CN106087546A - A kind of film coating and preparation method thereof - Google Patents
A kind of film coating and preparation method thereof Download PDFInfo
- Publication number
- CN106087546A CN106087546A CN201610462183.8A CN201610462183A CN106087546A CN 106087546 A CN106087546 A CN 106087546A CN 201610462183 A CN201610462183 A CN 201610462183A CN 106087546 A CN106087546 A CN 106087546A
- Authority
- CN
- China
- Prior art keywords
- film coating
- raw material
- preparation
- stilbene
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009501 film coating Methods 0.000 title claims abstract description 39
- 239000007888 film coating Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 23
- 229920001400 block copolymer Polymers 0.000 claims abstract description 23
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 23
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 alcohols fatty acid ester Chemical class 0.000 claims abstract description 22
- 239000013530 defoamer Substances 0.000 claims abstract description 22
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 22
- 229930195729 fatty acid Natural products 0.000 claims abstract description 22
- 239000000194 fatty acid Substances 0.000 claims abstract description 22
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims abstract description 21
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000021286 stilbenes Nutrition 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- 239000000376 reactant Substances 0.000 claims abstract description 4
- 239000002253 acid Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 230000003628 erosive effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000005282 brightening Methods 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 2
- 239000006081 fluorescent whitening agent Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/38—Corrosion-inhibiting agents or anti-oxidants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
The present invention relates to a kind of film coating and preparation method thereof, it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water 500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid ester compounded thing defoamer 0.2 ~ 1；The preparation method of described film coating, it comprises the following steps: the raw material of composition described above mixed, and is placed in closed reactor in 150～400 DEG C of melting reactions 0.5～2h, is taken out by reactant liquor and be cooled to room temperature, coat on base stock, i.e. can get described film coating.Film coating prepared by the method for photograph can make photomap as having height anti-corrosive properties and anti-ultraviolet erosion, for a long time Chang Xin, will never fade, do not turn yellow, more can increase strong third dimension, produce beyond thought effect.
Description
Technical field
The present invention relates to a kind of protective film, particularly to a kind of film coating and preparation method thereof.
Background technology
Along with improving constantly of people's living standard, people are more and more higher to the requirement of some advertisements, photograph, due to extensively
Accusing, particularly outdoor advertising is affected by the weather such as rainforest of exposing to the weather, and easily causes pollution or drenches so that the outdoor advertising longevity
Life is affected, and arise that after the article storage time length such as similar photograph fade, the phenomenon such as yellowing.In order to be able to make open air wide
It is longer to accuse the life-span, and photograph can have height anti-corrosive properties and anti-ultraviolet erosion, and for a long time Chang Xin is colour-fast, does not turns yellow, people
Starting with transparent protective film to cover on picture, the covering of current protective film mostly uses the mode that thermoplastic seals, and needs
Equipment is wanted to heat, operation inconvenience；But existing thin film light transmittance is low, covers and can obscure picture on picture.
Summary of the invention
It is an object of the invention to provide a kind of film coating and preparation method thereof, film coating prepared by the present invention for
Photograph can make photomap as having height anti-corrosive properties and anti-ultraviolet erosion, for a long time Chang Xin, will never fade, do not turn yellow, more can
Increase strong third dimension, produce beyond thought effect.
For achieving the above object, the technical solution used in the present invention is as follows:
The invention provides a kind of film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water
500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid
Ester complexes defoamer 0.2 ~ 1.
According to above-mentioned film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 100, pure water 550 ~
600, Stilbene-based Fluorescent Brighteners 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~ 1.5 and higher alcohols fatty acid ester
Complex defoamer 0.2 ~ 0.6.
According to above-mentioned film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, hexichol
Ethylene type fluorescent whitening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fatty acid ester compounded thing defoamer
0.5。
According to the preparation method of above-mentioned film coating, it comprises the following steps: is mixed by the raw material of composition described above, is placed in
Reactant liquor, in 150～400 DEG C of melting reactions 0.5～2h, is taken out and is cooled to room temperature, coat on base stock, i.e. by closed reactor
Available described film coating.
Compared with prior art, beneficial effects of the present invention:
Film coating adhesive force of the present invention is good, water-fast and light transmittance is high, and film coating prepared by the present invention can make phase for photograph
Sheet image has height anti-corrosive properties and anti-ultraviolet erosion, and for a long time Chang Xin is will never fade, do not turn yellow, more can increase strong
Third dimension, produces beyond thought effect.
Detailed description of the invention
By the following examples present disclosure is further described, but be not limited to these embodiments.
Raw material used in following example is commercially available.
Embodiment 1
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 100, pure water 550 ~ 600, hexichol second
Ene-type fluorescent whitening agent 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~ 1.5 and higher alcohols fatty acid ester compounded thing froth breaking
Agent 0.2 ~ 0.6.
The preparation method of described film coating, it comprises the following steps: is mixed by the raw material of composition described above, is placed in airtight
Reactant liquor, in 150～400 DEG C of melting reactions 0.5～2h, is taken out and is cooled to room temperature, coat on base stock by reactor,
To described film coating.
