffle furnace to 52°C and keep it for 14 hours, turn off the power, wait for the temperature of the muffle furnace to drop to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
本发明的优点在于:它是针对35kV设备区环境与西门子3AP1FG系列开关的安装特点设计的专用吊装工具,可在狭小空间中将西门子3AP1FG型断路器的单相开关吊起,以便更换损坏的单相开关。它的卷扬机可以通过连接绳带动钢管绕固定装置旋转,当需要吊装断路器时,卷扬机放松连接绳,使钢管向手动葫芦一侧倾斜,从而使手动葫芦探出,避免断路器与钢管之间发生碰撞,防止断路器损坏。本发明的手动葫芦可以方便操作人员无需使用电力就可以将断路器提升。本发明的吊臂、斜拉杆和固定杆构成三角形吊臂架可以提高吊臂与固定杆的连接强度,避免吊臂在吊装断路器过程中出现损坏。本发明的旋转环可以方便手动葫芦旋转,使操作人员可以从不同角度控制手动葫芦。本发明的含氮杂15-冠-5环状冠醚的荧光材料以含氮杂15-冠-5环状冠醚为发光基质,以铕或铽为激活剂,所合成的荧光材料吸收能力强,转换率高,并且稀土配合物中心离子的窄带发射有利于全色显示,该荧光材料的性质稳定;本发明的制备方法避免了合成复杂的有机小分子时产率低的缺陷,采用溶剂热法合成,操作简单,易于实现,产率高。本发明还具有结构简洁紧凑、制造成本低廉和使用简便的优点。The advantage of the present invention is that it is a special hoisting tool designed for the environment of the 35kV equipment area and the installation characteristics of Siemens 3AP1FG series switches. phase switch. Its hoist can drive the steel pipe to rotate around the fixing device through the connecting rope. When the circuit breaker needs to be hoisted, the hoist loosens the connecting rope so that the steel pipe tilts to the side of the manual hoist, so that the manual hoist protrudes to avoid the occurrence of accidents between the circuit breaker and the steel pipe. Collision, to prevent damage to the circuit breaker. The manual hoist of the invention can facilitate operators to lift the circuit breaker without using electric power. The triangular boom bracket formed by the boom, the diagonal stay rod and the fixed rod of the present invention can improve the connection strength between the boom and the fixed rod, and avoid damage to the boom during hoisting of the circuit breaker. The rotating ring of the invention can facilitate the rotation of the manual hoist, so that the operator can control the manual hoist from different angles. The fluorescent material containing aza-15-crown-5 cyclic crown ether of the present invention uses aza-containing 15-crown-5 cyclic crown ether as a light-emitting substrate, and uses europium or terbium as an activator, and the absorption capacity of the synthesized fluorescent material is strong, high conversion rate, and the narrow-band emission of the central ion of the rare earth complex is conducive to full-color display, and the properties of the fluorescent material are stable; the preparation method of the present invention avoids the defect of low yield when synthesizing complex organic small molecules. Thermal synthesis, simple operation, easy to realize, high yield. The invention also has the advantages of simple and compact structure, low manufacturing cost and easy use.
附图说明Description of drawings
图1为本发明所述断路器的专用吊装工具的结构示意图;图2是图1的I局部放大结构示意图;图3是本发明所述断路器的专用吊装工具的结构示意图,图中装有卷扬机;图4是本发明所述断路器的专用吊装工具的结构示意图,图中的驱动三角形吊臂架转动的电机;图5是图4的II局部放大结构示意图;图6是图5的A向结构示意图;图7是所述吊装工具的使用状态图,图中显示所述吊装工具固定于西门子3AP1FG型断路器的开关底座上并用手动葫芦与单相开关连接准备起吊。Fig. 1 is the structural representation of the special hoisting tool of the circuit breaker of the present invention; Fig. 2 is the partial enlarged structural representation of I of Fig. 1; Fig. 3 is the structural representation of the special hoisting tool of the circuit breaker of the present invention, in which Hoist; Fig. 4 is a structural schematic diagram of a special hoisting tool for a circuit breaker according to the present invention, the motor driving the rotation of the triangular boom frame in the figure; Fig. 5 is a schematic diagram of a partial enlarged structure of II of Fig. 4; Fig. 6 is a schematic diagram of A of Fig. 5 Figure 7 is a diagram of the state of use of the hoisting tool, which shows that the hoisting tool is fixed on the switch base of the Siemens 3AP1FG circuit breaker and connected with a single-phase switch with a manual hoist to prepare for hoisting.