Embodiment 2
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, Stilbene-based fluorescence
Brightening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 3
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80, pure water 550, Stilbene-based fluorescence
Brightening agent 2.5, polyoxyethylene polyoxypropylene block copolymer 0.9 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 4
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 85, pure water 570, Stilbene-based fluorescence
Brightening agent 2.5, polyoxyethylene polyoxypropylene block copolymer 1.2 and higher alcohols fatty acid ester compounded thing defoamer 0.4.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 5
A kind of film coating, it is made up of following raw material: polyvinyl alcohol: 120, pure water 700, Stilbene-based are glimmering
Optical brightener 4, polyoxyethylene polyoxypropylene block copolymer 2 and higher alcohols fatty acid ester compounded thing defoamer 0.7.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 6
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 110, pure water 620, Stilbene-based are glimmering
Optical brightener 3.6, polyoxyethylene polyoxypropylene block copolymer 1.8 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 7
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 95, pure water 560, Stilbene-based fluorescence
Brightening agent 2.2, polyoxyethylene polyoxypropylene block copolymer 0.6 and higher alcohols fatty acid ester compounded thing defoamer 0.9.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 8
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 105, pure water 540, Stilbene-based are glimmering
Optical brightener 2.7, polyoxyethylene polyoxypropylene block copolymer 0.5 and higher alcohols fatty acid ester compounded thing defoamer 0.7.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 9
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 115, pure water 650, Stilbene-based are glimmering
Optical brightener 4.5, polyoxyethylene polyoxypropylene block copolymer 1.6 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 10
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 95, pure water 510, Stilbene-based fluorescence
Brightening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 11
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80, pure water 590, Stilbene-based fluorescence
Brightening agent 2.8, polyoxyethylene polyoxypropylene block copolymer 2.2 and higher alcohols fatty acid ester compounded thing defoamer 0.4.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 12
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 86, pure water 530, Stilbene-based fluorescence
Brightening agent 4.1, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 13
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 94, pure water 620, Stilbene-based fluorescence
Brightening agent 4.4, polyoxyethylene polyoxypropylene block copolymer 1.9 and higher alcohols fatty acid ester compounded thing defoamer 0.6.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 14
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 103, pure water 640, Stilbene-based are glimmering
Optical brightener 2.5, polyoxyethylene polyoxypropylene block copolymer 1.5 and higher alcohols fatty acid ester compounded thing defoamer 0.9.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 15
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, Stilbene-based fluorescence
Brightening agent 2.2, polyoxyethylene polyoxypropylene block copolymer 1.4 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 16
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 106, pure water 680, Stilbene-based are glimmering
Optical brightener 4.3, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Above-mentioned for the preferred embodiment of the present invention, in the present invention limited without departing from claims appended by the present invention
In scope, any the change in form and details present invention done, broadly fall into protection scope of the present invention.
Claims (4)
1. a film coating, it is characterised in that it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water
500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid
Ester complexes defoamer 0.2 ~ 1.
Film coating the most according to claim 1, it is characterised in that it is made up of following raw material: polyvinyl alcohol
80 ~ 100, pure water 550 ~ 600, Stilbene-based Fluorescent Brighteners 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~
1.5 and higher alcohols fatty acid ester compounded thing defoamer 0.2 ~ 0.6.
Film coating the most according to claim 1, it is characterised in that it is made up of following raw material: polyvinyl alcohol
90, pure water 600, Stilbene-based Fluorescent Brighteners 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fat
Acid esters complex defoamer 0.5.
The preparation method of film coating the most according to claim 1, it is characterised in that it comprises the following steps: by above group
The raw material mixing become, is placed in closed reactor in 150～400 DEG C of melting reactions 0.5～2h, is taken out by reactant liquor and be cooled to room
Temperature, coats on base stock, i.e. can get described film coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610462183.8A CN106087546A (en) | 2016-06-23 | 2016-06-23 | A kind of film coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610462183.8A CN106087546A (en) | 2016-06-23 | 2016-06-23 | A kind of film coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106087546A true CN106087546A (en) | 2016-11-09 |
Family
ID=57252195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610462183.8A Pending CN106087546A (en) | 2016-06-23 | 2016-06-23 | A kind of film coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106087546A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638139A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Compound oil-proofing agent for paper and preparation method of compound oil-proofing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1890312A (en) * | 2003-12-09 | 2007-01-03 | 塞拉尼斯国际公司 | Optical brightener and method of preparing it |
| CN101068982A (en) * | 2004-11-29 | 2007-11-07 | 集伟纸业化工股份有限公司 | Sheet of high whiteness degree |
| CN101155962A (en) * | 2005-04-08 | 2008-04-02 | 克莱里安特财务(Bvi)有限公司 | Aqueous solutions of optical brighteners |
| CN102729682A (en) * | 2012-07-16 | 2012-10-17 | 江苏泰特尔化工有限公司 | Anti-aging, highlight and waterproof ahead-spraying lamp-house piece |
-
2016
- 2016-06-23 CN CN201610462183.8A patent/CN106087546A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1890312A (en) * | 2003-12-09 | 2007-01-03 | 塞拉尼斯国际公司 | Optical brightener and method of preparing it |
| CN101068982A (en) * | 2004-11-29 | 2007-11-07 | 集伟纸业化工股份有限公司 | Sheet of high whiteness degree |
| CN101155962A (en) * | 2005-04-08 | 2008-04-02 | 克莱里安特财务(Bvi)有限公司 | Aqueous solutions of optical brighteners |
| CN102729682A (en) * | 2012-07-16 | 2012-10-17 | 江苏泰特尔化工有限公司 | Anti-aging, highlight and waterproof ahead-spraying lamp-house piece |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638139A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Compound oil-proofing agent for paper and preparation method of compound oil-proofing agent |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20161109 |