附图说明:1手动葫芦 2吊环 3旋转环 4斜拉杆 5吊臂 6固定杆 7钢管 8连接绳9底座 10卷扬机 12螺母 13螺栓 14夹板 15铰链座 16挡板 17加强筋 18底板 19限位块20横杆 21基座 22电机 23小齿轮 24管卡 25大齿轮 26定位槽 27开关底座 28机构箱 29支架 30单相开关。Description of drawings: 1 manual hoist 2 lifting ring 3 rotating ring 4 inclined rod 5 boom 6 fixed rod 7 steel pipe 8 connecting rope 9 base 10 hoist 12 nut 13 bolt 14 splint 15 hinge seat 16 baffle 17 reinforcement rib 18 bottom plate 19 limit Block 20 crossbar 21 base 22 motor 23 pinion 24 tube clip 25 large gear 26 positioning groove 27 switch base 28 mechanism box 29 bracket 30 single-phase switch.
具体实施方式detailed description
本发明所述的断路器的专用吊装工具,如图1所示,包括固定装置包括夹板(14)和(18),夹板(14)和(18)通过螺母(12)和螺栓(13)连接,(18)上竖向安装钢管(7),钢管(7)的上端内安装固定杆(6),固定杆(6)的上段位于钢管(7)外,固定杆(6)上设有(16),(16)与钢管(7)配合限位,固定杆(6)能相对钢管(7)转动,固定杆(6)的一侧水平安装吊臂(5),吊臂(5)的上安装斜拉杆(4),斜拉杆(4)的一端与固定杆(6)连接,斜拉杆(4)的另一端与吊臂(5)的一端连接,吊臂(5)、斜拉杆(4)和固定杆(6)构成三角形吊臂架,吊臂(5)的外端安装旋转环(3),旋转环(3)上安装吊环(2),吊环(2)上安装手动葫芦(1)。所述三角形吊臂架的外周设有荧光材料,以起到警示作用,防止非工作人员误入吊装范围,以提高吊装过程的安全性。The special hoisting tool for circuit breaker of the present invention, as shown in Figure 1, comprises fixing device and comprises splint (14) and (18), and splint (14) and (18) are connected by nut (12) and bolt (13) , Steel pipe (7) is vertically installed on (18), fixed rod (6) is installed in the upper end of steel pipe (7), and the upper section of fixed rod (6) is positioned at outside steel pipe (7), and fixed rod (6) is provided with ( 16), (16) cooperates with the steel pipe (7) to limit, the fixed rod (6) can rotate relative to the steel pipe (7), and the horizontal installation of the boom (5) on one side of the fixed rod (6), and the boom (5) Diagonal tie rod (4) is installed on the top, and one end of diagonal stay rod (4) is connected with fixed rod (6), and the other end of diagonal stay rod (4) is connected with an end of boom (5), and boom (5), diagonal stay rod ( 4) and fixed rod (6) constitute triangular boom frame, the outer end of boom (5) is equipped with swivel ring (3), and suspension ring (2) is installed on the rotation ring (3), and manual hoist (2) is installed on the suspension ring (2) 1). The outer periphery of the triangular jib frame is provided with fluorescent materials to serve as a warning to prevent non-workers from entering the hoisting range by mistake, so as to improve the safety of the hoisting process.
使用时,如图7所示,通过夹板(14)、(18)、螺母(12)和螺栓(13)将钢管(7)竖直固定于开关底座27上,利用手动葫芦(1)将单相开关(30)固定,并将其吊起,转动固定杆(6)可将吊起的开关水平移动至设定位置上方,并最终下落至设定位置。During use, as shown in Figure 7, the steel pipe (7) is vertically fixed on the switch base 27 by splints (14), (18), nuts (12) and bolts (13), and the single Phase switch (30) is fixed, and it is hoisted, and rotating fixed rod (6) can move the hoisted switch horizontally above the set position, and finally falls to the set position.
如图1所示,所述钢管(7)与(18)之间均匀设置数块(17),以增加所述吊装工具负荷能力。As shown in Figure 1, several blocks (17) are evenly arranged between the steel pipes (7) and (18) to increase the load capacity of the lifting tool.
如图3所示,所述(18)底部设有底座(9),底座9上安装固定装置和卷扬机10,固定杆6所在直线与钢管7所在直线共线。卷扬机10的连接绳8的一端与钢管7的上部连接。所述旋转环3可使吊环2相对吊臂5水平旋转,以增加吊装过程中的灵活性。(18)上设有铰链座(15),(18)通过铰链座(15)与钢管(7)铰接,铰链座(15)朝向卷扬机(10)的一侧设有(19),(19)与钢管(7)配合。As shown in Figure 3, described (18) bottom is provided with base (9), and fixing device and winch 10 are installed on the base 9, and the straight line where fixed rod 6 is located is collinear with the straight line where steel pipe 7 is located. One end of the connecting rope 8 of the winch 10 is connected to the top of the steel pipe 7 . The rotating ring 3 can make the hoisting ring 2 rotate horizontally relative to the boom 5, so as to increase the flexibility in the hoisting process. (18) is provided with hinge seat (15), (18) is hinged with steel pipe (7) by hinge seat (15), and hinge seat (15) is provided with (19), (19) toward the side of winch (10). Cooperate with steel pipe (7).
本发明的卷扬机10可以通过连接绳8带动钢管7绕固定装置旋转,当需要吊装断路器的单相开关时,卷扬机10放松连接绳8,使钢管7向手动葫芦1一侧倾斜,从而使手动葫芦1探出,避免断路器与钢管7之间发生碰撞,防止碰坏断路器的单相开关。本发明的手动葫芦1可以方便操作人员无需使用电力就可以将断路器提升。本发明的吊臂5、斜拉杆4和固定杆6构成三角形吊臂架可以提高吊臂5与固定杆6的连接强度,避免吊臂5在吊装断路器过程中出现损坏。本发明的旋转环3可以方便手动葫芦1旋转,使操作人员可以从不同角度控制手动葫芦1。The hoist 10 of the present invention can drive the steel pipe 7 to rotate around the fixing device through the connecting rope 8. When the single-phase switch of the circuit breaker needs to be hoisted, the hoist 10 loosens the connecting rope 8 to make the steel pipe 7 tilt to the side of the manual hoist 1, so that the manual The gourd 1 protrudes to avoid collision between the circuit breaker and the steel pipe 7, and prevent the single-phase switch of the circuit breaker from being damaged. The manual hoist 1 of the present invention can facilitate the operator to lift the circuit breaker without using electric power. The boom 5, the diagonal tie rod 4 and the fixed rod 6 of the present invention form a triangular boom frame, which can improve the connection strength between the boom 5 and the fixed rod 6, and avoid damage to the boom 5 during the hoisting of the circuit breaker. The rotating ring 3 of the present invention can facilitate the rotation of the manual hoist 1, so that the operator can control the manual hoist 1 from different angles.
所述吊臂5与固定杆6垂直。本发明吊臂5与固定杆6垂直,可以是吊臂5受到的力转换到沿吊臂5方向上,从而减小吊臂5所受垂直于吊臂5方向上的力。The boom 5 is perpendicular to the fixed rod 6 . The boom 5 of the present invention is perpendicular to the fixed rod 6, and the force received by the boom 5 can be converted to the direction along the boom 5, thereby reducing the force on the boom 5 perpendicular to the direction of the boom 5.
为方便在吊装过程全局掌控所述吊装工具及起吊的单相开关的位置,并进行远程操控三角形吊臂架的转动角度,如图5和图6所示,所述钢管(7)上设有(20),(20)上安装(22),(22)底部设有(21),(21)内开设(26),(26)与(20)配合,(22)的输出轴上安装(23),固定杆(6)上安装(25),(25)与(23)啮合,(22)的一侧设在(24),(24)与钢管(7)固定。(22)通过(21)和(24)与钢管(7)连接,可实现随时拆装,既便于更换(22),又便于根据不同吊装情况选装(22),可满足用户不同的使用需求。使用时,将现有的远程控制装置与(22)连接。In order to facilitate the global control of the hoisting tool and the hoisting single-phase switch position during the hoisting process, and to remotely control the rotation angle of the triangular boom bracket, as shown in Figures 5 and 6, the steel pipe (7) is provided with (20), install (22) on (20), (22) bottom is provided with (21), offers (26) in (21), (26) cooperates with (20), installs on the output shaft of (22) ( 23), (25) is installed on the fixed rod (6), and (25) engages with (23), and one side of (22) is located at (24), and (24) is fixed with steel pipe (7). (22) is connected to the steel pipe (7) through (21) and (24), which can be disassembled at any time, which is not only convenient for replacing (22), but also convenient for selecting (22) according to different hoisting conditions, which can meet the different needs of users . During use, existing remote control device is connected with (22).
本发明所述的一种含氮杂15-冠-5环状冠醚的荧光材料及其制备方法,通过以下技术方案实现:A fluorescent material containing aza-15-crown-5 cyclic crown ether according to the present invention and a preparation method thereof are realized through the following technical solutions:
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为ML,其中M为Eu或Tb,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, whose general formula is ML, wherein M is Eu or Tb, L is aza-containing 15-crown-5 cyclic crown ether, and its structural formula is:
,其中R为H,-NO2或-CHO。 , wherein R is H, -NO 2 or -CHO.
优选的含氮杂15-冠-5环状冠醚的荧光材料,M为Eu,R为-NO2。In the preferred fluorescent material containing aza-15-crown-5 cyclic crown ether, M is Eu, and R is -NO 2 .
本发明还包括含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The present invention also includes a method for preparing a fluorescent material containing aza-15-crown-5 cyclic crown ether, comprising the following steps:
将铕或铽的可溶性盐、L和有机溶剂加入溶剂热罐子中,加10~15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述铕或铽的可溶性盐、L和有机溶剂的添加比例为1~1.5mol:1mol:20~30ml;所述的有机溶剂为二甲苯、环己醇或DMF;所述铕或铽的可溶性盐为硝酸盐或氯化盐;所述L的结构式为 Add the soluble salt of europium or terbium, L and organic solvent into the solvent heating jar, add 10~15ml of distilled water to seal, then put the sealed solvent heating jar into the muffle furnace; the soluble salt of europium or terbium, L The addition ratio of the organic solvent is 1 ~ 1.5mol: 1mol: 20 ~ 30ml; the organic solvent is xylene, cyclohexanol or DMF; the soluble salt of europium or terbium is nitrate or chloride; The structural formula of L is
,其中R为H,-NO2,-CHO; , wherein R is H, -NO 2 , -CHO;
先将马弗炉的温度升至190~195℃恒温48~72小时,然后将马弗炉的温度降至50~55℃保温12~15小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 190~195°C for 48~72 hours, then lower the temperature of the muffle furnace to 50~55°C for 12~15 hours, turn off the power, and wait until the temperature of the muffle furnace drops to room temperature , the solvothermal jar was removed from the muffle furnace to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,铕或铽的可溶性盐、L和有机溶剂的添加比例为1.2mol:1mol:25ml。In the preferred preparation method of fluorescent material containing aza-15-crown-5 cyclic crown ether, the addition ratio of soluble salt of europium or terbium, L and organic solvent is 1.2mol:1mol:25ml.
优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,先将马弗炉的温度升至192℃恒温60小时,然后将马弗炉的温度降至52℃保温14小时。The preferred preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether, the temperature of the muffle furnace is raised to 192°C for 60 hours, and then the temperature of the muffle furnace is lowered to 52°C for 14 hours. .
进一步优选的含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:A further preferred method for preparing a fluorescent material containing aza-15-crown-5 cyclic crown ether comprises the following steps:
将硝酸铕、L和DMF加入溶剂热罐子中,加15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述硝酸铕、L和DMF的添加比例为1.2mol:1mol:25ml;所述L的结构式为 Add europium nitrate, L and DMF in the solvent heating jar, add 15ml of distilled water to seal, then put the sealed solvent heating jar into the muffle furnace; the addition ratio of the europium nitrate, L and DMF is 1.2mol: 1mol: 25ml; the structural formula of the L is
; ;
先将马弗炉的温度升至192℃恒温60小时,然后将马弗炉的温度降至52℃保温14小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 192°C and keep it constant for 60 hours, then lower the temperature of the muffle furnace to 52°C and keep it for 14 hours, turn off the power, wait for the temperature of the muffle furnace to drop to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
以下结合具体实施例来对本发明作进一步的描述。The present invention will be further described below in conjunction with specific embodiments.
实施例1Example 1
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为EuL,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, its general formula is EuL, L is aza-containing 15-crown-5 cyclic crown ether, the structural formula is:
。 .
实施例2Example 2
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为TbL,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, whose general formula is TbL, L is aza-containing 15-crown-5 cyclic crown ether, and its structural formula is:
。 .
实施例3Example 3
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为TbL,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, whose general formula is TbL, L is aza-containing 15-crown-5 cyclic crown ether, and its structural formula is:
。 .
实施例4Example 4
一种含氮杂15-冠-5环状冠醚的荧光材料,其通式为EuL,L为含杂氮15-冠-5环状冠醚,结构式为:A fluorescent material containing aza-15-crown-5 cyclic crown ether, its general formula is EuL, L is aza-containing 15-crown-5 cyclic crown ether, the structural formula is:
。 .
实施例5Example 5
实施例1所述含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether described in embodiment 1 comprises the following steps:
将1mol氯化铕、1molL和20ml二甲苯加入溶剂热罐子中,加10ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述L的结构式为 Add 1mol europium chloride, 1molL and 20ml xylene into the solvent heat jar, add 10ml distilled water to seal, then put the sealed solvent heat jar into the muffle furnace; the structural formula of L is
; ;
先将马弗炉的温度升至190℃恒温48小时,然后将马弗炉的温度降至50℃保温12小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 190°C and keep it constant for 48 hours, then lower the temperature of the muffle furnace to 50°C and keep it for 12 hours, turn off the power, wait for the temperature of the muffle furnace to drop to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
实施例6Example 6
实施例2所述含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether described in embodiment 2 comprises the following steps:
将1.5mol硝酸铽、1molL和30ml环己醇加入溶剂热罐子中,加15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述L的结构式为 Add 1.5mol terbium nitrate, 1molL and 30ml cyclohexanol into the solvent heat jar, add 15ml distilled water to seal, then put the sealed solvent heat jar into the muffle furnace; the structural formula of L is
; ;
先将马弗炉的温度升至195℃恒温72小时,然后将马弗炉的温度降至55℃保温15小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 195°C and keep it constant for 72 hours, then lower the temperature of the muffle furnace to 55°C and keep it for 15 hours, then turn off the power, wait until the temperature of the muffle furnace drops to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
实施例7Example 7
实施例3所述含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether described in embodiment 3 comprises the following steps:
将1.3mol氯化铽、1molL和22mlDMF加入溶剂热罐子中,加10~15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述L的结构式为 Add 1.3mol terbium chloride, 1molL and 22ml DMF into the solvent heat jar, add 10-15ml distilled water to seal, then put the sealed solvent heat jar into the muffle furnace; the structural formula of L is
; ;
先将马弗炉的温度升至191℃恒温62小时,然后将马弗炉的温度降至53℃保温13小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 191°C and keep it constant for 62 hours, then lower the temperature of the muffle furnace to 53°C and keep it for 13 hours, turn off the power, wait for the temperature of the muffle furnace to drop to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
实施例8Example 8
实施例4所述含氮杂15-冠-5环状冠醚的荧光材料的制备方法,包括以下步骤:The preparation method of the fluorescent material containing aza-15-crown-5 cyclic crown ether described in embodiment 4 comprises the following steps:
将硝酸铕、L和DMF加入溶剂热罐子中,加15ml蒸馏水密封,然后将密封好的溶剂热罐子放入马弗炉中;所述硝酸铕、L和DMF的添加比例为1.2mol:1mol:25ml;所述L的结构式为 Add europium nitrate, L and DMF in the solvent heating jar, add 15ml of distilled water to seal, then put the sealed solvent heating jar into the muffle furnace; the addition ratio of the europium nitrate, L and DMF is 1.2mol: 1mol: 25ml; the structural formula of the L is
; ;
先将马弗炉的温度升至192℃恒温60小时,然后将马弗炉的温度降至52℃保温14小时,关闭电源,待马弗炉的温度降至室温,从马弗炉中取出溶剂热罐子,得到含氮杂15-冠-5环状冠醚的荧光材料。 First raise the temperature of the muffle furnace to 192°C and keep it constant for 60 hours, then lower the temperature of the muffle furnace to 52°C and keep it for 14 hours, turn off the power, wait for the temperature of the muffle furnace to drop to room temperature, and take out the solvent from the muffle furnace Heat the jar to obtain a fluorescent material containing aza-15-crown-5 cyclic crown ether.
本发明的技术方案并不限制于本发明所述的实施例的范围内。本发明未详尽描述的技术内容均为公知技术。The technical solutions of the present invention are not limited within the scope of the embodiments described in the present invention. The technical contents not described in detail in the present invention are all known technologies.
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